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My PhD thesis - Condensed Matter Theory - Imperial College London

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CHAPTER 8. APPLYING THE PLASMON NORMAL MODE THEORY TO<br />

SLAB SYSTEMS<br />

vacuum<br />

q<br />

z<br />

metal<br />

Figure 8.2: The surface charge density.<br />

To relate this to the previous calculation, note that v z = ˙q. It then follows that<br />

E (v)<br />

z<br />

− E (m)<br />

z<br />

= − n 0ev z<br />

iɛ 0 ω<br />

(8.25)<br />

= σ<br />

iɛ 0 ω E(m) z (8.26)<br />

= − ω2 p<br />

ω 2 E(m) z . (8.27)<br />

To summarise, the boundary conditions at an interface between metal and vacuum<br />

are:<br />

E (m)<br />

x<br />

E (m)<br />

y<br />

= E (v)<br />

x<br />

= E (v)<br />

y<br />

(8.28a)<br />

(8.28b)<br />

( )<br />

1 − ω2 p<br />

E (m)<br />

ω 2 z = E z (v) . (8.28c)<br />

Note that from now on, ω p is being used exclusively to refer to the plasma frequency<br />

of the metal.<br />

In the limit z → ±∞, all field components are required to tend to zero. This excludes<br />

both the non-physical (constant or increasing) and the radiative (oscillatory)<br />

solutions.<br />

8.1.4 Surface plasmons<br />

In order to maintain the relationship specified by equation (8.28) at the interfaces,<br />

k and ω must take the same values in the metal and the vacuum. One consequence<br />

125

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