Emergency Response Guidebook - Gujarat State Disaster ...

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TABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASESTABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASESMaterials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)When Spilled in WaterID Guide TIH Gas(es)No. No. Name of Material Produced1716 156 Acetyl bromide HBr1717 155 Acetyl chloride HCl1724 155 Allyltrichlorosilane, stabilized HCl1725 137 Aluminum bromide, anhydrous HBr1726 137 Aluminum chloride, anhydrous HCl1728 155 Amyltrichlorosilane HCl1732 157 Antimony pentafluoride HF1741 125 Boron trichloride HCl1745 144 Bromine pentafluoride HF Br 21746 144 Bromine trifluoride HF Br 21747 155 Butyltrichlorosilane HCl1752 156 Chloroacetyl chloride HCl1753 156 Chlorophenyltrichlorosilane HCl1754 137 Chlorosulfonic acid HCl1754 137 Chlorosulfonic acid and Sulfur trioxide mixture HCl1754 137 Chlorosulphonic acid HCl1754 137 Chlorosulphonic acid and Sulphur trioxide mixture HCl1754 137 Sulfur trioxide and Chlorosulfonic acid HCl1754 137 Sulphur trioxide and Chlorosulphonic acid HCl1758 137 Chromium oxychloride HCl1762 156 Cyclohexenyltrichlorosilane HCl1763 156 Cyclohexyltrichlorosilane HCl1765 156 Dichloroacetyl chloride HClMaterials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)When Spilled in WaterID Guide TIH Gas(es)No. No. Name of Material Produced1766 156 Dichlorophenyltrichlorosilane HCl1767 155 Diethyldichlorosilane HCl1769 156 Diphenyldichlorosilane Hcl1771 156 Dodecyltrichlorosilane HCl1777 137 Fluorosulfonic acid HF1777 137 Fluorosulphonic acid HF1781 156 Hexadecyltrichlorosilane HCl1784 156 Hexyltrichlorosilane HCl1799 156 Nonyltrichlorosilane HCl1800 156 Octadecyltrichlorosilane HCl1801 156 Octyltrichlorosilane HCl1804 156 Phenyltrichlorosilane HCl1806 137 Phosphorus pentachloride HCl1808 137 Phosphorus tribromide HBr1809 137 Phosphorus trichloride HCl1810 137 Phosphorus oxychloride HCl1815 132 Propionyl chloride HCl1816 155 Propyltrichlorosilane HCl1818 157 Silicon tetrachloride HCl1828 137 Sulfur chlorides HCl SO 2 H2S1828 137 Sulphur chlorides HCl SO2H2S1834 137 Sulfuryl chloride HCl1834 137 Sulphuryl chloride HClChemical Symbols for TIH Gases:Br 2 Bromine HF Hydrogen fluoride NO 2 Nitrogen dioxideCl 2 Chlorine HI Hydrogen iodide PH 3 PhosphineHbr Hydrogen bromide H2S Hydrogen sulfide SO 2 Sulfur dioxideHcl Hydrogen chloride H2S Hydrogen sulphide So2Sulphur dioxideHCN Hydrogen cyanide NH3AmmoniaChemical Symbols for TIH Gases:Br 2 Bromine HF Hydrogen fluoride NO 2 Nitrogen dioxideCl 2 Chlorine HI Hydrogen iodide PH 3 PhosphineHbr Hydrogen bromide H2S Hydrogen sulfide SO 2 Sulfur dioxideHcl Hydrogen chloride H2S Hydrogen sulphide So2Sulphur dioxideHCN Hydrogen cyanide NH3AmmoniaPage 348Use this list only when material is spilled in water.Use this list only when material is spilled in water.Page 349
TABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASESTABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASESMaterials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)When Spilled in WaterID Guide TIH Gas(es)No. No. Name of Material Produced1836 137 Thionyl chloride HCl SO 21838 137 Titanium tetrachloride HCl1898 156 Acetyl iodide HI1923 135 Calcium dithionite H2S SO21923 135 Calcium hydrosulfite H2S SO21923 135 Calcium hydrosulphite H2S SO21929 135 Potassium dithionite H2S SO21929 135 Potassium hydrosulfite H2S SO21929 135 Potassium hydrosulphite H2S SO21931 171 Zinc dithionite H2S SO21931 171 Zinc hydrosulfite H2S SO21931 171 Zinc hydrosulphite H2S SO22004 135 Magnesium diamide NH 32011 139 Magnesium phosphide PH 32012 139 Potassium phosphide PH 32013 139 Strontium phosphide PH 32308 157 Nitrosylsulfuric acid NO 22308 157 Nitrosylsulfuric acid, liquid NO 22308 157 Nitrosylsulfuric acid, solid NO 22308 157 Nitrosylsulphuric acid NO 22308 157 Nitrosylsulphuric acid, liquid NO 22308 157 Nitrosylsulphuric acid, solid NO 22353 132 Butyryl chloride HClChemical Symbols for TIH Gases:Br 2 Bromine HF Hydrogen fluoride NO 2 Nitrogen dioxideCl 2 Chlorine HI Hydrogen iodide PH 3 PhosphineHbr Hydrogen bromide H2S Hydrogen sulfide SO 2 Sulfur dioxideHcl Hydrogen chloride H2S Hydrogen sulphide So2Sulphur dioxideHCN Hydrogen cyanide NH3AmmoniaMaterials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)When Spilled in WaterID Guide TIH Gas(es)No. No. Name of Material Produced2395 132 Isobutyryl chloride HCl2434 156 Dibenzyldichlorosilane Hcl2435 156 Ethylphenyldichlorosilane HCl2437 156 Methylphenyldichlorosilane HCI2495 144 Iodine pentafluoride HF2691 137 Phosphorus pentabromide HBr2692 157 Boron tribromide HBr2806 138 Lithium nitride NH 32977 166 Radioactive material, Uranium hexafluoride, fissile HF2977 166 Uranium hexafluoride, fissile containing more than 1%Uranium-235HF2978 166 Radioactive material, Uranium hexafluoride