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This new membrane bioreactor cuts<br />

energy costs and boosts throughput<br />

GE Power & Water (Trevose, Penn.; ge.com) has introduced<br />

an improved membrane bioreactor (mbr) technology<br />

whose productivity is said to be 15% higher than that of<br />

its predecessor for wastewater treatment plants. The new<br />

system, called LEAPmbr, was derived from innovations to<br />

GE’s ZeeWeed 500 mbr.<br />

Glenn Vicevic, senior manager, Engineered Systems, says<br />

<strong>the</strong> system has been tested on a commercial scale at three<br />

of its customers’ plants and has demonstrated several improvements<br />

in addition to higher productivity. These include<br />

a 30% reduction in membrane energy costs, a 50%<br />

reduction in membrane aeration equipment and controls,<br />

and a 20% smaller footprint.<br />

The system consists of rectangular cassettes of PVDF<br />

hollow-fiber membranes, immersed in a bioreactor in which<br />

bacteria break down pollutants. A pump draws treated<br />

water through <strong>the</strong> membranes, while solids, bacteria and<br />

colloidal material are retained in <strong>the</strong> tank.<br />

An improved aeration method for cleaning <strong>the</strong> membranes<br />

was <strong>the</strong> key element in lowering energy costs, says<br />

Vicevic. “The conventional wisdom is that <strong>the</strong>re should be a<br />

continuous air scour of <strong>the</strong> membranes,” he says, “but over<br />

<strong>the</strong> last decade, we experimented with bubble-size-diffuser<br />

design and frequency of air release. From that we determined<br />

that large bubbles delivered intermittently was <strong>the</strong><br />

most effective.” He adds that <strong>the</strong> improved productivity<br />

was obtained by optimizing <strong>the</strong> manufacturing techniques,<br />

while <strong>the</strong> smaller footprint was achieved by increasing <strong>the</strong><br />

surface area of <strong>the</strong> membrane.<br />

Silicon passes a test in water-splitting<br />

T he<br />

use of solar energy to split water into hydrogen and<br />

oxygen is an appealing idea, given that sunlight is abundant<br />

in many parts of <strong>the</strong> world, but one of <strong>the</strong> challenges<br />

to its development is to find a suitable electrode material.<br />

Silicon, <strong>the</strong> popular photovoltaic material, seems like a<br />

logical choice, but when it is exposed to O2 it is rapidly oxidized<br />

and fails. Researchers at Stanford University (Stanford,<br />

Calif.; www.stanford.edu) may have a solution.<br />

Using atomic layer deposition, a common process in<br />

semiconductor manufacturing, <strong>the</strong>y have deposited a 2-nm<br />

protective coating of titanium dioxide on silicon electrodes,<br />

followed by a similar, evaporated layer of iridium. TiO2 is<br />

transparent to sunlight and <strong>the</strong> iridium boosts <strong>the</strong> rate of<br />

<strong>the</strong> splitting reaction, says Paul McIntyre, of Stanford’s<br />

Materials Science and Engineering Dept. In laboratory<br />

tests <strong>the</strong> coated electrodes have shown stable operation for<br />

more than 24 h, without apparent corrosion or loss of efficiency,<br />

he says, while uncoated electrodes corroded and<br />

failed in less than 30 min.<br />

Next, <strong>the</strong> researchers plan to scale up <strong>the</strong> process and<br />

test o<strong>the</strong>r semiconductor materials. The ultimate goal, says<br />

McIntyre, is <strong>the</strong> development of a commercial process in<br />

which H2 and O2 would be stored and used to generate<br />

electricity when <strong>the</strong> sun doesn’t shine. ■<br />

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Circle 24 on p. 54 or go to adlinks.che.com/35068-24

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