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Highlights: Fibres/Textiles/Nonwovens Barrier Materials Cover Story: Lightweighting PBAT

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Sep / Oct<br />

<strong>05</strong> | <strong>2019</strong><br />

bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />

Preview:<br />

Highlights<br />

Fibers / Textiles / Nonwovens | 16<br />

Barrier Materials | 42<br />

Cover Story<br />

Lightweighting PBAT<br />

based materials<br />

Jinhui Zhaolong<br />

... is read in 92 countries


Visit us in<br />

hall 6 at stand E 48<br />

16.–23.10.<strong>2019</strong><br />

Düsseldorf<br />

FEEL GOOD WITH<br />

REUSABLE COFFEE CUPS<br />

Visit us at K<strong>2019</strong> in Düsseldorf and have your revolutionary cup fi lled with<br />

freshly brewed coffee at booth E48 in hall 6. This cup is amazing as it‘s:<br />

• made from renewable raw materials,<br />

• reusable and<br />

• fully recyclable.


Editorial<br />

dear<br />

readers<br />

A few days ago, I visited FACHPACK, an international trade show for the packaging<br />

industry held annually in Germany. There was no doubt about this year’s key<br />

theme: I was overwhelmed by the wall-to-wall claims of sustainability that<br />

bedecked the show. In fact, greenwashing was a suspicion that sprang to mind.<br />

Everything was labelled as being sustainable or recyclable - just two of the<br />

buzzwords conspicuously being brandished at almost all the booths. Clearly, the<br />

concept of sustainability had arrived, at least in the marketing departmentsalthough<br />

not yet in the R&D departments, it would seem. Products that actually<br />

incorporated recycled content, especially PCR (post consumer recyclates), were<br />

very thin on the ground. Plus, if products are recyclable, but don’t actually get<br />

recycled, the benefits in terms of sustainability are zero.<br />

On the other hand, recycling plastics is not as easy as, for instance, recycling<br />

glass, metal or paper, as Remy Jongboom points out in his comment on page 40.<br />

Next to providing news and information on materials and applications, we<br />

also report on the latest innovations and ongoing advances in the world of<br />

bioplastics. As usual, we’re presenting some highlight topics in this issue.<br />

The first is Barrier solutions, a topic that is drawing more and more attention,<br />

as bioplastics find increasing application in the packaging of food and other<br />

sensitive goods.<br />

The other highlight is Fibers/Textiles/Nonwovens, which also includes spun<br />

monofilaments, for example, for medical applications.<br />

The third hot topic is the triennial K-show, the world’s leading trade fair for plastics<br />

and rubber. Please find our show preview, including a detachable Show Guide with<br />

floorplan in the center of the magazine.<br />

An important, not-to-be missed event during K <strong>2019</strong> is our 4 th Bioplastics Business<br />

Breakfast. It’s never too late to register for these mini conferences that will take place<br />

on October 17-18-19 and 20. We also accept on-site registrations. The BBB will be<br />

held on each of the four days from 8am-12:30pm, in the CCD-Ost on the fairgrounds.<br />

See pp 10-11 for details.<br />

We hope to see you at the K show and perhaps also later, at the 14 th European<br />

Bioplastics Conference, which is being hosted this year on December 3-4 in Berlin.<br />

At the conference, we will be presenting the annual Global Bioplastics Award to one<br />

of the five finalists shown on pp.14-15. Until then, enjoy reading<br />

bioplastics MAGAZINE.<br />

Sincerely yours<br />

Michael Thielen<br />

EcoComunicazione.it<br />

WWW.MATERBI.COM<br />

r1_<strong>05</strong>.2017<br />

<strong>05</strong>/<strong>05</strong>/17 11:39<br />

bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />

Preview:<br />

Highlights<br />

Fibers / Textiles / Nonwovens | 16<br />

Barrier Materials | 38<br />

Sep / Oct<br />

Cover Story<br />

Lightweighting PBAT<br />

based materials<br />

Jinhui Zhaolong<br />

<strong>05</strong> | <strong>2019</strong><br />

... is read in 92 countries<br />

Follow us on twitter!<br />

www.twitter.com/bioplasticsmag<br />

Like us on Facebook!<br />

www.facebook.com/bioplasticsmagazine<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 3


Content<br />

Imprint<br />

34 Porsche launches cars with biocomposites<br />

Sep / Oct <strong>05</strong>|<strong>2019</strong><br />

Cover Story<br />

12 Lightweight research on<br />

biodegradable Materials<br />

Fibers & Textiles<br />

16 Biobased additives for biopolymer-textiles<br />

18 A new generation of<br />

compostable monofilament<br />

20 Monofilament melt spinning<br />

22 Alternative materials for mussel socks<br />

23 Cellulose based fibers fully biodegradable<br />

in water soil and compost<br />

24 PLA-fibres in medical applications<br />

Report<br />

26 Inauguration of the world’s<br />

second largest PLA plant<br />

Opinion<br />

40 Bioplastics in the Circular Economy<br />

46 Equal footing for LCAs<br />

49 Biodegradation of plastics in nature:<br />

the future tasks of standardisation<br />

Barrier materials<br />

42 Ultra high barrier for bio-packaging<br />

43 New compostable barrier films<br />

44 Emerging circular biobased<br />

barrier solutions<br />

47 PVOH for barrier applications<br />

3 Editorial<br />

5 News<br />

10 Events<br />

18 Award<br />

28 K-Preview<br />

32 K-Showguide<br />

36 Application News<br />

48 10 years ago<br />

52 Patents<br />

54 Basics<br />

58 Suppliers Guide<br />

62 Companies in this issue<br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Samuel Brangenberg (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Samsales (German language)<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

sb@bioplasticsmagazine.com<br />

Michael Thielen (English Language)<br />

(see head office)<br />

Layout/Production<br />

Kerstin Neumeister<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

1004 Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

Print run: 7,000 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified subscribers<br />

(169 Euro for 6 issues).<br />

bioplastics MAGAZINE is read in<br />

92 countries.<br />

Every effort is made to verify all Information<br />

published, but Polymedia Publisher<br />

cannot accept responsibility for any errors<br />

or omissions or for any losses that may<br />

arise as a result.<br />

All articles appearing in<br />

bioplastics MAGAZINE, or on the website<br />

www.bioplasticsmagazine.com are strictly<br />

covered by copyright. No part of this<br />

publication may be reproduced, copied,<br />

scanned, photographed and/or stored<br />

in any form, including electronic format,<br />

without the prior consent of the publisher.<br />

Opinions expressed in articles do not necessarily<br />

reflect those of Polymedia Publisher.<br />

bioplastics MAGAZINE welcomes contributions<br />

for publication. Submissions are<br />

accepted on the basis of full assignment<br />

of copyright to Polymedia Publisher GmbH<br />

unless otherwise agreed in advance and in<br />

writing. We reserve the right to edit items<br />

for reasons of space, clarity or legality.<br />

Please contact the editorial office via<br />

mt@bioplasticsmagazine.com.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks<br />

is not an indication that such names are<br />

not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped bioplastic envelopes<br />

