Issue 05/2019
Highlights: Fibres/Textiles/Nonwovens Barrier Materials Cover Story: Lightweighting PBAT
Highlights:
Fibres/Textiles/Nonwovens
Barrier Materials
Cover Story:
Lightweighting PBAT
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Sep / Oct<br />
<strong>05</strong> | <strong>2019</strong><br />
bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />
Preview:<br />
Highlights<br />
Fibers / Textiles / Nonwovens | 16<br />
Barrier Materials | 42<br />
Cover Story<br />
Lightweighting PBAT<br />
based materials<br />
Jinhui Zhaolong<br />
... is read in 92 countries
Visit us in<br />
hall 6 at stand E 48<br />
16.–23.10.<strong>2019</strong><br />
Düsseldorf<br />
FEEL GOOD WITH<br />
REUSABLE COFFEE CUPS<br />
Visit us at K<strong>2019</strong> in Düsseldorf and have your revolutionary cup fi lled with<br />
freshly brewed coffee at booth E48 in hall 6. This cup is amazing as it‘s:<br />
• made from renewable raw materials,<br />
• reusable and<br />
• fully recyclable.
Editorial<br />
dear<br />
readers<br />
A few days ago, I visited FACHPACK, an international trade show for the packaging<br />
industry held annually in Germany. There was no doubt about this year’s key<br />
theme: I was overwhelmed by the wall-to-wall claims of sustainability that<br />
bedecked the show. In fact, greenwashing was a suspicion that sprang to mind.<br />
Everything was labelled as being sustainable or recyclable - just two of the<br />
buzzwords conspicuously being brandished at almost all the booths. Clearly, the<br />
concept of sustainability had arrived, at least in the marketing departmentsalthough<br />
not yet in the R&D departments, it would seem. Products that actually<br />
incorporated recycled content, especially PCR (post consumer recyclates), were<br />
very thin on the ground. Plus, if products are recyclable, but don’t actually get<br />
recycled, the benefits in terms of sustainability are zero.<br />
On the other hand, recycling plastics is not as easy as, for instance, recycling<br />
glass, metal or paper, as Remy Jongboom points out in his comment on page 40.<br />
Next to providing news and information on materials and applications, we<br />
also report on the latest innovations and ongoing advances in the world of<br />
bioplastics. As usual, we’re presenting some highlight topics in this issue.<br />
The first is Barrier solutions, a topic that is drawing more and more attention,<br />
as bioplastics find increasing application in the packaging of food and other<br />
sensitive goods.<br />
The other highlight is Fibers/Textiles/Nonwovens, which also includes spun<br />
monofilaments, for example, for medical applications.<br />
The third hot topic is the triennial K-show, the world’s leading trade fair for plastics<br />
and rubber. Please find our show preview, including a detachable Show Guide with<br />
floorplan in the center of the magazine.<br />
An important, not-to-be missed event during K <strong>2019</strong> is our 4 th Bioplastics Business<br />
Breakfast. It’s never too late to register for these mini conferences that will take place<br />
on October 17-18-19 and 20. We also accept on-site registrations. The BBB will be<br />
held on each of the four days from 8am-12:30pm, in the CCD-Ost on the fairgrounds.<br />
See pp 10-11 for details.<br />
We hope to see you at the K show and perhaps also later, at the 14 th European<br />
Bioplastics Conference, which is being hosted this year on December 3-4 in Berlin.<br />
At the conference, we will be presenting the annual Global Bioplastics Award to one<br />
of the five finalists shown on pp.14-15. Until then, enjoy reading<br />
bioplastics MAGAZINE.<br />
Sincerely yours<br />
Michael Thielen<br />
EcoComunicazione.it<br />
WWW.MATERBI.COM<br />
r1_<strong>05</strong>.2017<br />
<strong>05</strong>/<strong>05</strong>/17 11:39<br />
bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />
Preview:<br />
Highlights<br />
Fibers / Textiles / Nonwovens | 16<br />
Barrier Materials | 38<br />
Sep / Oct<br />
Cover Story<br />
Lightweighting PBAT<br />
based materials<br />
Jinhui Zhaolong<br />
<strong>05</strong> | <strong>2019</strong><br />
... is read in 92 countries<br />
Follow us on twitter!<br />
www.twitter.com/bioplasticsmag<br />
Like us on Facebook!<br />
www.facebook.com/bioplasticsmagazine<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 3
Content<br />
Imprint<br />
34 Porsche launches cars with biocomposites<br />
Sep / Oct <strong>05</strong>|<strong>2019</strong><br />
Cover Story<br />
12 Lightweight research on<br />
biodegradable Materials<br />
Fibers & Textiles<br />
16 Biobased additives for biopolymer-textiles<br />
18 A new generation of<br />
compostable monofilament<br />
20 Monofilament melt spinning<br />
22 Alternative materials for mussel socks<br />
23 Cellulose based fibers fully biodegradable<br />
in water soil and compost<br />
24 PLA-fibres in medical applications<br />
Report<br />
26 Inauguration of the world’s<br />
second largest PLA plant<br />
Opinion<br />
40 Bioplastics in the Circular Economy<br />
46 Equal footing for LCAs<br />
49 Biodegradation of plastics in nature:<br />
the future tasks of standardisation<br />
Barrier materials<br />
42 Ultra high barrier for bio-packaging<br />
43 New compostable barrier films<br />
44 Emerging circular biobased<br />
barrier solutions<br />
47 PVOH for barrier applications<br />
3 Editorial<br />
5 News<br />
10 Events<br />
18 Award<br />
28 K-Preview<br />
32 K-Showguide<br />
36 Application News<br />
48 10 years ago<br />
52 Patents<br />
54 Basics<br />
58 Suppliers Guide<br />
62 Companies in this issue<br />
Publisher / Editorial<br />
Dr. Michael Thielen (MT)<br />
Samuel Brangenberg (SB)<br />
Head Office<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach, Germany<br />
phone: +49 (0)2161 6884469<br />
fax: +49 (0)2161 6884468<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Media Adviser<br />
Samsales (German language)<br />
phone: +49(0)2161-6884467<br />
fax: +49(0)2161 6884468<br />
sb@bioplasticsmagazine.com<br />
Michael Thielen (English Language)<br />
(see head office)<br />
Layout/Production<br />
Kerstin Neumeister<br />
Print<br />
Poligrāfijas grupa Mūkusala Ltd.<br />
1004 Riga, Latvia<br />
bioplastics MAGAZINE is printed on<br />
chlorine-free FSC certified paper.<br />
Print run: 7,000 copies<br />
bioplastics magazine<br />
ISSN 1862-5258<br />
bM is published 6 times a year.<br />
This publication is sent to qualified subscribers<br />
(169 Euro for 6 issues).<br />
bioplastics MAGAZINE is read in<br />
92 countries.<br />
Every effort is made to verify all Information<br />
published, but Polymedia Publisher<br />
cannot accept responsibility for any errors<br />
or omissions or for any losses that may<br />
arise as a result.<br />
All articles appearing in<br />
bioplastics MAGAZINE, or on the website<br />
www.bioplasticsmagazine.com are strictly<br />
covered by copyright. No part of this<br />
publication may be reproduced, copied,<br />
scanned, photographed and/or stored<br />
in any form, including electronic format,<br />
without the prior consent of the publisher.<br />
Opinions expressed in articles do not necessarily<br />
reflect those of Polymedia Publisher.<br />
bioplastics MAGAZINE welcomes contributions<br />
for publication. Submissions are<br />
accepted on the basis of full assignment<br />
of copyright to Polymedia Publisher GmbH<br />
unless otherwise agreed in advance and in<br />
writing. We reserve the right to edit items<br />
for reasons of space, clarity or legality.<br />
Please contact the editorial office via<br />
mt@bioplasticsmagazine.com.<br />
The fact that product names may not be<br />
identified in our editorial as trade marks<br />
is not an indication that such names are<br />
not registered trade marks.<br />
bioplastics MAGAZINE tries to use British<br />
spelling. However, in articles based on<br />
information from the USA, American<br />
spelling may also be used.<br />
Envelopes<br />
A part of this print run is mailed to the<br />
readers wrapped bioplastic envelopes<br />
sponsored by Biotec GmbH, Emmerich,<br />
Germany<br />
Cover Ad<br />
Jinhui Zhaolong High Technology Co.,Ltd<br />
Follow us on twitter:<br />
http://twitter.com/bioplasticsmag<br />
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daily upated news at<br />
www.bioplasticsmagazine.com<br />
News<br />
Sicomin launches<br />
new bio epoxy-resin<br />
As the automotive industry focuses on more sustainable<br />
manufacturing, Sicomin, the leading supplier of eco-resins, has<br />
announced a replacement for petroleum based materials with<br />
the launch of its new bio-based epoxy resin aimed specifically for<br />
HP-RTM processing techniques.<br />
SR GreenPoxy 28 is the sixth product to be added to Sicomin’s<br />
renowned GreenPoxy range and is available with immediate<br />
effect in the industrial quantities typically required by Automotive<br />
OEM’s.<br />
Certified by Veritas, SR GreenPoxy 28 is a fast cycle, low toxicity,<br />
third generation bio based formulation aimed specifically at the<br />
HP-RTM moulding processes used for both high performance<br />
structural parts and aesthetic carbon fibre components. The new<br />
formulation has been optimized for fast production cycle times<br />
and superior mechanical performance.<br />
SR GreenPoxy 28 can be fully cured using a 2-minute cure<br />
cycle at 140°C, producing an onset T g<br />
of 147°C, as well as<br />
exceptional mechanical properties under both dry and hot/wet<br />
test conditions.<br />
As Philippe Marcovich, President, Sicomin commented, more<br />
and more manufacturers and suppliers are betting on biobased<br />
alternatives derived from renewable raw materials. “The<br />
latest addition to our GreenPoxy range, SR GreenPoxy 28, is an<br />
exciting alternative to traditional resins providing exceptional<br />
performance and quality for high volume programmes.” MT<br />
www.sicomin.com<br />
Novamont goes<br />
forward into FDCA<br />
Novamont (Novara, Italy) headquarters recently<br />
presented to Invitalia a project for the production<br />
of 2.5-furandicarboxylic acid (FDCA) in a new<br />
demonstration plant that will be built in Terni,<br />
obtaining a loan of 5.8 million Euros (5 million soft<br />
loans and the rest as a grant) as part of a total<br />
investment of 10 million Euros, which will lead to<br />
the creation of 12 new jobs. This was reported by<br />
polimerica.it on August 29. Invitalia ia an Italian<br />
National Agency for Investment Attraction and<br />
Enterprise Development<br />
Novamont has a proprietary technology for the<br />
synthesis of FDCA and is already working on a<br />
pilot plant to develop the process: the decision to<br />
move to the demonstration unit would suggest that<br />
the process, tested at laboratory level, is ripe for a<br />
further step towards production on a commercial<br />
scale.<br />
Novamont will use 2,5-furandicarboxylic acid<br />
(FDCA) as a monomer to produce V-generation<br />
Mater-bi and develop packaging with oxygen and<br />
carbon barrier properties. This intermediate can<br />
also be used to produce polyethylene-furanate<br />
(PEF), a polyester resin alternative to PET for<br />
packaging, biobased and recyclable in the PET flow,<br />
but not biodegradable.<br />
CEO Catia Bastioli on polimerica.it: "Novamont<br />
continues its process of innovation in the<br />
bioeconomy sector, allowing the diversification of<br />
production activities at the Terni site, thanks to a new<br />
proprietary technology. It is a demonstration plant<br />
for the production of furandicarboxylic acid, from<br />
renewable raw materials, for a range of polymers<br />
and biodegradable and compostable polymeric<br />
alloys, also proprietary, with high performance in<br />
the conditions of use". MT<br />
www.novamont.com<br />
Source: www.polimerica.it/articolo.asp?id=22350<br />
Picks & clicks<br />
Most frequently clicked news<br />
Here’s a look at our most popular online content of the past two months.<br />
The story that got the most clicks from the visitors to bioplasticsmagazine.com was:<br />
tinyurl.com/news-<strong>2019</strong>0910<br />
Grand opening of Total Corbion PLA's 75,000 tonnes per year<br />
bioplastics plant<br />
(10 September <strong>2019</strong>)<br />
Total Corbion PLA, a 50/50 joint venture between Total and Corbion, officially<br />
inaugurated its 75,000 tonnes per year PLA bioplastics plant in Rayong,<br />
Thailand on Sept. 09, <strong>2019</strong>. The world’s second largest PLA plant is located<br />
on the same premises, right next to a lactic acid plant of Corbion. It was<br />
finished in mid 2018 and commissioned end of 2018. As of yet, the PLA plant<br />
has produced more than 20,000 tonnes of PLA.<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 5
News<br />
daily upated news at<br />
www.bioplasticsmagazine.com<br />
First Mile and Vegware<br />
team up to boost<br />
compostable packaging<br />
recycling<br />
Plant-based packaging specialist, Vegware (Edinburgh,<br />
Scotland), is joining forces with leading recycling company,<br />
First Mile (London, UK), to provide a UK-wide end-of-life<br />
solution for its compostable foodservice disposables<br />
using RecycleBox, First Mile’s low cost, courier-led<br />
recycling service.<br />
First Mile currently collects over 25 material streams<br />
in London and Birmingham, including Vegware’s<br />
compostable packaging, but has now introduced<br />
RecycleBox to provide a national solution for those items<br />
not collected by local councils and other waste companies.<br />
This service is especially important for those items that<br />
require separate collections to be recycled effectively.<br />
Compostable packaging is a great example of this as<br />
it must be sent to a specialist facility to be organically<br />
recycled, and should not be put in mixed recycling.<br />
“First Mile’s RecycleBox service now creates full UK<br />
post-back coverage for used Vegware to access suitable<br />
waste infrastructure,” said Vegware’s environmental<br />
and communications director, Lucy Frankel. “Over two<br />
dozen UK facilities accept our compostable products, and<br />
trade collections for used Vegware now cover 38% of UK<br />
postcodes, up from 2% in 2012 when we started working<br />
with the waste sector. We introduced First Mile to a facility<br />
who had tested and approved Vegware products in their<br />
process, and see RecycleBox as an innovative solution for<br />
individuals and foodservice businesses throughout the<br />
UK.”<br />
RecycleBox is First Mile’s simple solution to overcoming<br />
the logistical barriers associated with recycling.<br />
Businesses or consumers can simply put the used<br />
Vegware disposables back in the cardboard box it came in<br />
(or order one from First Mile), and then book a collection<br />
online to return the box back to First Mile, who will then<br />
facilitate delivery to Vegware’s approved facility.<br />
The RecycleBox service is also available for other items<br />
– from used electrical items to coffee pods or old shoes.<br />
These items are sorted into the correct recycling stream<br />
or, for those items where an end-of-life solution doesn’t<br />
currently exist, sent to First Mile’s innovative RecycleLab<br />
where new recycling solutions are explored.<br />
Brands responsible for creating hard-to-recycle items<br />
can sponsor the RecycleBox service as a credible end-oflife<br />
solution to their products. Any brand needing help in<br />
finding a recycling solution can contact First Mile, who will<br />
assist them in finding a route via its network of processing<br />
partners. MT<br />
www.recyclebox.co.uk/taxons/vegware<br />
www.thefirstmile.co.uk<br />
www.vegware.com<br />
Membership milestone<br />
GO!PHA, the Global Organization for PHA is a memberdriven,<br />
non-profit initiative with as aim to accelerate the<br />
development of the PHA-platform industry. The platform<br />
looks to be filling a need: one month after its official<br />
incorporation on July 13, <strong>2019</strong>, its membership has<br />
already grown to 25.<br />
As part of the GO!PHA policy it will publish a series<br />
of white papers to inform policy makers and other<br />
stakeholders about the benefits and potential of PHAs.<br />
The first white paper, authored by PHA expert Jan<br />
Ravenstijn, focuses on the bio-benign nature of PHA,<br />
which is a crucial element of the future success of PHAs<br />
in different end-markets.<br />
The full paper, and future GO!PHA white papers can be<br />
accessed at:<br />
www.gopha.org/pha<br />
Russian TAIF Group<br />
bioplastic project<br />
going forward<br />
Russian petrochemical giant TAIF JSC Group and Bioon<br />
have released a joint statement announcing TAIF’s<br />
plans to produce PHA bioplastic at a site in Tatarstan are<br />
indeed going forward.<br />
The company will build a new plant for the production<br />
of PHA based on technology licensed by Italy’s Bio-on, at<br />
Alabuga, an industrial zone that has attracted a number<br />
of the technology companies.<br />
The contract for the turn-key construction of the<br />
production plant will be awarded by the end of the year;<br />
production is aimed to commence in the second half of<br />
2021. The plant will have an initial production capacity of<br />
10,000 tonnes per year, but set up with the possibility for<br />
expanding to double that at a later stage.<br />
"We really believe in this project," says Ruslan<br />
Shigabutinov, General Manager of TAIF, who visited<br />
Bio-on and its production and R&D facilities in Castel<br />
San Pietro Terme (BO) on July 25, together with a Taif<br />
Group delegation, including strategic advisor Mr. Albert<br />
Shigabutdinov, who is also the Chairman of 2BIO JSC.<br />
“It represents an important opportunity for a group like<br />
ours that, among others, is active in the field of plastics.<br />
Taif Group is strategically sensitive to innovations, to<br />
environmental protection elements and wants to be<br />
actors in sustainable initiatives like this,” he continued.<br />
"The choice of the industrial site area was driven by<br />
the presence of many foreign investors that ensure, in<br />
addition to some tax benefits, an excellent visibility on the<br />
international market." added Albert Shigabutinov. MT<br />
www.taif.ru | www.bio-on.it<br />
6 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
daily upated news at<br />
www.bioplasticsmagazine.com<br />
News<br />
Global bioplastics market unil 2024<br />
Eco-friendliness, favourable government policies, renewable raw material sources, and high acceptance from consumers are<br />
driving growth in the global bioplastics market. While Europe accounts for more than two-fifths of the total market share and<br />
is expected to maintain its lead status, AsiaPacific is expected to register the largest growth rate with a CAGR of 20.4% through<br />
2024.<br />
According to a new report published by Allied Market Research, titled, Bioplastics Market by Type and Application: Global<br />
Opportunity Analysis and Industry Forecast, 2018-2024 the global bioplastics market was valued at $21,126.31 million in 2017,<br />
and is projected to reach $68,577.25 million by 2024, registering a CAGR of 18.8% from 2018 to 2024. Bioplastics are extensively<br />
used in the production of rigid packaging. In 2017, the rigid packaging segment accounted for approximately one-third share<br />
in the global market in terms of value.<br />
The level of technical complexity of bioplastics packaging is increasing and their use in rigid is expected to grow at the same<br />
pace throughout 2024. For instance, the commercialization of co-extruded double or multiple layer film products has gained<br />
momentum in the recent years. It also finds applications in various end-use industries such as flexible packaging, textile,<br />
agriculture, and horticulture, consumer goods, automotive, electronics, building and construction, and others.<br />
The production and use of bioplastics are viewed as a sustainable solution due to low emission of greenhouse gasses.<br />
Factors such as eco-friendly properties, increase in consumer awareness, growth in environmental concerns, and favourable<br />
government policies drive the growth of the bioplastic market. However, high production cost and comparatively lower<br />
performance standards than synthetic plastics restrain the market growth to a certain extent.<br />
Key Findings of the Bioplastics Market:<br />
• In 2017, Asia-Pacific accounted for more than one-fifth share growing at a CAGR of 20.4% from 2018 to 2024.<br />
• In 2017, non-biodegradable plastic accounted for the highest market share and is expected to growth at the highest CAGR<br />
of 20.2%.<br />
• The rigid packaging application segment accounted for the highest market share in 2017 and is projected to grow at the<br />
highest CAGR of 28.3%.<br />
• In 2017, Europe accounted for the highest market share and is anticipated to grow at a significant CAGR of 18.7%.<br />
• India is anticipated to grow at the highest CAGR of 23.8% from 2018 to 2024.<br />
• In terms of value, Asia-Pacific and LAMEA collectively accounted for more than one-fourth share in the global bioplastics<br />
market in 2017.<br />
www.alliedmarketresearch.com/bioplastics-market<br />
Injection moulding simulation for bioplastics<br />
It is well known that bioplastics often behave very differently<br />
in injection moulding than their classical relatives. Simcon<br />
(Würselen, Germany), the<br />
expert for injection moulding<br />
simulation, has expanded its<br />
software products Cadmould<br />
and Varimos to include the<br />
calculation of bioplastics and<br />
biocomposites, i.e. classical<br />
polymers reinforced with<br />
natural fibres. Thanks to<br />
simulation, users of these<br />
materials can also benefit from<br />
the advantages of simulations<br />
and save an average of around<br />
30 % in both development time<br />
and cycle times.<br />
In the research project<br />
NFC-Simulation funded by the<br />
German Federal Ministry of<br />
Food and Agriculture (BMEL)<br />
Comparison measured and simulated deformation<br />
in which among others the car manufacturer Ford was a<br />
partner, Simcon has shown by means of a glove compartment<br />
assembly that influences of<br />
the injection moulding process<br />
such as filling, holding pressure,<br />
shrinkage and warpage are<br />
realistically mapped up to the<br />
transfer of the fibre orientations<br />
to the crash simulation. "Even<br />
the crash simulation at Ford<br />
delivered excellent results with<br />
the fiber orientations provided<br />
by Cadmould", Simcon owner<br />
Dr. Paul Filz looks back on the<br />
project.<br />
Cadmould has also been<br />
successfully used for bioplastics<br />
in other areas, such as<br />
consumer electronics and<br />
musical instruments. MT<br />
www.simcon-worldwide.com<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 7
News<br />
daily upated news at<br />
www.bioplasticsmagazine.com<br />
Dow and UPM partner<br />
to produce plastics<br />
made with renewable<br />
feedstock<br />
Michigan-based Dow, in partnership with Finland’s UPM<br />
Biofuels, a producer of advanced biofuels, announces the<br />
commercialization of a plastics offering for the packaging<br />
industry made from a biobased renewable feedstock.<br />
Dow is integrating wood-based UPM BioVerno renewable<br />
naphtha – a key raw material used to develop plastics – into<br />
its slate of raw materials, creating an alternative source for<br />
plastics production. Dow is using this feedstock to produce biobased<br />
polyethylene (PE) at its production facility in Terneuzen,<br />
The Netherlands, for use in packaging applications such as food<br />
packaging to reduce food waste. Following a successful yearlong<br />
trial program, Dow is now planning to scale production and<br />
address the increasing global demand for renewable plastics.<br />
UPM BioVerno naphtha is produced at UPM’s biorefinery in<br />
Lappeenranta, Finland, from crude tall oil, which is a residue of<br />
paper pulp production. Unlike many other alternative renewable<br />
feedstocks, no extra land is required for the feedstock production.<br />
The feedstock originates from sustainably managed forests.<br />
European Bioplastics<br />
& bioplastics MAGAZINE<br />
join forced at K'<strong>2019</strong><br />
The industry association European Bioplastics and<br />
bioplastics MAGAZINE, will again share a booth at K'<strong>2019</strong>,<br />
the world's biggest trade show on plastics & Rubber<br />
- 16-23 October in Düsseldorf, Germany. Even if the<br />
industry association and your favourite magazine are<br />
absolute independent organizations, we again decided<br />
to join forced to offer a hub for all visitors interested in<br />
bioplastics.<br />
Make sure to visit our booth #B10 in Hall 7a. This year<br />
we are grateful to Dr. BOY, manufacturer of injection<br />
moulding machines to place an XS-model injection<br />
moulder on our booth. And we thank Mitsubishi<br />
Chemical (MCPP) for sponsoring a couple of bags of<br />
their isosorbide based DURABIO TM resin to be run on<br />
that machine on our booth.<br />
Come by and grab a nice paper clip made of this<br />
unique biobased polycarbonate resin on our booth. MT<br />
www.dr-boy.de | www.mcpp.com<br />
This process also significantly reduces CO 2<br />
emissions,<br />
especially by carbon sequestration, compared to standard<br />
fossil derived PE resins, and the plastics produced can help<br />
brand owners meet their sustainability packaging goals. The<br />
entire supply chain is International Sustainability & Carbon<br />
Certification (ISCC) certified, based on mass balance approach,<br />
meaning all steps meet traceability criteria and reduce negative<br />
environmental impacts.<br />
Packaging made from this renewable feedstock can be fully<br />
recyclable as demonstrated through a collaboration with brand<br />
owner Elopak, an international supplier of paperboardbased<br />
packaging for food and beverage. Dow’s biobased low-density<br />
polyethylene (LDPE) resins are used to coat Elopak’s liquid<br />
carton containers and in the production of carton caps, resulting<br />
in a 100 % renewable beverage carton. This was achieved without<br />
compromising the benefits of the original form of plastic-coated<br />
packaging in addition to reducing the CO 2<br />
footprint of the<br />
packaging during production and use.<br />
This agreement with UPM is the latest example of Dow’s<br />
strategy to enable a shift to a circular economy for plastics by<br />
focusing on resource efficiency and integrating recycled content<br />
and renewable feedstocks into its production processes. Dow<br />
also recently partnered with the Fuenix Ecogy Group, based in<br />
Weert, The Netherlands, for the supply of pyrolysis oil feedstock,<br />
which is made from recycled plastic waste.<br />
Through these efforts, post-consumer plastics will continue<br />
to have value through an extended lifespan. These agreements<br />
also contribute to Dow’s commitment to incorporate at least<br />
100,000 tonnes of recycled plastics in its product offerings sold<br />
in the European Union by 2025. MT<br />
www.upmbiofuels.com | www.dow.com<br />
PHBH got JBA Award<br />
JBA’s Bioindustry Award <strong>2019</strong> has been presented to<br />
Kaneka and RIKEN researchers for the development<br />
of a PHBH polymer biodegradable on soil and in<br />
seawater.<br />
The poly-hexanoate-butyrate (PHBH) copolymer is<br />
produced by Kaneka from plant oil using a recombinant<br />
strain of Cupriavidus necator at a capacity of currently<br />
1,000 tonnes, with plans to increase production to<br />
5,000 and later to 100,000 tonnes a year.<br />
PHBH materials decompose not only on soil,<br />
but also in seawater (90 % within 6 months at<br />
30 °C) and have obtained the OK Biodegradable<br />
Marine certificate from TÜV AUSTRIA Belgium.<br />
The biopolymer-producing strain is based on joint<br />
research by Yoshiharu Doi, former Professor of the<br />
Tokyo Institute of Technology and Director at RIKEN,<br />
and five Kaneka researchers who will share the award<br />
of 3 million ¥. MT<br />
www.kaneka.com<br />
8 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
DuraSense<br />
®<br />
by Stora Enso<br />
The affordable<br />
way to go green<br />
Demand the game-changing biocomposite.<br />
Demand more. Demand renewable.<br />
Imagine a green, cost-efficient and<br />
versatile material for a wide range of<br />
injection moulded products. A blend<br />
of wood fibres and plastic material,<br />
offering a light and flexible solution<br />
with the mouldability of plastics, yet<br />
the sustainable benefits of wood.<br />
Resulting in up to 80% reduced CO 2<br />
footprint.<br />
DuraSense ® creates endless design<br />
possibilities that are limited only by<br />
your imagination. With little or no<br />
change to existing production<br />
techniques, our material is developed<br />
to match conventional plastics and<br />
therefore fit existing moulds.<br />
Visit us for a cup of coffee. We’ll show<br />
you around the biocomposite plant,<br />
and tell you more about this gamechanging<br />
material.<br />
Demand more. Demand renewable.<br />
www.storaenso.com/biocomposites<br />
Visit us at K-Fair 16 - 23 October <strong>2019</strong><br />
You will find us in stand 72G18 , hall 07 2<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 9
Events<br />
Bioplastics Business Breakfast<br />
Programme:<br />
For details of the event, see next page or visit www.bioplastics-breakfast.com<br />
Thursday, October 17, <strong>2019</strong><br />
8:00-8:<strong>05</strong> Michael Thielen, Welcome remarks<br />
8:<strong>05</strong>-8:25 Harald Kaeb, narocon Biobased Plastic Packaging in Europe - Update & Outlook<br />
8:25-8:45 Caroli Buitenhuis, Green Serendipity Future of biobased packaging<br />
8:45-9:<strong>05</strong> Patrick Gerritsen, Bio4Pack Biobased plastics and recycling<br />
9:<strong>05</strong>-9:25 Tim Wagler, Braskem Green PE, the biobased drop-in solution for the circular economy<br />
9:25-9:35 Q&A<br />
9:35-9:55 Francois de Bie, Total Corbion PLA The inauguration of our first 75.000 ton/year PLA production plant<br />
9:55-10:15 Viviana Conti, NatureWorks Latest developments (t.b.c.)<br />
10:15-10:35 Marie-Hélène Gramatikoff, Lactips A competitive and 100% biobased technology<br />
10:35-10:45 Q&A<br />
10:45-11:<strong>05</strong> Coffee & Networking Break<br />
11:<strong>05</strong>-11:25 David Sudolsky, Anellotech Making 100% biobased PET a reality<br />
11:25-11:45 Daniel Ganz, Sukano All you need to know to successfully run PBS<br />
11:45-12:<strong>05</strong> Neil Dewar, Mold-Masters Europe Critical Bio-Resin Processing Insights for Packaging<br />
12:<strong>05</strong>-12:25 Sam Deconinck, OWS Some of the challenges compostable packaging faces today<br />
12:25-12:30 Q&A<br />
Friday, October 18, <strong>2019</strong><br />
8:00-8:<strong>05</strong> Michael Thielen, bioplastics MAGAZINE Welcome remarks<br />
8:<strong>05</strong>-8:25 Mark Vergauwen, NatureWorks Latest developments (t.b.c.)<br />
8:25-8:45 Hugo Vuurens, Total Corbion PLA Luminy PLA in new applications and innovation in PLA end of life solutions<br />
8:45-9:<strong>05</strong> Caine Folkes-Miller, Floreon t.b.d.<br />
9:<strong>05</strong>-9:25 José Ángel Ramos, ADBioplastics Advanced biomaterials for packaging applications<br />
9:25-9:35 Q&A<br />
9:35-9:55 C. Arnault & S. Macedo, Carbiolice Evanesto, new enzymated technology making PLA fully compostable<br />
9:55-10:15 Thomas Unger, Leistritz Direct extrusion and Compounding of Biopolymers<br />
10:15-10:35 Patrick Zimmermann, FKuR PLA ompounds moving away from compostability (t.b.c.)<br />
10:35-10:45 Q&A<br />
10:45-11:<strong>05</strong> Coffee & Networking Break Coffe & Networking Break<br />
11:<strong>05</strong>-11:25 Daniel Ganz, Sukano Advances in PLA modification via additives masterbatches<br />
11:25-11:45 Karsten Schulz, Omya t.b.d.<br />
11:45-12:<strong>05</strong> Luis Roca, AIMPLAS Tailor made PLA by Reactive extrusion for packaging applications<br />
12:<strong>05</strong>-12:25 Michael Carus, nova Institute The role of PLA in the Bio-based Economy<br />
12:25-12:30 Q&A<br />
Saturday, October 19, <strong>2019</strong><br />
8:00-8:<strong>05</strong> Michael Thielen, bioplastics MAGAZINE Welcome remarks<br />
8:<strong>05</strong>-8:25 Harald Ruhland, Ricone Successful development of a bio-based technical product<br />
8:25-8:45 Alejandra de Noren, Neste Circular drop-in solutions for durable applications<br />
8:45-9:<strong>05</strong> Richard Lambert, Braskem I’m greenTM, the biobased drop-in solution for durable applications<br />
9:<strong>05</strong>-9:25 Silvana Maione, GCR Group BioGranic: Compostable filler solutions for flexible and rigid applications<br />
9:25-9:35 Q&A<br />
9:35-9:55 Uwe Michael Jakobs, Arkema Polyamide 11 durable by nature<br />
9:55-10:15 Stephane Wohlgemuth, DSM EcoPaXX: a drop in for when PA66 reaches its limits<br />
10:15-10:35 Dirk Schawaller, Tecnaro Latest developments with Arboform-Compounds (t.b.c.)<br />
10:35-10:45 Q&A<br />
10:45-11:<strong>05</strong> Coffee & Networking Break<br />
11:<strong>05</strong>-11:25 Patrick Zimmermann, FKuR Latest developments with Terralene-Compounds(t.b.c.)<br />
11:25-11:45 Salvador Ortega, NatureWorks Forging ahead with PLA in industrial applications<br />
11:45-12:<strong>05</strong> Thomas Köppl, Hexpol TPE How to meet growing demand for soft, safe and sustainable plastics<br />
12:<strong>05</strong>-12:25 Asta Partanen, nova-Institute Biocomposites<br />
12:25-12:30 Q&A Q&A<br />
Sunday, October 20, <strong>2019</strong><br />
8:00-8:<strong>05</strong> Michael Thielen, bioplastics MAGAZINE Welcome remarks<br />
8:<strong>05</strong>-8:25 Jan Ravenstijn, Jan Ravenstijn Consulting State-of-the-art of the PHA-platform industrialization<br />
8:25-8:45 Pieter Willot, deSter PHA for FMCG’s: challenges between raw material and the consumer market.<br />
8:45-9:<strong>05</strong> Anindya Mukherjee, i2i Consulting PHA’s cost equivalency to conventional plastics – A new value chain<br />
9:<strong>05</strong>-9:20 Q&A<br />
9:20-9:40 Daniel Pohludka, Nafigate PHB in cosmetic products<br />
9:40-10:00 Fabiana Fantinel, Sabio Materials Applications and application developments with PHA-polymers<br />
09:50-10:20 Silvia Kliem, IKT, University Stuttgart Impact Modification of PHB by the Building of a Block Copolymer<br />
10:20-10:35 Q&A<br />
10:35-10:55 Coffee & Networking Break<br />
10:55-11:15 Lara Dammer, nova Institute EU Circular Economy and Plastics Strategy<br />
11:15-11:35 Remy Jongboom, Biotec PHA compound applications (t.b.c.)<br />
11:35-11:55 Jan Ravenstijn, GO!PHA Status of the GO!PHA Organization<br />
11:55-12:15 Lara Dammer, nova Institute Natural polymers and PHA in EU legislation<br />
15:15-12:30 Q&A<br />
Subject to changes<br />
10 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
한국포장협회로고.ps 2016.11.21 8:26 PM 페이지1 MAC-18<br />
On-Site Registration<br />
is possible<br />
organized by<br />
17. - 20.10.<strong>2019</strong><br />
Messe Düsseldorf, Germany<br />
BIOPLASTICS<br />
BUSINESS<br />
BREAKFAST<br />
B 3<br />
Bioplastics in<br />
Packaging<br />
PLA, an Innovative<br />
Bioplastic<br />
Bioplastics in<br />
Durable Applications<br />
PHA, Opportunities<br />
& Challenges<br />
www.bioplastics-breakfast.com<br />
Gold Sponsor<br />
Media Partner<br />
Supported by<br />
1 st Media Partner<br />
KOREA PACKAGING ASSOCIATION INC.<br />
Getränke!<br />
TECHNOLOGIE & MARKETING<br />
At the World‘s biggest trade show<br />
on plastics and rubber: K‘<strong>2019</strong> in<br />
Düsseldorf, Germany, bioplastics<br />
will certainly play an important<br />
role again. On four days during the<br />
show bioplastics MAGAZINE will host<br />
a Bioplastics Business Breakfast:<br />
From 8am to 12pm the delegates<br />
will enjoy highclass presentations<br />
and unique networking opportunity.<br />
Venue: CCD Ost, Messe Düsseldorf<br />
The trade fair opens at 10 am.
