Organic Chemistry Structures of Organic Compounds
Organic Chemistry Structures of Organic Compounds
Organic Chemistry Structures of Organic Compounds
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cyclopentanolElimination15 Alcohols + Oxidizing AgentsOne can use inorganic salts to oxidize (remove H’s or introduce oxygen) onto organic molecules.eg. C r O 3 or K 2 Cr 2 O 7 /H 2 SO 4Chromium IV or Na 3 Cr 2 O 7 /H 2 SO 4or≡ H 2 CrO 4Chromic acidKMnO 4 (Mn VII )OOr “<strong>Organic</strong> Chromium Salts, like pyridine chlorochromate (PCC)N +HClCrOO1 o Alcohol C - CH 2 OH(a) with PCCOHH+ PCCHCH 2Cl 2Oremoves this H Ethanol (acetaldehyde)(b) with K 2 Cr 2 O 7 /H+ or KMnO 4HHOHH KMnO OH4+ KMnO 4OO2 o Alcohol + Any oxidantOHH2-propanol+ Na 2CrO 7H 2SO 4O2-propanone
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