sponsored by Biotec GmbH, Emmerich,<br />

Germany<br />

Cover Ad<br />

Jinhui Zhaolong High Technology Co.,Ltd<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

https://www.facebook.com/bioplasticsmagazine


daily upated news at<br />

www.bioplasticsmagazine.com<br />

News<br />

Sicomin launches<br />

new bio epoxy-resin<br />

As the automotive industry focuses on more sustainable<br />

manufacturing, Sicomin, the leading supplier of eco-resins, has<br />

announced a replacement for petroleum based materials with<br />

the launch of its new bio-based epoxy resin aimed specifically for<br />

HP-RTM processing techniques.<br />

SR GreenPoxy 28 is the sixth product to be added to Sicomin’s<br />

renowned GreenPoxy range and is available with immediate<br />

effect in the industrial quantities typically required by Automotive<br />

OEM’s.<br />

Certified by Veritas, SR GreenPoxy 28 is a fast cycle, low toxicity,<br />

third generation bio based formulation aimed specifically at the<br />

HP-RTM moulding processes used for both high performance<br />

structural parts and aesthetic carbon fibre components. The new<br />

formulation has been optimized for fast production cycle times<br />

and superior mechanical performance.<br />

SR GreenPoxy 28 can be fully cured using a 2-minute cure<br />

cycle at 140°C, producing an onset T g<br />

of 147°C, as well as<br />

exceptional mechanical properties under both dry and hot/wet<br />

test conditions.<br />

As Philippe Marcovich, President, Sicomin commented, more<br />

and more manufacturers and suppliers are betting on biobased<br />

alternatives derived from renewable raw materials. “The<br />

latest addition to our GreenPoxy range, SR GreenPoxy 28, is an<br />

exciting alternative to traditional resins providing exceptional<br />

performance and quality for high volume programmes.” MT<br />

www.sicomin.com<br />

Novamont goes<br />

forward into FDCA<br />

Novamont (Novara, Italy) headquarters recently<br />

presented to Invitalia a project for the production<br />

of 2.5-furandicarboxylic acid (FDCA) in a new<br />

demonstration plant that will be built in Terni,<br />

obtaining a loan of 5.8 million Euros (5 million soft<br />

loans and the rest as a grant) as part of a total<br />

investment of 10 million Euros, which will lead to<br />

the creation of 12 new jobs. This was reported by<br />

polimerica.it on August 29. Invitalia ia an Italian<br />

National Agency for Investment Attraction and<br />

Enterprise Development<br />

Novamont has a proprietary technology for the<br />

synthesis of FDCA and is already working on a<br />

pilot plant to develop the process: the decision to<br />

move to the demonstration unit would suggest that<br />

the process, tested at laboratory level, is ripe for a<br />

further step towards production on a commercial<br />

scale.<br />

Novamont will use 2,5-furandicarboxylic acid<br />

(FDCA) as a monomer to produce V-generation<br />

Mater-bi and develop packaging with oxygen and<br />

carbon barrier properties. This intermediate can<br />

also be used to produce polyethylene-furanate<br />

(PEF), a polyester resin alternative to PET for<br />

packaging, biobased and recyclable in the PET flow,<br />

but not biodegradable.<br />

CEO Catia Bastioli on polimerica.it: "Novamont<br />

continues its process of innovation in the<br />

bioeconomy sector, allowing the diversification of<br />

production activities at the Terni site, thanks to a new<br />

proprietary technology. It is a demonstration plant<br />

for the production of furandicarboxylic acid, from<br />

renewable raw materials, for a range of polymers<br />

and biodegradable and compostable polymeric<br />

alloys, also proprietary, with high performance in<br />

the conditions of use". MT<br />

www.novamont.com<br />

Source: www.polimerica.it/articolo.asp?id=22350<br />

Picks & clicks<br />

Most frequently clicked news<br />

Here’s a look at our most popular online content of the past two months.<br />

The story that got the most clicks from the visitors to bioplasticsmagazine.com was:<br />

tinyurl.com/news-<strong>2019</strong>0910<br />

Grand opening of Total Corbion PLA's 75,000 tonnes per year<br />

bioplastics plant<br />

(10 September <strong>2019</strong>)<br />

Total Corbion PLA, a 50/50 joint venture between Total and Corbion, officially<br />

inaugurated its 75,000 tonnes per year PLA bioplastics plant in Rayong,<br />

Thailand on Sept. 09, <strong>2019</strong>. The world’s second largest PLA plant is located<br />

on the same premises, right next to a lactic acid plant of Corbion. It was<br />

finished in mid 2018 and commissioned end of 2018. As of yet, the PLA plant<br />

has produced more than 20,000 tonnes of PLA.<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 5