Cover Story<br />
Advertorial<br />
Lightweighting PBATbased<br />
materials<br />
As society changes and evolves, people are increasingly<br />
seeking more convenience and ease in daily<br />
life, both at home and at work. This trend is boosting<br />
demand for lightweight and high-performance polymers<br />
in various industries. At present, the materials most commonly<br />
used are expandable particle foam materials (EPS,<br />
EPP, EPO), which can be expanded to ratios of more than 60<br />
with a density of down to 0.015-0.030 g/cm³. Extremely light<br />
and with good compression resistance, above all, these are<br />
relatively inexpensive and hence find application in many<br />
industries, including catering, packaging, construction and<br />
automobile. However, most of these particle foam materials<br />
break very easily, and their low weight makes them difficult<br />
to recycle. If residues end up in nature, they do not degrade,<br />
which causes huge pollution problems in the environment.<br />
As the leading manufacturer of biodegradable polymer<br />
sin China, Jinhui Zhaolong High Technology Co.,Ltd.<br />
(Shanxi, China) has always focused on the study of<br />
lightweighting biodegradable polymer materials. After<br />
repeated experiments and tests, Jinhui Zhaolong has<br />
successfully developed the Ecowill series of expandable and<br />
biodegradable modified polymers based on PBAT.<br />
Test results demonstrate that the Ecowill series of<br />
expandable and biodegradable modified polymers have<br />
a maximum foaming ratio of 13 times and an apparent<br />
density of 0.09g/cm³. Electron microscopy shows that the<br />
cell structure is compact and uniform, and the cell diameter<br />
lies between 20 and 40 µm. After further adjustments in<br />
formula and process, the density can be further reduced.<br />
The Shore-hardness of the new Ecowill series materials<br />
is between 40-65D, with a resilience of over 60 % and<br />
an elasticity comparable to TPEE and TPU elastomer<br />
materials. The materials can be converted into elastomeric<br />
foams with high elasticity requirements by steam bonding<br />
or other elastomer macromolecule material perfusion<br />
bonding and can thus be used for a wide range of large<br />
applications in the field of toys or shoes. Jinhui Zhalong<br />
have already applied it to large Lego-like bricks, airplane<br />
models, insoles and much more.<br />
The Ecowill family of materials is characterized by a<br />
high degree of toughness and high self-bonding strength,<br />
which is very resistant to damage. After being converted<br />
into packaging products, these can be used repeatedly.<br />
Currently, Jinhui Zhaolong is developing a reusable foam<br />
packaging box with its partners based on the molding<br />
characteristics of Ecowill series, which can be applied in<br />
the fields of fruits, vegetables and fresh package.<br />
Compared with standard PBAT, the heat resistance of the<br />
Ecowill series is significantly improved. The melting range<br />
has increased from 95-100 °C to almost 120 °C. At the same<br />
time, the Ecowill materials leave no residual foaming agent<br />
monomers behind. Jinhui Zhaolong is currently conducting<br />
food safety contact tests at 100°C. After passing the test,<br />
12 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Cover Story<br />
Advertorial<br />
By:<br />
Long Yanbo<br />
Jinhui Zhaolong<br />
Shanxi, China<br />
the new material is very<br />
likely to replace PP for a<br />
new generation of fast<br />
food boxes.<br />
In addition to the<br />
above applications,<br />
Jinhui Zhaolong believes<br />
that the Ecowill series will also be<br />
suitable for many applications that haven’t<br />
been developed yet. They hope more downstream<br />
foam material users will join them in further research<br />
and improvement of the Ecowill series formulation, the<br />
foaming process, forming technology and equipment, and<br />
promote the development and application of lightweight<br />
biodegradable materials.<br />
“Committing to the Development in Green Industry,<br />
Caring for Nature & Benefiting Mankind” is the mission of<br />
Jinhui Zhaolong. The company will continue to contribute to<br />
global environmental protection and to creating a greener<br />
world for future generations.<br />
www.jinhuizhaolong.com<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 13
Award<br />
The 14 th<br />
Bioplastics<br />
Award<br />
Presenting the<br />
five finalists<br />
bioplastics MAGAZINE is<br />
honoured to present the five<br />
finalists for the 14 th Global<br />
Bioplastics Award. Five judges<br />
from the academic world, the<br />
press and industry associations<br />
from America, Europe and Asia<br />
have again reviewed the incoming<br />
proposals. On these two pages we<br />
present details of the five finalists.<br />
The Global Bioplastics Award<br />
recognises innovation, success and<br />
achievements by manufacturers,<br />
processors, brand owners, or<br />
users of bioplastic materials. To<br />
be eligible for consideration in<br />
the awards scheme the proposed<br />
company, product, or service<br />
should have been developed or<br />
have been on the market during<br />
2018 or <strong>2019</strong>.<br />
The following companies/<br />
products are shortlisted (without<br />
any ranking) and from these<br />
five finalists the winner will<br />
be announced during the 14 th<br />
European Bioplastics Conference<br />
on December 3 rd , <strong>2019</strong> in Berlin,<br />
Germany.<br />
Carbiolice, (France)<br />
Enzymatic masterbatch to make<br />
PLA home compostable<br />
In December 2018 Carbiolice<br />
(Riom, France) launched its innovative<br />
and unique enzymated Evanesto ®<br />
masterbatch – an additive that enables<br />
PLA to biodegrade under typical home<br />
composting conditions.<br />
Even if PLA offers very good<br />
properties for rigid applications, its<br />
biodegradability is currently limited to<br />
industrial composting.<br />
Carbiolice has now developd<br />
Evanesto, a new enzymatic additive<br />
to be used as a masterbatch, that will<br />
make PLA polymer compostable under<br />
domestic conditions.<br />
“The masterbatch, in a concentration<br />
of less than 5%, is added to a compound<br />
with a high content of PLA during<br />
conventional converting processes like<br />
film extrusion, thermoforming, injection<br />
molding. It accelerates the natural<br />
PLA biodegradation process, making<br />
it suitable for home composting.”<br />
explained Clémentine Arnault R&D<br />
Manager at Carbiolice.<br />
Initial tests carried out by independent<br />
laboratory OWS on thin films containing<br />
30% of PLA and 5% of Evanesto, and<br />
the rest being other biodegradable and<br />
biobased polyesters, such as biobased<br />
PBAT, TPS…) have shown that complete<br />
disintegration is achieved within a time<br />
frame of 182 days (6 months) under<br />
home composting conditions.<br />
Tests on thicker films obtained by<br />
calandering and thermoforming are still<br />
ongoing, but the initial results are very<br />
positive.<br />
Earlier this year Carbiolice and<br />
Carbios have signed a joint development<br />
agreement with Denmark-based<br />
Novozymes, a global producer of<br />
enzymes, for the production and supply<br />
of enzymes for the manufacture of selfbiodegradable<br />
PLA plastics.<br />
www.carbiolice.com<br />
Bio4self (15 partners form EU)<br />
Self-reinforced PLA composites<br />
Self-reinforced PLA composite<br />
materials, which are being developed<br />
as part of the Bio4self project funded by<br />
European Research Fund H2020, open<br />
up completely new areas of application<br />
for the biobased plastic PLA.<br />
In the project, two different PLA types<br />
with different melting temperatures<br />
are combined to a self-reinforced PLA<br />
composite (PLA SRPC) in such a way that<br />
the higher melting PLA is embedded as<br />
a reinforcing fiber in the lower melting<br />
matrix. The resulting material stiffness<br />
can compete with commercially<br />
available self-reinforced polypropylene<br />
(PP) composites. This makes it possible<br />
to produce mechanically demanding<br />
components for the automotive and<br />
electrical household appliance sectors,<br />
among others.<br />
Although the composite materials<br />
developed have been functionalised<br />
for high mechanical strength and<br />
stiffness as well as for high temperature<br />
and hydrolysis stability, like pure<br />
PLA they are completely biobased,<br />
easily recyclable, formable and even<br />
industrially biodegradable.<br />
These industrial-scale composites<br />
represent a milestone in the development<br />
of functionalized, mechanically highstrength,<br />
biobased material systems.<br />
Furthermore, the development makes a<br />
significant contribution to the recycling<br />
economy.<br />
As an example, the application in a<br />
car seat structure was demonstrated at<br />
the JEC Composite trade show in March<br />
<strong>2019</strong>. During the show, this project was<br />
awarded a JEC Innovation Award for<br />
sustainability, announced at the JEC<br />
Innovation Award ceremony on March<br />
12, <strong>2019</strong>.<br />
www.bio4self.eu<br />
14 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Award<br />
Bio-On and Kartell (both Italy)<br />
First modular storage system<br />
from Bio-on’s bioplastic<br />
Kartell (Noviglio, Milan, Italy) is<br />
offering a new eco-friendly and<br />
sustainable edition of one of its best<br />
sellers - a modular storage unit in the<br />
100 % natural bioplastic material by<br />
Bio-on (Bologna, Italy). The Componibili<br />
storage unit, which is cylindrical in form<br />
with sliding panels, was first created by<br />
Italian designer and Kartell co-founder<br />
Anna Castelli Ferrieri in 1967. The 50-<br />
year old design is available in four<br />
colours: green, pink, cream and yellow<br />
in the three-module version.<br />
Originally made from ABS plastic in<br />
the 1960s, the updated bioplastic unit<br />
is made from Bio-on’s PHB Material,<br />
made from agricultural waste.<br />
For Kartell, research is a mission, said<br />
company president Claudio Luti. “We<br />
will continue to experiment to combine<br />
innovation and design.”<br />
“We have worked with Bio-on to be<br />
able to offer our public a very highquality<br />
bioplastic product and we have<br />
chosen to do it on one of our historic<br />
products, one of the most recognized in<br />
the world. Research on bioplastics fits<br />
with our quest for innovation and is part<br />
of the ‘Kartell loves the planet’ project<br />
aimed at enhancing good sustainability<br />
practices.”<br />
For Bio-on, it is “an honour”, said<br />
founder and CEO Marco Astorri. The<br />
company is proud to see its bioplastic<br />
showcased with one of the most famous<br />
Italian design brands in the world. To<br />
reciprocate and in gratitude for the trust<br />
placed in the material, Bio-on has given<br />
the biopolymer used for this specific<br />
application the name CL, the initials of<br />
Claudio Luti.<br />
www.bio-on.it | www.kartell.com<br />
Dantoy (Denmark)<br />
Biobased toys<br />
In February 2018, Dantoy,<br />
manufacturer of quality toys in<br />
Denmark for more than 50 years,<br />
launched its new line of BIO products,<br />
which has gained much more attention<br />
than initially anticipated. Today, more<br />
than 15% of all dantoy’s products are<br />
bio made from Braskem’s Green PE,<br />
supplied by FKuR, a development clearly<br />
contributing to this toy company’s<br />
healthy sales figures. Located in the<br />
middle of Jutland in Denmark and<br />
employing some 50 employees, most of<br />
whom have been with the company for<br />
more than 10 years, dantoy’s production<br />
facilities span an area of 15,000 m 2 . In<br />
addition, dantoy employs a number of<br />
affiliated colleagues who assemble<br />
the products at home or at sheltered<br />
workshops. All this says something<br />
about dantoy’s DNA, and the company<br />
culture dantoy is known for.<br />
All of Dantoy’s Plastic toys are licensed<br />
for the Nordic Swan Ecolabel, thus they<br />
must comply with the world’s strictest<br />
requirements for plastic contents, going<br />
far beyond the Danish law.<br />
In addition to using biobased plastic<br />
raw materials for the bio and the<br />
brand new Tiny lines, dantoy tries to<br />
minimise the impact of its operations<br />
on the environment. The company has<br />
therefore implemented eco-friendly<br />
processes to manage the consumption<br />
of energy, water and raw materials<br />
and to prevent the possibility of<br />
accidental releases or emissions via the<br />
manufacturing process.<br />
The success is not only based on the<br />
superior quality of the products, but<br />
also on the communication strategy.<br />
On every box it is clearly marked and<br />
explained what it’s all about with this<br />
bioplastic. A series of excellent Youtube<br />
videos also explain it.<br />
www.dantoy.dk<br />
Nölle Kunststofftechnik and<br />
Fraunhofer IAP (Germany)<br />
New splint for bone fractures<br />
A novel splint made of PLA for<br />
immobilizing bone fractures has been<br />
developed that can be repeatedly<br />
reshaped during treatment, such as, for<br />
example, when the swelling subsides.<br />
The new immobilisation concept,<br />
called RECAST was developed by Nölle<br />
Kunststofftechnik It makes use of<br />
variously sized preshaped splints made<br />
from biobased and biodegradable PLA.<br />
The splints are heated to between 55<br />
and 65 °C. The temperature of the<br />
splints is then reduced to a minimum.<br />
The now formable plastic is molded to<br />
fit the corresponding part of the body.<br />
This process takes about five minutes. If<br />
corrections are necessary, the hardened<br />
splint can simply be reheated.<br />
The plastics processor worked closely<br />
with the polymer developers at the<br />
Fraunhofer IAP in Potsdam-Golm on the<br />
development of the optimum material.<br />
It was decided to use PLA as a base<br />
polymer, a bioplastic that has a major<br />
disadvantage for most applications: It<br />
becomes soft at around 58 °C. The low<br />
thermal softening point of PLA is a great<br />
advantage when used as an orthopaedic<br />
splint. This means that the product can<br />
be shaped repeatedly and quickly by<br />
heating. The Fraunhofer researchers<br />
combined PLA with suitable fillers and<br />
developed a formulation that met all the<br />
requirements. In addition, they ensured<br />
that the material could also be produced<br />
in industry-relevant quantities.<br />
In order to make the splint even<br />
more comfortable for patients, RECAST<br />
products also feature a fleece padding<br />
made of PLA and viscose, which was<br />
developed jointly with the Saxon Textile<br />
Research Institute in Chemnitz.<br />
www.noelle-kunststofftechnik.de<br />
www.iap.fraunhofer.de<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 15
Fibers & Textiles<br />
Biobased additives for<br />
By:<br />
biopolymer-textiles<br />
Gunnar Seide<br />
Chair of Polymer Engineering<br />
Aachen-Maastricht Institute for Biobased Materials<br />
Geleen, The Netherlands<br />
Both Flanders and the south of the Netherlands, traditionally<br />
regions with large numbers of companies active in the plastics<br />
processing industry, particularly in the field of textiles are<br />
participating in the project. Both regions hold extensive expertise<br />
in the development and production of carpet and clothing.<br />
It is well-known that the properties of plastics are not inherent<br />
in the polymer itself, but that these are obtained through<br />
the use of functional additives. Nucleating agents, plasticizers,<br />
flame-retardants, colorants, anti-statics, stabilizers are all examples<br />
of additives that are indispensable in today’s materials.<br />
However, in many cases, biobased versions of these additives are<br />
unavailable. This makes it almost impossible to produce 100 %<br />
biobased products. To be able to do so, it is essential to develop<br />
biobased additives.<br />
Is that really necessary? Additives are used in such small<br />
amounts… As the history of microplastics shows, little notice<br />
is taken of the impact materials have on the environment,<br />
until significant effects are seen, which are viewed critically by<br />
consumers.<br />
If biodegradable plastics are to serve as a solution to the<br />
problem of microplastics, additives will need to be developed<br />
that are biodegradable or at least eco-toxicologically harmless.<br />
An example of changing customer expectations is the<br />
fact that a few textile companies have now for the first time<br />
announced they would refuse to use biopolymers produced<br />
by means of genetically modified organisms. Consumers are<br />
becoming increasingly demanding regarding aspects relating to<br />
the environment or sustainability. There are currently multiple<br />
research projects in progress on biobased additives for biobased<br />
polymers.<br />
Some examples: The objective of the BioTex Fieldlab is to set<br />
up an open innovation center for research into the development<br />
of fibers and yarns from biopolymers. Within this project, many<br />
companies, under the umbrella of Modint GmbH, Düsseldorf/<br />
Germany, and research institutes are working together. The<br />
center will develop new textile production processes and<br />
applications for this.<br />
Modint is an industry association of 600 textile companies.<br />
An EU project named “Pure nature: 100 % biobased (BB100)”<br />
is currently being run, the goal of which is to develop a process<br />
chain for fully biobased man-made fiber materials. This not<br />
only includes the processing of biopolymers, but also commonly<br />
used additive materials such as plasticizers, flame-retardants,<br />
colorants and nucleation agents. Fully biobased yarns and<br />
textile demonstrators will be developed.<br />
By 2030, the textile sector aims to use between 20-50 %<br />
biobased materials in its products. In textiles, for example, color<br />
intensity and stability are the most important quality indicators.<br />
However, biobased dyes are commercially available only to a<br />
limited extent and often do not meet quality criteria such as<br />
color authenticity.<br />
This project focuses on developing natural dyes from marine<br />
organisms (such as algae) and agricultural crops which<br />
(amongst others) contain sorghum and onion peels.<br />
In conclusion, the author would like to describe a personal<br />
experience of a panel discussion at a conference on<br />
sustainability in the textile industry this year. At the meeting,<br />
both students and corporate delegates from all over the world,<br />
including developing countries with textile production, were<br />
represented. In questions and statements during the panel<br />
discussion, it clearly emerged that today’s younger people, as<br />
represented by the participants in the conference, are forcefully<br />
demanding a shift towards sustainability, even if it has economic<br />
consequences in terms of lower growth, while industry<br />
representatives consider sustainability the basis for further<br />
business within a global growth philosophy.<br />
“I´m convinced that the union of both<br />
positions via new technologies is possible.<br />
A modern world is not conceivable without<br />
modern materials! Therefore: In for biobased<br />
polymers, in for biobased additives!”<br />
www.maastrichtuniversity.nl<br />
16 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Make the switch to bio<br />
For almost every conventional plastic, there is a bioplastic<br />
alternative. Our PLA masterbatches can help introduce PLA<br />
into your portfolio. Make the switch today.<br />
www.sukano.com<br />
Meet us at K <strong>2019</strong><br />
Hall 8a, H28<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 17
Fibers & Textiles<br />
Figure 5: Bio-monofilaments from the compound Sea212<br />
Figure 1: Mechanical strength in relation to diameter<br />
strength (N)<br />
160<br />
140<br />
120<br />
100<br />
80<br />
60<br />
40<br />
20<br />
0<br />
0,1<br />
0,2 0,3 0,4 0,5 0,6<br />
diameter (mm)<br />
Figure 2: Marine ageing of the monofilaments<br />
after one year of immersion.<br />
0,7 0,8 0,9<br />
A new<br />
generation of<br />
compostable<br />
monofilament<br />
for a wide<br />
range of<br />
applications<br />
SeaBird, based in Brittany, France, is a company that engages<br />
in the research, development and production of<br />
bioplastic materials. Since its founding in 2011, the company<br />
has focused on reducing the impact of conventional plastics<br />
in the marine environment by evolving sustainable waste<br />
management solutions.<br />
Seabird produces compostable bioplastic formulations<br />
enhanced with fillers and additives that are able to meet the<br />
specifications and process constraints of their industrial<br />
partners while retaining their environmentally-friendly nature<br />
(no volatile organic compounds (VOCs), toxic additives and<br />
others, end-of-life valuation).<br />
In 2017, the company validated the industrial production<br />
of monofilaments based on one of these compounds, called<br />
Sea212 ® . Developed for use on an extrusion spinning process<br />
line, the compound is a blend of different bio-polyesters and<br />
bio-additives. The various ingredients are expertly combined<br />
to meet all process specifications and provide the required<br />
physical properties, while at the same time complying both<br />
with the European composting standard EN13432 / EN 14995<br />
and the food contact standard. The monofilaments are used<br />
in many products developed by Seabird and some industrial<br />
partners.<br />
Special consideration was given to the homogeneity and<br />
rheological stability of the blend in order to guarantee the<br />
compound’s processability. The compound can be processed<br />
at 170 °C, which is lower than the temperature used for most<br />
conventional plastics.<br />
Properties of the monofilament<br />
A range of monofilament diameters (from 0.2 mm to 1.0 mm)<br />
were developed, targeted at a wide array of applications. Figure 1<br />
shows the mechanical strength of the monofilament in<br />
relation to the diameter. The mechanical tests were performed<br />
according to standard EN ISO 2062. Although a monofilament<br />
tenacity of 2.4 cN/dtex was found for a monofilament with a<br />
diameter of 0.65 mm - a quarter less than certain conventional<br />
monofilaments - it is still sufficient for many applications.<br />
18 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Fibers & Textiles<br />
The monofilament boasts numerous interesting properties.<br />
The material remains stable up to 80 °C; it is lighter than PET,<br />
easily dyable due to its natural white color, easy to tie and is<br />
resistant to common solvents such as acetone, ethanol and<br />
white spirit.<br />
Marine ageing<br />
The compound was developed for, among other things,<br />
marine applications, and designed to have a useful life of five<br />
years with no significant degradation of the properties. The<br />
objective, therefore is to produce compostable products that<br />
are economically viable; i.e. products with a useful life that is<br />
similar in length to conventional products, to avoid having to<br />
invest earlier in new equipment because of a shorter lifespan.<br />
To assess the lifespan of the monofilaments, ageing<br />
experiments have been carried out at Lorient’s harbor<br />
since 2017. Figure 2 shows scanning electron microscope<br />
(SEM) images of a monofilament after 12 months of marine<br />
immersion. These analyses demonstrated a surface<br />
degradation of the monofilament, but the mechanical<br />
properties remained stable.<br />
A compostable geotextile<br />
A new generation of industrially compostable geotextile<br />
fences have been under development with an industrial<br />
partner since 2017 (Figure 3). These fences protect dunes from<br />
wind erosion and because they are sometimes entirely covered<br />
by sand, they are not systematically cleared away after use. In<br />
order to develop a more ecofriendly product, biodegradation<br />
studies on this woven geotextile have been carried out on a<br />
beach since January <strong>2019</strong>. A compostable beach access and<br />
soil protect carpet is also being developed.<br />
Compostable trammel fishing nets<br />
It was recently reported that a 12m French gillnetter (fishing<br />
boat) produces about 8000 kg of waste per year, most of which<br />
takes the form of fishing nets. In order to find an alternative<br />
end-of-life solution to landfill or incineration, a compostable<br />
trammel fishing net prototype was developed in <strong>2019</strong>.<br />
A trammel net is composed of three layers: the two outside<br />
layers are made from a 0.60 mm monofilament and the inside<br />
layer (fishing layer) is produced from a 0.33 mm monofilament.<br />
These trials allowed the prototypes to be assessed for flaws in<br />
order to improve the net quality.<br />
Figure 4 shows a piece of the produced fishing layer. At the<br />
moment, Seabird’s R&D office is working on the enhancement<br />
of some of the properties of the monofilaments, such as the<br />
abrasion resistance. Net production and fishing trials in real<br />
conditions are scheduled for 2020.<br />
Others perspective products<br />
The technical potential of Sea212 compound and its<br />
monofilaments improves with each challenge encountered<br />
in the projects. Seabird works with other partners to develop<br />
ropes, mussel gillnets and oyster pockets. Also, Seabird is<br />
reaching out to other application sectors such as household,<br />
packaging and medical textiles.<br />
www.seabird.fr<br />
By:<br />
Vincent Mathel<br />
Bioplastic engineer and project manager.<br />
ICCI SEA (“Seabird”)<br />
Lorient, France.<br />
Figure 3: Fence to protect the dunes<br />
Figure 4: Piece of trammel fishing net<br />
from the bio-monofilaments<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 19
Fibers & Textiles<br />
Monofilament melt spinning<br />
of biopolymer-blends<br />
By:<br />
Pavan Kumar Manvi, Jonas Hunkemöller and, Thomas Gries<br />
Institut für Textiltechnik ITA, RWTH University<br />
Aachen, Germany<br />
Several efforts have been made to produce biobased<br />
multifilament yarn for textile applications. While these<br />
have generated considerable interest, monofilament<br />
applications of biopolymers have not yet been sufficiently<br />
researched to allow their use in textile applications. In the<br />
present research, a monofilament spinning process is developed<br />
for biopolymer blends with the aim of producing<br />
biobased monofilaments for use in agrotextile applications.<br />
Arboblend 3327 V is a renewable resource-based product<br />
manufactured by Tecnaro (Ilsfeld, Germany). The potential<br />
of this polymer blend for multifilament melt spinning was<br />
studied within the scope of the projects “Tailor-made melt<br />
the speed of Duo 1 between 20 m/min and 100 m/min<br />
was experimented with, but to no avail. Other efforts were<br />
made to decrease the throughput to make the filament<br />
thinner and more flexible. This decreased the frequency of<br />
filament breaks, but failed to eliminate them completely.<br />
During the experiments, a brittle fracture (break) of the<br />
filament was observed, which, it was thought, could be due<br />
to intensive cooling and the brittle nature of polylactic acid<br />
(a component in Arboblend 3327 V) at room temperature.<br />
The water cooling of the molten filament was therefore<br />
removed and replaced by a single godet. As the cooling rate<br />
of the filament was expected to be slower with air cooling,<br />
brittle fracture of the filament would be less likely to occur.<br />
Hopper<br />
Extruder<br />
Spinning<br />
head<br />
Water<br />
bath<br />
Filament<br />
DUO 1 DUO 2<br />
Heated drawing chamber<br />
Fig. 1: Set-up of monofilament<br />
spinning machine with water bath<br />
Winder<br />
spinnable biopolymer compound for textured filament<br />
yarn, elastic combination yarn and other fibrous materials<br />
(BioKombiGarn)”, a two year project running from 2015 –<br />
2017 and “Starch-based textiles: Cost-effective textiles<br />
made from biopolymers (Star-Tex)”, which ran from 2015<br />
– 2018. The blend was shown to offer good spinnability. It<br />
was therefore chosen to use Arboblend 3327 V to develop a<br />
monofilament melt spinning process.<br />
For the development of a melt spinning process, a melt<br />
spinning set-up with single screw extruder, a spinning<br />
head, a water bath, two duo godets, one heating chamber<br />
and a winder was used, as shown in Fig. 1.<br />
The initial parameters shown in Tab. 1 were chosen on<br />
the basis of previous experiments with multifilament melt<br />
spinning of Arboblend 3327 V.<br />
Observations and results: Experiments were started<br />
with the machine set-up shown in Fig. 1 and the process<br />
parameters listed in Tab. 1. During the experiments,<br />
intensive filament breakage was observed at the first galette<br />
duo (Duo 1). To stop the filament break at Duo 1, varying<br />
Tab. 1: Initial process parameters<br />
for monofilament melt spinning of<br />
Arboblend 3327 V<br />
Parameter Unit Value<br />
Extruder temperature zone 1 °C 180<br />
Extruder temperature zone 2 °C 200<br />
Extruder temperature zone 2 °C 220<br />
Spinning pump temperature °C 220<br />
Spinning head temperature °C 220<br />
Through put of spinning pump g/min 5.9<br />
Speed of drawing godet set 1 (Duo1) m/min 50<br />
Speed of drawing godet set 2 (Duo2) m/min 100<br />
Temperature of heating chamber °C 180<br />
Speed of winder m/min 201<br />
Aimed fineness dtex 70.4<br />
A schematic view of the machine set-up with a mono<br />
take-up godet is shown in Fig. 2.<br />
20 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Fibers & Textiles<br />
Hopper<br />
Extruder<br />
Spinning<br />
head<br />
Filament<br />
Fig. 2: Set-up of monofilament<br />
spinning machine mono godet<br />
Winder<br />
Take-up<br />
godet<br />
DUO 1 DUO 2<br />
Heated drawing chamber<br />
It was observed that after replacing the water bath<br />
with the godet, the filament could be passed through the<br />
first godet duo successfully. This led to the conclusion<br />
that monofilaments containing brittle polymers should<br />
preferably be cooled by air to prevent an increase in<br />
brittleness.<br />
Subsequent experiments were conducted using the setup<br />
shown in Fig. 2. Further challenges were observed when<br />
passing the filament through a heated drawing chamber. As<br />
soon as the filament passed through the heated chamber<br />
and the second godet duo, filament break occurred. After<br />
several trials, this problem remained, meaning it could<br />
not be considered an artefact of the experiment. Further<br />
improvement in the set-up and the process parameters<br />
became necessary.<br />
One hypothesis to explain the phenomenon was that a<br />
sudden increase in the filament temperature resulted in too<br />
little tension on the filament. This in turn caused slugging,<br />
leading to breakage of the filament in contact with the<br />
bottom of heating chamber. By decreasing the temperature<br />
of the heated drawing chamber it was thought that the<br />
problem could be solved. This was tested by lowering the<br />
