Heavy metal adsorption on iron oxide and iron oxide-coated silica ...

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Figure 8.5 Fourier transforms (magnitude and imaginary part) of Ni K-edge XASspectra of Ni-HFO sorption complexes (Fourier transformed and fitted over ranges: 2.4-9.3 A-1 and 0.84-3.80 A).116
Table 8.3 EXAFS Results of Ni/HFO Samples at Ni K-EdgeNR (A)0.2 (A2)C3 (A3) AE0 (eV) Residual4.41 ± 0.054.00 + 0.032.04 ± 0.023.02 ± 0.020.002 ± 0.0010.007 ± 0.001-0.0009 ± 0.0001 -9 .91 ± 0 .229.024.38 ± 0.130.67 ± 0.062.05 ± 0.022.93 ± 0.020.006 ± 0.0020.005 + 0.002-0.0045 ± 0.0003-5 '77 ± 0 .335.746.74 ± 0.212.83 + 0.212.05 ± 0.023.01 ± 0.020.009 ± 0.0010.012 ± 0.002-0.0023 ± 0.0001-7.45 ± 0.216.085.61 E 0.571.75 ± 0.662.05 + 0.023.05 ± 0.020.007 ± 0.0020.007 ± 0.005-0.0013 ± 0.0007 -7 .20 ± 0 .327.964.93 ± 0.611.79 + 0.222.04 ± 0.023.02 ± 0.020.004 ± 0.0020.006 ± 0.002-0.0015 ± 0.0003-7.72 ± 1.649.034.56 ± 0.162.77 ± 0.202.06 ±0.022.99 + 0.020.005 ± 0.0010.011 ± 0.001-0.0029 ± 0.0004 -5 .97 ± 0 . 318.414.80 ± 0.322.44 ± 0.132.05 ±0.022.95 ± 0.020.004 ± 0.0010.009 ± 0.001-0.0032 ± 0.0002 -7 .79 ± 0 .678.973.36 ± 0.702.75 ± 0.772.03 ±0.022.92 ± 0.040.001 ± 0.0020.011 ± 0.003-0.0041 ± 0.0009-5.97 ± 1.178.85Fourier transform was performed over range 2.4-9.3 k I, fitted over 0.84-3.8 A.N, coordination number; R, interatomic distance; o-2, Debye-Waller factor; AE 0, edge shift.
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Copyright Warning & RestrictionsThe
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ABSTRACTHEAVY METAL ADSORPTION ON I
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HEAVY METAL ADSORPTION ON IRON OXID
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APPROVAL PAGEHEAVY METAL ADSORPTION
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Fan, M.; Boonfueng, T.; Xu, Y.; Axe
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ACKNOWLEDGMENTI would like to expre
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TABLE OF CONTENTS(Continued)Chapter
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TABLE OF CONTENTS(Continued)Chapter
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LIST OF TABLES(Continued)TablePageB
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LIST OF FIGURES(Continued)FigurePag
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LIST OF FIGURES(Continued)FigurePag
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CHAPTER 1INTRODUCTIONHeavy<
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3and Sigg, 1992; Gunneriusson et al
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CHAPTER 2OXIDES AND THEIR EFFECT ON
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7et al. 1996; Green-Pedersen et al.