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

First Mile and Vegware<br />

team up to boost<br />

compostable packaging<br />

recycling<br />

Plant-based packaging specialist, Vegware (Edinburgh,<br />

Scotland), is joining forces with leading recycling company,<br />

First Mile (London, UK), to provide a UK-wide end-of-life<br />

solution for its compostable foodservice disposables<br />

using RecycleBox, First Mile’s low cost, courier-led<br />

recycling service.<br />

First Mile currently collects over 25 material streams<br />

in London and Birmingham, including Vegware’s<br />

compostable packaging, but has now introduced<br />

RecycleBox to provide a national solution for those items<br />

not collected by local councils and other waste companies.<br />

This service is especially important for those items that<br />

require separate collections to be recycled effectively.<br />

Compostable packaging is a great example of this as<br />

it must be sent to a specialist facility to be organically<br />

recycled, and should not be put in mixed recycling.<br />

“First Mile’s RecycleBox service now creates full UK<br />

post-back coverage for used Vegware to access suitable<br />

waste infrastructure,” said Vegware’s environmental<br />

and communications director, Lucy Frankel. “Over two<br />

dozen UK facilities accept our compostable products, and<br />

trade collections for used Vegware now cover 38% of UK<br />

postcodes, up from 2% in 2012 when we started working<br />

with the waste sector. We introduced First Mile to a facility<br />

who had tested and approved Vegware products in their<br />

process, and see RecycleBox as an innovative solution for<br />

individuals and foodservice businesses throughout the<br />

UK.”<br />

RecycleBox is First Mile’s simple solution to overcoming<br />

the logistical barriers associated with recycling.<br />

Businesses or consumers can simply put the used<br />

Vegware disposables back in the cardboard box it came in<br />

(or order one from First Mile), and then book a collection<br />

online to return the box back to First Mile, who will then<br />

facilitate delivery to Vegware’s approved facility.<br />

The RecycleBox service is also available for other items<br />

– from used electrical items to coffee pods or old shoes.<br />

These items are sorted into the correct recycling stream<br />

or, for those items where an end-of-life solution doesn’t<br />

currently exist, sent to First Mile’s innovative RecycleLab<br />

where new recycling solutions are explored.<br />

Brands responsible for creating hard-to-recycle items<br />

can sponsor the RecycleBox service as a credible end-oflife<br />

solution to their products. Any brand needing help in<br />

finding a recycling solution can contact First Mile, who will<br />

assist them in finding a route via its network of processing<br />

partners. MT<br />

www.recyclebox.co.uk/taxons/vegware<br />

www.thefirstmile.co.uk<br />

www.vegware.com<br />

Membership milestone<br />

GO!PHA, the Global Organization for PHA is a memberdriven,<br />

non-profit initiative with as aim to accelerate the<br />

development of the PHA-platform industry. The platform<br />

looks to be filling a need: one month after its official<br />

incorporation on July 13, <strong>2019</strong>, its membership has<br />

already grown to 25.<br />

As part of the GO!PHA policy it will publish a series<br />

of white papers to inform policy makers and other<br />

stakeholders about the benefits and potential of PHAs.<br />

The first white paper, authored by PHA expert Jan<br />

Ravenstijn, focuses on the bio-benign nature of PHA,<br />

which is a crucial element of the future success of PHAs<br />

in different end-markets.<br />

The full paper, and future GO!PHA white papers can be<br />

accessed at:<br />

www.gopha.org/pha<br />

Russian TAIF Group<br />

bioplastic project<br />

going forward<br />

Russian petrochemical giant TAIF JSC Group and Bioon<br />

have released a joint statement announcing TAIF’s<br />

plans to produce PHA bioplastic at a site in Tatarstan are<br />

indeed going forward.<br />

The company will build a new plant for the production<br />

of PHA based on technology licensed by Italy’s Bio-on, at<br />

Alabuga, an industrial zone that has attracted a number<br />

of the technology companies.<br />

The contract for the turn-key construction of the<br />

production plant will be awarded by the end of the year;<br />

production is aimed to commence in the second half of<br />

2021. The plant will have an initial production capacity of<br />

10,000 tonnes per year, but set up with the possibility for<br />

expanding to double that at a later stage.<br />

"We really believe in this project," says Ruslan<br />

Shigabutinov, General Manager of TAIF, who visited<br />

Bio-on and its production and R&D facilities in Castel<br />

San Pietro Terme (BO) on July 25, together with a Taif<br />

Group delegation, including strategic advisor Mr. Albert<br />

Shigabutdinov, who is also the Chairman of 2BIO JSC.<br />

“It represents an important opportunity for a group like<br />

ours that, among others, is active in the field of plastics.<br />

Taif Group is strategically sensitive to innovations, to<br />

environmental protection elements and wants to be<br />

actors in sustainable initiatives like this,” he continued.<br />

"The choice of the industrial site area was driven by<br />

the presence of many foreign investors that ensure, in<br />

addition to some tax benefits, an excellent visibility on the<br />

international market." added Albert Shigabutinov. MT<br />

www.taif.ru | www.bio-on.it<br />

6 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


daily upated news at<br />

www.bioplasticsmagazine.com<br />

News<br />

Global bioplastics market unil 2024<br />

Eco-friendliness, favourable government policies, renewable raw material sources, and high acceptance from consumers are<br />

driving growth in the global bioplastics market. While Europe accounts for more than two-fifths of the total market share and<br />

is expected to maintain its lead status, AsiaPacific is expected to register the largest growth rate with a CAGR of 20.4% through<br />

2024.<br />

According to a new report published by Allied Market Research, titled, Bioplastics Market by Type and Application: Global<br />

Opportunity Analysis and Industry Forecast, 2018-2024 the global bioplastics market was valued at $21,126.31 million in 2017,<br />

and is projected to reach $68,577.25 million by 2024, registering a CAGR of 18.8% from 2018 to 2024. Bioplastics are extensively<br />

used in the production of rigid packaging. In 2017, the rigid packaging segment accounted for approximately one-third share<br />

in the global market in terms of value.<br />

The level of technical complexity of bioplastics packaging is increasing and their use in rigid is expected to grow at the same<br />

pace throughout 2024. For instance, the commercialization of co-extruded double or multiple layer film products has gained<br />

momentum in the recent years. It also finds applications in various end-use industries such as flexible packaging, textile,<br />

agriculture, and horticulture, consumer goods, automotive, electronics, building and construction, and others.<br />

The production and use of bioplastics are viewed as a sustainable solution due to low emission of greenhouse gasses.<br />

Factors such as eco-friendly properties, increase in consumer awareness, growth in environmental concerns, and favourable<br />

government policies drive the growth of the bioplastic market. However, high production cost and comparatively lower<br />

performance standards than synthetic plastics restrain the market growth to a certain extent.<br />

Key Findings of the Bioplastics Market:<br />

• In 2017, Asia-Pacific accounted for more than one-fifth share growing at a CAGR of 20.4% from 2018 to 2024.<br />

• In 2017, non-biodegradable plastic accounted for the highest market share and is expected to growth at the highest CAGR<br />

of 20.2%.<br />

• The rigid packaging application segment accounted for the highest market share in 2017 and is projected to grow at the<br />

highest CAGR of 28.3%.<br />

• In 2017, Europe accounted for the highest market share and is anticipated to grow at a significant CAGR of 18.7%.<br />

• India is anticipated to grow at the highest CAGR of 23.8% from 2018 to 2024.<br />

• In terms of value, Asia-Pacific and LAMEA collectively accounted for more than one-fourth share in the global bioplastics<br />

