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My PhD thesis - Condensed Matter Theory - Imperial College London

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CHAPTER 8. APPLYING THE PLASMON NORMAL MODE THEORY TO<br />

SLAB SYSTEMS<br />

This reproduces equation (7.62). In the slab and the vacuum, ω 2 p is constant; the<br />

equation of motion in each of these regions becomes<br />

∇ 2 ¨φ = −ω<br />

2<br />

p ∇ 2 φ. (8.75)<br />

Searching for a travelling-wave solution of the form<br />

φ(r, t) = φ z (z)e i(ωt−kx) (8.76)<br />

leads to the following equation for φ z :<br />

(<br />

ω 2 k 2 φ z<br />

)<br />

− d2 φ z<br />

= ω 2<br />

dz 2 p<br />

(<br />

)<br />

k 2 φ z − d2 φ z<br />

. (8.77)<br />

dz 2<br />

As noted above, the bulk plasmons (with ω = ω p ) are solutions of this equation.<br />

When ω ≠ ω p , the solutions must satisfy Laplace’s equation:<br />

d 2 φ z<br />

dz 2 − k2 φ z = 0. (8.78)<br />

In the case of the slab, the solutions take the simple form<br />

⎧<br />

Ae<br />

⎪⎨<br />

kz when z < 0<br />

φ z = Be kz + Ce −kz when 0 < z < s<br />

⎪⎩<br />

De −kz otherwise.<br />

(8.79)<br />

This ensures that φ → 0 as z → ±∞, as long as the trivial solution with k = 0 is<br />

excluded. The other boundary conditions (as derived in section 8.1.3) are:<br />

∂φ (m)<br />

( )<br />

∂x<br />

1 − ω2 p ∂φ<br />

(m)<br />

ω 2 ∂z<br />

= ∂φ(v)<br />

∂x<br />

(8.80)<br />

= ∂φ(v)<br />

∂z . (8.81)<br />

Applying these conditions to equation (8.79) leads to the dispersion relation<br />

√<br />

ω 1 ± e<br />

−ks<br />

=<br />

ω p 2<br />

(8.82)<br />

which is plotted in figure 8.5. The relationship between the amplitudes A, B, C,<br />

135

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