Organic Chemistry Structures of Organic Compounds

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ExamplesOrganometallic + Ketone (8)aldehyde → secondary alcoholketone → alcoholPhδ+ δ-Mgδ+Oδ-BrMgBrOetherPhH 3O +OMgBrPhOH16 Reduction with NaBH 4PhNaBH 4PhOCH 3OHOH17 Reduction with H 2 and a Pt catalystNOTE: This is exactly the same as addition of H 2 to an alkenePhPhH 2OPt-catalystEtOH solventOH18 Reaction with N-CompoundsHNe.g., hydrazine H 2 NNH 2 ; 2,4-dinitrophenylhydrazine O 2 N NO 2NH 2; hydroxylamine H 2 NOH
ON+H 2NNH 2 NH2 +H 2Oin EtOHO+H 2NNH 2O+ NH 2NH 2O+ NH 2NH 2OHNH NH 2H + NNNH2NH 2+ H 2O19 Oxidation - AldehydesOccurs very easily, while can use strong oxidants such as K 2 Cr 2 O 7 /H+ or KMnO 4Can also use weak oxidizing agents eg. AgOOH+ KMnO 4OH+ MnO 2Another more relevant oxidant – how to make a mirrorHOHOOHOHOHOHOHOOHHOHOHOAg +HOHOOHHOOHO+ AgHOmirrorNOTE: Ketones + oxidantsNo reaction at normal tempsCarboxylic AcidsStructures: Pure glacial acetic acidMethanoic acid (formic acid)
Page 1 and 2: Organic ChemistryYou will need to b
Page 3 and 4: C=C, CH,AromaticC=O, C-O, C-C, CHCa
Page 5 and 6: These combine to give a π-bondHHCC
Page 7 and 8: Your eyeH HHHH HH HHHHHWhen there a
Page 9 and 10: longest chain = 4= butane2) if same
Page 11 and 12: Therefore C=C is more reactive than
Page 13 and 14: 1. Molecular FormulaC 4 H 8 C 3 H 8
Page 15 and 16: hard to start reactions. Reactions
Page 19 and 20: 793(C 5 H 10 )4.1 AAlkyl Halides ?
Page 21 and 22: Called S N 2 “substitution nucleo
Page 23 and 24: Cl+ Ag + ClAg C + ClpptAgNuNuThis i
Page 25 and 26: H 3 C δ + -Iδ -+ Mg → H 3 C δ-
Page 27 and 28: These are extremely reactive almost
Page 29 and 30: HXHC +XHXX = OH, need H + as cataly
Page 31 and 32: Alcohols PreparationS N 2 of alkyl
Page 33 and 34: Reactions of AlcoholsPreparation of
Page 35: 3 o Alcoholno reaction at normal te
Page 39 and 40: (Phenyl acetic acid)1 o Alcohol + A

Organic Chemistry Structures of Organic Compounds

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