market in 2017.<br />

www.alliedmarketresearch.com/bioplastics-market<br />

Injection moulding simulation for bioplastics<br />

It is well known that bioplastics often behave very differently<br />

in injection moulding than their classical relatives. Simcon<br />

(Würselen, Germany), the<br />

expert for injection moulding<br />

simulation, has expanded its<br />

software products Cadmould<br />

and Varimos to include the<br />

calculation of bioplastics and<br />

biocomposites, i.e. classical<br />

polymers reinforced with<br />

natural fibres. Thanks to<br />

simulation, users of these<br />

materials can also benefit from<br />

the advantages of simulations<br />

and save an average of around<br />

30 % in both development time<br />

and cycle times.<br />

In the research project<br />

NFC-Simulation funded by the<br />

German Federal Ministry of<br />

Food and Agriculture (BMEL)<br />

Comparison measured and simulated deformation<br />

in which among others the car manufacturer Ford was a<br />

partner, Simcon has shown by means of a glove compartment<br />

assembly that influences of<br />

the injection moulding process<br />

such as filling, holding pressure,<br />

shrinkage and warpage are<br />

realistically mapped up to the<br />

transfer of the fibre orientations<br />

to the crash simulation. "Even<br />

the crash simulation at Ford<br />

delivered excellent results with<br />

the fiber orientations provided<br />

by Cadmould", Simcon owner<br />

Dr. Paul Filz looks back on the<br />

project.<br />

Cadmould has also been<br />

successfully used for bioplastics<br />

in other areas, such as<br />

consumer electronics and<br />

musical instruments. MT<br />

www.simcon-worldwide.com<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 7


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

Dow and UPM partner<br />

to produce plastics<br />

made with renewable<br />

feedstock<br />

Michigan-based Dow, in partnership with Finland’s UPM<br />

Biofuels, a producer of advanced biofuels, announces the<br />

commercialization of a plastics offering for the packaging<br />

industry made from a biobased renewable feedstock.<br />

Dow is integrating wood-based UPM BioVerno renewable<br />

naphtha – a key raw material used to develop plastics – into<br />

its slate of raw materials, creating an alternative source for<br />

plastics production. Dow is using this feedstock to produce biobased<br />

polyethylene (PE) at its production facility in Terneuzen,<br />

The Netherlands, for use in packaging applications such as food<br />

packaging to reduce food waste. Following a successful yearlong<br />

trial program, Dow is now planning to scale production and<br />

address the increasing global demand for renewable plastics.<br />

UPM BioVerno naphtha is produced at UPM’s biorefinery in<br />

Lappeenranta, Finland, from crude tall oil, which is a residue of<br />

paper pulp production. Unlike many other alternative renewable<br />

feedstocks, no extra land is required for the feedstock production.<br />

The feedstock originates from sustainably managed forests.<br />

European Bioplastics<br />

& bioplastics MAGAZINE<br />

join forced at K'<strong>2019</strong><br />

The industry association European Bioplastics and<br />

bioplastics MAGAZINE, will again share a booth at K'<strong>2019</strong>,<br />

the world's biggest trade show on plastics & Rubber<br />

- 16-23 October in Düsseldorf, Germany. Even if the<br />

industry association and your favourite magazine are<br />

absolute independent organizations, we again decided<br />

to join forced to offer a hub for all visitors interested in<br />

bioplastics.<br />

Make sure to visit our booth #B10 in Hall 7a. This year<br />

we are grateful to Dr. BOY, manufacturer of injection<br />

moulding machines to place an XS-model injection<br />

moulder on our booth. And we thank Mitsubishi<br />

Chemical (MCPP) for sponsoring a couple of bags of<br />

their isosorbide based DURABIO TM resin to be run on<br />

that machine on our booth.<br />

Come by and grab a nice paper clip made of this<br />

unique biobased polycarbonate resin on our booth. MT<br />

www.dr-boy.de | www.mcpp.com<br />

This process also significantly reduces CO 2<br />

emissions,<br />

especially by carbon sequestration, compared to standard<br />

fossil derived PE resins, and the plastics produced can help<br />

brand owners meet their sustainability packaging goals. The<br />

entire supply chain is International Sustainability & Carbon<br />

Certification (ISCC) certified, based on mass balance approach,<br />

meaning all steps meet traceability criteria and reduce negative<br />

environmental impacts.<br />

Packaging made from this renewable feedstock can be fully<br />

recyclable as demonstrated through a collaboration with brand<br />

owner Elopak, an international supplier of paperboardbased<br />

packaging for food and beverage. Dow’s biobased low-density<br />

polyethylene (LDPE) resins are used to coat Elopak’s liquid<br />

carton containers and in the production of carton caps, resulting<br />

in a 100 % renewable beverage carton. This was achieved without<br />

compromising the benefits of the original form of plastic-coated<br />

packaging in addition to reducing the CO 2<br />

footprint of the<br />

packaging during production and use.<br />

This agreement with UPM is the latest example of Dow’s<br />

strategy to enable a shift to a circular economy for plastics by<br />

focusing on resource efficiency and integrating recycled content<br />

and renewable feedstocks into its production processes. Dow<br />

also recently partnered with the Fuenix Ecogy Group, based in<br />

Weert, The Netherlands, for the supply of pyrolysis oil feedstock,<br />

which is made from recycled plastic waste.<br />

Through these efforts, post-consumer plastics will continue<br />

to have value through an extended lifespan. These agreements<br />

also contribute to Dow’s commitment to incorporate at least<br />

100,000 tonnes of recycled plastics in its product offerings sold<br />

in the European Union by 2025. MT<br />

www.upmbiofuels.com | www.dow.com<br />

PHBH got JBA Award<br />

JBA’s Bioindustry Award <strong>2019</strong> has been presented to<br />

Kaneka and RIKEN researchers for the development<br />

of a PHBH polymer biodegradable on soil and in<br />

seawater.<br />

The poly-hexanoate-butyrate (PHBH) copolymer is<br />

produced by Kaneka from plant oil using a recombinant<br />

strain of Cupriavidus necator at a capacity of currently<br />

1,000 tonnes, with plans to increase production to<br />

5,000 and later to 100,000 tonnes a year.<br />

PHBH materials decompose not only on soil,<br />

but also in seawater (90 % within 6 months at<br />

30 °C) and have obtained the OK Biodegradable<br />

Marine certificate from TÜV AUSTRIA Belgium.<br />

The biopolymer-producing strain is based on joint<br />

research by Yoshiharu Doi, former Professor of the<br />

Tokyo Institute of Technology and Director at RIKEN,<br />

and five Kaneka researchers who will share the award<br />

of 3 million ¥. MT<br />

www.kaneka.com<br />

8 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


DuraSense<br />

®<br />

by Stora Enso<br />

The affordable<br />

way to go green<br />

Demand the game-changing biocomposite.<br />

Demand more. Demand renewable.<br />

Imagine a green, cost-efficient and<br />

versatile material for a wide range of<br />

injection moulded products. A blend<br />

of wood fibres and plastic material,<br />

offering a light and flexible solution<br />

with the mouldability of plastics, yet<br />

the sustainable benefits of wood.<br />

Resulting in up to 80% reduced CO 2<br />

footprint.<br />

DuraSense ® creates endless design<br />

possibilities that are limited only by<br />

your imagination. With little or no<br />

change to existing production<br />

techniques, our material is developed<br />

to match conventional plastics and<br />

therefore fit existing moulds.<br />

Visit us for a cup of coffee. We’ll show<br />

you around the biocomposite plant,<br />

and tell you more about this gamechanging<br />

material.<br />

Demand more. Demand renewable.<br />

www.storaenso.com/biocomposites<br />

Visit us at K-Fair 16 - 23 October <strong>2019</strong><br />

You will find us in stand 72G18 , hall 07 2<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 9


Events<br />

Bioplastics Business Breakfast<br />

Programme:<br />

For details of the event, see next page or visit www.bioplastics-breakfast.com<br />

Thursday, October 17, <strong>2019</strong><br />

8:00-8:<strong>05</strong> Michael Thielen, Welcome remarks<br />

8:<strong>05</strong>-8:25 Harald Kaeb, narocon Biobased Plastic Packaging in Europe - Update & Outlook<br />

8:25-8:45 Caroli Buitenhuis, Green Serendipity Future of biobased packaging<br />

8:45-9:<strong>05</strong> Patrick Gerritsen, Bio4Pack Biobased plastics and recycling<br />

9:<strong>05</strong>-9:25 Tim Wagler, Braskem Green PE, the biobased drop-in solution for the circular economy<br />

9:25-9:35 Q&A<br />

9:35-9:55 Francois de Bie, Total Corbion PLA The inauguration of our first 75.000 ton/year PLA production plant<br />

9:55-10:15 Viviana Conti, NatureWorks Latest developments (t.b.c.)<br />

10:15-10:35 Marie-Hélène Gramatikoff, Lactips A competitive and 100% biobased technology<br />

10:35-10:45 Q&A<br />

10:45-11:<strong>05</strong> Coffee & Networking Break<br />

11:<strong>05</strong>-11:25 David Sudolsky, Anellotech Making 100% biobased PET a reality<br />

11:25-11:45 Daniel Ganz, Sukano All you need to know to successfully run PBS<br />