temperature by 10 °C steps. As the temperature of the<br />
heated drawing chamber dropped, the number of filament<br />
breaks also decreased. The temperature was therefore<br />
lowered to 100°C, at which point a significant improvement<br />
in the process stability was observed.<br />
Another approach to solving the problem was to increase<br />
the draw ratio, which would increase the tension on the<br />
filament and thus avoid or reduce the slugging of the<br />
filament. To test this, the draw ratio between Duo 1 and<br />
Duo 2 was increased by decreasing the speed of Duo 1<br />
and increasing the speed of Duo 2. This approach again<br />
improved the process stability.<br />
The optimization of the process parameters led to a stable<br />
process. However, some sudden breaks were still observed<br />
in the heated drawing chamber during a continuous run<br />
of the filament. It was concluded that a movement of the<br />
filament on Duo1 and Duo 2 caused sudden contact of the<br />
monofilament with the wall of the heated chamber, leading<br />
to filament break. To avoid this, two filament guides were<br />
placed at the entrance and at the exit of the heated drawing<br />
chamber to ensure a continuous pass of the monofilament<br />
through the heated drawing chamber without contact with<br />
the hot surface.<br />
The changes in the process and the machine set-up<br />
outlined above enabled a stable monofilament melt spinning<br />
process with Arboblend 3327 V polymer. The process<br />
parameters for a stable monofilament melt spinning<br />
process with Arboblend 3327 V polymer are shown in Tab. 2.<br />
A successful monofilament melt spinning process with<br />
biobased Arboblend 3327 V polymer could be established<br />
and a melt spun monofilament is shown in Fig. 3.<br />
The melt spun Arboblend 3327 V monofilament was also<br />
tested for its mechanical and shrinkage properties. These<br />
properties are shown in Tab. 3.<br />
Tab. 2: Process parameters for a stable monofilament melt<br />
spinning process with Arboblend 3327 V polymer<br />
Parameter Unit Value<br />
Extruder temperature Zone 1 °C 180<br />
Extruder temperature Zone 2 °C 190<br />
Extruder temperature Zone 2 °C 200<br />
Spinning pump temperature °C 200<br />
Spinning head temperature °C 200<br />
Through put of spinning pump g/min 8.8<br />
Speed of mono godet m/min 27<br />
Speed of Duo 1 m/min 30<br />
Speed of Duo 2 m/min 150<br />
Temperature of heating chamber °C 100<br />
Speed of Winder m/min 153<br />
Fig. 3: Arboblend 3327 V monofilament bobbin<br />
Tab. 3: Properties of Arboblend 3327 V monofilament<br />
Property<br />
Unit<br />
Arboblend 3327 V<br />
monofilament<br />
Monofilament fineness dtex 141<br />
Tensile strength cN/tex 28,28<br />
Breaking elongation % 26,51<br />
Hot air shrinkage % 27,49<br />
www.ita.rwth-aachen.de<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 21
Fibers & Textiles<br />
Alternative materials for<br />
mussel socks<br />
By:<br />
Bas Krins<br />
Technical Manager<br />
Senbis Polymer Innovations<br />
Emmen, The Netherlands<br />
Mussel cultivation involves a number of different<br />
steps. In The Netherlands mussel seed is collected<br />
on ropes hanging in the Waddenzee. The seed is<br />
harvested from these ropes and collected. Subsequently<br />
this seed is used for the cultivation of mussels. This can be<br />
done on the bottom of the sea. But more than 95 % of all<br />
mussels produced worldwide are grown on ropes. In that<br />
case, mussel seed is attached to a rope hanging in the sea.<br />
While there are various ways to ensure the mussel seed becomes<br />
attached to the rope, a common one is by using a<br />
so-called mussel sock. This sock is placed around the rope<br />
and the space between the rope and the sock is filled with<br />
mussel seed. This allows the mussels to grow and adhere<br />
to the rope. After about one month, the mussel sock is no<br />
longer required to support the mussels and should then<br />
start degrading. If the sock does not degrade in time, it will<br />
hamper the further growth of the mussels.<br />
The mussel sock<br />
Usually the mussel sock is produced from cotton by a<br />
knitting technique. This material has several disadvantages.<br />
The multifilament yarn developed was successfully<br />
processed on existing knitting machines for mussel socks.<br />
These mussel socks are now being tested in live mussel<br />
cultivation conditions at Blackshell Farm in Westport,<br />
Ireland. The degradation time is about a month in sea water<br />
and can be tuned by the diameter of the filaments and the<br />
composition of the compound. In the next months Senbis<br />
will optimize the yarn and set-up the requirements for<br />
market entry.<br />
www.senbis.com<br />
The degradation time can be adjusted somewhat by<br />
varying the thickness of the yarn. This means that in<br />
areas where mussels grow slower because of the low<br />
temperature of the water, for example off the coast of<br />
Iceland, the sock will degrade too fast. As a consequence,<br />
the part of the mussel seed not attached to the rope when<br />
the net degrades will be lost.<br />
A second issue relates to the environmental consequences<br />
of the use of cotton. Cultivating cotton requires larger<br />
amounts of water. Pesticides are also used. Hence<br />
customers seeking to market mussels under a biologically<br />
farmed label will suppliers of mussels not to use cotton.<br />
The challenge<br />
Senbis (Emmen, The Netherlands) is cooperating with<br />
Machinefabriek W. Bakker (Yerseke, The Netherlands), a<br />
supplier of equipment for the mussel industry, in order to<br />
develop a yarn that can serve as an alternative for cotton<br />
in this application. The degradation time in sea water<br />
must be similar to that of cotton, i.e. about a month.<br />
Very few biopolymers can fulfil this requirement as most<br />
do not biodegrade sufficiently quickly in sea water. In<br />
addition, the mechanical properties have to be sufficient<br />
for this application. This combination, fast degradation<br />
and mechanical properties, could not be realized with<br />
existing polymers. But by making a compound based on<br />
thermoplastic starch and other polymers, Senbis has been<br />
able to develop a material that can be converted into a<br />
multifilament yarns with sufficient tenacity and elongation.<br />
22 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Fibers & Textiles<br />
Cellulose based fibers fully<br />
biodegradable in water, soil<br />
and compost<br />
The Lenzing Group (Lenzing, Austria) received confirmation<br />
of the full biodegradability of its fibers in fresh<br />
water by the independent research laboratory Organic<br />
Waste Systems (OWS) (Ghent, Belgium). The new and existing<br />
international certifications conducted by OWS and issued<br />
by TÜV Austria (Kraainem, Belgium) verify that LENZING<br />
Viscose fibers, LENZING Modal fibers and LENZING Lyocell<br />
fibers are biodegradable in all natural and industrial<br />
environments: in the soil, compost as well as in fresh and<br />
in marine water.<br />
The biodegradability of cellulosic products and the<br />
synthetic fiber polyester was tested in fresh water at<br />
OWS according to valid international standards, e.g. ISO<br />
14851. At the end of the trial period, Lenzing wood-based<br />
cellulosic fibers, cotton and paper pulp were shown to be<br />
fully biodegradable in fresh water in contrast to synthetic<br />
polyester fibers. The fact that synthetic materials are not<br />
biodegradable leads to major problems in wastewater<br />
treatment plants and potentially marine litter. In turn, this<br />
not only harms fish and birds living in and close to the<br />
oceans but also all marine organisms and us humans.<br />
“The Lenzing Group operates a truly circular business<br />
model based on the renewable raw material wood to<br />
produce biodegradable fibers returning to nature after use.<br />
This complete cycle comprises the starting point of the core<br />
value of sustainability embedded in our company strategy<br />
sCore TEN and is the ‘raison d’etre’ of our company”, says<br />
Stefan Doboczky, Chief Executive Officer of the Lenzing<br />
Group. “In living up to this positioning, we not only enhance<br />
the business of our suppliers, customers and partners<br />
along the value chain but also improve the state of the<br />
entire textile and nonwovens industries.”<br />
Both the textile and nonwovens industries face huge<br />
challenges with respect to littering. Therefore, legislative<br />
bodies worldwide can no longer ignore the issue and have<br />
moved towards plastics legislation aimed at limiting the<br />
vast amount of waste. In response, European lawmakers<br />
issued the Single-Use Plastics Directive currently being<br />
transposed into national legislation in the EU member<br />
states.<br />
Conventional wet wipes and hygiene products mostly<br />
contain plastic and were thus identified as one of the product<br />
categories to be singled out. Less polluting alternatives<br />
are generally encouraged by NGOs and legislators, e.g.<br />
products made of biodegradable wood-based cellulosic<br />
fibers. Plastic waste including microplastic can persist in<br />
the environment for centuries. In contrast, biodegradable<br />
materials are the best alternative to single-use plastics<br />
because they fully convert back to nature by definition and<br />
thus do not require recycling. MT<br />
www.lenzing.com<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 23
Fibers & Textiles<br />
PLA-fibres<br />
in medical<br />
applications<br />
New composite material for<br />
non-acidic degradation of<br />
medically used PLA<br />
PLA<br />
3D-printing<br />
+<br />
Microgel<br />
Solution<br />
spinning<br />
Electrospinning<br />
Fig. 2: In the framework of the pHMed project<br />
different processes for achieving PLA structures on<br />
various scales are developed<br />
Fig. 1: Wet spinning<br />
equipment for PLAfilament<br />
spinning<br />
By:<br />
Georg-Philipp Paar<br />
Dept. of Biohybrid & Medical Textile (BioTex)<br />
Institut für Textiltechnik der RWTH Aachen University<br />
Aachen, Germany<br />
Biodegradable materials, such as polyglycolic acid<br />
(PGA) and polylactic acid (PLA), are used commercially<br />
in medicine for sutures, osteosynthesis systems<br />
and drug delivery systems. The degradation of these materials<br />
inside the body offers a big advantage in implants,<br />
like meshes and support structures (scaffolds), as a second<br />
operation for removal is not necessary and long-term foreign<br />
body reactions are prevented. Furthermore, a gradual<br />
reduction of the mechanical support function is possible,<br />
which allows load transfer from the temporary structure to<br />
the healing tissue, unlike when using metal implants.<br />
However, the degradation of PLA and PGA in the body is<br />
problematic, as acidic degradation products are released,<br />
which can cause a local acidosis. This may lead to<br />
inflammation or even tissue death.<br />
To compensate the acidic environment and local drop of<br />
the pH in the tissue buffering salts were incorporated in<br />
PGA filaments in the cooperation of the Dept. of Biohybrid<br />
& Medical Textiles (BioTex) and the Institut für Textiltechnik<br />
ITA (both RWTH Aachen University). Unfortunately, the<br />
buffering capacity was insufficient and the salts caused<br />
instabilities in the spinning process. A promising alternative<br />
are amine based microgels, developed by the DWI - Leibniz<br />
Institute for Interactive Materials (also RWTH Aachen<br />
University). These colloidal polymers show a high buffering<br />
capacity while being suitable for the use in medical products<br />
because of a good biocompatibility.<br />
PLA filaments with microgels were dry spun, as the<br />
microgels function is preserved only at low temperatures.<br />
The buffering of the pH value was successful, but the<br />
filaments showed a low tensile strength with a high<br />
variation in values. Current research results show that<br />
a wet spinning process is a promising alternative, as it<br />
allows production of PLA filaments with increased tensile<br />
strength. First experiments indicate that the filaments can<br />
be processed further by braiding and knitting technology to<br />
produce sutures and scaffolds.<br />
In addition to the production of textile filaments also other<br />
manufacturing processes are developed within the project<br />
pHMed. For example, the DWI integrated the microgels into<br />
electrospun nonwovens, which could be used for skin or<br />
cartilage replacement. The EnvisionTec GmbH (Gladback,<br />
Germany) tries to incorporate microgels into 3D printed<br />
PLA structures. With this flexible process it is possible to<br />
build up three-dimensional structures, which can be used<br />
for stabilizing materials after a bone fracture. An important<br />
aspect for industrialization of the material – the upscaling<br />
of the microgels synthesis – is investigated as well by DWI<br />
within the framework of the project.<br />
Acknowledgement: The Project pHMed is supported by<br />
the European Regional Development Fund North Rhine-<br />
Westphalia (EFRE.NRW).<br />
www.biotex-aachen.de | www.ita.rwth-aachen.de<br />
24 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
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bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 25
Report<br />
Inauguration of the world’s<br />
second largest PLA plant<br />
Total Corbion PLA’s first 75,000 tons per year bioplastics<br />
plant officially opened in Rayon/Thailand<br />
By:<br />
Michael Thielen<br />
T<br />
otal Corbion PLA, a 50/50 joint venture between Total and<br />
Corbion, officially inaugurated its 75,000 tonnes per year<br />
PLA (Poly Lactic Acid) bioplastics plant in Rayong, Thailand<br />
on Sept. 09, <strong>2019</strong>. The world’s second largest PLA plant is located<br />
on the same premises, right next to a lactic acid plant of Corbion.<br />
It was finished in mid 2018 and commissioned end of 2018. As of<br />
yet, the PLA plant has produced more than 20,000 tonnes of PLA.<br />
The Grand Opening ceremony was chaired by Ms. Duangjai<br />
Asawachintachit, Secretary General of the Thailand Board of<br />
Investment (BOI). The event was opened with a traditional religious<br />
ceremony in which the plant was blessed by Buddhist monks.<br />
Honorable guests included Dr. Somchint Pilouk from the<br />
Industrial Estate Authority of Thailand, Mr. Jirasak Tapajot,<br />
Banchang District Chief, H.E. Jacques Lapouge, the French<br />
Ambassador, and H.E. Kees Rade, the Dutch Ambassador (in<br />
absentia). bioplastics MAGAZINE participated in the Grand Opening<br />
and spoke to different representatives on Total Corbion PLA and<br />
Corbion.<br />
“This opening is an important milestone for us and the circular<br />
economy,“ said Stéphane Dion, CEO of Total Corbion PLA. “The<br />
strategic fit between Corbion and Total is no less than perfect.<br />
Benefitting from the lactic acid supply of Corbion and benefitting<br />
from Total’s expertise in polymer technology and its sales network<br />
we are poised to become a major player in the PLA industry.<br />
With this plant we demonstrate how passionate we are about<br />
contributing to a circular economy.”<br />
“The creation of sustainable growth with PLA bioplastics truly<br />
fits with our ambition to build new business platforms, applying<br />
disruptive technologies. PLA bioplastics will also drive further<br />
development and growth of Lactic Acid, which is at the centre<br />
of Corbion’s strategy to develop sustainable ingredient solutions<br />
to improve the quality of life for people today and for future<br />
generations,” said Marc den Hartog, Executive Vice President<br />
Innovation platforms of Corbion.<br />
“I’m very pleased to inaugurate Total<br />
Corbion PLA’s plant today, which has started<br />
up rapidly and now serves customers all<br />
around the globe” said Valérie Goff, Senior<br />
Vice President Polymers at Refining &<br />
Chemicals, Total. “PLA bioplastics<br />
will help meeting the rising<br />
demand for polymers<br />
while contributing to<br />
reducing end-of-life<br />
concerns.”<br />
Les 2 Vaches’<br />
yoghurt pot. Les 2<br />
Vache is an organic<br />
brand within the<br />
Danone family. The<br />
product launched<br />
in April this year<br />
The official ribbon<br />
cutting was performed<br />
by Ms. Duangjai Asawachintachit, the French Ambassador,<br />
Stéphane Dion, as well as the two parent companies of the joint<br />
venture, represented by Valérie Goff, together with Marc den<br />
Hartog. Thereafter, attendees were given a guided tour of the<br />
facility.<br />
Total Corbion’s Luminy PLA<br />
The new 75,000 tonnes per year facility currently produces ten<br />
different grades of Luminy ® PLA. “This is the widest range of<br />
PLA grades available on the market today,” said François de Bie,<br />
Senior Marketing Director of Total Corbion PLA, “covering all kind<br />
of grades from pure PDLA through pure PLLA”. Total Corbion PLA<br />
is the only resin manufacturer producing pure PDLA. “This is one<br />
of our key products and it allows us also to produce the high heat<br />
resistant stereocomplex PLA types,” François added.<br />
The new plant started production in December 2018 and has<br />
so far produced over 20,000 tonnes of different PLA grades. “The<br />
PLA went to a mix of different applications,” François continued.<br />
“The biggest part of our production goes for flexible packaging<br />
applications. Another significant amount is being compounded<br />
with e.g. PBAT and/or starch for different bag applications.”<br />
Depending on the required strength of the bags or the desired<br />
The plant was first blessed by monks in a religious ceremony<br />
Stéphane Dion, CEO Total Corbion PLA<br />
26 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Report<br />
100,000 tonne/annum lactide plant<br />
composting speed, the amount of PLA in the blends is higher or<br />
lower. For more rigid bags for multiple usage the PLA amount is<br />
higher, whereas for home-compostability for instance, it is lower.<br />
Another big field of applications is catering serviceware, such<br />
as thermoformed cups, plates and trays and injection moulded<br />
cutlery. Some smaller customers receive PLA for 3D-printing<br />
filaments. Spun into fibres, the PLA is also delivered for<br />
applications like nonwovens for e.g. teabags or hygiene products<br />
such as wet wipes.<br />
Blends of PLA and PHA are being used for example for a<br />
compostable PLA/PHA-based potato chip packaging developed by<br />
Pepsico and Danimer, now supplied to Chile as a test market. PLA/<br />
PHA-based drinking straws from Danimer are another innovation<br />
that help reduce the environmental impact of plastics.<br />
Being 100 % biobased Total Corbion’s PLA offers an alternative<br />
solution to traditional, comparable products made from fossil<br />
oil and its derivatives. The significant sustainability benefits over<br />
their fossil-based counterparts, like a reduced CO 2<br />
footprint and<br />
a reduced dependency on fossil resources contribute to solutions<br />
within the framework of today’s climate policy discussions.<br />
Geographically the biggest market of Total Corbion PLA is<br />
Europe, followed by Asia/Pacific and the Americas.<br />
“The demand for PLA is significantly higher than we can meet at<br />
the moment,” said François de Bie. One bottleneck at the moment<br />
is the capacity of Corbion’s latic acid plant, which is currently being<br />
increased. Strategically speaking François added “This is our first<br />
PLA plant, but with the market demand we are seeing and two<br />
strong parent companies we are certainly looking into further<br />
expansions.”<br />
Locally sourced sugar<br />
The Luminy PLA resins are made from renewable, non-GMO<br />
sugarcane sourced locally in Thailand. Of the total raw sugar<br />
production of Thailand of annually about 35 million tonnes, Total<br />
Corbion needs just 150,000 tonnes. And for Corbion and Total<br />
Corbion PLA it is quite important where the sugar comes from.<br />
“We seriously look at the quality of the sugar,” Marc den Hartog<br />
told bioplastics MAGAZINE. “This, together with how the sugar<br />
is grown and harvested including social responsibility, is more<br />
important than sourcing the sugar from the shortest distances.“<br />
One of the major local sugar supply partners of Corbion in Thailand<br />
is the company Mitr Phol, headquartered in Khlong Toei, Bangkok.<br />
In fact, the selection and the subsequent sustainable sourcing<br />
of these feedstocks is driven by a number of sustainability aspects.<br />
Corbion’s approach to a sustainable supply chain and responsible<br />
sourcing is founded on principles of ethical business practices,<br />
human and labor rights and environmental protection. For this<br />
reason the company has developed its Cane Sugar Code. Corbion’s<br />
code is based on the definitions for sustainable sugarcane and<br />
derived products as set out by Bonsucro. Bonsucro is a global,<br />
non-profit, multi-stakeholder organization founded by WWF in<br />
20<strong>05</strong>. Part of Bonsucro’s activities is the creation of the “Bonsucro<br />
Production Standard”, which covers five key principles: obey the<br />
law, respect human rights and labor standards, manage input,<br />
production and processing efficiencies to enhance sustainability,<br />
actively manage biodiversity and ecosystem services and lastly,<br />
continuously improve key areas of the social, environmental and<br />
economic sustainability. In 2017, Total Corbion PLA became the<br />
first company to offer PLA bioplastic resins made from Bonsucro<br />
ceritified sugar to the market.<br />
100,000 tonnes/annum lactide plant<br />
In addition to the PLA plant, Total Corbion PLA operates a 100,000<br />
tonnes per year lactide plant, which produces the monomer<br />
required for the production of PLA, a 1,000 tonnes per year PLA<br />
pilot plant for product development, and a chemical recycling<br />
facility, currently used for recycling of production waste. Combined<br />
with Corbion’s lactic acid plant, located on the same site, this<br />
enables a fully integrated production chain from sugar to PLA.<br />
www.total-corbion.com<br />
Ribbon Cutting<br />
François de Bie<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 27
ioplastics MAGAZINE<br />
and European<br />
Bioplastics<br />
The joint booth of<br />
bioplastics MAGAZINE and<br />
the industry association<br />
European Bioplastics,<br />
will again be a hub for all<br />
visitors interested in these<br />
trendsetting materials.<br />
More than 175 companies<br />
will present their bioplastics<br />
products and services in<br />
Düsseldorf. So the joint<br />
booth will assist everyone<br />
to find the right company<br />
for their needs. In addition,<br />
bioplastics MAGAZINE will<br />
present the trade journal, the<br />
smartphone and tablet app,<br />
their books and consulting<br />
services and finally their<br />
conference programme. The<br />
latter includes the Bioplastics<br />
Business Breakfast, now<br />
organized already for the<br />
fourth time (see pp 10 for<br />
details).<br />
www.bioplasticsmagazine.com<br />
www.european-bioplastics.org<br />
7a / B10<br />
Show<br />
Preview<br />
K <strong>2019</strong>, known as “The World’s No. 1<br />
Trade Fair for Plastics and Rubber” and<br />
scheduled to take place in Düsseldorf<br />
from 16 to 23 October <strong>2019</strong>, is fully booked.<br />
Over 3,000 exhibitors from more than 60<br />
countries have registered to participate,<br />
and more than 200,000 trade visitors from<br />
all over the world are expected to come to<br />
the event. And this year again, bioplastics<br />
will play a major role at the K-show.<br />
K is the performance barometer for the<br />
entire industry and its global marketplace<br />
for innovations. For eight days, the “Who’s<br />
Who” of the entire plastics and rubber<br />
world will meet here to demonstrate the<br />
industry’s capabilities, discuss the latest<br />
trends and set the course for the future. K<br />
<strong>2019</strong> also addresses the current challenges<br />
of our era and especially of its sector, first<br />
and foremost in regard to “plastics for<br />
sustainable development” and the “circular<br />
economy”.<br />
The idea of the circular economy concept<br />
is quite simple: once used, valuable raw<br />
material can be processed at the end of<br />
its service life and be reused to create a<br />
new product – in an infinite loop. A vast<br />
array of polymer materials are perfectly<br />
suitable for this approach. A circular<br />
economy dramatically reduces waste and<br />
also protects the resource of crude oil.<br />
However, the implementation of a circular<br />
economy is still very much in its infancy.<br />
Many prerequisites still have to be met.<br />
Product design is important: recyclability<br />
should become an important aspect that<br />
comes in the early product development<br />
stages. A waste collecting system has to<br />
be implemented as well as recycling. We<br />
need technologies that allow cleaning,<br />
segregation, shredding and pelletizing of<br />
used plastics to ensure that it is ready to<br />
reuse in the production of plastic parts.<br />
Networking waste management and<br />
recycling with production is a core aspect<br />
of the circular economy concept. And so<br />
are bioplastics.<br />
These issues will play a major role not<br />
only at the exhibitors’ stands but also in<br />
the supporting programme of K <strong>2019</strong>, e.g.<br />
the 4 th Bioplastics Business Breakfast<br />
conferences hosted by bioplastics<br />
MAGAZINE (see pp 10 for details) as well<br />
as the special exhibition “Plastics Shape<br />
the Future” and “VDMA Circular Economy<br />
Forum” the joint appearance of the VDMA<br />
(Verband Deutscher Maschinen- und<br />
Anlagenbau – The Mechanical Engineering<br />
Industry Association) and its member<br />
companies.<br />
(Foto: Messe Düsseldorf / ctillmann)<br />
On the following pages a number of<br />
companies present their exhibits at K <strong>2019</strong>.<br />
This will be rounded off by a comprehensive<br />
K-show-review in issue 06/<strong>2019</strong>.<br />
Kompuestos<br />
Kompuestos (Palau Solità i Plegamans,<br />
Spain) will be presenting its latest<br />
innovations. Between other cutting-edge<br />
products designed to reduce environmental<br />
impact, Kompuestos has developed<br />
Biokomp, a range of fully compostable<br />
resins, duly certified according to EN 13432.<br />
Biokomp grades are based on proprietary<br />
thermoplastic starch and other renewable<br />
sources. Biokomp offers the ideal solution<br />
for products with a short life cycle such as<br />
single-use products.<br />
Kompuestos has been providing tailor<br />
made solutions for the plastic industry<br />
for over 30 years. Driven by innovation,<br />
Kompuestos has been able to develop<br />
and implement new products while<br />
maintaining a sustainable and continuous<br />
growth of over 15 % per years.<br />
www.kompuestos.com<br />
7.1 / A10<br />
28 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
K‘<strong>2019</strong> Preview<br />
FKuR<br />
FKuR (Willich, Germany) will be showcasing its expanded<br />
portfolio of biobased thermoplastics for a growing range<br />
of applications including packaging, consumer products,<br />
sporting goods and technical parts.<br />
Current additions to the portfolio include two glassreinforced<br />
grades within the Bio-Flex ® and Terralene ® product<br />
family, both with high rigidity, and three Terraprene ® TPE<br />
grades, one of which is characterized by its high bio-content,<br />
while the other two are oil-free.<br />
Bio-Flex GF30 is a PLA based compound with a glass fiber<br />
content of 30 wt % and a biobased carbon content (BBC) of over<br />
70% (calculated). This combines a relatively high stiffness of<br />
around 8,400 MPa with an equally high tensile strength of 70 MPa<br />
(ISO 527) and a good notched impact strength of 6.4 kJ/m².<br />
Applications examples include housings, castors, gears,<br />
sports equipment, orthotic devices, pipes and pipe systems.<br />
Terralene GF30 is a Green PE compound with a glass fiber<br />
content of 30 wt % and a calculated BCC of more than 94 %.<br />
The stiffness of 4.800 MPa is significantly higher than that<br />
of the mineral-filled grades with a wear resistance which<br />
is superior to the unfilled grades. It offers a wide range of<br />
applications, ranging from engineering parts to tubes and<br />
tube systems, dowels and brackets for the construction<br />
industry, orthotic devices and design products.<br />
New within the biobased Terraprene TPE compounds<br />
family are the grades SI 701 and SI 801 (calculated BBC 55%<br />
- 75%). They are available in Shore A40 to A80 grades and<br />
their properties are largely similar to those of conventional<br />
TPE-S grades. Typical applications include two-component<br />
injection molding, especially with polyolefins, which provide<br />
good adhesion.<br />
Terraprene CI 250 84A and Terrapene CI 450 93A are two oilfree<br />
TPEs with Shore A hardness of 84 or 93. With their softtouch<br />
surface, high resistance to kinking and deformation,<br />
they can substitute TPE-O and PVC in many injection molding<br />
applications.<br />
www.fkur.com<br />
6 / E48<br />
Ventilation covers (as shown in this example) are a possible<br />
application for the new glass fiber reinforced Bio-Flex and Terralene<br />
compounds from FKuR. (www.istockphoto.comSadeugra)<br />
ADBioplastics<br />
ADBioplastics (Valencia, Spain) is a startup dedicated to the<br />
development and commercial exploitation of custom-made<br />
bioplastics. Their material is biobased and biodegradable/<br />
compostable. From the origin because they are produced<br />
by corn, sugar cane, and sugar beet to renewable and<br />
biodegradable. The material goes down by 90 % within six<br />
months in an industrial composting process. A process that<br />
will help our target, packaging manufacturers in the food<br />
sector to fulfill the EU´s Strategy of plastic reduction by 2030<br />
as well as contribute to make the world a better place to live,<br />
our leitmotiv.<br />
With their background (ITENE spin-off) they are able to<br />
modify PLA into a PLA-Premium and improve its properties<br />
such as higher barrier OTR/WVTR than conventional PLA,<br />
thermal stability and improved mechanical properties,<br />
tunable transparency an good processability. All these meet<br />
the requirements demanded in the food sector.<br />
www.adbioplastics.com<br />
Albis / Dr. BOY<br />
5 / E01<br />
Dr. BOY, manufacturer of injection moulding machines from<br />
Neustadt-Fernthal, Germany, is planning an extensive live<br />
show at K <strong>2019</strong>. The company will spray produce 2-component<br />
(2K) ice scrapers, design trays and magnifiers continuously<br />
and at high frequency on various machines. The biobased<br />
plastic solutions for this demonstration will be supplied by<br />
Albis Plastic (Hamburg, Germany).<br />
"We want to offer our visitors something, so they can see for<br />
themselves the high quality of our injection moulding machines<br />
live," says Michael Kleinebrahm, Head of BOY Application<br />
Technology. "At the same time, we want to take responsibility<br />
and rely on biobased plastics. ALBIS products combine the<br />
