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Edited by Gerald Ondrey August 2011<br />

Three-mechanism grinding mill achieves finer, more uniform particles<br />

newly introduced cryogenic grinding<br />

A mill from Air Products and Chemicals<br />

Inc. (Allentown, Pa.; www.airproducts.com/<br />

ultrafine) can generate consistent yields of<br />

particles between 45 and 250 µm, and in<br />

some applications can achieve particle sizes<br />

of 10 µm. The ultrafine grinding mill also<br />

achieves narrower particle size distributions<br />

than conventional impact mills.<br />

Known as <strong>the</strong> PolarFit ultrafine-grinding<br />

mill (diagram), <strong>the</strong> cryogenic grinder<br />

employs a combination of size-reduction<br />

strategies — impact, particle attrition and<br />

particle-particle collisions — in one machine<br />

to reach finer particle sizes and raise yields<br />

within a particular size range. “We set out<br />

to design a highly flexible machine,” says<br />

technology manager Jon Trembley, “and one<br />

that both lowers energy input and makes<br />

efficient use of liquid nitrogen” (to remove<br />

heat generated by <strong>the</strong> grinding process).<br />

The PolarFit mill has an easily adjustable<br />

grinding gap, and is intended for low-maintenance<br />

operation.<br />

Before being launched at last month’s PTX<br />

Canada tradeshow in Toronto, <strong>the</strong> PolarFit<br />

mill had undergone an internal analysis<br />

A promising new forward-osmosis membrane<br />

Forward osmosis (FO) has been recognized<br />

as a valuable technology for many applications<br />

including wastewater reclamation,<br />

seawater desalination, and energy production,<br />

due to <strong>the</strong> low energy input required.<br />

The osmotic pressure gradient across a<br />

semipermeable FO membrane causes water<br />

to diffuse naturally through <strong>the</strong> membrane,<br />

leaving impurities behind. However, when<br />

water diffuses through <strong>the</strong> selective layer<br />

of <strong>the</strong> FO membrane, <strong>the</strong> draw solution<br />

at <strong>the</strong> permeate side is substantially diluted,<br />

while <strong>the</strong> back diffusion of draw solutes<br />

through <strong>the</strong> support layer works to<br />

compensate <strong>the</strong> diluted draw solutes. The<br />

compensation process is severely hindered<br />

by <strong>the</strong> tortuous, dense and thick support<br />

layers of conventional FO membranes. As<br />

a result, <strong>the</strong> competing process between<br />

dilution and back diffusion equilibrates<br />

at a transverse draw-solute concentration<br />

profile, leading to an internal concentration<br />

polarization (ICP) problem.<br />

To overcome this problem, researchers<br />

Note: For more information, circle <strong>the</strong> 3-digit number<br />

on p. 54, or use <strong>the</strong> website designation.<br />

Granulated<br />

feed<br />

Cooling conveyor<br />

Control console<br />

program, processing 2–3 tons of material at<br />

a time while being compared to competing<br />

products. The product performed well for<br />

various cryogenic size-reduction applications,<br />

including plastics, pigments, powder<br />

coatings, <strong>the</strong>rmoplastic elastomers, spices<br />

and o<strong>the</strong>r food products. The PolarFit mill is<br />

available with grinding rotors in three standard<br />

sizes — 200, 400 and 800 mm, as well<br />

as in custom-made sizes.<br />

from <strong>the</strong> School of Civil and Environmental<br />

Engineering, Nanyang Technological University<br />

(Singapore; www.ntu.edu.sg) fabricated<br />

a novel nanocomposite FO membrane<br />

with a scaffold-like nanofiber layer that, <strong>the</strong><br />

researchers claim, possesses remarkable advantages<br />

over conventional sponge-like support<br />

layers, such as low “tortuosity”, high porosity<br />

and extreme thinness. This structure<br />

guarantees direct paths for salt and water<br />

diffusion, which could also eliminate <strong>the</strong><br />

ICP bottleneck, <strong>the</strong> researchers say.<br />

An electrospinning technique is used to<br />

fabricate <strong>the</strong> membrane. A rotating drum<br />

is employed to fabricate a large-area polye<strong>the</strong>rsulfone<br />

nanofiber support on a nonwoven<br />

fabric, where <strong>the</strong> diameters of <strong>the</strong><br />

nanofibers are in <strong>the</strong> range 50 to 150 nm.<br />

The thickness of <strong>the</strong> support layer can be<br />

adjusted by controlling <strong>the</strong> electrospinning<br />

time. The water permeability of <strong>the</strong> new<br />

nanocomposite membrane was observed<br />

to be about 3.5 times higher than that of a<br />

commercial FO membrane.<br />

Grinding<br />

mill<br />

Powdered product<br />

Liquid<br />

nitrogen<br />

tank<br />

Graphene from dry ice<br />

Researchers at Nor<strong>the</strong>rn Illinois<br />

University (NIU; DeKalb,<br />

Ill.; www.niu.edu) discovered a<br />

new method for producing graphene<br />

that involves burning<br />

pure magnesium metal in dry<br />

ice. The method, which is capable<br />

of producing large quantities<br />

of graphene in sheets<br />

less than ten atoms thick, is<br />

simpler than conventional<br />

methods for generating graphene,<br />

and avoids hazardous<br />

chemicals. The NIU scientists<br />

knew that burning Mg metal<br />

in carbon dioxide produced<br />

carbon, but <strong>the</strong> structure of<br />

<strong>the</strong> resulting carbon had not<br />

been studied carefully before,<br />

says NIU researcher Amartya<br />

Chakrabarti. Graphene, twodimensional<br />

carbon arranged<br />

in hexagonal lattice, has<br />

been <strong>the</strong> focus of extensive<br />

research because of its electrical<br />

and mechanical properties.<br />

A new <strong>the</strong>rmophile<br />

Scientists from <strong>the</strong> University<br />

of Calif., Berkeley (UCB; www.<br />

berkeley.edu) and <strong>the</strong> University<br />

of Maryland School of<br />

Medicine have discovered a<br />

microbe in a Nevada hot spring<br />

that metabolizes cellulose at<br />

a record-high temperature of<br />

109°C. The hyper<strong>the</strong>rmophil-<br />

(Continues on p. 10)<br />

CHEMICAL ENGINEERING WWW.CHE.COM AUGUST 2011 9

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