11:45-12:<strong>05</strong> Neil Dewar, Mold-Masters Europe Critical Bio-Resin Processing Insights for Packaging<br />

12:<strong>05</strong>-12:25 Sam Deconinck, OWS Some of the challenges compostable packaging faces today<br />

12:25-12:30 Q&A<br />

Friday, October 18, <strong>2019</strong><br />

8:00-8:<strong>05</strong> Michael Thielen, bioplastics MAGAZINE Welcome remarks<br />

8:<strong>05</strong>-8:25 Mark Vergauwen, NatureWorks Latest developments (t.b.c.)<br />

8:25-8:45 Hugo Vuurens, Total Corbion PLA Luminy PLA in new applications and innovation in PLA end of life solutions<br />

8:45-9:<strong>05</strong> Caine Folkes-Miller, Floreon t.b.d.<br />

9:<strong>05</strong>-9:25 José Ángel Ramos, ADBioplastics Advanced biomaterials for packaging applications<br />

9:25-9:35 Q&A<br />

9:35-9:55 C. Arnault & S. Macedo, Carbiolice Evanesto, new enzymated technology making PLA fully compostable<br />

9:55-10:15 Thomas Unger, Leistritz Direct extrusion and Compounding of Biopolymers<br />

10:15-10:35 Patrick Zimmermann, FKuR PLA ompounds moving away from compostability (t.b.c.)<br />

10:35-10:45 Q&A<br />

10:45-11:<strong>05</strong> Coffee & Networking Break Coffe & Networking Break<br />

11:<strong>05</strong>-11:25 Daniel Ganz, Sukano Advances in PLA modification via additives masterbatches<br />

11:25-11:45 Karsten Schulz, Omya t.b.d.<br />

11:45-12:<strong>05</strong> Luis Roca, AIMPLAS Tailor made PLA by Reactive extrusion for packaging applications<br />

12:<strong>05</strong>-12:25 Michael Carus, nova Institute The role of PLA in the Bio-based Economy<br />

12:25-12:30 Q&A<br />

Saturday, October 19, <strong>2019</strong><br />

8:00-8:<strong>05</strong> Michael Thielen, bioplastics MAGAZINE Welcome remarks<br />

8:<strong>05</strong>-8:25 Harald Ruhland, Ricone Successful development of a bio-based technical product<br />

8:25-8:45 Alejandra de Noren, Neste Circular drop-in solutions for durable applications<br />

8:45-9:<strong>05</strong> Richard Lambert, Braskem I’m greenTM, the biobased drop-in solution for durable applications<br />

9:<strong>05</strong>-9:25 Silvana Maione, GCR Group BioGranic: Compostable filler solutions for flexible and rigid applications<br />

9:25-9:35 Q&A<br />

9:35-9:55 Uwe Michael Jakobs, Arkema Polyamide 11 durable by nature<br />

9:55-10:15 Stephane Wohlgemuth, DSM EcoPaXX: a drop in for when PA66 reaches its limits<br />

10:15-10:35 Dirk Schawaller, Tecnaro Latest developments with Arboform-Compounds (t.b.c.)<br />

10:35-10:45 Q&A<br />

10:45-11:<strong>05</strong> Coffee & Networking Break<br />

11:<strong>05</strong>-11:25 Patrick Zimmermann, FKuR Latest developments with Terralene-Compounds(t.b.c.)<br />

11:25-11:45 Salvador Ortega, NatureWorks Forging ahead with PLA in industrial applications<br />

11:45-12:<strong>05</strong> Thomas Köppl, Hexpol TPE How to meet growing demand for soft, safe and sustainable plastics<br />

12:<strong>05</strong>-12:25 Asta Partanen, nova-Institute Biocomposites<br />

12:25-12:30 Q&A Q&A<br />

Sunday, October 20, <strong>2019</strong><br />

8:00-8:<strong>05</strong> Michael Thielen, bioplastics MAGAZINE Welcome remarks<br />

8:<strong>05</strong>-8:25 Jan Ravenstijn, Jan Ravenstijn Consulting State-of-the-art of the PHA-platform industrialization<br />

8:25-8:45 Pieter Willot, deSter PHA for FMCG’s: challenges between raw material and the consumer market.<br />

8:45-9:<strong>05</strong> Anindya Mukherjee, i2i Consulting PHA’s cost equivalency to conventional plastics – A new value chain<br />

9:<strong>05</strong>-9:20 Q&A<br />

9:20-9:40 Daniel Pohludka, Nafigate PHB in cosmetic products<br />

9:40-10:00 Fabiana Fantinel, Sabio Materials Applications and application developments with PHA-polymers<br />

09:50-10:20 Silvia Kliem, IKT, University Stuttgart Impact Modification of PHB by the Building of a Block Copolymer<br />

10:20-10:35 Q&A<br />

10:35-10:55 Coffee & Networking Break<br />

10:55-11:15 Lara Dammer, nova Institute EU Circular Economy and Plastics Strategy<br />

11:15-11:35 Remy Jongboom, Biotec PHA compound applications (t.b.c.)<br />

11:35-11:55 Jan Ravenstijn, GO!PHA Status of the GO!PHA Organization<br />

11:55-12:15 Lara Dammer, nova Institute Natural polymers and PHA in EU legislation<br />

15:15-12:30 Q&A<br />

Subject to changes<br />

10 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


한국포장협회로고.ps 2016.11.21 8:26 PM 페이지1 MAC-18<br />

On-Site Registration<br />

is possible<br />

organized by<br />

17. - 20.10.<strong>2019</strong><br />

Messe Düsseldorf, Germany<br />

BIOPLASTICS<br />

BUSINESS<br />

BREAKFAST<br />

B 3<br />

Bioplastics in<br />

Packaging<br />

PLA, an Innovative<br />

Bioplastic<br />

Bioplastics in<br />

Durable Applications<br />

PHA, Opportunities<br />

& Challenges<br />

www.bioplastics-breakfast.com<br />

Gold Sponsor<br />

Media Partner<br />

Supported by<br />

1 st Media Partner<br />

KOREA PACKAGING ASSOCIATION INC.<br />

Getränke!<br />

TECHNOLOGIE & MARKETING<br />

At the World‘s biggest trade show<br />

on plastics and rubber: K‘<strong>2019</strong> in<br />

Düsseldorf, Germany, bioplastics<br />

will certainly play an important<br />

role again. On four days during the<br />

show bioplastics MAGAZINE will host<br />

a Bioplastics Business Breakfast:<br />

From 8am to 12pm the delegates<br />

will enjoy highclass presentations<br />

and unique networking opportunity.<br />

Venue: CCD Ost, Messe Düsseldorf<br />

The trade fair opens at 10 am.