highest quality with sustainability, that convinced us".<br />
CELLIDOR ® CP 410-10 BK 32/082 is used for the<br />
design trays. Cellidor is a plastic based on cellulose from<br />
sustainable, natural sources of raw materials, which ALBIS<br />
is compounding. It is characterised by an excellent gloss,<br />
a very good depth effect and self-polishing property. The<br />
magnifying glass contains Cellidor CP 400-10 CC, which is<br />
characterized by high transparency (comparable to PMMA)<br />
and a self-polishing surface. ALBIS supplies an ALFATERXL ®<br />
ECO with Shore A75 hardness as a soft component for the 2K<br />
ice scraper (2K with PP/LyondellBasell´s Adstif HA 840 R). It<br />
is recommended for this application due to good 2K adhesion<br />
on polyolefins in combination with 100% PP recyclate and<br />
biobased EPDM.<br />
And finally, on the booth of bioplastics MAGAZINE and<br />
European Bioplastics (7a/B10) paperclips made with<br />
Mitsubishi Chemical's Durabio TM are produced on a BOY XXS<br />
machine.<br />
www.albis.com | www.dr-boy.de<br />
8b/A61( Albis) 13/A43 (Dr. Boy) B03-03<br />
Please visit<br />
www.bioplasticsmagazine.com<br />
for updated information<br />
about K‘<strong>2019</strong>.<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 29
Novamont<br />
In collaboration with a number of leading machine<br />
manufacturers, Novamont, the world’s leading company in<br />
the sector of bioplastics and the development of bioproducts<br />
obtained from the integration of chemistry, environment<br />
and agriculture, will be presenting extrusion testing and the<br />
complete production cycle of MATER-BI fruit and vegetable<br />
bags. It will be an occasion to see first-hand the transparency<br />
and mechanical characteristics of biodegradable and<br />
compostable bags produced with a 50 % renewable content.<br />
The Italian company from Novara has always been driven<br />
by innovation and investment in R&D. It develops new<br />
proprietary technologies with which to constantly improve the<br />
performance and environmental profile of its products.<br />
The development model adopted starts with the local areas.<br />
It creates integrated biorefineries by rehabilitating industrial<br />
sites that have fallen into disuse, respecting the specific<br />
characteristics of the local areas, in partnership with all the<br />
stakeholders in the value chain.<br />
In an approach that is both cultural and industrial, jobs<br />
are created and competitiveness restored, while local skills<br />
are enhanced and training programmes rolled out at various<br />
levels.<br />
www.novamont.com<br />
Carbiolice<br />
6 / A58<br />
CARBIOLICE (Riom, France) has developed a unique and<br />
disruptive technology to fight white pollution, using enzymes<br />
to accelerate at least by 30 % (measured by OWS) the<br />
compostability and biodegradability of PLA-based materials.<br />
Under the trade name EVANESTO ® , this innovative patented<br />
concentrate is universal and compatible with any PLA-based<br />
compounds, best suited for applications such as single-use<br />
plastics, but also films, bags for biowaste collection, food<br />
packaging, coffee-pod… In fact, all applications in which<br />
composting is a meaningful end-of-life and where reuse or<br />
recycling have reached their limits.<br />
PLA is naturally compostable, but its decomposition takes<br />
too long according to norms to be certified OK Compost Home,<br />
i.e. in domestic conditions. Thanks to Evanesto upgrading<br />
PLA, it is now possible to compost PLA-based products at<br />
home, and improve its positive impact on the environment.<br />
In compost, PLA will be disintegrated in less than 6 months,<br />
according to norms EN 13432 and NF T51-800.<br />
Developed as a Masterbatch, Evanesto can be used<br />
on conventional plastic transforming processes without<br />
adaptation or investments.<br />
Carbiolice latest technological advances will simplify<br />
composting certification procedure for all the PLA industry..<br />
www.carbiolice.com 5 / D04-03<br />
Agiplast<br />
Agiplast (Casalbuttano, Italy) is a world leader group in<br />
polymer compounding and regeneration since 1994.<br />
The company has developed a large range focused<br />
on the polyamides as well as fluoropolymers and other<br />
thermoplastics. They are distributed through 2 business units<br />
and 4 brands including RGN by Agiplast, the feeding brand<br />
guaranteeing the sustainable origin of the raw material.<br />
Thanks to its intensive international activity, Agiplast exports<br />
worldwide its high quality products in most of European,<br />
American, Asian and African countries.<br />
The mission of Agiplast, plastic compound manufacturer,<br />
is to be a protagonist in the engineering plastic market in<br />
offering sustainable solutions to the companies interested<br />
in decreasing the planet resources use and improving their<br />
proposals to the consumers.<br />
That is why the brand RGN by Agiplast has been created<br />
in order to offer to the consumers confidence in using<br />
regenerated raw materials with first choice quality.<br />
www.agiplast-group.com<br />
Omya<br />
Omya (Cologne, Germany) is presenting Omya Smartfill ®<br />
55 - OM, a new functionalized Calcium Carbonate for use in<br />
biopolymers and in particular Polylactic Acid (PLA).<br />
Conventional Calcium Carbonate products lead to PLA<br />
degradation because of hydrolysis during processing. Omya<br />
Smartfill 55 - OM demonstrates almost no hydrolysis when<br />
processed at filler loads of up to 40 %. At the same time,<br />
the addition of Omya Smartfill 55 – OM in films, sheets and<br />
injection molded items improves product stiffness, impact<br />
resistance, elongation, heat transfer, and it contributes to an<br />
overall reduction in formulation cost.<br />
Omya Smartfill 55 - OM is food contact compliant according<br />
to (EU) Regulation No 10/2011 and FDA approved. It also<br />
passes the compostable evaluation criteria for heavy metals,<br />
fluorine and ecotoxicity, outlined in the European norm EN<br />
13432.<br />
This new product reflects the company’s commitment to<br />
offer sustainable and innovative solutions for the plastics<br />
industry.<br />
www.omya.com<br />
6 / D75<br />
7.0 / B25<br />
30 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
K‘<strong>2019</strong> Preview<br />
Polykum<br />
Two Polykum members – Yizumi and Exipnos – celebrate<br />
a world premiere on the Booth of POLYKUM (Merseburg,<br />
Germany), that will find especially the interest of biopolymer<br />
processors. The new Direct Compounding Injection Molding<br />
(DCIM) system allows gentle, continuous processing with<br />
lowest shear and heat stress. Burdensome impacts like<br />
heating up, cooling down and granulating are eliminated. It<br />
saves energy, time and money. The CO 2<br />
-savings of up to 264 kg<br />
per ton of processed material minimize the ecological<br />
footprint of the final products significantly.<br />
On the Polykum booth visitors can follow the live production<br />
of design coffee cups of 100 % biobased and biodegredable<br />
compound. The exhibition unit consists of a standard injction<br />
moulding machine and the brand new Yizumi DCIM Compound<br />
Delivery System (CDS 35, on the photo on the right).<br />
The DCIM CDS module mixes the ingredients just where<br />
and when the compound is needed to be processed. Docked<br />
directly on the injection molding machine the CDS delivers it<br />
instantly to the injection unit.<br />
The joint project of Yizumi and Exipnos is 100 % in line<br />
with the Polykum politics. The german non-profit association<br />
hosts the congress „Biopolymer – Processing & Moulding“<br />
and offers the „Biopolymer Innovation Award“.<br />
www.polykum.de<br />
Gema Polimer<br />
12 / A27<br />
Gema Polimer ® (Izmir, Turkey) is the leading manufacturer<br />
of Masterbatch & Compounds in Turkey. Gema offers product<br />
solutions to various industries such as Hygiene, Packaging,<br />
White goods, Disposables, Construction and Automotive etc.<br />
GEMABiO ® is the brand name of Gema Polimer’s<br />
compostable Bioplastic Compounds. Gemabio grades of<br />
Bioplastic compounds are suitable for Flexible Packaging<br />
Film applications, Injection moulding, Thermoforming and<br />
other extrusion applications. The major end use are shopping/<br />
carrier bags, mailing bags, textile bags, cups/plates, cutlery,<br />
teaspoon, and many more. The products made from Gemabio<br />
are suitable for food contact and compostable according to EN<br />
13432 and ASTM D 6400. This year at K <strong>2019</strong>, Gema Polimer<br />
will be presenting its new certified Bioplastic compounds<br />
GEMABiO F 2910, GEMABiO E 2869, GEMABiO P 2884.<br />
www.gemapolimer.com<br />
7.1 / C21<br />
Foto Exipnos<br />
United Biopolymers<br />
United Biopolymers (Figueira da Foz, Portugal) through<br />
the BIOPAR ® Technology enables the production of nextgeneration<br />
starch-based bioplastics, with added capabilities<br />
& functionalities.<br />
The Biopar Technology enables blending two or more<br />
functional polymers to produce CoRez´s new material.<br />
CoRez is a compound Compostable Resin product achieved<br />
by the action of a compatibilizer that creates a unique bico-continues<br />
phase structure. This one brings several<br />
competitive advantages over any of the disperse technologies<br />
currently available in the market.<br />
Corez new material, under designation of Biopar allows<br />
formulation up 90 % green carbon content, it has the industrial<br />
compost and home compost Certification and is recyclable.<br />
The aim is to make CoRez the industry reference for the<br />
new material generation replacing Plastic as it is known.<br />
www.guiltfreeplastics.com<br />
Total Corbion PLA<br />
7.2 / G32<br />
Total Corbion PLA will be co-exhibiting together with parent<br />
company Total, and will highlight its Luminy ® Poly Lactic Acid<br />
(PLA) portfolio and the most recent application innovations.<br />
The Luminy PLA portfolio includes both high heat and<br />
standard grades and is used in a wide range of markets, from<br />
packaging to durable consumer goods and electronics.<br />
At K <strong>2019</strong>, Total Corbion PLA will be showcasing a number<br />
of partner applications based on PLA to illustrate the range of<br />
possibilities offered by this versatile biopolymer such as PLA<br />
pots from organic yoghurt brand Les 2 Vaches (Danone) will<br />
be on display, which replace traditional PS yoghurt pots.<br />
To showcase the high heat capabilities of PLA, visitors are<br />
welcome to enjoy a fresh cup of coffee at the Total Corbion<br />
PLA booth, served in a PLA thermoformed cup. The cups are<br />
available under the naturesse product range by Pacovis. The<br />
cups are biobased, made from renewable materials and have<br />
a reduced carbon footprint compared to PS cups.<br />
Total Corbion PLA is a global technology leader in Poly<br />
Lactic Acid (PLA) and lactide monomers. Total Corbion PLA,<br />
headquartered in the Netherlands, operates a 75,000 tonnes<br />
per year PLA production facility in Rayong, Thailand. The<br />
company is a 50/50 joint venture between Total and Corbion.<br />
www.total-corbion.com<br />
6 / E23<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 31
6 th PLA World Congress<br />
19 + 20 MAY 2020 MUNICH › GERMANY<br />
organized by<br />
www.pla-world-congress.com<br />
02-03 Sep 2020<br />
Cologne, Germany<br />
Save the dates!<br />
organized by<br />
www.pla-world-congress.com<br />
1D12<br />
Hall 1<br />
Fostag Formenbau<br />
Hall 3<br />
3F23 Eurolaser<br />
3C70-02 Lincore Depestele<br />
Hall 5<br />
5D04-08 Actiplast<br />
5E01 Adbio Composites<br />
5D04-13 Addiplast Group<br />
5C21–<br />
D21<br />
BASF<br />
5B18 Biesterfeld Plastic<br />
5A25 Blow Moulding Technologies<br />
5D04-03 Carbiolice<br />
5C07-01<br />
Center for Bioplastics<br />
and Biocomposites<br />
5E08 EcoForte<br />
5D<strong>05</strong> Ensinger<br />
5C06-01 FRX Polymers<br />
5B40 Gabriel-Chemie<br />
5E01 ITENE<br />
5F30-04 Kruschitz<br />
5D04-10 Lactips<br />
5D41 Montello<br />
5B39 Polyscope Polymers<br />
5D04-01 Polytechs<br />
5E08 The Compound Company<br />
5E08 Transmare Compounding<br />
5B09 Victrex Europa<br />
5C43 WKI Kunststoffe<br />
5E08 Yparex<br />
6A11<br />
6B42<br />
6C57<br />
6B42<br />
6D27 /<br />
6.1W01<br />
5E26<br />
6B11<br />
6B11<br />
6C43<br />
6C10<br />
6E61<br />
6D50<br />
6B28<br />
6E48<br />
6D76<br />
6E75\..<br />
E77<br />
6D76<br />
6D76<br />
6A23<br />
6D43<br />
6E80<br />
6A20<br />
6E27<br />
6A58<br />
6D75<br />
6C11<br />
6B55<br />
6C50<br />
6C50<br />
6D11<br />
6E16<br />
6C50<br />
Hall 6<br />
Adeka Polymer Additives Europe<br />
Akro-Plastic<br />
Arkema France<br />
Bio-Fed<br />
Braskem<br />
Cabopol - Polymer Compounds<br />
DSM Engineering Plastics Europe<br />
DSM Engineering Plastics Europe<br />
DuPont<br />
Elastron Kimya Sanayi ve Ticaret<br />
EMS-CHEMIE Deutschland<br />
Epsan Plastik<br />
Evonik Industries AG<br />
FKuR Kunststoff<br />
Fraunhofer-UMSICHT<br />
Grafe Advanced Polymers<br />
Grässlin Nord<br />
Hoffmann + Voss<br />
IMCD Deutschland<br />
Interpolimeri<br />
IRPC Public Company<br />
Kaneka Belgium<br />
Meraxis<br />
Novamont<br />
Omya<br />
Petrochemical Commercial<br />
Polimarky<br />
Polyblend<br />
Polymer-Chemie<br />
Reliance Industries<br />
Sidiac<br />
TechnoCompound<br />
6C58-01 Teknor Apex<br />
6E23 Total Corbion PLA<br />
6E23 Total Petrochemicals & Refining<br />
6E08 UBE Europe<br />
6A10 Wacker Chemie<br />
6E16 Weber & Schaer<br />
Hall 7<br />
7.0B25 Agiplast<br />
7.0B30 Daikin Chemical Europe<br />
7.0B08 Finproject<br />
7.0C23 Forplas Plastik<br />
7.0SC01 Fraunhofer IGB<br />
7.0B30 Heroflon<br />
7.0A37 Meltem Kimya ve Tekstil<br />
7.0C21 Nanox - Antimicrobial Protection<br />
7.0B03 Silon<br />
7.1A23 A.J. Plast Public Company<br />
7.1B21 Biotec<br />
7.1E03-13 Chnv Technology<br />
7.1A38 Doill Ecotec<br />
7.1D10 Elachem<br />
7.1D10 Epaflex Polyurethanes<br />
7.1C21 Gema Elektro Plastik<br />
7.1E03-28 Guangzhou Lushan<br />
7.1C06 Ingenia Polymers<br />
7.1B45 Jiangsu Torise Biomaterials<br />
7.1D01 Kandui Industries<br />
7.1A10 Kompuestos<br />
7.1B50 Merit Polyplast (Partnership)<br />
7.1D39 Parsa Polymer Sharif<br />
7.1C12 Ravago<br />
7.1E44 Shandong Dawn Polymer<br />
7.1C09 Soltex Petro Products.<br />
7.1D24 Toyobo Chemicals Europe<br />
7.1B19 UBQ Materials<br />
7.2A07 Art Plast<br />
7.2G11 Bajaj Superpack India<br />
7.2E10 Gianeco<br />
7.2C21 Greenage Industries<br />
7.2A06 Jinhui Zhaolong High Technology<br />
7.2E13 Laborplast<br />
7.2C27 Mesgo<br />
7.2G18 Stora Enso Timber<br />
7.2A14 Sumika Polymer Compounds (Eu)<br />
7.2C17 Technocom<br />
7.2G21 Tecnofilm<br />
7.2G31 United Biopolymers<br />
7aC24<br />
7aB10<br />
7aD<strong>05</strong><br />
7aB10<br />
7aD06<br />
7aD25<br />
7aD21<br />
7aC30<br />
7aD40<br />
Bassermann Minerals<br />
bioplastics MAGAZINE<br />
Croda Europe<br />
European Bioplastics<br />
Kuraray Europe<br />
Marubeni Europe Plc.<br />
Nurel<br />
Sojitz Europe<br />
West-Chemie<br />
Hall 8a<br />
8aH20 Add-Chem Germany<br />
8aE12-08 AIMPLAS<br />
8aB12 Alok Masterbatches<br />
8aF12 Benvic Europe<br />
8aE35 Beologic<br />
8aJ11 Clariant<br />
8aF20 Constab<br />
8aF37 Cromex<br />
8aH10 Dufor Resins<br />
8aH34 Fortum Waste Solutions<br />
8aK27 GCR Group<br />
8aK27 Gestora Catalana de Residuos<br />
8aH18 Hexpol TPE<br />
8aF40 Imerys Talc Europe<br />
8aB09 Inno-Comp<br />
8aF20 Kafrit Industries<br />
8aD12 LyondellBasell<br />
8aF50 Metaclay<br />
8aG41 Plastika Kritis<br />
8aK<strong>05</strong> Polyram Plastic Industries.<br />
8aG41 Romcolor 2000<br />
8aB28 Romira<br />
8aH28 Sukano<br />
8aE42 Tecni-Plasper<br />
8aD01 Tosaf Group<br />
8aK20 TPV Compound<br />
Hall 8b<br />
8bA61 Albis Plastic<br />
8bD60 almaak international<br />
8bH54 Coating P. Materials<br />
8bE68 Euro Commerciale<br />
8bA31 Forever Plast<br />
8bF22 Granulat<br />
8bH70 Indochine Bio Plastiques<br />
8bA52 Koksan Pet Ve Plastik Ambalaj<br />
8bH83 Loxim Industries<br />
8bE71-02 Maskom Plastik<br />
8bF80 Mexichem Specialty Compounds<br />
8bH28 MGG Polymers<br />
8bE11-<strong>05</strong> Nanjing Lesun Screw<br />
8bC68 Nanocyl<br />
8bC55 Pebo
8bH79-06<br />
8bC66<br />
8bH70<br />
8bC32<br />
8bH70<br />
8bF63<br />
8bH48<br />
8bC37-02<br />
Rák Antenna<br />
Raw Materials Recycling<br />
Respack Manufacturing<br />
SCJ Plastics<br />
Sheng Foong Plastic Industries<br />
Sirmax<br />
Taro Plast<br />
Woodplastic Group<br />
16F71<br />
FG Halle<br />
4 / 04.1<br />
FG04.1<br />
FG04.1<br />
Hall<br />
Sulzer Chemtech<br />
Outdoor area<br />
Nippon Gohsei Europe<br />
Mitsubishi Chemical - MCPP<br />
Mitsubishi Polyester<br />
10C67<br />
Hall 10<br />
Ww Ekochem<br />
Hall12a<br />
12A48 Aquafil Engineering<br />
12C45 Bayern Innovativ<br />
12A52-29 Intype Enterprise<br />
12C45 Neue Materialien Bayreuth<br />
12A27 Polykum<br />
12E19 Tecnaro<br />
Hall 813<br />
13A79 ICEE Containers Pty.<br />
Show<br />
Guide<br />
14A68<br />
Hall 14<br />
Biofibre<br />
Note: All companies listed in this guide<br />
were found in the official K’<strong>2019</strong><br />
catalogue under bioplastics.<br />
About companies listed in bold you find<br />
a short K-Show preview on pp 28-35<br />
bioplastics MAGAZINE,<br />
Polymedia Publisher GmbH<br />
Hall 07a, B10<br />
1<br />
BIOPLASTICS<br />
BUSINESS<br />
BREAKFAST<br />
B 3<br />
17. - 20.10.<strong>2019</strong><br />
You can use this double page as your<br />
personal show guide.<br />
As there are usually a lot of last minute<br />
changes, you’ll find up-to-date<br />
information at<br />
www.bioplasticsmagazine.com<br />
PLA Bioplastics for a brighter future<br />
Visit us:<br />
Hall 6 / booth E23<br />
Learn more about<br />
• Luminy® PLA Portfolio<br />
• Our 1st 75,000 tons p.a. plant<br />
• PLA applications
Beologic<br />
Beologic (Sint Denijs, Belgium) a compounding company<br />
with more than 20 years experience, is dedicated to the<br />
production of sustainable compounds. They develop,<br />
manufacture and market compounds for the plastic industry.<br />
Together with their R&D company Innologic, they are able<br />
to optimize and improve our materials depending on the<br />
application.<br />
At K <strong>2019</strong>, the company will launch different and innovative<br />
solutions to improve sustainability. For instance, a biobased<br />
ASA compound with good weathering properties, a 100 %<br />
fully biobased roto moulding powder and our latest range of<br />
Beograde materials.<br />
Over the years this has resulted in four product brands;<br />
either being biobased (Beobase – adding natural fibres),<br />
biodegradable or compostable (Beograde), fully recycled<br />
(Beocycle) or ecologic (Beosmart). The Beograde family is<br />
made of thermoplastic compounds containing renewable<br />
resources and designed to degrade under compost<br />
conditions. The materials can be processed with a wide range<br />
of tchnologies: extrusion, injection moulding, rotomoulding,<br />
thermoforming, or blow moulding. Adding wood creates a look<br />
and feel that emphasizes<br />
the biodegradable<br />
characteristics. It’s the<br />
company‘s ambition to<br />
replace traditional polymers<br />
but maintain their technical<br />
characteristics, whilst<br />
at the same time being<br />
sustainable.<br />
www.beologic.com<br />
AIMPLAS<br />
8A / E35<br />
AIMPLAS, the Plastics Technology Centre (Paterna, Spain)<br />
will display its main technological developments in the<br />
circular economy, active and smart packaging, sustainable<br />
mobility, medicine and decarbonization of the economy.<br />
Most of the projects to be presented will be on the circular<br />
economy. New sorting and treatment systems for waste of<br />
different origin (e.g. agri-food, packaging, bulky, automotive<br />
and PVC waste) so it can be recovered and used to generate<br />
new products and chemical compounds, thus reducing<br />
dependence on fossil sources.<br />
Aimplas will also exhibit its new developments in active<br />
and smart packaging designed to keep food fresh and also<br />
preserve completely different products such as audiovisual<br />
heritage. This new packaging contains sensors, improved<br />
barrier properties, additives and absorbents to extend the<br />
contents’ shelf life.<br />
The centre will also present projects on decarbonization of<br />
the economy, CO 2<br />
capture and storage for subsequent reuse<br />
as a raw material, and range solutions for electric cars that<br />
will lead to real progress in sustainable mobility. This is the<br />
case of new air conditioning methods that are more efficient<br />
because they reduce power consumption and increase vehicle<br />
range.<br />
www.aimplas.net<br />
08A / E-12-08<br />
Sukano<br />
At K <strong>2019</strong>, SUKANO (Schindellegi, Switzerland) will<br />
showcase new developments in functional additives and<br />
color masterbatches to expand the use of PLA and PBS in<br />
packaging applications and beyond. Several case studies will<br />
be presented to highlight advances in material modification<br />
using Sukano compostable masterbatches to achieve the best<br />
performance for biodegradable plastics. Sukano is a global<br />
leader in the development and production of additive and<br />
color masterbatches for biodegradable polymers such as PLA<br />
and PBS.<br />
All Sukano products are certified compostable according to<br />
EN13432. Their biobased carbon content is certified according<br />
to ASTM 6866. Sukano © Masterbatches are intended for<br />
packaging applications that are used in compostable<br />
certified products, and customers will be supported to attain<br />
certification for products where Sukano’s solutions are<br />
included. Sukano also assists our customers in their strategies<br />
and goals towards a circular economy; and contribute to the<br />
European roadmap towards a bioeconomy.<br />
www.carbiolice.com 5 / D04-03<br />
Biofibre<br />
Biofibre (Altdorf, Germany) shows the new product portfolio<br />
at their mother´s company Steinl Group.<br />
The complete product portfolio comprises Biofibre ® Silva,<br />
Biofibre Sustra, Biofibre Solva and Biofibre Lenta. Real<br />
show cases with our business partners and customized<br />
developments will be presented as well.<br />
Biofibre Lenta, as the newest development, is a compound<br />
that has been developed to substitute or replace HDPE (High<br />
Density Polyethylene) on an organic basis.<br />
Processing capabilities and product properties are almost<br />
equivalent to HDPE. The name Lenta is derived from the Latin<br />
origin lenta, i.e. tough and indicates the very stable material<br />
properties of this product group.<br />
In addition at the Circular Economy Pavillion of VDMA (open<br />
area outside halle 16) Biofibre presents new 90 % biobased<br />
material Biofibre Lenta - In use as a shoe tree!<br />
Biofibre client nico NORBERT SCHMID GMBH + CO. KG<br />
replaces a part of their product range by bioplastic based<br />
material solutions. In this particular case, a shoe tree.<br />
There are some challenging aspects for the development<br />
of a suitable substitute material in order to fully fulfill the<br />
required flexibility, strength, durability in that special footwear<br />
environment. The resulting material is over 90 % biobased<br />
recyclable, and colorable.<br />
www.biofibre.de/en<br />
14 / A68<br />
34 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
K‘<strong>2019</strong> Preview<br />
Evonik<br />
The German sports equipment manufacturer VAUDE uses<br />
the biobased polyamides of Evonik's ® Terra brand in its new<br />
collection of bags and backpacks.<br />
High-performance material with multiple benefits biobased<br />
VESTAMID Terra (PA 610) offers excellent impact resistance<br />
in cold temperatures. That makes the material ideally suited<br />
for all-weather buckles and other durable elements in<br />
equipment for demanding mountaineering and other leisure<br />
activities. Thanks to their low water absorption, buckles made<br />
of PA 610 are less likely to become brittle when used in the<br />
sports equipment of Vaude. This reduces the risk of tearing<br />
and improves product safety. Moreover, the low density of<br />
Vestamid Terra allows for manufacturing lighter sports<br />
equipment with a natural feel.<br />
Bio-based high-performance fibers in textiles Vaude plans to<br />
expand the successful use of Vestamid Terra to other product<br />
ranges in the future. For example, textile fibers made from Evonik's<br />
biopolyamides are lightweight, stretchable and breathable. The<br />
fabrics stand out for low moisture absorption, they dry quickly and<br />
don’t need ironing. The unique innovative high-performance fibers<br />
can be processed in all textile applications.<br />
Vestamid Terra is made up to 100 % from the seeds of<br />
the castor bean plant, but its sustainability concept goes<br />
beyond environmental benefits. Since castor bean plants can<br />
survive prolonged drought, they are typically cultivated in arid<br />
regions with no other agricultural use. As a result, the highperformance<br />
polymer does not have a negative impact on the<br />
human food chain.<br />
www.evonik.com<br />
6 / B28<br />
Arkema<br />
As a global player in specialty chemicals and advanced<br />
materials, Arkema (Colombes, France) strives to generate<br />
sustainable growth by providing its customers with innovative<br />
and environmentally sound solutions. Among these visitors will<br />
find some engineering plastics made from renewable resources.<br />
Over more than 70 years, Arkema’s Rilsan ® biosourced<br />
polyamide 11 flagship range has been renowned for its<br />
outstanding wide-ranging performance including resistance<br />
to high temperatures, chemical stability, and durability in the<br />
most demanding applications. It is used primarily in underhood<br />
applications as a substitute to metal and rubber.<br />
With its unique properties of energy return, light weight,<br />
elasticity, flexibility and impact resistance, Pebax ® elastomer<br />
remains the choice material for football boots. In the <strong>2019</strong><br />
Women’s World Cup, it was featured in 61 % of the sole of<br />
the shoes of the players during the competition. Arkema has<br />
also brought out an innovation with Pebax Rnew, the first<br />
biosourced thermoplastic elastomer.<br />
High performance Sarbio ® liquid resins from Sartomer ® ,<br />
derived from renewable raw materials, are unique and<br />
accommodate thermal curing as well as UV-curing for<br />
high output yield. They offer a sustainable approach to the<br />
development of consumer goods, and impart high performance<br />
plastic coatings to components used in smartphones,<br />
television sets, cosmetics packaging, household appliances,<br />
etc.<br />
www.arkema.com<br />
6 / B28<br />
14 –15 NOVEMBER <strong>2019</strong>, MATERNUSHAUS, COLOGNE, GERMANY<br />
BIOCOMPOSITES CONFERENCE COLOGNE is the world‘s largest conference<br />
and exhibition on the topic. This event offers the unique opportunity to gain a<br />
comprehensive overview of the world of biocomposites. See you in Cologne.<br />
Organiser:<br />
www.nova-institute.eu<br />
Sponsor Innovation Award:<br />
www.coperion.com<br />
Vote for the Innovation Award<br />
“Biocomposite of the Year <strong>2019</strong>”!<br />
© PICTURE: AMORIM CORK COMPOSITES<br />
www.biocompositescc.com<br />
www.biocompositescc.com<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 35
Application News<br />
CaixaBank launches new biodegradable cards<br />
CaixaBank (Valencia, Spain) recently started releasing<br />
its first biodegradable cards, 150,000 units of which will<br />
be distributed per year. It is a new type of card that can be<br />
acquired in any branch of the CaixaBank network, in the<br />
format of a gift card. In fact, from now on, all gift cards<br />
issued by CaixaBank will be biodegradable.<br />
The launch of this product represents a significant<br />
step forward in a plan specifically designed to reduce the<br />
environmental impact of the Company’s cards, a business<br />
in which CaixaBank is the leading company in Spain, with a<br />
total of 17.4 million cards and a market share of 23.38 % in<br />
terms of turnover.<br />
The plan includes both<br />
replacing the manufacturing<br />
material of the range of gift<br />
cards, and creating a new<br />
recycling programme for all<br />
card types. The cards will now be<br />
fully made from a biodegradable<br />
material, primarily formed of<br />
PLA. All other components of<br />
the card are biomass derived as<br />
well.<br />
Cards that use this material last<br />
for approximately two years, which<br />
makes it an ideal material for the<br />
gift cards, which expire within a<br />
maximum period of two years. As well as being biodegradable,<br />
the new CaixaBank cards use a different manufacturing process,<br />
which halves the carbon footprint of their production and entails<br />
the reduction of practically half the CO 2<br />
emitted.<br />
In order for customers to clearly recognise the biodegradable<br />
cards, CaixaBank is presenting a new design, with a more<br />
environmentally-friendly and minimalist feel, including a logo<br />
that indicates that it is a biodegradable product. In parallel to<br />
the launch of these new biodegradable cards, CaixaBank is<br />
continually analysing the materials that offer better durability to<br />
reduce the number of card replacements and thus reduce their<br />
carbon footprint.<br />
CaixaBank has also joined the United<br />
Nations Environment Programme<br />
- Finance Initiative (UNEP FI), which<br />
has three main goals: commitment<br />
to sustainable development, sustainability<br />
management and public<br />
awareness. MT<br />
www.caixabank.com<br />
New electric motorbike made with<br />
hemp biocomposite<br />
Cake (Stockholm, Sweden), which recently launched a<br />
groundbreaking electric motorbike, will now collaborate<br />
with Trifilon, an exciting Swedish startup from Nyköping<br />
that designs and sells sustainable materials with advanced<br />
biocomposite technology.<br />
The partnership was born of Cake’s mission to explore<br />
new sustainable technologies while producing exciting<br />
high-performance motorbikes. Trifilon’s biocomposites,<br />
which are produced with fibers from hemp and flax plants,<br />
can help the company improve its sustainability merits<br />
while maintaining the performance of its motorbikes.<br />
The current project will seek to replace<br />
current plastic components with Trifilon’s<br />
plant-based biocomposites. With Cake’s<br />
ethos of sustainability and clean<br />
transportation, the company has found<br />
a good match in the green-tech startup<br />
Trifilon, which helps companies<br />
systematically lower CO 2<br />
emissions<br />
and integrate renewable materials.<br />
Trifilon’s hemp-based biocomposite BioLite reduces the CO 2<br />
footprint from its manufacture by at least one third.<br />
“This is a great match because our companies are both<br />
about performance and sustainability. I think fans of Cake<br />
motorbikes will respond positively to having our plant-fiber<br />
composites in their motorbikes. It will mean that some<br />
ingredients in their motorbikes come from European farms.<br />
That makes these exciting motorbikes even cooler and more<br />
sustainable,” said Trifilon’s CEO and co-founder Martin<br />
Lidstrand.<br />
The technology behind Trifilon’s biocomposites<br />