HF2978 166 Uranium hexafluoride HF2978 166 Uranium hexafluoride, non fissile or fissile-excepted HF2985 155 Chlorosilanes, flammable, corrosive, n.o.s HCl2985 155 Chlorosilanes, n.o.s HCl2986 155 Chlorosilanes, corrosive, flammable, n.o.s HCl2986 155 Chlorosilanes, n.o.s HCl2987 156 Chlorosilanes, corrosive, n.o.s HCl2987 156 Chlorosilanes, n.o.s HCl2988 139 Chlorosilanes, n.o.s HCl2988 139 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. HCl3048 157 Aluminum phosphide pesticide PH 3Chemical Symbols for TIH Gases:Br 2 Bromine HF Hydrogen fluoride NO 2 Nitrogen dioxideCl 2 Chlorine HI Hydrogen iodide PH 3 PhosphineHbr Hydrogen bromide H2S Hydrogen sulfide SO 2 Sulfur dioxideHcl Hydrogen chloride H2S Hydrogen sulphide So2Sulphur dioxideHCN Hydrogen cyanide NH3AmmoniaPage 350Use this list only when material is spilled in water.Use this list only when material is spilled in water.Page 351
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SHIPPING DOCUMENTS (PAPERS)Shipping
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HAZARD CLASSIFICATION SYSTEMThe haz
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EMERGENCY INFORMATION PANEL800In In
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HAZARD IDENTIFICATION NUMBERSDISPLA
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PIPELINE TRANSPORTATIONIn Gujarat,
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• If flames present, driving away
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ID Guid Name of Material ID Guid Na
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Name of Material Guid ID Name of Ma
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GUIDE INDEXGuide No. Type of Substa
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GUIDE112Explosives* - Division 1.1,
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GUIDE114Explosives* - Division 1.4
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GUIDE116Gases - Flammable (Unstable
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GUIDE118Gases - Flammable - Corrosi
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GUIDE120Gases - Inert(Including Ref
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GUIDE122Gases - Oxidizing(Including
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GUIDE124Gases - Toxic and/or Corros
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GUIDE126Gases - Compressed or Lique
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GUIDE128Flammable Liquids(Non-Polar
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GUIDE130Flammable Liquids(Non-Polar
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GUIDE132Flammable Liquids - Corrosi
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GUIDE134Flammable Solids - Toxic an
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GUIDE136Substances - Spontaneously
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GUIDE138Substances - Water - Reacti
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GUIDE140OxidizersERG2012ERG2012Oxid
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GUIDE142Oxidizers - Toxic (Liquid)E
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GUIDE144Oxidizers (Water-Reactive)E
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GUIDE146Organic Peroxides (Heat, Co
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GUIDE148Organic Peroxides (Heat and
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GUIDE150Substances (Self-Reactive/T
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GUIDE152Substances - Toxic (Combust
Page 126 and 127: GUIDE154Substances - Toxic and/or C
Page 128 and 129: GUIDE156Substances - Toxic and/or C
Page 130 and 131: GUIDE158Infectious SubstancesERG201
Page 132 and 133: GUIDE160Halogenated SolventsERG2012
Page 134 and 135: GUIDE162Radioactive Materials(Low t
Page 136 and 137: GUIDE164Radioactive Materials (Spec
Page 138 and 139: GUIDE166Radioactive Materials - Cor
Page 140 and 141: GUIDE168Carbon Monoxide (Refrigerat
Page 142 and 143: GUIDE170Metals (Powders, Dusts, Sha
Page 144 and 145: GUIDE172Gallium and MercuryERG2012E
Page 146 and 147: Materials which react with water to
Page 148 and 149: HOW TO USE TABLE 1 - INITIAL ISOLAT
Page 150 and 151: TABLE 1 - INITIAL ISOLATION AND PRO
Page 178 and 179: TABLE 2 - WATER-REACTIVE MATERIALS
Page 180 and 181: UN1005 Ammonia, anhydrous: Large Sp
Page 182 and 183: 4-Green-bordered pages: This sectio
Page 184 and 185: Protective Suits (NFPA 1992 & 1993)
Page 186 and 187: BLEVE - SAFETY PRECAUTIONSUse with
Page 188 and 189: INDICATORS OF A POSSIBLE RADIOLOGIC
Page 190 and 191: GlossaryGlossaryAEGL(s)AEGL-1AEGL-2
Page 192 and 193: Flash pointGlossaryLowest temperatu
Page 194 and 195: ViscosityWarm zoneWater-sensitiveWa
Page 196: Emergency Response Telephone Number
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