Cover Story<br />

Advertorial<br />

Lightweighting PBATbased<br />

materials<br />

As society changes and evolves, people are increasingly<br />

seeking more convenience and ease in daily<br />

life, both at home and at work. This trend is boosting<br />

demand for lightweight and high-performance polymers<br />

in various industries. At present, the materials most commonly<br />

used are expandable particle foam materials (EPS,<br />

EPP, EPO), which can be expanded to ratios of more than 60<br />

with a density of down to 0.015-0.030 g/cm³. Extremely light<br />

and with good compression resistance, above all, these are<br />

relatively inexpensive and hence find application in many<br />

industries, including catering, packaging, construction and<br />

automobile. However, most of these particle foam materials<br />

break very easily, and their low weight makes them difficult<br />

to recycle. If residues end up in nature, they do not degrade,<br />

which causes huge pollution problems in the environment.<br />

As the leading manufacturer of biodegradable polymer<br />

sin China, Jinhui Zhaolong High Technology Co.,Ltd.<br />

(Shanxi, China) has always focused on the study of<br />

lightweighting biodegradable polymer materials. After<br />

repeated experiments and tests, Jinhui Zhaolong has<br />

successfully developed the Ecowill series of expandable and<br />

biodegradable modified polymers based on PBAT.<br />

Test results demonstrate that the Ecowill series of<br />

expandable and biodegradable modified polymers have<br />

a maximum foaming ratio of 13 times and an apparent<br />

density of 0.09g/cm³. Electron microscopy shows that the<br />

cell structure is compact and uniform, and the cell diameter<br />

lies between 20 and 40 µm. After further adjustments in<br />

formula and process, the density can be further reduced.<br />

The Shore-hardness of the new Ecowill series materials<br />

is between 40-65D, with a resilience of over 60 % and<br />

an elasticity comparable to TPEE and TPU elastomer<br />

materials. The materials can be converted into elastomeric<br />

foams with high elasticity requirements by steam bonding<br />

or other elastomer macromolecule material perfusion<br />

bonding and can thus be used for a wide range of large<br />

applications in the field of toys or shoes. Jinhui Zhalong<br />

have already applied it to large Lego-like bricks, airplane<br />

models, insoles and much more.<br />

The Ecowill family of materials is characterized by a<br />

high degree of toughness and high self-bonding strength,<br />

which is very resistant to damage. After being converted<br />

into packaging products, these can be used repeatedly.<br />

Currently, Jinhui Zhaolong is developing a reusable foam<br />

packaging box with its partners based on the molding<br />

characteristics of Ecowill series, which can be applied in<br />

the fields of fruits, vegetables and fresh package.<br />

Compared with standard PBAT, the heat resistance of the<br />

Ecowill series is significantly improved. The melting range<br />

has increased from 95-100 °C to almost 120 °C. At the same<br />

time, the Ecowill materials leave no residual foaming agent<br />

monomers behind. Jinhui Zhaolong is currently conducting<br />

food safety contact tests at 100°C. After passing the test,<br />

12 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Cover Story<br />

Advertorial<br />

By:<br />

Long Yanbo<br />

Jinhui Zhaolong<br />

Shanxi, China<br />

the new material is very<br />

likely to replace PP for a<br />

new generation of fast<br />

food boxes.<br />

In addition to the<br />

above applications,<br />

Jinhui Zhaolong believes<br />

that the Ecowill series will also be<br />

suitable for many applications that haven’t<br />

been developed yet. They hope more downstream<br />

foam material users will join them in further research<br />

and improvement of the Ecowill series formulation, the<br />

foaming process, forming technology and equipment, and<br />

promote the development and application of lightweight<br />

biodegradable materials.<br />

“Committing to the Development in Green Industry,<br />

Caring for Nature & Benefiting Mankind” is the mission of<br />

Jinhui Zhaolong. The company will continue to contribute to<br />

global environmental protection and to creating a greener<br />

world for future generations.<br />

www.jinhuizhaolong.com<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 13


Award<br />

The 14 th<br />

Bioplastics<br />

Award<br />

Presenting the<br />

five finalists<br />

bioplastics MAGAZINE is<br />

honoured to present the five<br />

finalists for the 14 th Global<br />

Bioplastics Award. Five judges<br />

from the academic world, the<br />

press and industry associations<br />

from America, Europe and Asia<br />

have again reviewed the incoming<br />

proposals. On these two pages we<br />

present details of the five finalists.<br />

The Global Bioplastics Award<br />

recognises innovation, success and<br />

achievements by manufacturers,<br />

processors, brand owners, or<br />

users of bioplastic materials. To<br />

be eligible for consideration in<br />

the awards scheme the proposed<br />

company, product, or service<br />

should have been developed or<br />

have been on the market during<br />

2018 or <strong>2019</strong>.<br />

The following companies/<br />

products are shortlisted (without<br />

any ranking) and from these<br />

five finalists the winner will<br />

be announced during the 14 th<br />

European Bioplastics Conference<br />

on December 3 rd , <strong>2019</strong> in Berlin,<br />

Germany.<br />

Carbiolice, (France)<br />

Enzymatic masterbatch to make<br />

PLA home compostable<br />

In December 2018 Carbiolice<br />

(Riom, France) launched its innovative<br />

and unique enzymated Evanesto ®<br />

masterbatch – an additive that enables<br />

PLA to biodegrade under typical home<br />

composting conditions.<br />

Even if PLA offers very good<br />

properties for rigid applications, its<br />

biodegradability is currently limited to<br />

industrial composting.<br />

Carbiolice has now developd<br />

Evanesto, a new enzymatic additive<br />

to be used as a masterbatch, that will<br />

make PLA polymer compostable under<br />

domestic conditions.<br />

“The masterbatch, in a concentration<br />

of less than 5%, is added to a compound<br />

with a high content of PLA during<br />

conventional converting processes like<br />

film extrusion, thermoforming, injection<br />

molding. It accelerates the natural<br />

PLA biodegradation process, making<br />

it suitable for home composting.”<br />

explained Clémentine Arnault R&D<br />

Manager at Carbiolice.<br />

Initial tests carried out by independent<br />

laboratory OWS on thin films containing<br />

30% of PLA and 5% of Evanesto, and<br />

the rest being other biodegradable and<br />

biobased polyesters, such as biobased<br />

PBAT, TPS…) have shown that complete<br />

disintegration is achieved within a time<br />

frame of 182 days (6 months) under<br />

home composting conditions.<br />

Tests on thicker films obtained by<br />

calandering and thermoforming are still<br />

ongoing, but the initial results are very<br />

positive.<br />

Earlier this year Carbiolice and<br />

Carbios have signed a joint development<br />

agreement with Denmark-based<br />

Novozymes, a global producer of<br />

enzymes, for the production and supply<br />

of enzymes for the manufacture of selfbiodegradable<br />

PLA plastics.<br />

www.carbiolice.com<br />

Bio4self (15 partners form EU)<br />

Self-reinforced PLA composites<br />

Self-reinforced PLA composite<br />

materials, which are being developed<br />

as part of the Bio4self project funded by<br />

European Research Fund H2020, open<br />

up completely new areas of application<br />

for the biobased plastic PLA.<br />

In the project, two different PLA types<br />

with different melting temperatures<br />

are combined to a self-reinforced PLA<br />

composite (PLA SRPC) in such a way that<br />

the higher melting PLA is embedded as<br />

a reinforcing fiber in the lower melting<br />

matrix. The resulting material stiffness<br />