was initially intended for the automotive<br />
segment, as a substitute for lightweight,<br />
strong carbon fiber. Trifilon had previously<br />
developed and built the body of a car<br />
for Volkswagen Rally with its hempbased<br />
biocomposite, BioLite. MT<br />
www.ridecake.com | www.trifilon.com<br />
36 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
green@hexpolTPE.com<br />
www.hexpolTPE.com<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 37
Natural Rubber © -Institut.eu | 2018<br />
Starch-based Polymers<br />
Lignin-based Polymers<br />
Cellulose-based Polymers<br />
©<br />
PBAT<br />
PET-like<br />
PU<br />
APC<br />
PTT<br />
PLA<br />
PU<br />
PA<br />
PTF<br />
PHA<br />
-Institut.eu | 2017<br />
PMMA<br />
HDMA<br />
DN5<br />
PVC<br />
Isosorbide<br />
1,3 Propanediol<br />
Caprolactam<br />
UPR<br />
PP<br />
Propylene<br />
Vinyl Chloride<br />
Ethylene<br />
Sorbitol<br />
Lysine<br />
MPG<br />
Epoxy resins<br />
Epichlorohydrin<br />
EPDM<br />
Ethanol<br />
Glucose<br />
PE<br />
MEG<br />
Terephthalic<br />
acid<br />
Isobutanol<br />
PET<br />
p-Xylene<br />
Starch Saccharose<br />
Fructose<br />
Lignocellulose<br />
Natural Rubber<br />
Plant oils<br />
Hemicellulose<br />
Glycerol<br />
PU<br />
Fatty acids<br />
NOPs<br />
Polyols<br />
PU<br />
PU<br />
LCDA<br />
THF<br />
PBT<br />
1,4-Butanediol<br />
Succinic acid<br />
3-HP<br />
5-HMF/<br />
5-CMF<br />
Aniline<br />
Furfural<br />
PA<br />
SBR<br />
Acrylic acid<br />
2,5-FDCA/<br />
FDME<br />
PU<br />
PFA<br />
PU<br />
PTF<br />
ABS<br />
PHA<br />
Full study available at www.bio-based.eu/reports<br />
Full study available at www.bio-based.eu/reports<br />
PEF<br />
PBS(X)<br />
©<br />
-Institut.eu | 2017<br />
Full study available at www.bio-based.eu/markets<br />
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7 th<br />
Bio-based Polymers & Building Blocks<br />
The best market reports available<br />
Commercialisation updates on<br />
bio-based building blocks<br />
7 th 1<br />
Data Data for for<br />
2018 2018<br />
UPDATE<br />
<strong>2019</strong><br />
UPDATE<br />
<strong>2019</strong><br />
Bio-based Building Blocks<br />
Bio-based Building Blocks<br />
and Polymers – Global Capacities<br />
and Polymers – Global Capacities<br />
and Trends 2018-2023<br />
and Trends 2017-2022<br />
Carbon dioxide (CO 2 ) as chemical<br />
feedstock for polymers – technologies,<br />
polymers, developers and producers<br />
Succinic acid: New bio-based<br />
building block with a huge market<br />
and environmental potential?<br />
Million Tonnes<br />
6<br />
5<br />
4<br />
3<br />
2<br />
1<br />
2011<br />
Bio-based polymers:<br />
Evolution of worldwide production capacities from 2011 to 2022<br />
Lactic<br />
acid<br />
Adipic<br />
acid<br />
Methyl<br />
Metacrylate<br />
Itaconic<br />
acid<br />
Furfuryl<br />
alcohol<br />
Levulinic<br />
acid<br />
2012 2013 2014 2015 2016 2017 2018 <strong>2019</strong> 2020 2021 2022<br />
Dedicated<br />
Drop-in<br />
Smart Drop-in<br />
Superabsorbent<br />
Polymers<br />
Pharmaceutical/Cosmetic<br />
Acidic ingredient for denture cleaner/toothpaste<br />
Antidote<br />
Calcium-succinate is anticarcinogenic<br />
Efferescent tablets<br />
Intermediate for perfumes<br />
Pharmaceutical intermediates (sedatives,<br />
antiphlegm/-phogistics, antibacterial, disinfectant)<br />
Preservative for toiletries<br />
Removes fish odour<br />
Used in the preparation of vitamin A<br />
Food<br />
Bread-softening agent<br />
Flavour-enhancer<br />
Flavouring agent and acidic seasoning<br />
in beverages/food<br />
Microencapsulation of flavouring oils<br />
Preservative (chicken, dog food)<br />
Protein gelatinisation and in dry gelatine<br />
desserts/cake flavourings<br />
Used in synthesis of modified starch<br />
Succinic<br />
Acid<br />
Industrial<br />
De-icer<br />
Engineering plastics and epoxy curing<br />
agents/hardeners<br />
Herbicides, fungicides, regulators of plantgrowth<br />
Intermediate for lacquers + photographic chemicals<br />
Plasticizer (replaces phtalates, adipic acid)<br />
Polymers<br />
Solvents, lubricants<br />
Surface cleaning agent<br />
(metal-/electronic-/semiconductor-industry)<br />
Other<br />
Anodizing Aluminium<br />
Chemical metal plating, electroplating baths<br />
Coatings, inks, pigments (powder/radiation-curable<br />
coating, resins for water-based paint,<br />
dye intermediate, photocurable ink, toners)<br />
Fabric finish, dyeing aid for fibres<br />
Part of antismut-treatment for barley seeds<br />
Preservative for cut flowers<br />
Soil-chelating agent<br />
Authors:<br />
Raj Authors: Chinthapalli, Raj Chinthapalli, Dr. Pia Skoczinski, Michael Carus, Michael Wolfgang Carus, Wolfgang Baltus, Baltus,<br />
Doris Doris de de Guzman, Harald Harald Käb, Käb, Achim Achim Raschka, Jan Jan Ravenstijn,<br />
April 2018<br />
<strong>2019</strong><br />
This and other reports on the bio-based economy are available at<br />
This www.bio-based.eu/reports<br />
and other on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Achim Raschka, Dr. Pia Skoczinski, Jan Ravenstijn and<br />
Michael Carus<br />
nova-Institut GmbH, Germany<br />
February <strong>2019</strong><br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Raj Chinthapalli, Dr. Pia Skoczinski, Achim Raschka,<br />
Michael Carus, nova-Institut GmbH, Germany<br />
Update March <strong>2019</strong><br />
This and other reports on the bio-based economy are available<br />
at www.bio-based.eu/reports<br />
Standards and labels for<br />
bio-based products<br />
Bio-based polymers, a revolutionary change<br />
Comprehensive trend report on PHA, PLA, PUR/TPU, PA<br />
and polymers based on FDCA and SA: Latest developments,<br />
producers, drivers and lessons learnt<br />
million t/a<br />
Selected bio-based building blocks: Evolution of worldwide<br />
production capacities from 2011 to 2021<br />
3,5<br />
actual data<br />
forecast<br />
3<br />
2,5<br />
Bio-based polymers, a<br />
revolutionary change<br />
2<br />
1,5<br />
Jan Ravenstijn 2017<br />
1<br />
0,5<br />
Picture: Gehr Kunststoffwerk<br />
2011<br />
2012<br />
2013<br />
2014<br />
2015 2016 2017 2018 <strong>2019</strong> 2020<br />
2021<br />
L-LA<br />
Epichlorohydrin<br />
MEG<br />
Ethylene<br />
Sebacic<br />
acid<br />
1,3-PDO<br />
MPG<br />
Lactide<br />
E-mail:<br />
j.ravenstijn@kpnmail.nl<br />
Succinic<br />
acid<br />
1,4-BDO<br />
2,5-FDCA<br />
D-LA<br />
11-Aminoundecanoic acid<br />
DDDA<br />
Adipic<br />
acid<br />
Mobile: +31.6.2247.8593<br />
Author: Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />
July 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />
nova-Institut GmbH, Germany<br />
May 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />
April 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Policies impacting bio-based<br />
plastics market development<br />
and plastic bags legislation in Europe<br />
Asian markets for bio-based chemical<br />
building blocks and polymers<br />
Market study on the consumption<br />
of biodegradable and compostable<br />
plastic products in Europe<br />
2015 and 2020<br />
Share of Asian production capacity on global production by polymer in 2016<br />
100%<br />
A comprehensive market research report including<br />
consumption figures by polymer and application types<br />
as well as by geography, plus analyses of key players,<br />
relevant policies and legislation and a special feature on<br />
biodegradation and composting standards and labels<br />
80%<br />
60%<br />
Bestsellers<br />
40%<br />
20%<br />
0%<br />
PBS(X)<br />
APC –<br />
cyclic<br />
PA<br />
PET<br />
PTT<br />
PBAT<br />
Starch<br />
PHA<br />
PLA<br />
PE<br />
Blends<br />
Disposable<br />
tableware<br />
Biowaste<br />
bags<br />
Carrier<br />
bags<br />
Rigid<br />
packaging<br />
Flexible<br />
packaging<br />
Authors: Dirk Carrez, Clever Consult, Belgium<br />
Jim Philp, OECD, France<br />
Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />
Lara Dammer & Michael Carus, nova-Institute, Germany<br />
March 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Wolfgang Baltus, Wobalt Expedition Consultancy, Thailand<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />
Lara Dammer, Michael Carus (nova-Institute)<br />
April 2016<br />
The full market study (more than 300 slides, 3,500€) is available at<br />
bio-based.eu/top-downloads.<br />
www.bio-based.eu/reports<br />
1<br />
38 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Application News<br />
Revolutionary dog plush toy line with<br />
starch based stuffing<br />
The Good Stuffing Company announced the launch of its first line of plush dog toys, which<br />
will be exclusively available at Petco and Petco.com through the end of the year. What makes<br />
the Good Stuffing offerings unique is that, unlike almost any other canine plush toy that is<br />
filled with poly-fill, the Good Stuffing line is filled with SafeFill Stuffing. SafeFill Stuffing is<br />
a proprietary alternative fill made from natural plant starch. If a dog tears open a plush toy<br />
filled with poly-fill, there is a real choking hazard. Conversely, the SafeFill Stuffing will dissolve<br />
harmlessly in the dog’s mouth like cotton candy does in people.<br />
While the principle ingredient used in the manufacturing of poly-fill is ethylene, which<br />
is derived from petroleum, SafeFill Stuffing is derived from natural plant starch. SafeFill<br />
Stuffing, manufactured without any crude oil component or toxic byproducts, is eco-friendly,<br />
biodegradable, sustainable, fire-resistant, and hypoallergenic. The line at Petco is launching<br />
with over two-dozen fun and attractive animals for all sized dogs MT<br />
www.goodstuffingcompany.com<br />
Natural Farm<br />
pet food packaging<br />
Braskem and Natural<br />
Farm, a leading provider<br />
of 100% natural pet food<br />
based in Atlanta, recently<br />
announced the adoption<br />
of Braskem’s I’m green TM<br />
Polyethylene (PE) bioplastic for<br />
the consumer packaging of its<br />
Natural Farm’s TM line of highquality<br />
pet food products.<br />
Marcus Maximo, Founder<br />
and CEO of Natural Farm stated,<br />
“Natural Farm was founded on a passion for dogs and the<br />
love we share with our pets. We’re delighted that as well<br />
as preparing the highest quality dog treats, we’re equally<br />
focused on being responsible environmental stewards.<br />
We’re excited to have found the perfect partner with<br />
Braskem and its bio-PE allowing Natural Farm so ensure<br />
we’re being socially responsible with our packaging.”<br />
Natural Farm is one of the few companies in the pet<br />
retail space who own and operate their own facility and<br />
The Natural Farm commitment stretches from its fields<br />
to its packaging, consistently supporting its people and<br />
the local communities where they live and operate. This<br />
spirit of “Care, Quality, and Transparency” extends to<br />
everything Natural Farm creates through its 360 Degree<br />
Plan towards sustainability. This includes integrating 51%<br />
bio-based, fossil fuel-free and fully recyclable, I’m greenT<br />
Polyethylene (PE) bioplastic into its packaging. Natural<br />
Farm also donates a portion of its proceeds to helping<br />
animals in local community shelters. MT<br />
Cushion for<br />
artificial turf<br />
Braskem and ProdTek, a product development and<br />
manufacturing company serving the artificial turf, flooring<br />
and textile industries with innovative solutions announced the<br />
integration of Braskem’s biobased Polyethylene in ProdTek’s<br />
new Turf Cushion line of turf underlay products.<br />
ProdTek’s revolutionary new Turf Cushion is installed under<br />
artificial turf for a wide range of applications including play<br />
grounds, play areas, sports fields, roof tops, indoor play<br />
areas and other areas where shock attenuation is critical for<br />
users. The Turf Cushion underlay is composed of recycled<br />
polyethylene and Eco Raw, which utilizes Braskem’s bio-<br />
PE and qualifies for High Recycled Content (HRC) status.<br />
In utilizing Braskem’s bio-PE as a renewable alternative<br />
to petroleum based polyethylene, ProdTek’s Turf Cushion<br />
can make a significant contribution to reducing the level of<br />
greenhouse gas emissions in the product value creation chain<br />
John Karr, President at ProdTek, stated, “We feel very<br />
good about our new Turf Cushion Pad. Not only is it carbon<br />
neutral and 100 % recyclable, it provides enhanced safety<br />
for children in playground environments and is economically<br />
advantageous for turf installation companies. We feel like we<br />
have a product that creates value for everyone and serves<br />
society as well.” MT<br />
www.turfcushion.com<br />
www.naturalfarmpet.com<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 39
Opinion<br />
Bioplastics in the<br />
Circular Economy<br />
R.O.J. Jongboom, Director Business Development, Biotec<br />
Founded in 1992, BIOTEC (Emmerich, Germany) is one<br />
of the oldest and most experienced companies worldwide<br />
in the area of compostable and biodegradable<br />
plastics. Looking back at nearly 30 years of history in this<br />
field, it is remarkable how some trends and focus points<br />
seem to change, whereas - even after almost 3 decades -<br />
others remain stubbornly the same.<br />
In the early nineties of the previous century, the number<br />
of companies using starch as a feedstock for alternative<br />
plastic materials was very limited. In those days,<br />
biodegradable starch plastics were considered an exotic<br />
novelty providing an elegant way to help farmers to find<br />
new outlets for their surplus production of crops such as<br />
potatoes and corn - and make a contribution to a cleaner<br />
world for future generations. Organic waste collection<br />
and composting were still in their infancy and landfill was<br />
a commonly accepted waste disposal method. Worries<br />
about climate change or plastic soup were far away in the<br />
distant future. Global plastic consumption was roughly 30 %<br />
of current volumes and plastics recycling was something<br />
that - at best - occurred inside the factory with production<br />
scraps.<br />
The image and reputation of plastics have shifted over<br />
the last few decades: from materials representing hope,<br />
growth, progress and wealth, they have become a scourge,<br />
increasingly associated with pollution, climate change and<br />
irreparable environmental damage.<br />
Many governments and multinationals are focusing<br />
in their long term sustainability policies on the Circular<br />
Economy. Much of the inspiration is coming from the<br />
work of the Ellen MacArthur Foundation. Unfortunately,<br />
the translation of this well-elaborated vision on a Circular<br />
Economy into legislation and policies has in many cases<br />
simply been distilled into a focus on plastics recycling, while<br />
ignoring the added value of compostable and biodegradable<br />
plastics in specific applications.<br />
Is focusing purely on plastic recycling a responsible<br />
strategy or policy? At first sight, it seems a charming<br />
concept: keep plastics materials in circulation, preferably<br />
for eternity, and minimize dependency on crude oil as<br />
feedstock. In the perception of the public at large, recycling<br />
is a positive approach, supported by decades of positive<br />
experiences with the recycling of glass, metal and paper.<br />
For these materials, recycling, however, is well established.<br />
Once recycled, these materials have a positive value and<br />
there is a market or outlet for them.<br />
The situation for most plastics, however, is much more<br />
complicated, as anyone that ever played with clay in different<br />
colors as a child knows: once the bright colors are mixed,<br />
you cannot separate them back again. Likewise, mixed<br />
plastics are extremely difficult to separate, and as many<br />
products available in the<br />
market consist of different<br />
materials, colorants,<br />
printing inks, labels and<br />
numerous contaminations,<br />
recycling becomes a<br />
challenge. Separating,<br />
cleaning, upgrading, and<br />
recycling is currently only<br />
possible for mono-stream<br />
products for which a proper<br />
collection system is in place,<br />
such as e.g. (most) PET<br />
bottles. Some polyolefins, like PE or PP, can, up to a certain<br />
point, be used to produce various products.<br />
It is currently an illusion to think that plastics will be able<br />
to be mechanically recycled on the same scale as glass,<br />
paper and metals anytime in the near future. Suggesting<br />
this as a policy would be thoroughly misleading and a<br />
serious oversimplification.<br />
Yet, what does the general public hear? “Plastics are<br />
bad, and recycling is good” is the highly oversimplified and<br />
incorrect message which is being communicated over and<br />
over again in the news. As a result, people see no need for<br />
other steps, even though these would actually be much<br />
better in the long run.<br />
Recycling is not something that is exclusively done<br />
by humans. Nature has developed biological processes<br />
over millions of years, keeping creation and degradation<br />
in balance and harmony. As a result, nature is able to<br />
“recycle” enormous amounts of organic material. Look,<br />
for example, at what happens in autumn, when the leaves<br />
fall from the trees. Nature is able to effectively break the<br />
mass of different leaves, other plant materials and dead<br />
insects back down into simple building blocks. The CO 2<br />
that green plants bind during growth via photosynthesis, is<br />
released back into the atmosphere without contributing to<br />
the formation of greenhouse gasses.<br />
Nature is actually much better at organic recycling<br />
than mankind, as nature can handle complex mixtures of<br />
organic materials, whereas technical/mechanical recycling<br />
processes can only work effectively when there is a very low<br />
degree of contamination. Washing, cleaning, and separating<br />
is fine for glass, metal and paper, but is very difficult for<br />
plastics. There is a need for recycling processes that can<br />
handle heterogenic feedstock. Both chemical recycling and<br />
organic recycling are able to do so. Chemical recycling is<br />
still in its infancy, but compostable products and industrial<br />
composting are well established, with demonstrated<br />
products and technologies.<br />
40 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Opinion<br />
There are many applications in which plastics run a<br />
high risk of being contaminated with food waste or other<br />
undesirable materials that make regular recycling of these<br />
plastics virtually impossible. Typical examples are coffee<br />
capsules, food trays, yoghurt or mayonnaise cups and alike.<br />
Cleaning these plastic products is costly and negatively<br />
influences the technical and economic feasibility of plastic<br />
recycling. And vise versa as well: consumers can have a<br />
tendency to (wrongfully) assume that such products can be<br />
disposed of via organic waste collection and that removing<br />
plastics after composting or biogas production is a simple<br />
step.<br />
Either way, contamination is undesirable and leads<br />
both to additional costs and a lower quality of output (of<br />
both recycled plastic and compost). Compost should not<br />
be contaminated with plastics, and plastics should not<br />
be contaminated with food. And in cases where the risk<br />
of cross contamination is high, alternatives that can be<br />
processed via organic recycling, i.e., composting or biogas<br />
production, should be sought.<br />
Biotec strongly supports the objectives of the Circular<br />
Economy. With numerous different Bioplast grades,<br />
different high quality applications can be achieved for blown<br />
films, sheet material, thermoformed or injection molded<br />
trays, fibers, and laminated products. To achieve the<br />
objectives of the Circular Economy, the general public must<br />
become more aware, which would force multinationals<br />
and governments to pursue higher ambition levels and<br />
to fully embrace the suggestions of the Ellen MacArthur<br />
Foundation, rather than simply cherry picking the initiatives<br />
relating to plastics recycling only.<br />
www.biotec.de<br />
Compostable plastics can strongly support the objectives<br />
of the Circular Economy, ensuring that less (food)<br />
contaminated materials end up in the plastics recycling<br />
stream and that more AND cleaner organic waste is<br />
collected. This organic waste can be effectively converted<br />
into compost for improving the carbon binding capacity of<br />
the soil, or into biogas for decentral energy generation (gas<br />
or electricity).<br />
It would really help a lot if companies that are involved in<br />
post-consumer waste processing were not paid per ton of<br />
waste processed, but instead per ton of high quality recycled<br />
plastic or clean compost that is applied in the market. The<br />
currently existing profit incentives for post-consumer waste<br />
processors act as a legal stimulation for them to optimize<br />
their profits. This does not take into account the price<br />
that future generations will be paying for cleaning up the<br />
garbage we are dumping in the soil and the oceans.<br />
All industrial composting facilities are perfectly able to<br />
convert certified compostable products into water, CO 2<br />
and<br />
humus. What they need to do is to stop focusing on the high<br />
speed processing of large volumes of contaminated organic<br />
waste that has no agricultural value, and instead to aim<br />
more at producing high quality compost with significant<br />
agricultural benefits. The currently existing financial<br />
incentives for these companies do not justify investments<br />
in delivering quality but are optimized for converting the<br />
highest possible volumes in the shortest possible time,<br />
thus creating the highest value for their shareholders and<br />
leaving the bill that the future generations will need to take<br />
care of unpaid.<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 41
Barrier materials<br />
Ultra high barrier for<br />
bio-packaging<br />
S<br />
olving the world’s problems of plastic<br />
and food waste is right at the forefront<br />
of Plantic Technologies business.<br />
To fight food waste Plantic supplies<br />
ultra-high barrier films made from renewable<br />
and recycled materials throughout the<br />
world. The recycled content in the materials<br />
is providing a source for food grade<br />
waste plastics that would otherwise be<br />
going to land fill.<br />
As part of Kuraray (headquartered<br />
in Chiyoda, Japan) who are the world<br />
largest supplier of barrier resins, Plantic<br />
Technologies Ltd (Altona, Victoria,<br />
Australia) has achieved a unique place<br />
in the world market for bioplastics<br />
through proprietary technology that<br />
delivers biodegradable and renewable<br />
sourced alternatives to conventional<br />
plastics based on corn and cassava;<br />
which is not genetically modified. The<br />
barrier properties of the materials start<br />
with an Oxygen Transmission Rate (OTR) below<br />
1.0 cm³/m²·day.<br />
Unlike other bioplastics companies who utilise organic<br />
materials, but whose polymers are still developed in<br />
refineries, Plantic’s polymer as well as its raw material, are<br />
grown in a field. The entire process integrates the science<br />
of organic innovation with commercial and industrial<br />
productivity in a new way. The result is both a broad range<br />
of immediate performance and cost advantages, and longterm<br />
environmental and sustainability benefits.<br />
Flexible, rigid and semi rigid materials from Plantic<br />
have shown to give extension of shelf life for the products<br />
packed, this is through the ultra-high barrier in the<br />
packaging material. With thermoformable webs for Skin,<br />
MAP and Flexible applications the benefits for retailers and<br />
brand owners are proven, this enables them to meet their<br />
packaging targets and goals.<br />
PLANTIC HP a fully biodegradable high barrier<br />
structure forms the core of all Plantic products and<br />
depending on the customer needs the outer skins can be<br />
made to seal onto conventional PE and PET sealing layers.<br />
Other materials that are being used with PLANTIC HP are<br />
PBS, rPET, Cellulose<br />
An additional benefit of these multilayer materials is the<br />
ability for them to go through a standard recycling process.<br />
A unique process of separation of polymers occurs when<br />
the materials are sent through the recycling system.<br />
Plantic has recently released a range of high barrier<br />
recyclable paper-based structures being used in<br />
applications such as coffee pouches. These paper based and<br />
paper board structures have the additional<br />
benefit of being able to go through a<br />
standard thermforming machine, giving<br />
producers the chance to use a board or<br />
paper structure on standard equipment<br />
Plantic Technologies is supplying<br />
major retailers and brand owners<br />
throughout the world in applications<br />
such as fresh case ready beef, pork,<br />
lamb and veal, smoked and processed<br />
meats, chicken, fresh pasta and<br />
cheese applications.<br />
Plantic Technologies is expanding<br />
rapidly and refining its technology<br />
to meet the ever-growing global<br />
needs for more environmentally and<br />
performance efficient materials.<br />
With global recognition through<br />
multiple award wins including DuPont<br />
Packaging, World Star, PIDA and others,<br />
Plantic has a solution for Retailers,<br />
Processors and Brand owners who want<br />
to fulfill their future packaging targets.<br />
“Plantic materials are not just about being a<br />
sustainable material, it has an ultra-high barrier that can<br />
improve the shelf life of a product, and reduce food waste.<br />
With Plantic materials you can have an enormous impact<br />
on value change and reduce the effects of climate change,<br />
both by reducing food waste and using more sustainable<br />
materials.” Brendan Morris Plantic Technologies Limited<br />
CEO and Managing Director said. MT<br />
www.plantic.com.au<br />
42 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Barrier materials<br />
New compostable barrier films<br />
Development of a biodegradable flexible film with barrier properties for<br />
food packaging application<br />
Using multilayer films for food packaging<br />
in which the layers consist of different<br />
types of material makes<br />
it possible to combine different<br />
properties of different materials,<br />
such as oxygen and water<br />
vapour protection into a single<br />
packaging solution. However,<br />
the use of different materials<br />
to achieve these different<br />
properties makes the multilayer<br />
packaging developed to<br />
date impossible to recycle at the<br />
end of life. And as biodegradable or<br />
compostable materials do not offer<br />
sufficient barrier properties to<br />
be applied in packaging for fresh foodstuffs<br />
like cheese, compostable packaging<br />
cannot be used, either.<br />
To improve the environmental sustainability of multilayer<br />
film, the MULTIBIOBARRIER project is working on the<br />
development of a new biodegradable and compostable<br />
multilayer film for cheese that will offer good oxygen and<br />
water vapour barrier properties. The objectives of the project<br />
are listed below:<br />
• To develop new biodegradable materials to produce flexible<br />
and fully compostable packaging according to EN 13432<br />
• To develop a new biodegradable and compostable<br />
multilayer film with an oxygen barrier (< 2cm³/m²·day·bar)<br />
and water vapour barrier (< 4g/m²·day) suitable for cheese<br />
packaging. The new film will be able to be composted<br />
together with the food residues as the composition of the<br />
film is 100% compostable<br />
• Flexible and easily recyclable film, because the layers of<br />
the film can be separated easily<br />
• To obtain sustainable packaging complying with the<br />
legislative changes related to single-use products in<br />
countries where biodegradables are exempted from bans<br />
• To convince legislators to allow the use of biodegradable<br />
and compostable materials for manufacturing single-use<br />
products<br />
The development of biodegradable materials with an oxygen<br />
barrier, the task for which AIMPLAS (Paterna, Spain) is mainly<br />
responsible, will be based on a mixture of non-thermoplastic<br />
PVOH, additives and plasticizers. It will be processed through<br />
blown film extrusion technology<br />
During the project, the researchers will be working on the<br />
optimization of a formulation to keep oxygen barrier below<br />
2 cm³/m²·day·bar at the lowest possible thickness.<br />
On the other hand, biodegradable materials with a water<br />
vapour barrier are being developed by Nurel (Zaragoza, Spain).<br />
By:<br />
Nuria López Aznar<br />
Senior polymer researcher<br />
AIMPLAS<br />
Paterna, Spain<br />
These will be based on a mixture<br />
of biopolymers derived from<br />
starch, biopolyesters and additives,<br />
which will allow the water vapour barrier<br />
to be improved. The main goal is to obtain<br />
a biopolymer with a moisture vapour<br />
transmission rate below 4 g/m²·day, measured at<br />
85 % RH and 23°C.<br />
In addition, the focus will also be on the compatibility of<br />
both materials to avoid using a tie layer.<br />
Based on the biopolymers developed by Aimplas and Nurel,<br />
a coextruded biodegradable multilayer film will be produced<br />
by Gaviplas (Alfarrasí, Spain). The cheese packaging will<br />
be manufactured from this film, after which the functional<br />
validation of the packaging developed will be studied.<br />
Taking advantage of the soluble character of the PVOH,<br />
a recyclability study of the external layers of the film will be<br />
undertaken at the end of the project.<br />
MULTIBIOBARRIER is a three-year project funded by<br />
the RETOS – COLABORACIÓN 2018 national call with file<br />
number RTC-2017-6034-2. Aimplas, the Plastics Technology<br />
Centre, is the technical coordinator of the project. The other<br />
participants in the consortium are Nurel and Gaviplas who will<br />
also contribute to the development of the new biodegradable,<br />
compostable and flexible food packaging.<br />
The project<br />
has been running<br />
for one year<br />
and the first<br />
biodegradable<br />
grades have<br />
been already<br />
developed from<br />
which film will<br />
be produced at<br />
pilot plant level<br />
using blown<br />
film extrusion<br />
technology.<br />
www.aimplas.es<br />
www.nurel.com<br />
www.gaviplas.es<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 43
Barrier materials<br />
Emerging circular biobased<br />
barrier solutions<br />
Multilayer plastic packaging films are commonly used<br />
to pack sensitive food products. Their share on the<br />
packaging market is increasing as they enable lightweighting<br />
and increase resource efficiency in their primary<br />
use in comparison to rigid packaging. However, multilayer<br />
packaging concepts are currently not recyclable. Indeed,<br />
high purity fractions are needed for reprocessing and the<br />
vast majority of them end up in land fill or in energy recovery<br />
systems. In addition, most of the barrier materials such as<br />
Ethylene Vinyl Alcohol (EVOH) or polyamides (PA), are fossil<br />
based. In this article, emerging solutions in recent research<br />
