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Stresses in Cu Thin Films and Ag/Ni Multilayers - Harvard School of ...

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Chapter 1: Background 5<br />

<strong>and</strong> the Hookean stresses are def<strong>in</strong>ed by<br />

dw = σij dɛij. (1.5)<br />

For the small stra<strong>in</strong> assumption, the dist<strong>in</strong>ction between the undeformed <strong>and</strong> deformed state<br />

is unnecessary.<br />

Mak<strong>in</strong>g the small stra<strong>in</strong> approximation is tantamount to choos<strong>in</strong>g a harmonic potential<br />

(the dashed curve <strong>in</strong> Figure 1.1 (a)). The stress then varies l<strong>in</strong>early with stra<strong>in</strong>, as shown<br />

<strong>in</strong> Figure 1.1 (b), <strong>and</strong> we may write<br />

σij = cijklɛkl (1.6a)<br />

or ɛij = sijklσkl (1.6b)<br />

depend<strong>in</strong>g on which is the <strong>in</strong>dependent variable. For the one-dimensional model depicted<br />

<strong>in</strong> Figure 1.1, c1111 is <strong>in</strong>dependent <strong>of</strong> stra<strong>in</strong> (Figure 1.1 (c)).<br />

In addition to writ<strong>in</strong>g the stress <strong>in</strong> terms <strong>of</strong> stra<strong>in</strong>, I can also write stress <strong>in</strong> terms <strong>of</strong> its<br />

def<strong>in</strong>ition <strong>of</strong> force per unit area:<br />

σij = Fi<br />

A j<br />

where the area vector po<strong>in</strong>ts along the plane normal.<br />

(1.7)<br />

A material’s measured elastic constants may differ substantially from those calculated<br />

from the curvature <strong>of</strong> the potential well. This may result from either po<strong>in</strong>t, l<strong>in</strong>e, areal, or<br />

volume defects <strong>in</strong> the material. If the properties are time-dependent <strong>and</strong> reversible, they are<br />

anelastic. The reversible motion <strong>of</strong> defects can cause an abnormally large stra<strong>in</strong>, thereby<br />

reduc<strong>in</strong>g the measured elastic constant. This phenomenon may or may not be measurable<br />

depend<strong>in</strong>g on the time scale <strong>of</strong> the experiment s<strong>in</strong>ce the defect k<strong>in</strong>etics have characteristic<br />

time constants.

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