can compete with commercially<br />

available self-reinforced polypropylene<br />

(PP) composites. This makes it possible<br />

to produce mechanically demanding<br />

components for the automotive and<br />

electrical household appliance sectors,<br />

among others.<br />

Although the composite materials<br />

developed have been functionalised<br />

for high mechanical strength and<br />

stiffness as well as for high temperature<br />

and hydrolysis stability, like pure<br />

PLA they are completely biobased,<br />

easily recyclable, formable and even<br />

industrially biodegradable.<br />

These industrial-scale composites<br />

represent a milestone in the development<br />

of functionalized, mechanically highstrength,<br />

biobased material systems.<br />

Furthermore, the development makes a<br />

significant contribution to the recycling<br />

economy.<br />

As an example, the application in a<br />

car seat structure was demonstrated at<br />

the JEC Composite trade show in March<br />

<strong>2019</strong>. During the show, this project was<br />

awarded a JEC Innovation Award for<br />

sustainability, announced at the JEC<br />

Innovation Award ceremony on March<br />

12, <strong>2019</strong>.<br />

www.bio4self.eu<br />

14 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Award<br />

Bio-On and Kartell (both Italy)<br />

First modular storage system<br />

from Bio-on’s bioplastic<br />

Kartell (Noviglio, Milan, Italy) is<br />

offering a new eco-friendly and<br />

sustainable edition of one of its best<br />

sellers - a modular storage unit in the<br />

100 % natural bioplastic material by<br />

Bio-on (Bologna, Italy). The Componibili<br />

storage unit, which is cylindrical in form<br />

with sliding panels, was first created by<br />

Italian designer and Kartell co-founder<br />

Anna Castelli Ferrieri in 1967. The 50-<br />

year old design is available in four<br />

colours: green, pink, cream and yellow<br />

in the three-module version.<br />

Originally made from ABS plastic in<br />

the 1960s, the updated bioplastic unit<br />

is made from Bio-on’s PHB Material,<br />

made from agricultural waste.<br />

For Kartell, research is a mission, said<br />

company president Claudio Luti. “We<br />

will continue to experiment to combine<br />

innovation and design.”<br />

“We have worked with Bio-on to be<br />

able to offer our public a very highquality<br />

bioplastic product and we have<br />

chosen to do it on one of our historic<br />

products, one of the most recognized in<br />

the world. Research on bioplastics fits<br />

with our quest for innovation and is part<br />

of the ‘Kartell loves the planet’ project<br />

aimed at enhancing good sustainability<br />

practices.”<br />

For Bio-on, it is “an honour”, said<br />

founder and CEO Marco Astorri. The<br />

company is proud to see its bioplastic<br />

showcased with one of the most famous<br />

Italian design brands in the world. To<br />

reciprocate and in gratitude for the trust<br />

placed in the material, Bio-on has given<br />

the biopolymer used for this specific<br />

application the name CL, the initials of<br />

Claudio Luti.<br />

www.bio-on.it | www.kartell.com<br />

Dantoy (Denmark)<br />

Biobased toys<br />

In February 2018, Dantoy,<br />

manufacturer of quality toys in<br />

Denmark for more than 50 years,<br />

launched its new line of BIO products,<br />

which has gained much more attention<br />

than initially anticipated. Today, more<br />

than 15% of all dantoy’s products are<br />

bio made from Braskem’s Green PE,<br />

supplied by FKuR, a development clearly<br />

contributing to this toy company’s<br />

healthy sales figures. Located in the<br />

middle of Jutland in Denmark and<br />

employing some 50 employees, most of<br />

whom have been with the company for<br />

more than 10 years, dantoy’s production<br />

facilities span an area of 15,000 m 2 . In<br />

addition, dantoy employs a number of<br />

affiliated colleagues who assemble<br />

the products at home or at sheltered<br />

workshops. All this says something<br />

about dantoy’s DNA, and the company<br />

culture dantoy is known for.<br />

All of Dantoy’s Plastic toys are licensed<br />

for the Nordic Swan Ecolabel, thus they<br />

must comply with the world’s strictest<br />

requirements for plastic contents, going<br />

far beyond the Danish law.<br />

In addition to using biobased plastic<br />

raw materials for the bio and the<br />

brand new Tiny lines, dantoy tries to<br />

minimise the impact of its operations<br />

on the environment. The company has<br />

therefore implemented eco-friendly<br />

processes to manage the consumption<br />

of energy, water and raw materials<br />

and to prevent the possibility of<br />

accidental releases or emissions via the<br />

manufacturing process.<br />

The success is not only based on the<br />

superior quality of the products, but<br />

also on the communication strategy.<br />

On every box it is clearly marked and<br />

explained what it’s all about with this<br />

bioplastic. A series of excellent Youtube<br />

videos also explain it.<br />

www.dantoy.dk<br />

Nölle Kunststofftechnik and<br />

Fraunhofer IAP (Germany)<br />

New splint for bone fractures<br />

A novel splint made of PLA for<br />

immobilizing bone fractures has been<br />

developed that can be repeatedly<br />

reshaped during treatment, such as, for<br />

example, when the swelling subsides.<br />

The new immobilisation concept,<br />

called RECAST was developed by Nölle<br />

Kunststofftechnik It makes use of<br />

variously sized preshaped splints made<br />

from biobased and biodegradable PLA.<br />

The splints are heated to between 55<br />

and 65 °C. The temperature of the<br />

splints is then reduced to a minimum.<br />

The now formable plastic is molded to<br />

fit the corresponding part of the body.<br />

This process takes about five minutes. If<br />

corrections are necessary, the hardened<br />

splint can simply be reheated.<br />

The plastics processor worked closely<br />

with the polymer developers at the<br />

Fraunhofer IAP in Potsdam-Golm on the<br />

development of the optimum material.<br />

It was decided to use PLA as a base<br />

polymer, a bioplastic that has a major<br />

disadvantage for most applications: It<br />

becomes soft at around 58 °C. The low<br />

thermal softening point of PLA is a great<br />

advantage when used as an orthopaedic<br />

splint. This means that the product can<br />

be shaped repeatedly and quickly by<br />

heating. The Fraunhofer researchers<br />

combined PLA with suitable fillers and<br />

developed a formulation that met all the<br />

requirements. In addition, they ensured<br />

that the material could also be produced<br />

in industry-relevant quantities.<br />

In order to make the splint even<br />

more comfortable for patients, RECAST<br />

products also feature a fleece padding<br />

made of PLA and viscose, which was<br />

developed jointly with the Saxon Textile<br />

Research Institute in Chemnitz.<br />

www.noelle-kunststofftechnik.de<br />

www.iap.fraunhofer.de<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 15


Fibers & Textiles<br />

Biobased additives for<br />

By:<br />

biopolymer-textiles<br />

Gunnar Seide<br />

Chair of Polymer Engineering<br />

Aachen-Maastricht Institute for Biobased Materials<br />

Geleen, The Netherlands<br />

Both Flanders and the south of the Netherlands, traditionally<br />

regions with large numbers of companies active in the plastics<br />

processing industry, particularly in the field of textiles are<br />

participating in the project. Both regions hold extensive expertise<br />

in the development and production of carpet and clothing.<br />

It is well-known that the properties of plastics are not inherent<br />

in the polymer itself, but that these are obtained through<br />

the use of functional additives. Nucleating agents, plasticizers,<br />

flame-retardants, colorants, anti-statics, stabilizers are all examples<br />

of additives that are indispensable in today’s materials.<br />

However, in many cases, biobased versions of these additives are<br />

unavailable. This makes it almost impossible to produce 100 %<br />