and innovation initiatives will subsequently be reviewed,<br />
first in terms of new biobased feedstocks from which barrier<br />
materials can be sourced and second on how using them<br />
can positively affect the end of life of the derived laminates.<br />
An array of potential sources in nature<br />
Many biopolymers made of polysaccharides or proteins<br />
offer good barrier properties against oxygen permeation<br />
and can be used as edible coatings such as chitosan,<br />
proteins from dairy, fish, potatoes or legumes. In addition,<br />
those can be extracted from non-edible food fractions or<br />
agro-food industry by products.<br />
For example, in the project DAFIA [1], marine rest rawmaterials<br />
such as salmon skin and backbones are harnessed<br />
to develop cost-efficient isolated and purified gelatin and<br />
hydrolysates. Gelatin is a denatured polypeptide extracted<br />
by hydrolysis from pre-treated collagen sources, mainly<br />
animal skins and bones, which is mostly affected by its amino<br />
acid composition and molecular weight distribution. The<br />
fractionation and lipids separation pre-treatment protocols<br />
have been optimized in mild conditions. The coating was<br />
formulated comparing different natural plasticizers, pH<br />
and temperature as well as drying condition. Furthermore,<br />
the mechanically separated salmon muscle has been<br />
hydrolysed with proteases as potential active compound.<br />
The addition of hydrolysates has shown positive antioxidant<br />
activity (Gallic acid equivalent GAeq of 66 +/-7 ppm<br />
and Ferric Reducing Ability of Plasma FRAP of<br />
189 +/-17 µmol/L), but no antibacterial effects were<br />
observed. The coating application and lamination have<br />
been successfully carried out at pilot scale by AIMPLAS<br />
resulting in laminates with promising oxygen barrier<br />
(1.58 OTR (cm³/(m²·day) at 23°C, 1 atm and 50 % relative<br />
humidity for a 10 µm coating). This shows that biomacromolecules<br />
from marine sub-products have a great<br />
potential to be used as high added value active barrier coatings for<br />
multilayer packaging or edible coatings directly applied on food.<br />
Previously reported Wheylayer ® barrier materials have<br />
also been obtained from whey protein [2] (which can be<br />
extracted from a cheese by-product). Further development<br />
also allowed obtaining thermoformable versions of the<br />
same (Thermowhey) [3]. In the recent project OptiNanoPro<br />
[4], nano-enhancement of the whey protein coating was<br />
performed adding food contact approved nanoclays. Those<br />
were converted into a so-called “ready-to-use” formulation<br />
by means of a solid-state pre-dispersion process using<br />
ball-milling. The process yielded a nearly dust-free, freeflowing<br />
powder containing agglomerated particles, which<br />
can easily be mixed with water. The preparation of a coating<br />
Oxygen transmission rate °C/50% RH<br />
(cm 3 · 100µm (STP) m -2 d -1 bar -1 )<br />
Fig 1. top: microscopic picture of the cross-section picture of<br />
a laminate including PET 23 µm and 4 µm of whey proteins<br />
nanocomposite coatings produced semi-industrial-scale,<br />
and bottom: Scanning electron microscopy (SEM) images at a<br />
magnification of 50,000 on the nanocomposite coating<br />
Fig. 2: Permeability values for different whey coatings vs. standard<br />
and biobased polymers (all normalized to 100 μm)<br />
10000<br />
1000<br />
100<br />
10<br />
1<br />
0.1<br />
PE-HD<br />
PP (oriented)<br />
PA 12<br />
PE-LD<br />
PC<br />
PUR-elastomer<br />
Celluloseacetate<br />
Wax/paper<br />
PA 11<br />
PS (oriented)<br />
PVC-U<br />
PA 12<br />
PET (oriented) PA 66<br />
PVC-U (oriented) PA 6<br />
EVOH 44%<br />
PVDC<br />
EVOH 38%<br />
Wheylayer<br />
Cellulose-acetobutyrate<br />
Thermowhey<br />
OPTIANOPRO<br />
EVA-copolymer,<br />
VAC 20%<br />
0.01<br />
0.01 0.1 1 10 100 1000<br />
Water vapour transmission rate<br />
23°C/85 0% RH (g · 100µm · m -2 d -1 )<br />
44 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Barrier materials<br />
By:<br />
Multilayer<br />
Film<br />
Elodie Bugnicourt, Simona Neri<br />
IRIS Technology Solutions<br />
Barcelona, Spain<br />
Esra Kucukpinar<br />
Fraunhofer IVV<br />
Freising, Germany<br />
Markus Schmid<br />
Faculty of Life Sciences, Albstadt-Sigmaringen University<br />
Sigmaringen, Germany<br />
Patrizia Cinelli, Andrea Lazzeri<br />
INSTM, University of Pisa<br />
Pisa, Italy<br />
Fig. 3: Illustration of the<br />
materials recyclability of<br />
whey coated laminates<br />
Grinding Wheylayer Removal Density Separation<br />
Recycled<br />
PE<br />
Recycling<br />
Recycled<br />
PET<br />
formulation and its upscaling for roll-to-roll converting<br />
at pilot- and semi-industrial scale was also successfully<br />
implemented [5]. This process resulted in a good dispersion<br />
and orientation of the nanoparticles (Fig. 1) and an<br />
interesting barrier improvement that allowed resulting<br />
coating laminates matching the properties of EVOH (Fig. 2).<br />
Nevertheless, as seen from the graph (Fig. 2), the<br />
developed protein coatings are not able to compete with<br />
standard plastics in terms of water vapour barrier. In<br />
BIOnTop [6], to reach such performance, the previously<br />
developed whey protein coatings will be improved by<br />
nano-coatings of fatty acids applied by a resource efficient<br />
grafting technology.<br />
But what about the End Of Life?<br />
All the previously mentioned protein-based coatings<br />
are compostable by nature. Indeed, their composition<br />
makes them ideal for metabolization by microorganisms.<br />
They can be applied on a range of biodegradable or nonbiodegradable<br />
substrate films and the end of life of the later<br />
is what mainly determines that of the whole laminate.<br />
Fig. 4:<br />
Representation<br />
of the end of life<br />
scenarios that will<br />
be compatible with<br />
the new BIOnTop<br />
materials, some of<br />
them coated with<br />
barrier materials<br />
Biontop<br />
Copolymers<br />
& Compounds<br />
Coating<br />
Organic & Materials Recycling<br />
Indeed, when applied for example on PLA, the nitrogen<br />
(as amino-acid rich component) of the coating was even<br />
reported to speed up the biodegradation of the overall<br />
multilayer films [7] resulting in industrially compostable<br />
packaging solutions.<br />
When the protein coating is applied on conventional<br />
substrates, its removability using enzymatic detergent<br />
during the washing step of the packaging recycling can be<br />
exploited (Fig. 3). In that case, the cleaned layers of e.g. PE<br />
and PET can then be separated by density and reprocessed<br />
separately with a minor loss of properties [8].<br />
After showing the capability for automatic sorting<br />
of the packaging containing the new biobased barrier<br />
coatings, BIOnTop aims at upscaling the recycling process<br />
of the barrier multilayer packaging. In addition, to match<br />
virtually any controlled waste management demand, PLA<br />
copolymers suitable for home composting are also being<br />
developed. Such end of life versatility, depicted in Fig. 4,<br />
is key in the view of the difficulty to remove the organic<br />
content in specific packaging formats such as tea bags or<br />
when fruits or vegetables get rotten in their trays or nets.<br />
It is also key to be able to adjust to the most sustainable<br />
end of life option depending on the packed products and<br />
the actually feasible waste management for which available<br />
logistics are extremely variable between regions.<br />
Conclusion<br />
lead<br />
Home<br />
Composting<br />
Echoing the increasingly stringent<br />
legislations and public demands,<br />
the packaging industry is<br />
requesting more sustainable<br />
barrier solutions. This is boosting<br />
the research in renewably sourced<br />
materials which in turn also<br />
have the ability to support the<br />
circular economy transition<br />
by enabling improved organic<br />
or materials recycling routes.<br />
Different protein solutions<br />
based on cheese or fish byproducts<br />
have been discussed and<br />
to barrier properties close to their<br />
fossil counterpart while making<br />
laminates recyclable organically or<br />
in terms of materials.<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 45
Barrier materials<br />
Opinion<br />
Despite such advances, the maturity of these<br />
developments needs to grow to substitute the wellconsolidated<br />
fossil-based counterparts in terms of<br />
costs and markets. Besides, the number of progresses<br />
improving the end of life of conventional plastic<br />
packaging can also change the conditions of the<br />
competition. New emerging solutions for recycling<br />
standard multilayers packaging e.g., a preferential<br />
solvent based extraction of each of the main fractions<br />
in multi-materials laminates or composites, is being<br />
brought to semi-industrial scale in the Multicycle<br />
project [9]. All these solutions, also compatible with<br />
biobased barrier coatings, shall co-exist in a global<br />
plastic strategy to solve the different issues currently<br />
met by the plastic industry. This shows that, for circular<br />
biobased barrier solutions to get a lion’s share in this<br />
massive opportunity for change in the plastic packaging<br />
sector and lead to an actual decarbonisation of the<br />
society, further innovations embedded in a concerted<br />
action along the value chain are needed including not<br />
only materials providers but also waste management<br />
bodies and end users (including consumers).<br />
References<br />
[1] DAFIA, H2020 BIOTEC, GA 720770, Biomacromolecules from<br />
municipal solid bio-waste fractions and fish waste for high added<br />
value applications.<br />
[2] “Films with excellent barrier properties”, E. Bugnicourt, M.<br />
Schmid; Bioplastics magazine; Vol. 8, p 44; Sept. 2013.<br />
[3] Barrier… but also bio-based and thermoformable!, E. Bugnicourt,<br />
Bioplastics magazine, Vol 5, p 36. Sept. Oct 2015<br />
[4] OPTINANOPRO, H2020 NMP, GA 686116, Processing and control<br />
of novel nanomaterials in packaging, automotive and solar panel<br />
processing lines<br />
[5] Dispersion and Performance of a Nanoclay/Whey Protein<br />
Isolate Coating upon its Upscaling as a Novel Ready-to-Use<br />
Formulation for Packaging Converters. Bugnicourt, E.; Brzoska,<br />
N.; Kucukpinar, E.; Philippe, S.; Forlin, E.; Bianchin, A.; Schmid,<br />
M. Polymers <strong>2019</strong>, 11, 1410.<br />
[6] BIOnTop, H2020 BBI, GA 837761, Novel packaging films and<br />
textiles with tailored end of life and performance based on biobased<br />
copolymers and coatings<br />
[7] Whey protein layer applied on biodegradable packaging film to<br />
improve barrier properties while maintaining biodegradability”,<br />
P. Cinelli, M. Schmid, E. Bugnicourt, J. Wildner, A. Bazzichi, I.<br />
Anuillesi, A. Lazzeri, Polymer Degradation and Stability. 07/2014;<br />
DOI: 10.1016/j.polymdegradstab.2014.07.007<br />
[8] Recyclability of PET/WPI/PE Multilayer Films by Removal of Whey<br />
Protein Isolate-Based Coatings with Enzymatic Detergents”, P.<br />
Cinelli, M. Schmid, E. Bugnicourt, A. Lazzeri, Materials 9(6):473 ·<br />
June 2016, DOI: 10.3390/ma9060473<br />
[9] MULTICYCLE, H2020 SPIRE, GA 820695, Advanced and sustainable<br />
recycling processes and value chains for plastic-based multimaterials<br />
www.iris.cat | www.ivv.fraunhofer.de<br />
www.hs-albsig.de | www.instm.it<br />
ACKNOWLEDGEMENTS<br />
In addition to other past projects quoted in footnote,<br />
the authors would like to acknowledge the H2020<br />
and BBI-JU fundings for the DAFIA project under<br />
Grant Agreement No. 720770, MultiCycle project<br />
under Grant Agreement No. 820695 and BIOnTop<br />
project under Grant Agreement No. 837761.<br />
They would also like to thank the collaboration of<br />
AIMPLAS plastic technology centre.<br />
Equal footing<br />
for LCAs<br />
I<br />
n the current efforts to develop an LCA methodology<br />
for biobased polymers by the JRC (Joint Research<br />
Centre), fundamental problems must be confronted if<br />
an equal and fair comparison is to be made between the<br />
environmental effects of biobased polymers and those of<br />
petrochemical polymers, write four scientists from Germany’s<br />
nova Institute in an open letter to the JRC.<br />
The JRC is the European Commission’s science and<br />
knowledge service, tasked with carrying out research in<br />
order to provide independent scientific advice and support<br />
to EU policy. Its activities currently include the elaboration<br />
of a consistent and appropriate LCA-based method for<br />
the purpose of a “Comparative Life-Cycle Assessment of<br />
alternative feedstock for plastics production.” The final<br />
report is expected by end of this year, or early 2020. The<br />
authors of the open letter, led by Michael Carus, point<br />
to the various methodological and technical stumbling<br />
blocks that remain to be overcome and put forward a<br />
number of proposals in aid of the development of LCA<br />
standards for biobased polymers.<br />
As the authors write, biobased technologies are subject<br />
to highly critical evaluation, while the petrochemical<br />
industry, which uses non-renewable resources and which<br />
has been and still is involved in many environmental<br />
disasters, is not scrutinized with the same level of detail<br />
and transparency, making a comparison on equal footing<br />
impossible. In addition, the importance of renewable<br />
carbon is not sufficiently valued in the LCA methodology<br />
developed by the JRC. The LCA methodology for<br />
biobased polymers will also differ considerably from<br />
the methodology for biofuels, “which could lead to<br />
greenhouse gas (GHG) reductions for biofuels being<br />
relatively higher than for biobased polymers, purely as a<br />
result of the different methodologies (each in comparison<br />
to their petrochemical counterpart)…. The only option:<br />
the same LCA rules must apply to all uses of biomass,<br />
whether it is for fuels or for chemicals!”, they argue.<br />
The solution proposed by the nova Institute lies in<br />
the use of a prospective LCA. To that end, a scenario<br />
could be developed and a quasi-standardised life cycle<br />
assessment conducted for the year 2<strong>05</strong>0, in addition to<br />
the present situation. “A comparison between bio- and<br />
petro-based polymers would then look entirely different,”<br />
write the authors of the open letter.<br />
“Biobased polymers are considered as a sustainable<br />
solution for the circular economy of the future. That is<br />
why, for a fair comparison, it is so important to consider<br />
how they perform not only in the present, but in particular<br />
in the future. This is not accounted for in the methods<br />
prevailing today,” the scientists conclude. MT<br />
The complete text of the open letter to the JRC can be<br />
downloaded from:<br />
https://tinyurl.com/openletter-jrc<br />
46 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Barrier materials<br />
PVOH for<br />
barrier<br />
applications<br />
Today’s expectations are very high for primary packaging<br />
for such applications as food, cosmetics and<br />
household goods, as the products packed should be<br />
kept clean, fresh and sweet-smelling. In addition, nothing<br />
from the surroundings should get into the packaging. However,<br />
the entire pack should also be sustainable as well as<br />
environmentally friendly. The matter of recycling is also an<br />
important issue.<br />
A PVOH barrier layer could be a possible solution. PVOH<br />
(polyvinyl alcohol) is a synthetically produced water-soluble<br />
polymer which is non-toxic and environmentally friendly as<br />
it biodegrades into water and CO 2<br />
. In waste incineration, it<br />
burns without residues.<br />
As a result of its good processing and printing properties,<br />
PVOH is particularly suitable to produce mono films.<br />
The common applications include laundry bags for<br />
hospitals, detergent packaging and sachets. PVOH films<br />
also demonstrate high flexibility and tensile strength. In<br />
combination with other bioplastics as a multilayer film,<br />
it can be used as an environmentally friendly alternative<br />
to EVOH or aluminum due to its outstanding gas barrier<br />
properties towards oxygen and carbon dioxide. Its resistance<br />
to chemicals, oils and greases means that it can also be<br />
used as a shield against oils, fats and solvents.<br />
FKuR Kunststoff GmbH (Willich, Germany) now has<br />
PVOH in the portfolio of their biobased and biodegradable<br />
plastics, offering their customers individual solutions,<br />
either as mono or multi-layer applications with PLA-based<br />
film materials. This guarantees films with particularly<br />
good breathability which also have good barrier properties<br />
against O 2<br />
and CO 2<br />
. If used with compostable films, organic<br />
recycling may be possible. MT<br />
www.fkur.com<br />
Material<br />
“Oxygen permeability<br />
(ml/m²day) “<br />
Hot-water soluble PVOH 0.24<br />
Warm-water soluble PVOH 0.36<br />
Cold-water soluble PVOH 1,85<br />
Ethylene-vinyl alcohol (EVOH) 0.29-2.4<br />
Nylon 6 26-38<br />
Polyethylene terephthalate (PET) 40-80<br />
PVC 50-390<br />
HDPE 1,700-2,400<br />
Polypropylene 2,000-10‚00<br />
Low Density Polyethylene 12,000<br />
Join us at the<br />
14th European Bioplastics<br />
Conference<br />
The leading business forum for the<br />
bioplastics industry<br />
3/4 December <strong>2019</strong><br />
Titanic Chaussee Hotel<br />
Berlin, Germany<br />
@EUBioplastics #eubpconf<br />
www.european-bioplastics.org/events<br />
REGISTER<br />
NOW!<br />
For more information email:<br />
conference@european-bioplastics.org<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 47
News<br />
10<br />
Years ago<br />
Published in<br />
bioplastics MAGAZINE<br />
from left: Patrick Gerritsen, Frank<br />
Eijkman, Jhon Bollen, Oliver Fraaije.<br />
Bio4Pack offers<br />
One-Stop Shopping<br />
Two Dutch thermoforming companies, Nedupak<br />
Thermoforming BV (of Rheden, NL) and Plastics2Pack (of<br />
Uden, NL), recently announced the forming of ‘Bio4Pack‘<br />
as a new packaging supply company. The new company is<br />
headed by Managing Director Patrick Gerritsen, who brings<br />
with him several years of know-how and expertise in the area<br />
of biobased and biodegradable packaging.<br />
Bio4Pack not only offers thermoformed packaging but<br />
also all other kinds of packaging made from biobased and/or<br />
biodegradable materials, including films, bags and netting,<br />
and through to sugar cane trays made from the bagasse, a<br />
by-product from the sugar cane industry.<br />
“We want to offer our customers a total packaging<br />
solution,“ says Oliver Fraajie, Commercial Director of<br />
Nedupack, “not just a thermoformed tray or bulk pack.“<br />
And thus the portfolio of Bio4Pack comprises the traditional<br />
thermoformed packaging made from bioplastics such as<br />
PLA or new thermoformable materials.<br />
The range also includes films and bags for all kinds of<br />
purposes, e.g shopping bags or flow wrap packaging made<br />
from starch based bioplastics such as Biolice ® , Materbi ® or<br />
Bioflex ® from FKUR, and also nets for onions, potatoes or<br />
fruit and, of course, the labelling on the packaging.<br />
“We also offer meat packaging consisting of a<br />
thermoformed PLA tray with peelable SiOx coated PLA<br />
film, having the same properties as conventional packing“<br />
adds Frank Eijkman, Managing Director of Plastics2Pack.<br />
“And for bakery goods such as cakes and cookies we have<br />
thermoformed trays and folded boxes from a more rigid PLA<br />
sheet. This kind of box is also available for the packaging of<br />
bio-chocolate for example.“<br />
Blisters for liquor gift packs or batteries round off the<br />
list of examples. “In a nutshell: We are a trading company<br />
that offers all types of packaging made from biobased or<br />
biodegradable materials,“ says Patrick Gerritsen, “Those that<br />
we don‘t produce ourselves at Nedupack or Plastics2pack,<br />
we get from partners who I know from the past“.<br />
Of course all products are certified according to EN 13432<br />
and Patrick goes even one step further: “We are investigating<br />
the possibility of having our products certified and labeled<br />
with ‘Climate Neutral‘ (www.climatepartner.de)“.<br />
Bio4Pack started operations in early August and is proud of<br />
the first orders from leading companies in the fresh produce<br />
and supermarket businesses. Even if the company initially<br />
targets the European market, clients from all over the world<br />
can be served via Nedupack‘s partners in many countries.<br />
“Another big advantage is that Nedupack Thermoforming<br />
have their own design and tool-making department, so we<br />
are more flexible and can react much quicker than many<br />
other suppliers,“ says Jhon Bollen, Technical Director of<br />
Nedupack.<br />
Although this new company was founded in a generally<br />
difficult economic situation, the entrepreneurs have full<br />
confidence in the development of this market. “We are<br />
looking forward to convincing more and more supermarkets<br />
and other suppliers to switch to bioplastic products - and<br />
not only because the traditional resources are finite,“ says<br />
Patrick Gerritsen. Oliver Fraaije is convinced that “the<br />
customers who buy bio-food are also willing to buy biopackaging.“<br />
- MT<br />
www.bio4pack.com<br />
In September <strong>2019</strong>, Patrick Gerritsen,<br />
founder and CEO of Bio4Pack said:<br />
10 years of Bio4Pack means 10 years<br />
of fighting for the opportunities of<br />
sustainable packaging.<br />
On July 15 it was exactly 10 years ago<br />
that Bio4pack was founded. At the time, 4<br />
enthusiastic entrepreneurs knew for sure:<br />
sustainable packaging is the packaging of<br />
the future. Now, 10 years later, it appears<br />
that they had a good foresight. Sustainable<br />
packaging is more popular than ever, partly<br />
due to the relentless energy that our team<br />
has put into convincing large retailers and<br />
packers to switch to this environmentally<br />
friendly packaging. Bio4Pack has benefited<br />
from this and has since grown into a leading<br />
supplier of compostable and sustainable<br />
packaging.<br />
In the initial phase of Bio4Pack the<br />
emphasis was on packaging intended for<br />
organically grown fruit and vegetables. Net<br />
packaging, film for packaging of potatoes<br />
and carrots, among other things, and PLA<br />
trays for packaging fruit were the most<br />
important products that Bio4Pack sold in<br />
the initial phase. Under the influence of<br />
the development of new sustainable raw<br />
materials and production techniques,<br />
the range has since been expanded to<br />
include packaging for a wide variety of<br />
products that do not have a biological<br />
background. Consider, for example, the<br />
packaging of peppermint. Bio4Pack<br />
recently introduced a completely<br />
new sustainable packaging made<br />
from the waste of rice plantations.<br />
This packaging is so special that the<br />
product immediately received the<br />
silver cradle-to-cradle certificate.<br />
The success of Bio4Pack has<br />
led the company to move into a<br />
completely new business premises<br />
in Nordhorn (D) at the beginning<br />
of this year with sufficient office<br />
space and a large warehouse. Here<br />
the company has room for further<br />
growth in the coming years.<br />
tinyurl.com/2009-bio4pack<br />
6 bioplastics MAGAZINE [<strong>05</strong>/09] Vol. 4<br />
48 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Opinion<br />
Biodegradation of plastics in<br />
nature: the future tasks of<br />
standardisation<br />
Francesco Degli Innocenti,<br />
Ecology of Products Director, Novamont, Italy<br />
What is the minimum timeframe for complete biodegradation<br />
for plastics designed to biodegrade?<br />
Faced everyday with these type of questions, as a<br />
biodegradation expert, I realize that there is a communication<br />
deficit in our industry that must be filled.<br />
Two tiers are necessary to characterize the biodegradation<br />
of plastics at sea.<br />
The first tier testing is to verify whether the plastic material<br />
shows intrinsic biodegradability. This is the potential of<br />
the plastic to be cleaved by enzymes and assimilated by<br />
microorganisms present in the biosphere. Achieving high levels<br />
of conversion to CO 2<br />
, comparable to those achieved by GRAB<br />
(Generally Recognized As Biodegradable) substances, is a<br />
strong indication that plastic is biodegradable. When addressing<br />
the first tier, test conditions must be optimised, because it<br />
does not make any sense to limit the growth and activity of<br />
microbes. Obviously, when a biodegradable product “leaves<br />
the laboratory” and goes into the real world its biodegradation<br />
rate can be slower if conditions are sub-optimal. This is true<br />
for any biodegradable material, whether natural or synthetic.<br />
Food stored in the fridge does not biodegrade quickly and keeps<br />
for years if stored in the freezer. Nobody will claim “food is not<br />
biodegradable!” because it does not go bad at 4°C.<br />
The second tier is about the environmental fate of<br />
products placed on the market that are littered. Here the<br />
purpose is to assess the ecological risk of littering. “Risk”<br />
is a probabilistic concept, the probability that a certain<br />
event will occur that can cause harm to flora and fauna. For<br />
example, a bag (the hazard) can be mistaken for a jellyfish<br />
by a fish causing its death by suffocation (the harm). That is,<br />
a potential hazard can become<br />
real harm. The probability of<br />
this event happening depends<br />
on the number of bags present<br />
in the environment and their<br />
residence time. The greater<br />
the number of bags, the<br />
longer their residence time,<br />
the greater the probability of<br />
harm. For the layman: if I have<br />
to cross a highway blindfolded it is better to do it at 3 a.m.<br />
(when the “concentration” of cars is very low) and running<br />
fast (i.e. with the lowest “residence time”) than at 5 p.m.<br />
(when the “concentration” of cars is very high) and walking<br />
slow (i.e. with the highest “residence time.”) From this, it<br />
follows that littering products whether they are biodegradable<br />
or not, causes a risk because it increases one factor of the<br />
multiplication: “concentration x residence time”. The other<br />
factor is the residence time to be predicted based on the<br />
physical characteristics and the biodegradation behaviour of<br />
products. Biodegradation reduces residence times and thus<br />
the risk.<br />
In conclusion, the intrinsic biodegradability, demonstrated in the<br />
laboratory under optimal conditions and using a GRAB material<br />
as a reference, characterizes the plastic material from the point of<br />
view of its propensity to degrade similarly to natural materials. The<br />
definition of the impact of any product (including biodegradable<br />
plastics) in case of littering requires methodologies for the<br />
estimation of amount of litter and the effective biodegradation<br />
rates. This will be the task of research and standardisation in the<br />
near future.<br />
Magnetic<br />
for Plastics<br />
www.plasticker.com<br />
• International Trade<br />
in Raw Materials, Machinery & Products Free of Charge.<br />
• Daily News<br />
from the Industrial Sector and the Plastics Markets.<br />
• Current Market Prices<br />
for Plastics.<br />
• Buyer’s Guide<br />
for Plastics & Additives, Machinery & Equipment, Subcontractors<br />
and Services.<br />
• Job Market<br />
for Specialists and Executive Staff in the Plastics Industry.<br />
Up-to-date • Fast • Professional<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 49
Research & Development<br />
Opportunity for developers<br />
Use or invest in (biobased) Polymerization Shared Facility –<br />
Call for Partners<br />
G<br />
reen Chemistry Campus (Bergen op Zoom), REWIN<br />
(Breda) and Wageningen University (Wageningen,<br />
all in the Netherlands) are planning the development<br />
of the first multipurpose Polymerization Shared<br />
Facility Pilot Plant in Bergen op Zoom. In this facility new<br />
and redesigned bio-polymers can be produced at a subcommercial<br />
scale. Currently the consortium is looking for<br />
companies in the field of new (biobased) polymers that are<br />
interested to either use this unique infrastructure or that<br />
want to become a shareholder.<br />
Test new & redesigned polymers at a<br />
sub-commercial scale<br />
Many developers of (bio-)polymers are ready to scale-up<br />
production from lab-scale to industrial-scale. The current<br />
lack of R&D infrastructure prevents them from optimally<br />
developing their innovations that could potentially green the<br />
chemical industry. The Polymerization Shared Facility Pilot<br />
aims to bridge this valley of death in polymer innovation by<br />
sharing costly infrastructure between multiple users.<br />
The plant embraces ring-opening and polycondensation<br />
polymerization as well as de-polymerization. With the<br />
possibility of continuous production of larger volumes of new<br />
and re-designed polymers, both the behavior of the polymer<br />
in production (upstream) and the processing (downstream)<br />
can be investigated at pre-commercial volumes (tonnesscale).<br />
The figure below shows the Polymerization Shared<br />
Facility Pilot across the value chain.<br />
Call for industrial partners to use or invest in<br />
the Polymerization Shared Facility Pilot Plant<br />
The Consortium is looking for companies who are<br />
active in the research and development of (bio)-polymers,<br />
either new polymers and/or drop-ins. This facility will help<br />
polymer developers or an end-users in materials to make<br />
the innovation process of developing new polymers and<br />
materials more efficient and sustainable.<br />
The offer is open for business partner(s) who want to use<br />
this facility in coming years or who want to be a shareholder<br />
of this facility. For any type of business partner, very<br />
attractive offerings are available, which include:<br />
• a pilot plant designed to your requirements (with broad<br />
process-operating window)<br />
• opportunity to co-invest<br />
• guaranteed use of the facility<br />
• competitive costs<br />
• located in the thriving bio-economy ecosystem of the<br />
Biobased Delta (South-West Netherlands)<br />
Consortium Partners & Context<br />
Consortium Partners Green Chemistry Campus, REWIN<br />
and Wageningen University are planning to develop this<br />
Polymerization Shared Facility at the site of the Green<br />
Chemistry Campus in Bergen op Zoom.<br />
The facility reinforces the Biobased Delta ecosystem and<br />
is additional to existing research infrastructure such as<br />
the Wageningen Food & Biobased Research, Bioprocess<br />
Pilot Facility in Delft and the Bio Base Europe Pilot Plant<br />
in Ghent. It increases the attractiveness of the region for<br />
companies in the world to establish R&D centers here. The<br />
Wageningen Food & Biobased Research will give specifically<br />
scientific and engineering support to this polymerization<br />
pilot plant.<br />
About two third of the plant will be publicly funded.<br />