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9identify components, distribution,
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11oxides. Because extraction method
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13Table 2.2 Some Coating Work and C
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15increasing the sorbate concentrat
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17mole Cu g-1 goethite (-1-7% of th
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19Overall, macroscopic adso
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21hematite (up to 9.9 limo' Pb ril-
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23concentration in their system was
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25Surface complexation modeling (SC
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27Overall, surface complexation mod
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29Spectroscopic techniques, especia
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31• Understand the effect of comp
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33existing in almost all soils and
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CHAPTER 4EXPERIMENTAL METHODSIn thi
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37included coating temperature (T),
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39generated at 45 kV and 40 mA, sca
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41PZC include electrophoretic mobil
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43Lin-edge, from 8,133 to 8,884 eV
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CHAPTER 5CHARACTERIZATION OF IRON O
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47measured by potentiometric titrat
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Table 5.2 XRD Data of Alfa Aesar (A
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51Table 5.3 XRF Results for Alfa Ae
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Figure 5.4 Particle size distributi
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55Figure 5.5 ESEM micrograph for Al
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585.2.5 Surface Charge Distribution
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Figure 5.10 Potentiometric titratio
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CHAPTER 6SYNTHESIS AND CHARACTERIZA
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Figure 6.1 Comparison between Fecon
Page 88 and 89: Figure 6.2 XRD patterns for goethit
Page 90 and 91: 68iron oxide coatings at 60 °C, go
Page 92 and 93: 70substrate diameter of 0.2 mm, an
Page 94 and 95: 72goethite and silica results in on
Page 96 and 97: Figure 6.7 ESEM micrograph (9000x)
Page 98 and 99: 76Furthermore, because discrete goe
Page 100 and 101: 78Table 6.2 Surface Area and Porosi
Page 102 and 103: Figure 6.10 Surface charge distribu
Page 104 and 105: Figure 6.11 Ni adsorption</
Page 106 and 107: 84that for pure silica, and the goe
Page 108 and 109: Table 7.1 Sample Preparation Condit
Page 110 and 111: Figure 7.2 EXAFS spectra of Pb/HFO
Page 112 and 113: Figure 7.3 Fourier transform and fi
Page 114 and 115: Figure 7.4 Fourier transform and fi
Page 116 and 117: Table 7.3 EXAFS Results of Pb/HFO S
Page 118 and 119: 967.2 Fe XAS of Iron Oxides and Pb/
Page 120 and 121: Figure 7.7 EXAFS spectra of iron ox
Page 122 and 123: 100and Venturelli, 1999). Overall t
Page 124 and 125: 102(hematite, goethite, akaganeite,
Page 126 and 127: 104adsorption proc
Page 128 and 129: 106of pH, ionic strength, Pb loadin
Page 130 and 131: Figure 8.1 Ni adsorption</s
Page 132 and 133: 110high metal load
Page 134 and 135: Figure 8.3 x(k)•k3 spectra and Fo
Page 136 and 137: Figure 8.4 (k)•k3 spectra of Ni-H
Page 140 and 141: 118be fit using either Fe or Ni ato
Page 142 and 143: 1208.3 EXAFS Analysis of FeThe x(k)
Page 144 and 145: Table 8.4 EXAFS Results of HFO and
Page 146 and 147: CHAPTER 9SURFACE COMPLEXATION MODEL
Page 148 and 149: Figure 9.1 Potentiometric titration
Page 150 and 151: 128Table 9.1 Surface Reactions and
Page 154 and 155: 132Table 9.2 Model Parameters for N
Page 158 and 159: 1369.3 Zn Adsorption on GoethiteReg
Page 160 and 161: Figure 9.6 Zn adsorption</s
Page 162 and 163: 140data over a broad range of condi
Page 164 and 165: 142Figure 9.8 Ni adsorption
Page 166 and 167: 144oxide-coated silica. Ni and Zn s
Page 170 and 171: Figure 10.2 Zn adsorption</
Page 174 and 175: 152one for GACS (2.77x10 -6 mole si
Page 176 and 177: Figure 10.6 Zn adsorption</
Page 178 and 179: CHAPTER 11CONCLUSIONS AND FUTURE WO
Page 180 and 181: 158surfaces are needed for successf
Page 182 and 183: Figure A.2 Ni speciation in 1x10 -5
Page 184 and 185: Figure A.4 Pb speciation in 5x10 -8
Page 186 and 187: Figure A.6 Zn speciation in 1x10 -5
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166Table B.2 Potentiometric Titrati
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168Table BA Potentiometric Titratio
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170Table C.3 Zn Adsorption Edges on
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APPENDIX DADSORPTION STUDIES ON SIL
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174Table D.5 Zn Adsorption Isotherm
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176Table E.3 Pb CBC Study on 0.3 g
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APPENDIX GINTRAPARTICLE DIFFUSION M
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180DofA = flier ^ 2fA = Exp(-fD * f
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REFERENCES1. Adamson A. W. (1982) P
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18426. Blake R. L., Hessevick R. E.
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18650. Combes J. M., Manceau A. and
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18876. Elzinga E. J. and Sparks D.
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190102. Gupta V. K. (1998) Equilibr
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192126. Joshi A. and Chaudhuri M. (
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194150. Liu C. and Huang P. M. (200
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196175. Muller B. and Sigg L. (1992
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200. Perry R. H. and Green D. W. (1
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200226. Scheinost A. C., Kretzschma
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202252. Swallow C. K., Hume D. N. a
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204278. Villalobos M., Trotz M. A.
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304. Zhong Z. Y., Prozorov T., Feln
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