More Information<br />
The Consortium would be happy to send you<br />
more information or (preferably) talk to interested<br />
parties to explore possibilities that<br />
could help your company to successfully<br />
scale-up production of new (bio-)polymers.<br />
Please contact:<br />
Marcel van Berkel<br />
CEO Polymerization Shared Facility<br />
+31 6222 03144<br />
marcel@polymerizationsharedfacility.com<br />
Up-scaling<br />
Research &<br />
Development<br />
Upscaling<br />
(pilot)<br />
Demo/<br />
Commercial<br />
scale<br />
(Cellulosic)<br />
Sugars<br />
Universities, private R&D at multinationals, -startups,<br />
Pilot plants for<br />
monomers<br />
Value Chain<br />
Monomers<br />
Polymers &<br />
Materials<br />
Polymerization Shared<br />
Facility<br />
End product<br />
Compounders,<br />
Converters & End use<br />
Feedstock suppliers Polymer producers Brand owners<br />
50 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
ORDER<br />
NOW!<br />
BOOK<br />
STORE<br />
www.bioplasticsmagazine.com/en/books<br />
email: books@bioplasticsmagazine.com<br />
phone: +49 2161 6884463<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 51
By:<br />
BIOPLASTIC<br />
patents<br />
Barry Dean,<br />
Naperville, Illinois, USA<br />
U.S. Patent 10,246,799 (April 2, <strong>2019</strong>) “Polylactic Acid Resin<br />
Composition For 3D Printing”, Min-young Kim, Jong Ryang<br />
Kim, Tae-Young Kim, Sung-wan Jeon, (SK Chemicals Co, Ltd),<br />
(Seongnam-si Korea)<br />
Ref: WO2016/043440<br />
This patent teaches a composition and a process for making<br />
a composition for 3D printing. The composition taught consists<br />
of a hard segment polylactic acid (65 – 95 weight %) and a<br />
soft segment polyol (5 – 35 weight %) connected via urethane<br />
linkages by reaction with a diisocyanate. The PLA hard<br />
segment is prepared via reaction of D/L lactide while the soft<br />
segment is derived from a polyol such as polyethyleneglycol,<br />
polybutyleneglycol or polypropyleneglycol. The hard segment<br />
offers a melting point of 170°C and a glass transition of 55°C;<br />
while the soft segment glass transition can be tailored by<br />
the selection of polyol or mixtures of polyol. The polyol soft<br />
segment provides for a greater practical toughness of the<br />
resin and hence the 3D printed article.<br />
Key to the composition and its use for 3D printing is a<br />
practical melt viscosity which is taught based on a measured<br />
viscosity of
U.S. Patent 10,351,755 (July 16, <strong>2019</strong>) “Loss Circulation<br />
Material Composition Having Alkaline Nanoparticle Based<br />
Dispersion and Water Insoluble Hydrolysable Polyester”,<br />
Vikrant Wagle, Rajendra Kalgaonkar, Abdullah Al-Yami, Zalnab<br />
Alsaihati (Saudi Arabian Oil Company), (Dhahran, Saudi Arabia)<br />
Ref. WO 2015116044<br />
This patent teaches a composition to address loss of<br />
drilling fluids in the wellbore. The composition consists<br />
of alkaline nanosilica dispersion and a water insoluble<br />
polyester where the ratio of the nanosilica: polyester is 50<br />
– 80:1. The water insoluble polyester can be polylactic acid,<br />
polyhydroxyalkanoate, polyglycolide or polycaprolactone,<br />
The combined nanosilica and insoluble polyester(powder<br />
or fiber) form a gel which when introduced into a well enter<br />
subterranean formations of low pressure and/or fractured<br />
areas. Under well temperatures the polyester hydrolyzes to<br />
form monomeric acid residues which react with the alkaline<br />
nanosilica forming a solid, physical barrier to the drilling fluids<br />
thereby increasing the efficiency and recovery of the drilling<br />
fluids.<br />
Process PLA<br />
with Improved<br />
Molecular Weight<br />
Retention<br />
LOWER MELT<br />
TEMPERATURE<br />
REDUCED ENERGY<br />
CONSUMPTION<br />
HIGHER FILL<br />
LEVELS<br />
U.S. Patent 10,314,683 (June 11, <strong>2019</strong>) “Polyhydroxyalkanoate<br />
Medical Textiles and Fibers”, David P Martin, Said Rizk,<br />
Ajay Ahuja, Simon F. Williams, (Tepha, Inc), (Lexington,<br />
Massachusetts)<br />
This patent teaches absorbable polyester fibers, braids and<br />
surgical meshes with good in vivo strength retention based<br />
on monofilament or multifilament fiber made from poly-4-<br />
hydroxybutyrate homopolymer and copolymers. Multifilament<br />
fiber tenacity is greater than 3.5 g/denier and monofilament<br />
fiber has tensile strength greater than 126 MPa. These<br />
strength properties are key for in vivo sutures and surgical<br />
meshes<br />
These absorbable fibers are suggested to offer improved<br />
performance for anti-adhesion properties and reduced risks<br />
of infection.<br />
This patent also teaches the process for forming useful<br />
4-PHB fiber while overcoming the challenges of melt fracture,<br />
low crystallization and fiber tackiness.<br />
U.S. Patent 10,351,973 (July 16, <strong>2019</strong>) “Process For The<br />
Preparation Of A Fiber, A Fiber and A Yarn Made From Such A<br />
Fiber”, Jeffrey John Kolstad, Gerardus Johannes Maria Gruter,<br />
(Furanix Technologiers B.V.), (Amsterdam, Netherlands)<br />
Ref: WO2014/204313<br />
A fiber by melt spinning of polyethylene-2.5-<br />
furandicarboxylate is taught. The PEF resin exhibits a solution<br />
viscosity of 0.45 – 0.85 dL/g. PEF fiber with draw ratios of 1:<br />
1.4 – 1.6 are shown to exhibit good fiber tenacity 200 – 1000<br />
mN/tex. It is also taught that PEF fiber can be subjected to<br />
traditional fiber techniques such as texturing, finishing and<br />
dyeing. In a comparative example with poly(trimethylene-2,5-<br />
furanoate), PEF was demonstrated to have improved fiber<br />
forming properties, e.g. reduced number of spin breaks.<br />
The PEF resin can be 100 % renewable with a biobased<br />
source of ethylene glycol.<br />
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bioplastics MAGAZINE [03/19] Vol. 14 53
Basics<br />
Glossary 4.4 last update issue <strong>05</strong>/<strong>2019</strong><br />
In bioplastics MAGAZINE again and again<br />
the same expressions appear that some of our readers<br />
might not (yet) be familiar with. This glossary shall help<br />
with these terms and shall help avoid repeated explanations<br />
such as PLA (Polylactide) in various articles.<br />
Bioplastics (as defined by European Bioplastics<br />
e.V.) is a term used to define two different<br />
kinds of plastics:<br />
a. Plastics based on → renewable resources<br />
(the focus is the origin of the raw material<br />
used). These can be biodegradable or not.<br />
b. → Biodegradable and → compostable<br />
plastics according to EN13432 or similar<br />
standards (the focus is the compostability of<br />
the final product; biodegradable and compostable<br />
plastics can be based on renewable<br />
(biobased) and/or non-renewable (fossil) resources).<br />
Bioplastics may be<br />
- based on renewable resources and biodegradable;<br />
- based on renewable resources but not be<br />
biodegradable; and<br />
- based on fossil resources and biodegradable.<br />
1 st Generation feedstock | Carbohydrate rich<br />
plants such as corn or sugar cane that can<br />
also be used as food or animal feed are called<br />
food crops or 1 st generation feedstock. Bred<br />
my mankind over centuries for highest energy<br />
efficiency, currently, 1 st generation feedstock<br />
is the most efficient feedstock for the production<br />
of bioplastics as it requires the least<br />
amount of land to grow and produce the highest<br />
yields. [bM 04/09]<br />
2 nd Generation feedstock | refers to feedstock<br />
not suitable for food or feed. It can be either<br />
non-food crops (e.g. cellulose) or waste materials<br />
from 1 st generation feedstock (e.g.<br />
waste vegetable oil). [bM 06/11]<br />
3 rd Generation feedstock | This term currently<br />
relates to biomass from algae, which – having<br />
a higher growth yield than 1 st and 2 nd generation<br />
feedstock – were given their own category.<br />
It also relates to bioplastics from waste<br />
streams such as CO 2<br />
or methane [bM 02/16]<br />
Aerobic digestion | Aerobic means in the<br />
presence of oxygen. In →composting, which is<br />
an aerobic process, →microorganisms access<br />
the present oxygen from the surrounding atmosphere.<br />
They metabolize the organic material<br />
to energy, CO 2<br />
, water and cell biomass,<br />
whereby part of the energy of the organic material<br />
is released as heat. [bM 03/07, bM 02/09]<br />
Since this Glossary will not be printed<br />
in each issue you can download a pdf version<br />
from our website (bit.ly/OunBB0)<br />
bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />
Version 4.0 was revised using EuBP’s latest version (Jan 2015).<br />
[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />
Anaerobic digestion | In anaerobic digestion,<br />
organic matter is degraded by a microbial<br />
population in the absence of oxygen<br />
and producing methane and carbon dioxide<br />
(= →biogas) and a solid residue that can be<br />
composted in a subsequent step without<br />
practically releasing any heat. The biogas can<br />
be treated in a Combined Heat and Power<br />
Plant (CHP), producing electricity and heat, or<br />
can be upgraded to bio-methane [14] [bM 06/09]<br />
Amorphous | non-crystalline, glassy with unordered<br />
lattice<br />
Amylopectin | Polymeric branched starch<br />
molecule with very high molecular weight<br />
(biopolymer, monomer is →Glucose) [bM <strong>05</strong>/09]<br />
Amylose | Polymeric non-branched starch<br />
molecule with high molecular weight (biopolymer,<br />
monomer is →Glucose) [bM <strong>05</strong>/09]<br />
Biobased | The term biobased describes the<br />
part of a material or product that is stemming<br />
from →biomass. When making a biobasedclaim,<br />
the unit (→biobased carbon content,<br />
→biobased mass content), a percentage and<br />
the measuring method should be clearly stated [1]<br />
Biobased carbon | carbon contained in or<br />
stemming from →biomass. A material or<br />
product made of fossil and →renewable resources<br />
contains fossil and →biobased carbon.<br />
The biobased carbon content is measured via<br />
the 14 C method (radio carbon dating method)<br />
that adheres to the technical specifications as<br />
described in [1,4,5,6].<br />
Biobased labels | The fact that (and to<br />
what percentage) a product or a material is<br />
→biobased can be indicated by respective<br />
labels. Ideally, meaningful labels should be<br />
based on harmonised standards and a corresponding<br />
certification process by independent<br />
third party institutions. For the property<br />
biobased such labels are in place by certifiers<br />
→DIN CERTCO and →TÜV Austria who both<br />
base their certifications on the technical specification<br />
as described in [4,5]<br />
A certification and corresponding label depicting<br />
the biobased mass content was developed<br />
by the French Association Chimie du Végétal<br />
[ACDV].<br />
Biobased mass content | describes the<br />
amount of biobased mass contained in a material<br />
or product. This method is complementary<br />
to the 14 C method, and furthermore, takes<br />
other chemical elements besides the biobased<br />
carbon into account, such as oxygen, nitrogen<br />
and hydrogen. A measuring method has<br />
been developed and tested by the Association<br />
Chimie du Végétal (ACDV) [1]<br />
Biobased plastic | A plastic in which constitutional<br />
units are totally or partly from →<br />
biomass [3]. If this claim is used, a percentage<br />
should always be given to which extent<br />
the product/material is → biobased [1]<br />
[bM 01/07, bM 03/10]<br />
Biodegradable Plastics | Biodegradable Plastics<br />
are plastics that are completely assimilated<br />
by the → microorganisms present a defined<br />
environment as food for their energy. The<br />
carbon of the plastic must completely be converted<br />
into CO 2<br />
during the microbial process.<br />
The process of biodegradation depends on<br />
the environmental conditions, which influence<br />
it (e.g. location, temperature, humidity) and<br />
on the material or application itself. Consequently,<br />
the process and its outcome can vary<br />
considerably. Biodegradability is linked to the<br />
structure of the polymer chain; it does not depend<br />
on the origin of the raw materials.<br />
There is currently no single, overarching standard<br />
to back up claims about biodegradability.<br />
One standard for example is ISO or in Europe:<br />
EN 14995 Plastics- Evaluation of compostability<br />
- Test scheme and specifications<br />
[bM 02/06, bM 01/07]<br />
Biogas | → Anaerobic digestion<br />
Biomass | Material of biological origin excluding<br />
material embedded in geological formations<br />
and material transformed to fossilised<br />
material. This includes organic material, e.g.<br />
trees, crops, grasses, tree litter, algae and<br />
waste of biological origin, e.g. manure [1, 2]<br />
Biorefinery | the co-production of a spectrum<br />
of bio-based products (food, feed, materials,<br />
chemicals including monomers or building<br />
blocks for bioplastics) and energy (fuels, power,<br />
heat) from biomass.[bM 02/13]<br />
Blend | Mixture of plastics, polymer alloy of at<br />
least two microscopically dispersed and molecularly<br />
distributed base polymers<br />
Bisphenol-A (BPA) | Monomer used to produce<br />
different polymers. BPA is said to cause<br />
health problems, due to the fact that is behaves<br />
like a hormone. Therefore it is banned<br />
for use in children’s products in many countries.<br />
BPI | Biodegradable Products Institute, a notfor-profit<br />
association. Through their innovative<br />
compostable label program, BPI educates<br />
manufacturers, legislators and consumers<br />
about the importance of scientifically based<br />
standards for compostable materials which<br />
biodegrade in large composting facilities.<br />
Carbon footprint | (CFPs resp. PCFs – Product<br />
Carbon Footprint): Sum of →greenhouse<br />
gas emissions and removals in a product system,<br />
expressed as CO 2<br />
equivalent, and based<br />
on a →life cycle assessment. The CO 2<br />
equivalent<br />
of a specific amount of a greenhouse gas<br />
is calculated as the mass of a given greenhouse<br />
gas multiplied by its →global warmingpotential<br />
[1,2,15]<br />
54 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Basics<br />
Carbon neutral, CO 2<br />
neutral | describes a<br />
product or process that has a negligible impact<br />
on total atmospheric CO 2<br />
levels. For<br />
example, carbon neutrality means that any<br />
CO 2<br />
released when a plant decomposes or<br />
is burnt is offset by an equal amount of CO 2<br />
absorbed by the plant through photosynthesis<br />
when it is growing.<br />
Carbon neutrality can also be achieved<br />
through buying sufficient carbon credits to<br />
make up the difference. The latter option is<br />
not allowed when communicating → LCAs<br />
or carbon footprints regarding a material or<br />
product [1, 2].<br />
Carbon-neutral claims are tricky as products<br />
will not in most cases reach carbon neutrality<br />
if their complete life cycle is taken into consideration<br />
(including the end-of life).<br />
If an assessment of a material, however, is<br />
conducted (cradle to gate), carbon neutrality<br />
might be a valid claim in a B2B context. In this<br />
case, the unit assessed in the complete life<br />
cycle has to be clarified [1]<br />
Cascade use | of →renewable resources means<br />
to first use the →biomass to produce biobased<br />
industrial products and afterwards – due to<br />
their favourable energy balance – use them<br />
for energy generation (e.g. from a biobased<br />
plastic product to →biogas production). The<br />
feedstock is used efficiently and value generation<br />
increases decisively.<br />
Catalyst | substance that enables and accelerates<br />
a chemical reaction<br />
Cellophane | Clear film on the basis of →cellulose<br />
[bM 01/10]<br />
Cellulose | Cellulose is the principal component<br />
of cell walls in all higher forms of plant<br />
life, at varying percentages. It is therefore the<br />
most common organic compound and also<br />
the most common polysaccharide (multisugar)<br />
[11]. Cellulose is a polymeric molecule<br />
with very high molecular weight (monomer is<br />
→Glucose), industrial production from wood<br />
or cotton, to manufacture paper, plastics and<br />
fibres [bM 01/10]<br />
Cellulose ester | Cellulose esters occur by<br />
the esterification of cellulose with organic<br />
acids. The most important cellulose esters<br />
from a technical point of view are cellulose<br />
acetate (CA with acetic acid), cellulose propionate<br />
(CP with propionic acid) and cellulose<br />
butyrate (CB with butanoic acid). Mixed polymerisates,<br />
such as cellulose acetate propionate<br />
(CAP) can also be formed. One of the most<br />
well-known applications of cellulose aceto<br />
butyrate (CAB) is the moulded handle on the<br />
Swiss army knife [11]<br />
Cellulose acetate CA | → Cellulose ester<br />
CEN | Comité Européen de Normalisation<br />
(European organisation for standardization)<br />
Certification | is a process in which materials/products<br />
undergo a string of (laboratory)<br />
tests in order to verify that the fulfil certain<br />
requirements. Sound certification systems<br />
should be based on (ideally harmonised) European<br />
standards or technical specifications<br />
(e.g. by →CEN, USDA, ASTM, etc.) and be<br />
performed by independent third party laboratories.<br />
Successful certification guarantees<br />
a high product safety - also on this basis interconnected<br />
labels can be awarded that help<br />
the consumer to make an informed decision.<br />
Compost | A soil conditioning material of decomposing<br />
organic matter which provides nutrients<br />
and enhances soil structure.<br />
[bM 06/08, 02/09]<br />
Compostable Plastics | Plastics that are<br />
→ biodegradable under →composting conditions:<br />
specified humidity, temperature,<br />
→ microorganisms and timeframe. In order<br />
to make accurate and specific claims about<br />
compostability, the location (home, → industrial)<br />
and timeframe need to be specified [1].<br />
Several national and international standards<br />
exist for clearer definitions, for example EN<br />
14995 Plastics - Evaluation of compostability -<br />
Test scheme and specifications. [bM 02/06, bM 01/07]<br />
Composting | is the controlled →aerobic, or<br />
oxygen-requiring, decomposition of organic<br />
materials by →microorganisms, under controlled<br />
conditions. It reduces the volume and<br />
mass of the raw materials while transforming<br />
them into CO 2<br />
, water and a valuable soil conditioner<br />
– compost.<br />
When talking about composting of bioplastics,<br />
foremost →industrial composting in a<br />
managed composting facility is meant (criteria<br />
defined in EN 13432).<br />
The main difference between industrial and<br />
home composting is, that in industrial composting<br />
facilities temperatures are much<br />
higher and kept stable, whereas in the composting<br />
pile temperatures are usually lower,<br />
and less constant as depending on factors<br />
such as weather conditions. Home composting<br />
is a way slower-paced process than<br />
industrial composting. Also a comparatively<br />
smaller volume of waste is involved. [bM 03/07]<br />
Compound | plastic mixture from different<br />
raw materials (polymer and additives) [bM 04/10)<br />
Copolymer | Plastic composed of different<br />
monomers.<br />
Cradle-to-Gate | Describes the system<br />
boundaries of an environmental →Life Cycle<br />
Assessment (LCA) which covers all activities<br />
from the cradle (i.e., the extraction of raw materials,<br />
agricultural activities and forestry) up<br />
to the factory gate<br />
Cradle-to-Cradle | (sometimes abbreviated<br />
as C2C): Is an expression which communicates<br />
the concept of a closed-cycle economy,<br />
in which waste is used as raw material<br />
(‘waste equals food’). Cradle-to-Cradle is not<br />
a term that is typically used in →LCA studies.<br />
Cradle-to-Grave | Describes the system<br />
boundaries of a full →Life Cycle Assessment<br />
from manufacture (cradle) to use phase and<br />
disposal phase (grave).<br />
Crystalline | Plastic with regularly arranged<br />
molecules in a lattice structure<br />
Density | Quotient from mass and volume of<br />
a material, also referred to as specific weight<br />
DIN | Deutsches Institut für Normung (German<br />
organisation for standardization)<br />
DIN-CERTCO | independant certifying organisation<br />
for the assessment on the conformity<br />
of bioplastics<br />
Dispersing | fine distribution of non-miscible<br />
liquids into a homogeneous, stable mixture<br />
Drop-In bioplastics | chemically indentical<br />
to conventional petroleum based plastics,<br />
but made from renewable resources. Examples<br />
are bio-PE made from bio-ethanol (from<br />
e.g. sugar cane) or partly biobased PET; the<br />
monoethylene glykol made from bio-ethanol<br />
(from e.g. sugar cane). Developments to<br />
make terephthalic acid from renewable resources<br />
are under way. Other examples are<br />
polyamides (partly biobased e.g. PA 4.10 or PA<br />
6.10 or fully biobased like PA 5.10 or PA10.10)<br />
EN 13432 | European standard for the assessment<br />
of the → compostability of plastic<br />
packaging products<br />
Energy recovery | recovery and exploitation<br />
of the energy potential in (plastic) waste for<br />
the production of electricity or heat in waste<br />
incineration pants (waste-to-energy)<br />
Environmental claim | A statement, symbol<br />
or graphic that indicates one or more environmental<br />
aspect(s) of a product, a component,<br />
packaging or a service. [16]<br />
Enzymes | proteins that catalyze chemical<br />
reactions<br />
Enzyme-mediated plastics | are no →bioplastics.<br />
Instead, a conventional non-biodegradable<br />
plastic (e.g. fossil-based PE) is enriched<br />
with small amounts of an organic additive.<br />
Microorganisms are supposed to consume<br />
these additives and the degradation process<br />
should then expand to the non-biodegradable<br />
PE and thus make the material degrade. After<br />
some time the plastic is supposed to visually<br />
disappear and to be completely converted to<br />
carbon dioxide and water. This is a theoretical<br />
concept which has not been backed up by<br />
any verifiable proof so far. Producers promote<br />
enzyme-mediated plastics as a solution to littering.<br />
As no proof for the degradation process<br />
has been provided, environmental beneficial<br />
effects are highly questionable.<br />
Ethylene | colour- and odourless gas, made<br />
e.g. from, Naphtha (petroleum) by cracking or<br />
from bio-ethanol by dehydration, monomer of<br />
the polymer polyethylene (PE)<br />
European Bioplastics e.V. | The industry association<br />
representing the interests of Europe’s<br />
thriving bioplastics’ industry. Founded<br />
in Germany in 1993 as IBAW, European<br />
Bioplastics today represents the interests<br />
of about 50 member companies throughout<br />
the European Union and worldwide. With<br />
members from the agricultural feedstock,<br />
chemical and plastics industries, as well as<br />
industrial users and recycling companies, European<br />
Bioplastics serves as both a contact<br />
platform and catalyst for advancing the aims<br />
of the growing bioplastics industry.<br />
Extrusion | process used to create plastic<br />
profiles (or sheet) of a fixed cross-section<br />
consisting of mixing, melting, homogenising<br />
and shaping of the plastic.<br />
FDCA | 2,5-furandicarboxylic acid, an intermediate<br />
chemical produced from 5-HMF.<br />
The dicarboxylic acid can be used to make →<br />
PEF = polyethylene furanoate, a polyester that<br />
could be a 100% biobased alternative to PET.<br />
Fermentation | Biochemical reactions controlled<br />
by → microorganisms or → enyzmes (e.g.<br />
the transformation of sugar into lactic acid).<br />
FSC | Forest Stewardship Council. FSC is an<br />
independent, non-governmental, not-forprofit<br />
organization established to promote the<br />
responsible and sustainable management of<br />
the world’s forests.<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 55
Basics<br />
Gelatine | Translucent brittle solid substance,<br />
colorless or slightly yellow, nearly tasteless<br />
and odorless, extracted from the collagen inside<br />
animals‘ connective tissue.<br />
Genetically modified organism (GMO) | Organisms,<br />
such as plants and animals, whose<br />
genetic material (DNA) has been altered<br />
are called genetically modified organisms<br />
(GMOs). Food and feed which contain or<br />
consist of such GMOs, or are produced from<br />
GMOs, are called genetically modified (GM)<br />
food or feed [1]. If GM crops are used in bioplastics<br />
production, the multiple-stage processing<br />
and the high heat used to create the<br />
polymer removes all traces of genetic material.<br />
This means that the final bioplastics product<br />
contains no genetic traces. The resulting<br />
bioplastics is therefore well suited to use in<br />
food packaging as it contains no genetically<br />
modified material and cannot interact with<br />
the contents.<br />
Global Warming | Global warming is the rise<br />
in the average temperature of Earth’s atmosphere<br />
and oceans since the late 19th century<br />
and its projected continuation [8]. Global<br />
warming is said to be accelerated by → green<br />
house gases.<br />
Glucose | Monosaccharide (or simple sugar).<br />
G. is the most important carbohydrate (sugar)<br />
in biology. G. is formed by photosynthesis or<br />
hydrolyse of many carbohydrates e. g. starch.<br />
Greenhouse gas GHG | Gaseous constituent<br />
of the atmosphere, both natural and anthropogenic,<br />
that absorbs and emits radiation at<br />
specific wavelengths within the spectrum of<br />
infrared radiation emitted by the earth’s surface,<br />
the atmosphere, and clouds [1, 9]<br />
Greenwashing | The act of misleading consumers<br />
regarding the environmental practices<br />
of a company, or the environmental benefits<br />
of a product or service [1, 10]<br />
Granulate, granules | small plastic particles<br />
(3-4 millimetres), a form in which plastic is<br />
sold and fed into machines, easy to handle<br />
and dose.<br />
HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />
organic compound derived from sugar dehydration.<br />
It is a platform chemical, a building<br />
block for 20 performance polymers and over<br />
175 different chemical substances. The molecule<br />
consists of a furan ring which contains<br />
both aldehyde and alcohol functional groups.<br />
5-HMF has applications in many different<br />
industries such as bioplastics, packaging,<br />
pharmaceuticals, adhesives and chemicals.<br />
One of the most promising routes is 2,5<br />
furandicarboxylic acid (FDCA), produced as an<br />
intermediate when 5-HMF is oxidised. FDCA<br />
is used to produce PEF, which can substitute<br />
terephthalic acid in polyester, especially polyethylene<br />
terephthalate (PET). [bM 03/14, 02/16]<br />
Home composting | →composting [bM 06/08]<br />
Humus | In agriculture, humus is often used<br />
simply to mean mature →compost, or natural<br />
compost extracted from a forest or other<br />
spontaneous source for use to amend soil.<br />
Hydrophilic | Property: water-friendly, soluble<br />
in water or other polar solvents (e.g. used<br />
in conjunction with a plastic which is not water<br />
resistant and weather proof or that absorbs<br />
water such as Polyamide (PA).<br />
Hydrophobic | Property: water-resistant, not<br />
soluble in water (e.g. a plastic which is water<br />
resistant and weather proof, or that does not<br />
absorb any water such as Polyethylene (PE)<br />
or Polypropylene (PP).<br />
Industrial composting | is an established<br />
process with commonly agreed upon requirements<br />
(e.g. temperature, timeframe) for transforming<br />
biodegradable waste into stable, sanitised<br />
products to be used in agriculture. The<br />
criteria for industrial compostability of packaging<br />
have been defined in the EN 13432. Materials<br />
and products complying with this standard<br />
can be certified and subsequently labelled<br />
accordingly [1,7] [bM 06/08, 02/09]<br />
ISO | International Organization for Standardization<br />
JBPA | Japan Bioplastics Association<br />
Land use | The surface required to grow sufficient<br />
feedstock (land use) for today’s bioplastic<br />
production is less than 0.01 percent of the<br />
global agricultural area of 5 billion hectares.<br />
It is not yet foreseeable to what extent an increased<br />
use of food residues, non-food crops<br />
or cellulosic biomass (see also →1 st /2 nd /3 rd<br />
generation feedstock) in bioplastics production<br />
might lead to an even further reduced<br />
land use in the future [bM 04/09, 01/14]<br />
LCA | is the compilation and evaluation of the<br />
input, output and the potential environmental<br />
impact of a product system throughout its life<br />
cycle [17]. It is sometimes also referred to as<br />
life cycle analysis, ecobalance or cradle-tograve<br />
analysis. [bM 01/09]<br />
Littering | is the (illegal) act of leaving waste<br />
such as cigarette butts, paper, tins, bottles,<br />
cups, plates, cutlery or bags lying in an open<br />
or public place.<br />
Marine litter | Following the European Commission’s<br />
definition, “marine litter consists of<br />
items that have been deliberately discarded,<br />
unintentionally lost, or transported by winds<br />
and rivers, into the sea and on beaches. It<br />
mainly consists of plastics, wood, metals,<br />
glass, rubber, clothing and paper”. Marine<br />
debris originates from a variety of sources.<br />
Shipping and fishing activities are the predominant<br />
sea-based, ineffectively managed<br />
landfills as well as public littering the main<br />
land-based sources. Marine litter can pose a<br />
threat to living organisms, especially due to<br />
ingestion or entanglement.<br />
Currently, there is no international standard<br />
available, which appropriately describes the<br />
biodegradation of plastics in the marine environment.<br />
However, a number of standardisation<br />
projects are in progress at ISO and ASTM<br />
level. Furthermore, the European project<br />
OPEN BIO addresses the marine biodegradation<br />
of biobased products.[bM 02/16]<br />
Mass balance | describes the relationship between<br />
input and output of a specific substance<br />
within a system in which the output from the<br />
system cannot exceed the input into the system.<br />
First attempts were made by plastic raw material<br />
producers to claim their products renewable<br />
(plastics) based on a certain input<br />
of biomass in a huge and complex chemical<br />
plant, then mathematically allocating this<br />
biomass input to the produced plastic.<br />
These approaches are at least controversially<br />
disputed [bM 04/14, <strong>05</strong>/14, 01/15]<br />
Microorganism | Living organisms of microscopic<br />
size, such as bacteria, funghi or yeast.<br />
Molecule | group of at least two atoms held<br />
together by covalent chemical bonds.<br />
Monomer | molecules that are linked by polymerization<br />
to form chains of molecules and<br />
then plastics<br />
Mulch film | Foil to cover bottom of farmland<br />
Organic recycling | means the treatment of<br />
separately collected organic waste by anaerobic<br />
digestion and/or composting.<br />
Oxo-degradable / Oxo-fragmentable | materials<br />
and products that do not biodegrade!<br />
The underlying technology of oxo-degradability<br />
or oxo-fragmentation is based on special additives,<br />
which, if incorporated into standard<br />
resins, are purported to accelerate the fragmentation<br />
of products made thereof. Oxodegradable<br />
or oxo-fragmentable materials do<br />
not meet accepted industry standards on compostability<br />
such as EN 13432. [bM 01/09, <strong>05</strong>/09]<br />
PBAT | Polybutylene adipate terephthalate, is<br />
an aliphatic-aromatic copolyester that has the<br />
properties of conventional polyethylene but is<br />
fully biodegradable under industrial composting.<br />
PBAT is made from fossil petroleum with<br />
first attempts being made to produce it partly<br />
from renewable resources [bM 06/09]<br />
PBS | Polybutylene succinate, a 100% biodegradable<br />
polymer, made from (e.g. bio-BDO)<br />
and succinic acid, which can also be produced<br />
biobased [bM 03/12].<br />
PC | Polycarbonate, thermoplastic polyester,<br />
petroleum based and not degradable, used<br />
for e.g. baby bottles or CDs. Criticized for its<br />
BPA (→ Bisphenol-A) content.<br />
PCL | Polycaprolactone, a synthetic (fossil<br />
based), biodegradable bioplastic, e.g. used as<br />
a blend component.<br />
PE | Polyethylene, thermoplastic polymerised<br />
from ethylene. Can be made from renewable<br />
resources (sugar cane via bio-ethanol) [bM <strong>05</strong>/10]<br />
PEF | polyethylene furanoate, a polyester<br />
made from monoethylene glycol (MEG) and<br />
→FDCA (2,5-furandicarboxylic acid , an intermediate<br />
chemical produced from 5-HMF). It<br />
can be a 100% biobased alternative for PET.<br />
PEF also has improved product characteristics,<br />
such as better structural strength and<br />
improved barrier behaviour, which will allow<br />
for the use of PEF bottles in additional applications.<br />
[bM 03/11, 04/12]<br />
PET | Polyethylenterephthalate, transparent<br />
polyester used for bottles and film. The<br />
polyester is made from monoethylene glycol<br />
(MEG), that can be renewably sourced from<br />
bio-ethanol (sugar cane) and (until now fossil)<br />
terephthalic acid [bM 04/14]<br />
PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />
thermoplastic polymer and the<br />
simplest linear, aliphatic polyester. Besides<br />
ist use in the biomedical field, PGA has been<br />
introduced as a barrier resin [bM 03/09]<br />
PHA | Polyhydroxyalkanoates (PHA) or the<br />
polyhydroxy fatty acids, are a family of biodegradable<br />
polyesters. As in many mammals,<br />
including humans, that hold energy reserves<br />
in the form of body fat there are also bacteria<br />
that hold intracellular reserves in for of<br />
of polyhydroxy alkanoates. Here the microorganisms<br />
store a particularly high level of<br />
56 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Basics<br />
energy reserves (up to 80% of their own body<br />
weight) for when their sources of nutrition become<br />
scarce. By farming this type of bacteria,<br />
and feeding them on sugar or starch (mostly<br />
from maize), or at times on plant oils or other<br />
nutrients rich in carbonates, it is possible to<br />
obtain PHA‘s on an industrial scale [11]. The<br />
most common types of PHA are PHB (Polyhydroxybutyrate,<br />
PHBV and PHBH. Depending<br />
on the bacteria and their food, PHAs with<br />
different mechanical properties, from rubbery<br />
soft trough stiff and hard as ABS, can be produced.<br />
Some PHSs are even biodegradable in<br />
soil or in a marine environment<br />
PLA | Polylactide or Polylactic Acid (PLA), a<br />
biodegradable, thermoplastic, linear aliphatic<br />
polyester based on lactic acid, a natural acid,<br />
is mainly produced by fermentation of sugar<br />
or starch with the help of micro-organisms.<br />
Lactic acid comes in two isomer forms, i.e. as<br />
laevorotatory D(-)lactic acid and as dextrorotary<br />
L(+)lactic acid.<br />
Modified PLA types can be produced by the<br />
use of the right additives or by certain combinations<br />
of L- and D- lactides (stereocomplexing),<br />
which then have the required rigidity for<br />
use at higher temperatures [13] [bM 01/09, 01/12]<br />
Plastics | Materials with large molecular<br />
chains of natural or fossil raw materials, produced<br />
by chemical or biochemical reactions.<br />
PPC | Polypropylene Carbonate, a bioplastic<br />
made by copolymerizing CO 2<br />
with propylene<br />
oxide (PO) [bM 04/12]<br />
PTT | Polytrimethylterephthalate (PTT), partially<br />
biobased polyester, is similarly to PET<br />
produced using terephthalic acid or dimethyl<br />
terephthalate and a diol. In this case it is a<br />
biobased 1,3 propanediol, also known as bio-<br />
PDO [bM 01/13]<br />
Renewable Resources | agricultural raw materials,<br />
which are not used as food or feed,<br />
but as raw material for industrial products<br />
or to generate energy. The use of renewable<br />
resources by industry saves fossil resources<br />
and reduces the amount of → greenhouse gas<br />
emissions. Biobased plastics are predominantly<br />
made of annual crops such as corn,<br />
cereals and sugar beets or perennial cultures<br />
such as cassava and sugar cane.<br />
Resource efficiency | Use of limited natural<br />
resources in a sustainable way while minimising<br />
impacts on the environment. A resource<br />
efficient economy creates more output<br />
or value with lesser input.<br />
Seedling Logo | The compostability label or<br />
logo Seedling is connected to the standard<br />
EN 13432/EN 14995 and a certification process<br />
managed by the independent institutions<br />
→DIN CERTCO and → TÜV Austria. Bioplastics<br />
products carrying the Seedling fulfil the criteria<br />
laid down in the EN 13432 regarding industrial<br />
compostability. [bM 01/06, 02/10]<br />
Saccharins or carbohydrates | Saccharins or<br />
carbohydrates are name for the sugar-family.<br />
Saccharins are monomer or polymer sugar<br />
units. For example, there are known mono-,<br />
di- and polysaccharose. → glucose is a monosaccarin.<br />
They are important for the diet and<br />
produced biology in plants.<br />
Semi-finished products | plastic in form of<br />
sheet, film, rods or the like to be further processed<br />
into finshed products<br />
Sorbitol | Sugar alcohol, obtained by reduction<br />
of glucose changing the aldehyde group<br />
to an additional hydroxyl group. S. is used as<br />
a plasticiser for bioplastics based on starch.<br />
Starch | Natural polymer (carbohydrate)<br />
consisting of → amylose and → amylopectin,<br />
gained from maize, potatoes, wheat, tapioca<br />
etc. When glucose is connected to polymerchains<br />
in definite way the result (product) is<br />
called starch. Each molecule is based on 300<br />
-12000-glucose units. Depending on the connection,<br />
there are two types → amylose and →<br />
amylopectin known. [bM <strong>05</strong>/09]<br />
Starch derivatives | Starch derivatives are<br />
based on the chemical structure of → starch.<br />
The chemical structure can be changed by<br />
introducing new functional groups without<br />
changing the → starch polymer. The product<br />
has different chemical qualities. Mostly the<br />
hydrophilic character is not the same.<br />
Starch-ester | One characteristic of every<br />
starch-chain is a free hydroxyl group. When<br />
every hydroxyl group is connected with an<br />
acid one product is starch-ester with different<br />
chemical properties.<br />
Starch propionate and starch butyrate |<br />
Starch propionate and starch butyrate can be<br />
synthesised by treating the → starch with propane<br />
or butanic acid. The product structure<br />
is still based on → starch. Every based → glucose<br />
fragment is connected with a propionate<br />
or butyrate ester group. The product is more<br />
hydrophobic than → starch.<br />
Sustainable | An attempt to provide the best<br />
outcomes for the human and natural environments<br />
both now and into the indefinite future.<br />
One famous definition of sustainability is the<br />
one created by the Brundtland Commission,<br />
led by the former Norwegian Prime Minister<br />
G. H. Brundtland. The Brundtland Commission<br />
defined sustainable development as<br />
development that ‘meets the needs of the<br />
present without compromising the ability of<br />
future generations to meet their own needs.’<br />
Sustainability relates to the continuity of economic,<br />
social, institutional and environmental<br />
aspects of human society, as well as the nonhuman<br />
environment).<br />
Sustainable sourcing | of renewable feedstock<br />
for biobased plastics is a prerequisite<br />
for more sustainable products. Impacts such<br />
as the deforestation of protected habitats<br />
or social and environmental damage arising<br />
from poor agricultural practices must<br />
be avoided. Corresponding certification<br />
schemes, such as ISCC PLUS, WLC or Bon-<br />
Sucro, are an appropriate tool to ensure the<br />
sustainable sourcing of biomass for all applications<br />
around the globe.<br />
Sustainability | as defined by European Bioplastics,<br />
has three dimensions: economic, social<br />
and environmental. This has been known<br />
as “the triple bottom line of sustainability”.<br />
This means that sustainable development involves<br />
the simultaneous pursuit of economic<br />
prosperity, environmental protection and social<br />
equity. In other words, businesses have<br />
to expand their responsibility to include these<br />
environmental and social dimensions. Sustainability<br />
is about making products useful to<br />
markets and, at the same time, having societal<br />
benefits and lower environmental impact<br />
than the alternatives currently available. It also<br />
implies a commitment to continuous improvement<br />
that should result in a further reduction<br />
of the environmental footprint of today’s products,<br />
processes and raw materials used.<br />
Thermoplastics | Plastics which soften or<br />
melt when heated and solidify when cooled<br />
(solid at room temperature).<br />
Thermoplastic Starch | (TPS) → starch that<br />
was modified (cooked, complexed) to make it<br />
a plastic resin<br />
Thermoset | Plastics (resins) which do not<br />
soften or melt when heated. Examples are<br />
epoxy resins or unsaturated polyester resins.<br />
TÜV Austria Belgium | independant certifying<br />
organisation for the assessment on the conformity<br />
of bioplastics (formerly Vinçotte)<br />
Vinçotte | → TÜV Austria Belgium<br />
WPC | Wood Plastic Composite. Composite<br />
materials made of wood fiber/flour and plastics<br />
(mostly polypropylene).<br />
Yard Waste | Grass clippings, leaves, trimmings,<br />
garden residue.<br />
References:<br />
[1] Environmental Communication Guide,<br />
European Bioplastics, Berlin, Germany,<br />
2012<br />
[2] ISO 14067. Carbon footprint of products -<br />
Requirements and guidelines for quantification<br />
and communication<br />
[3] CEN TR 15932, Plastics - Recommendation<br />
for terminology and characterisation<br />
of biopolymers and bioplastics, 2010<br />
[4] CEN/TS 16137, Plastics - Determination<br />
of bio-based carbon content, 2011<br />
[5] ASTM D6866, Standard Test Methods for<br />
Determining the Biobased Content of<br />
Solid, Liquid, and Gaseous Samples Using<br />
Radiocarbon Analysis<br />
[6] SPI: Understanding Biobased Carbon<br />
Content, 2012<br />
[7] EN 13432, Requirements for packaging<br />
recoverable through composting and biodegradation.<br />
Test scheme and evaluation<br />
criteria for the final acceptance of packaging,<br />
2000<br />
[8] Wikipedia<br />
[9] ISO 14064 Greenhouse gases -- Part 1:<br />
Specification with guidance..., 2006<br />
[10] Terrachoice, 2010, www.terrachoice.com<br />
[11] Thielen, M.: Bioplastics: Basics. Applications.<br />
Markets, Polymedia Publisher,<br />
2012<br />
[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />
FNR, 20<strong>05</strong><br />
[13] de Vos, S.: Improving heat-resistance of<br />
PLA using poly(D-lactide),<br />
bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />
[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />
MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />
[15] ISO 14067 onb Corbon Footprint of<br />
Products<br />
[16] ISO 14021 on Self-declared Environmental<br />
claims<br />
[17] ISO 14044 on Life Cycle Assessment<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 57
Suppliers Guide<br />
1. Raw Materials<br />
AGRANA Starch<br />
Bioplastics<br />
Conrathstraße 7<br />
A-3950 Gmuend, Austria<br />
bioplastics.starch@agrana.com<br />
www.agrana.com<br />
Xinjiang Blue Ridge Tunhe<br />
Polyester Co., Ltd.<br />
No. 316, South Beijing Rd. Changji,<br />
Xinjiang, 831100, P.R.China<br />
Tel.: +86 994 22 90 90 9<br />
Mob: +86 187 99 283 100<br />
chenjianhui@lanshantunhe.com<br />
www.lanshantunhe.com<br />
PBAT & PBS resin supplier<br />
Kingfa Sci. & Tech. Co., Ltd.<br />
No.33 Kefeng Rd, Sc. City, Guangzhou<br />
Hi-Tech Ind. Development Zone,<br />
Guangdong, P.R. China. 510663<br />
Tel: +86 (0)20 6622 1696<br />
info@ecopond.com.cn<br />
www.kingfa.com<br />
39 mm<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
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Suppliers Guide with your company<br />
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For only 6,– EUR per mm, per issue you<br />
can be present among top suppliers in<br />
the field of bioplastics.<br />
For Example:<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
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The entry in our Suppliers Guide is<br />
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extends automatically if it’s not canceled<br />
three month before expiry.<br />
www.facebook.com<br />
www.issuu.com<br />
www.twitter.com<br />
www.youtube.com<br />
BASF SE<br />
Ludwigshafen, Germany<br />
Tel: +49 621 60-99951<br />
martin.bussmann@basf.com<br />
www.ecovio.com<br />
Gianeco S.r.l.<br />
Via Magenta 57 10128 Torino - Italy<br />
Tel.+390119370420<br />
info@gianeco.com<br />
www.gianeco.com<br />
PTT MCC Biochem Co., Ltd.<br />
info@pttmcc.com / www.pttmcc.com<br />
Tel: +66(0) 2 140-3563<br />
MCPP Germany GmbH<br />
+49 (0) 152-018 920 51<br />
frank.steinbrecher@mcpp-europe.com<br />
MCPP France SAS<br />
+33 (0) 6 07 22 25 32<br />
fabien.resweber@mcpp-europe.com<br />
Microtec Srl<br />
Via Po’, 53/55<br />
30030, Mellaredo di Pianiga (VE),<br />
Italy<br />
Tel.: +39 041 5190621<br />
Fax.: +39 041 5194765<br />
info@microtecsrl.com<br />
www.biocomp.it<br />
Tel: +86 351-8689356<br />
Fax: +86 351-8689718<br />
www.jinhuizhaolong.com<br />
ecoworldsales@jinhuigroup.com<br />
Jincheng, Lin‘an, Hangzhou,<br />
Zhejiang 311300, P.R. China<br />
China contact: Grace Jin<br />
mobile: 0086 135 7578 9843<br />
Grace@xinfupharm.comEurope<br />
contact(Belgium): Susan Zhang<br />
mobile: 0032 478 991619<br />
zxh0612@hotmail.com<br />
www.xinfupharm.com<br />
1.1 bio based monomers<br />
1.2 compounds<br />
Cardia Bioplastics<br />
Suite 6, 2<strong>05</strong>-211 Forster Rd<br />
Mt. Waverley, VIC, 3149 Australia<br />
Tel. +61 3 85666800<br />
info@cardiabioplastics.com<br />
www.cardiabioplastics.com<br />
API S.p.A.<br />
Via Dante Alighieri, 27<br />
36065 Mussolente (VI), Italy<br />
Telephone +39 0424 579711<br />
www.apiplastic.com<br />
www.apinatbio.com<br />
BIO-FED<br />
Branch of AKRO-PLASTIC GmbH<br />
BioCampus Cologne<br />
Nattermannallee 1<br />
50829 Cologne, Germany<br />
Tel.: +49 221 88 88 94-00<br />
info@bio-fed.com<br />
www.bio-fed.com<br />
Global Biopolymers Co.,Ltd.<br />
Bioplastics compounds<br />
(PLA+starch;PLA+rubber)<br />
194 Lardproa80 yak 14<br />
Wangthonglang, Bangkok<br />
Thailand 10310<br />
info@globalbiopolymers.com<br />
www.globalbiopolymers.com<br />
Tel +66 81 9150446<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel. +49 2154 9251-0<br />
Tel.: +49 2154 9251-51<br />
sales@fkur.com<br />
www.fkur.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Green Dot Bioplastics<br />
226 Broadway | PO Box #142<br />
Cottonwood Falls, KS 66845, USA<br />
Tel.: +1 620-273-8919<br />
info@greendotholdings.com<br />
www.greendotpure.com<br />
NUREL Engineering Polymers<br />
Ctra. Barcelona, km 329<br />
50016 Zaragoza, Spain<br />
Tel: +34 976 465 579<br />
inzea@samca.com<br />
www.inzea-biopolymers.com<br />
Sukano AG<br />
Chaltenbodenstraße 23<br />
CH-8834 Schindellegi<br />
Tel. +41 44 787 57 77<br />
Fax +41 44 787 57 78<br />
www.sukano.com<br />
58 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
Suppliers Guide<br />
Natureplast – Biopolynov<br />
11 rue François Arago<br />
14123 IFS<br />
Tel: +33 (0)2 31 83 50 87<br />
www.natureplast.eu<br />
TECNARO GmbH<br />
Bustadt 40<br />
D-74360 Ilsfeld. Germany<br />
Tel: +49 (0)7062/97687-0<br />
www.tecnaro.de<br />
1.3 PLA<br />
Total Corbion PLA bv<br />
Arkelsedijk 46, P.O. Box 21<br />
4200 AA Gorinchem<br />
The Netherlands<br />
Tel.: +31 183 695 695<br />
Fax.: +31 183 695 604<br />
www.total-corbion.com<br />
pla@total-corbion.com<br />
Zhejiang Hisun Biomaterials Co.,Ltd.<br />
No.97 Waisha Rd, Jiaojiang District,<br />
Taizhou City, Zhejiang Province, China<br />
Tel: +86-576-88827723<br />
pla@hisunpharm.com<br />
www.hisunplas.com<br />
1.4 starch-based bioplastics<br />
BIOTEC<br />
Biologische Naturverpackungen<br />
Werner-Heisenberg-Strasse 32<br />
46446 Emmerich/Germany<br />
Tel.: +49 (0) 2822 – 92510<br />
info@biotec.de<br />
www.biotec.de<br />
Plásticos Compuestos S.A.<br />
C/ Basters 15<br />
08184 Palau Solità i Plegamans<br />
Barcelona, Spain<br />
Tel. +34 93 863 96 70<br />
info@kompuestos.com<br />
www.kompuestos.com<br />
1.5 PHA<br />
Bio-on S.p.A.<br />
Via Santa Margherita al Colle 10/3<br />
40136 Bologna - ITALY<br />
Tel.: +39 <strong>05</strong>1 392336<br />
info@bio-on.it<br />
www.bio-on.it<br />
Kaneka Belgium N.V.<br />
Nijverheidsstraat 16<br />
2260 Westerlo-Oevel, Belgium<br />
Tel: +32 (0)14 25 78 36<br />
Fax: +32 (0)14 25 78 81<br />
info.biopolymer@kaneka.be<br />
TianAn Biopolymer<br />
No. 68 Dagang 6th Rd,<br />
Beilun, Ningbo, China, 315800<br />
Tel. +86-57 48 68 62 50 2<br />
Fax +86-57 48 68 77 98 0<br />
enquiry@tianan-enmat.com<br />
www.tianan-enmat.com<br />
1.6 masterbatches<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Albrecht Dinkelaker<br />
Polymer and Product Development<br />
Blumenweg 2<br />
79669 Zell im Wiesental, Germany<br />
Tel.:+49 (0) 7625 91 84 58<br />
info@polyfea2.de<br />
www.caprowax-p.eu<br />
Treffert GmbH & Co. KG<br />
In der Weide 17<br />
55411 Bingen am Rhein; Germany<br />
+49 6721 403 0<br />
www.treffert.eu<br />
Treffert S.A.S.<br />
Rue de la Jontière<br />
57255 Sainte-Marie-aux-Chênes,<br />
France<br />
+33 3 87 31 84 84<br />
www.treffert.fr<br />
2. Additives/Secondary raw materials<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
3. Semi finished products<br />
3.1 films<br />
4. Bioplastics products<br />
Bio-on S.p.A.<br />
Via Santa Margherita al Colle 10/3<br />
40136 Bologna - ITALY<br />
Tel.: +39 <strong>05</strong>1 392336<br />
info@bio-on.it<br />
www.bio-on.it<br />
Bio4Pack GmbH<br />
D-48529 Nordhorn, Germany<br />
Tel.: +49 (0) 5921 818 37 00<br />
info@bio4pack.com<br />
www.bio4pack.com<br />
BeoPlast Besgen GmbH<br />
Bioplastics injection moulding<br />
Industriestraße 64<br />
D-40764 Langenfeld, Germany<br />
Tel. +49 2173 84840-0<br />
info@beoplast.de<br />
www.beoplast.de<br />
INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />
45, 0,90, 0<br />
10, 0, 80,0<br />
(ICBP) C, M, Y, KSDN BHD<br />
C, M, Y, K<br />
50, 0 ,0, 0<br />
0, 0, 0, 0<br />
12, Jalan i-Park SAC 3<br />
Senai Airport City<br />
81400 Senai, Johor, Malaysia<br />
Tel. +60 7 5959 159<br />
marketing@icbp.com.my<br />
www.icbp.com.my<br />
Minima Technology Co., Ltd.<br />
Esmy Huang, COO<br />
No.33. Yichang E. Rd., Taipin City,<br />
Taichung County<br />
411, Taiwan (R.O.C.)<br />
Tel. +886(4)2277 6888<br />
Fax +883(4)2277 6989<br />
Mobil +886(0)982-829988<br />
esmy@minima-tech.com<br />
Skype esmy325<br />
www.minima.com<br />
Natur-Tec ® - Northern Technologies<br />
4201 Woodland Road<br />
Circle Pines, MN 55014 USA<br />
Tel. +1 763.404.8700<br />
Fax +1 763.225.6645<br />
info@natur-tec.com<br />
www.natur-tec.com<br />
NOVAMONT S.p.A.<br />
Via Fauser , 8<br />
28100 Novara - ITALIA<br />
Fax +39.0321.699.601<br />
Tel. +39.0321.699.611<br />
www.novamont.com<br />
6. Equipment<br />
6.1 Machinery & Molds<br />
Buss AG<br />
Hohenrainstrasse 10<br />
4133 Pratteln / Switzerland<br />
Tel.: +41 61 825 66 00<br />
Fax: +41 61 825 68 58<br />
info@busscorp.com<br />
www.busscorp.com<br />
6.2 Degradability Analyzer<br />
MODA: Biodegradability Analyzer<br />
SAIDA FDS INC.<br />
143-10 Isshiki, Yaizu,<br />
Shizuoka,Japan<br />
Tel:+81-54-624-6155<br />
Fax: +81-54-623-8623<br />
info_fds@saidagroup.jp<br />
www.saidagroup.jp/fds_en/<br />
7. Plant engineering<br />
EREMA Engineering Recycling<br />
Maschinen und Anlagen GmbH<br />
Unterfeldstrasse 3<br />
4<strong>05</strong>2 Ansfelden, AUSTRIA<br />
Phone: +43 (0) 732 / 3190-0<br />
Fax: +43 (0) 732 / 3190-23<br />
erema@erema.at<br />
www.erema.at<br />
Uhde Inventa-Fischer GmbH<br />
Holzhauser Strasse 157–159<br />
D-13509 Berlin<br />
Tel. +49 30 43 567 5<br />
Fax +49 30 43 567 699<br />
sales.de@uhde-inventa-fischer.com<br />
Uhde Inventa-Fischer AG<br />
Via Innovativa 31, CH-7013 Domat/Ems<br />
Tel. +41 81 632 63 11<br />
Fax +41 81 632 74 03<br />
sales.ch@uhde-inventa-fischer.com<br />
www.uhde-inventa-fischer.com<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 59
Suppliers Guide<br />
9. Services<br />
10.2 Universities<br />
10.3 Other Institutions<br />
Osterfelder Str. 3<br />
46047 Oberhausen<br />
Tel.: +49 (0)208 8598 1227<br />
thomas.wodke@umsicht.fhg.de<br />
www.umsicht.fraunhofer.de<br />
Innovation Consulting Harald Kaeb<br />
narocon<br />
Dr. Harald Kaeb<br />
Tel.: +49 30-28096930<br />
kaeb@narocon.de<br />
www.narocon.de<br />
9. Services (continued)<br />
nova-Institut GmbH<br />
Chemiepark Knapsack<br />
Industriestrasse 300<br />
50354 Huerth, Germany<br />
Tel.: +49(0)2233-48-14 40<br />
E-Mail: contact@nova-institut.de<br />
www.biobased.eu<br />
Bioplastics Consulting<br />
Tel. +49 2161 664864<br />
info@polymediaconsult.com<br />
10. Institutions<br />
10.1 Associations<br />
BPI - The Biodegradable<br />
Products Institute<br />
331 West 57th Street, Suite 415<br />
New York, NY 10019, USA<br />
Tel. +1-888-274-5646<br />
info@bpiworld.org<br />
European Bioplastics e.V.<br />
Marienstr. 19/20<br />
10117 Berlin, Germany<br />
Tel. +49 30 284 82 350<br />
Fax +49 30 284 84 359<br />
info@european-bioplastics.org<br />
www.european-bioplastics.org<br />
Institut für Kunststofftechnik<br />
Universität Stuttgart<br />
Böblinger Straße 70<br />
70199 Stuttgart<br />
Tel +49 711/685-62831<br />
silvia.kliem@ikt.uni-stuttgart.de<br />
www.ikt.uni-stuttgart.de<br />
Michigan State University<br />
Dept. of Chem. Eng & Mat. Sc.<br />
Professor Ramani Narayan<br />
East Lansing MI 48824, USA<br />
Tel. +1 517 719 7163<br />
narayan@msu.edu<br />
IfBB – Institute for Bioplastics<br />
and Biocomposites<br />
University of Applied Sciences<br />
and Arts Hanover<br />
Faculty II – Mechanical and<br />
Bioprocess Engineering<br />
Heisterbergallee 12<br />
30453 Hannover, Germany<br />
Tel.: +49 5 11 / 92 96 - 22 69<br />
Fax: +49 5 11 / 92 96 - 99 - 22 69<br />
lisa.mundzeck@hs-hannover.de<br />
www.ifbb-hannover.de/<br />
GO!PHA<br />
Rick Passenier<br />
Oudebrugsteeg 9<br />
1012JN Amsterdam<br />
The Netherlands<br />
info@gopha.org<br />
www.gopha.org<br />
Green Serendipity<br />
Caroli Buitenhuis<br />
IJburglaan 836<br />
1087 EM Amsterdam<br />
The Netherlands<br />
Tel.: +31 6-24216733<br />
www.greenseredipity.nl<br />
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60 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
1_<strong>05</strong>.2017<br />
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13.10.<strong>2019</strong> - 14.10.<strong>2019</strong> - Kuweit<br />
https://traiconevents.com/sustainable/kuwait/<br />
K <strong>2019</strong><br />
16.10.<strong>2019</strong> - 23.10.<strong>2019</strong> - Duesseldorf, Germany<br />
www.k-online.com<br />
Bioplastics Business Breakfast K‘<strong>2019</strong><br />
17.10.<strong>2019</strong> - 20.10.<strong>2019</strong> - Duesseldorf, Germany<br />
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23.10.<strong>2019</strong> - 24.10.<strong>2019</strong> - London, Great Britain<br />
https://sustainablepackaging.org/events/spc-engage-london/<br />
WWW.MATERBI.COM<br />
North American Biopolymer Summit <strong>2019</strong><br />
06.11.<strong>2019</strong> - 07.11.<strong>2019</strong> - Chicago,IL,USA<br />
https://www.wplgroup.com/aci/event/biopolymer-summit-usa/<br />
bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />
Basics<br />
Home composting | 44<br />
Highlights<br />
Bottles / Blow Moulding | 10<br />
Biocomposites | 24<br />
r1_<strong>05</strong>.2017<br />
<strong>05</strong>/<strong>05</strong>/17 11:39<br />
Jul / Aug<br />
bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />
04 | <strong>2019</strong><br />
Cover Story<br />
Cove PHA bottles<br />
Preview:<br />
Highlights<br />
Fibers / Textiles / Nonwovens | 16<br />
Barrier Materials | 38<br />
... is read in 92 countries<br />
Sep / Oct<br />
Cover Story<br />
Lightweighting PBAT<br />
based materials<br />
Jinhui Zhaolong<br />
<strong>05</strong> | <strong>2019</strong><br />
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BioPlastEx’<strong>2019</strong><br />
08.11.<strong>2019</strong> - 09.11.<strong>2019</strong> - Bangalore, India<br />
www.BioPlastEx.com<br />
8th Biocomposites Conference Cologne<br />
14.11.<strong>2019</strong> - 15.11.<strong>2019</strong> - Cologne, Germany<br />
www.biocompositescc.com<br />
Frontiers in Polymer Chemistry and Biopolymers<br />
18.11.<strong>2019</strong> - 19.11.<strong>2019</strong> - Rome, Italy<br />
https://www.longdom.com/polymerchemistry<br />
14th European Bioplastics Conference <strong>2019</strong><br />
03.12.<strong>2019</strong> - 04.12.<strong>2019</strong> - Berlin, Germany<br />
https://www.european-bioplastics.org/events/eubp-conference/<br />
4th European Chemistry Partnering<br />
27.02.2020 - Frankfurt, Germany<br />
https://european-chemistry-partnering.com/<br />
<strong>05</strong>/<strong>05</strong>/17 11:39<br />
+<br />
or<br />
Plastics beyond Petroleum-BioMass & Recycling<br />
12.<strong>05</strong>.2020 - 13.<strong>05</strong>.2020 - New York City Area, USA<br />
http://innoplastsolutions.com/conference.html<br />
The Greener Manufacturing Show<br />
16.06.2020 - 17.06.2020 - Cologne, Germany<br />
https://www.greener-manufacturing.com/welcome<br />
Mention the promotion code ‘watch‘ or ‘book‘<br />
and you will get our watch or the book 3)<br />
Bioplastics Basics. Applications. Markets. for free<br />
(new subscribers only)<br />
1) Offer valid until 31 Dec. <strong>2019</strong><br />
3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />
bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 61
Companies in this issue<br />
Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />
Abioplastics 29<br />
Agiplast 30<br />
Agrana Starch Bioplastics 58<br />
AIMPLAS 34, 43<br />
Albis 29<br />
Allied Market Research 7<br />
AMIBM 16<br />
API 58<br />
Arkema 35<br />
BASF 7 58<br />
Beologic 34<br />
BeoPlast Besgen 59<br />
Bio4Pack 48 59<br />
Bio4Self 14<br />
Bio-Fed Branch of Akro-Plastic 58<br />
Biofribre 34<br />
Bio-On 7, 14 59<br />
Biotec 40 59, 63<br />
BPI 60<br />
Braskem 15, 39<br />
Buss 59<br />
CaixaBank 36<br />
Cake 36<br />
Caprowachs, Albrecht Dinkelaker 59<br />
Carbiolice 14, 30<br />
Cardia Bioplastics 58<br />
Corbion 26, 31<br />
Dantoy 15<br />
Dr. BOY 8, 29<br />
Dr. Heinz Gupta Verlag 60<br />
DuPont 42<br />
DWI Leibniz Inst. F. Interactive Mat. 24<br />
Erema 37, 59<br />
European Bioplastics 8, 28, 29 47, 60<br />
Evonik 35<br />
Faculty of Life Scienes, Albst Sigm. 45<br />
Farrel 53<br />
Federal Mogul Powertrian 52<br />
First Mile 6<br />
FKuR 15, 29, 47 2, 58<br />
Fraunhofer IAP 15<br />
Fraunhofer IVV 45<br />
Fraunhofer UMSICHT 60<br />
Furanix Technologies 53<br />
Gema Polimer 31<br />
Gianeco 58<br />
Global Biopolymers 58<br />
Go!PHA 6 60<br />
Grafe 58, 59<br />
Green Chemistry Campus 50<br />
Green Dot Bioplastics 58<br />
Green Serendipity 60<br />
Hexpol TPE 37<br />
ICCI SEA 18<br />
Indochine Bio Plastiques 59<br />
Inst. F. Bioplastics & Biocomposites 60<br />
Institut f. Kunststofftechnik, Stuttgart 60<br />
Institut für Textiltechnik ITA 20, 24<br />
INSTM, Univ. Pisa 45<br />
IRIS Technology Solutions 45<br />
JinHui ZhaoLong High Technology 15 1, 58<br />
Kaneka 8 59<br />
Kartell 15<br />
Kingfa 58<br />
Kompuestos 28 59<br />
Kuraray 42<br />
Lenzing 23<br />
Machinefabriek W. Bakker 22<br />
Messe Düsseldorf 28 28<br />
Michigan State University 60<br />
Microtec 58<br />
Minima Technology 59<br />
Mitr Phol 27 47<br />
Mitsubishi Chemical 8<br />
Modint 16<br />
narocon 8 60<br />
Natural Farm 39<br />
Natureplast-Biopolynov 59<br />
Natur-Tec 59<br />
Nölle Kunststofftechnik 15<br />
Norbert Schmid 34<br />
nova Institute 46 35, 38, 60<br />
Novamont 5, 30, 49 59, 64<br />
Novozymes 14<br />
Nurel 58<br />
Omya 30<br />
Plantic 42<br />
plasticker 49<br />
Polykum 31<br />
polymediaconsult 60<br />
Polymerization Shared Facility 50<br />
ProdTek<br />
PTTMCC 42 58<br />
RIKEN 8<br />
REWIN 50<br />
Saida 59<br />
Saudi Arabian Oil Company 53<br />
Saxon Textile Research Inst. 15<br />
SeaBird 18<br />
Senbis Polymer Innovation 22<br />
Sicomin 5<br />
Simcon 7<br />
SK Chemicals 52<br />
Sukano 34 17, 58<br />
TAIF Group 7<br />
Tecnaro 59<br />
Tepha 53<br />
The Good Stuffing Company 39<br />
TianAn Biopolymer 59<br />
Total 26, 31<br />
Total Corbion PLA 6, 26, 31 33, 59<br />
Treffert 59<br />
Trifilon 36<br />
Uhde Inventa-Fischer 59<br />
United Biopolymers 31<br />
Univ. Stuttgart (IKT) 60<br />
Vaude 35<br />
Vegware 6<br />
Wageningen Univ. 50<br />
Xinjiang Blue Ridge Tunhe Polyester 58<br />
Zeijiang Hisun Biomaterials 58<br />
Zhejiang Hangzhou Xinfu Pharm. 58<br />
Editorial Planner<br />
<strong>2019</strong>/2020<br />
<strong>Issue</strong><br />
Month<br />
Publ.<br />
Date<br />
edit/ad/<br />
Deadline<br />
06/<strong>2019</strong> Nov/Dec 02.12.19 01.11.19 Films/Flexibles/<br />
Bags<br />
Edit. Focus 1 Edit. Focus 2 Basics<br />
Consumer & office<br />
electronics<br />
Multilayer films<br />
Trade-Fair<br />
Specials<br />
K'<strong>2019</strong> Review<br />
01/2020 Jan/Feb 10.02.20 31.12.19 Automotive Foam t.b.c. t.b.c.<br />
02/2020 Mar/Apr 06.04.20 06.03.20 Thermoforming /<br />
Rigid packaging<br />
Additives /<br />
Masterbatches<br />
t.b.c.<br />
interpack preview<br />
Subject to changes<br />
www.bioplasticsmagazine.com<br />
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62 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14
MEET US AT THE K<strong>2019</strong><br />
HALL 7 LEVEL 1 / STAND B 21<br />
A COMPLETE RANGE<br />
OF SOLUTIONS.<br />
BIOPLAST®,<br />
INNOVATIVE<br />
SOLUTIONS FOR<br />
EVERYDAY PRODUCTS.<br />
Made from potato starch,<br />
BIOPLAST® resins are<br />
designed to work on<br />
existing standard<br />
equipment for blown<br />
film, flat film, cast<br />
film, injection molded<br />
and thermoformed<br />
components.<br />
100 % biodegradable,<br />
BIOPLAST® is particularly<br />
suitable for ultra-light<br />
films with a thickness of<br />
approx. 10-15 μm.<br />
S002<br />
S002<br />
TRANSPARENT ODORLESS PLASTICIZER<br />
FREE<br />
OK COMPOST<br />
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r1_<strong>05</strong>.2017