biobased products. To be able to do so, it is essential to develop<br />

biobased additives.<br />

Is that really necessary? Additives are used in such small<br />

amounts… As the history of microplastics shows, little notice<br />

is taken of the impact materials have on the environment,<br />

until significant effects are seen, which are viewed critically by<br />

consumers.<br />

If biodegradable plastics are to serve as a solution to the<br />

problem of microplastics, additives will need to be developed<br />

that are biodegradable or at least eco-toxicologically harmless.<br />

An example of changing customer expectations is the<br />

fact that a few textile companies have now for the first time<br />

announced they would refuse to use biopolymers produced<br />

by means of genetically modified organisms. Consumers are<br />

becoming increasingly demanding regarding aspects relating to<br />

the environment or sustainability. There are currently multiple<br />

research projects in progress on biobased additives for biobased<br />

polymers.<br />

Some examples: The objective of the BioTex Fieldlab is to set<br />

up an open innovation center for research into the development<br />

of fibers and yarns from biopolymers. Within this project, many<br />

companies, under the umbrella of Modint GmbH, Düsseldorf/<br />

Germany, and research institutes are working together. The<br />

center will develop new textile production processes and<br />

applications for this.<br />

Modint is an industry association of 600 textile companies.<br />

An EU project named “Pure nature: 100 % biobased (BB100)”<br />

is currently being run, the goal of which is to develop a process<br />

chain for fully biobased man-made fiber materials. This not<br />

only includes the processing of biopolymers, but also commonly<br />

used additive materials such as plasticizers, flame-retardants,<br />

colorants and nucleation agents. Fully biobased yarns and<br />

textile demonstrators will be developed.<br />

By 2030, the textile sector aims to use between 20-50 %<br />

biobased materials in its products. In textiles, for example, color<br />

intensity and stability are the most important quality indicators.<br />

However, biobased dyes are commercially available only to a<br />

limited extent and often do not meet quality criteria such as<br />

color authenticity.<br />

This project focuses on developing natural dyes from marine<br />

organisms (such as algae) and agricultural crops which<br />

(amongst others) contain sorghum and onion peels.<br />

In conclusion, the author would like to describe a personal<br />

experience of a panel discussion at a conference on<br />

sustainability in the textile industry this year. At the meeting,<br />

both students and corporate delegates from all over the world,<br />

including developing countries with textile production, were<br />

represented. In questions and statements during the panel<br />

discussion, it clearly emerged that today’s younger people, as<br />

represented by the participants in the conference, are forcefully<br />

demanding a shift towards sustainability, even if it has economic<br />

consequences in terms of lower growth, while industry<br />

representatives consider sustainability the basis for further<br />

business within a global growth philosophy.<br />

“I´m convinced that the union of both<br />

positions via new technologies is possible.<br />

A modern world is not conceivable without<br />

modern materials! Therefore: In for biobased<br />

polymers, in for biobased additives!”<br />

www.maastrichtuniversity.nl<br />

16 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Make the switch to bio<br />

For almost every conventional plastic, there is a bioplastic<br />

alternative. Our PLA masterbatches can help introduce PLA<br />

into your portfolio. Make the switch today.<br />

www.sukano.com<br />

Meet us at K <strong>2019</strong><br />

Hall 8a, H28<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 17


Fibers & Textiles<br />

Figure 5: Bio-monofilaments from the compound Sea212<br />

Figure 1: Mechanical strength in relation to diameter<br />

strength (N)<br />

160<br />

140<br />

120<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

0,1<br />

0,2 0,3 0,4 0,5 0,6<br />

diameter (mm)<br />

Figure 2: Marine ageing of the monofilaments<br />

after one year of immersion.<br />

0,7 0,8 0,9<br />

A new<br />

generation of<br />

compostable<br />

monofilament<br />

for a wide<br />

range of<br />

applications<br />

SeaBird, based in Brittany, France, is a company that engages<br />

in the research, development and production of<br />

bioplastic materials. Since its founding in 2011, the company<br />

has focused on reducing the impact of conventional plastics<br />

in the marine environment by evolving sustainable waste<br />

management solutions.<br />

Seabird produces compostable bioplastic formulations<br />

enhanced with fillers and additives that are able to meet the<br />

specifications and process constraints of their industrial<br />

partners while retaining their environmentally-friendly nature<br />

(no volatile organic compounds (VOCs), toxic additives and<br />

others, end-of-life valuation).<br />

In 2017, the company validated the industrial production<br />

of monofilaments based on one of these compounds, called<br />

Sea212 ® . Developed for use on an extrusion spinning process<br />

line, the compound is a blend of different bio-polyesters and<br />

bio-additives. The various ingredients are expertly combined<br />

to meet all process specifications and provide the required<br />

physical properties, while at the same time complying both<br />

with the European composting standard EN13432 / EN 14995<br />

and the food contact standard. The monofilaments are used<br />

in many products developed by Seabird and some industrial<br />

partners.<br />

Special consideration was given to the homogeneity and<br />

rheological stability of the blend in order to guarantee the<br />

compound’s processability. The compound can be processed<br />

at 170 °C, which is lower than the temperature used for most<br />

conventional plastics.<br />

Properties of the monofilament<br />

A range of monofilament diameters (from 0.2 mm to 1.0 mm)<br />

were developed, targeted at a wide array of applications. Figure 1<br />

shows the mechanical strength of the monofilament in<br />

relation to the diameter. The mechanical tests were performed<br />

according to standard EN ISO 2062. Although a monofilament<br />

tenacity of 2.4 cN/dtex was found for a monofilament with a<br />

diameter of 0.65 mm - a quarter less than certain conventional<br />

monofilaments - it is still sufficient for many applications.<br />

18 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Fibers & Textiles<br />

The monofilament boasts numerous interesting properties.<br />

The material remains stable up to 80 °C; it is lighter than PET,<br />

easily dyable due to its natural white color, easy to tie and is<br />

resistant to common solvents such as acetone, ethanol and<br />

white spirit.<br />

Marine ageing<br />

The compound was developed for, among other things,<br />

marine applications, and designed to have a useful life of five<br />

years with no significant degradation of the properties. The<br />

objective, therefore is to produce compostable products that<br />

are economically viable; i.e. products with a useful life that is<br />

similar in length to conventional products, to avoid having to<br />

invest earlier in new equipment because of a shorter lifespan.<br />

To assess the lifespan of the monofilaments, ageing<br />

experiments have been carried out at Lorient’s harbor<br />

since 2017. Figure 2 shows scanning electron microscope<br />

(SEM) images of a monofilament after 12 months of marine<br />

immersion. These analyses demonstrated a surface<br />

degradation of the monofilament, but the mechanical<br />

properties remained stable.<br />

A compostable geotextile<br />

A new generation of industrially compostable geotextile<br />

fences have been under development with an industrial<br />

partner since 2017 (Figure 3). These fences protect dunes from<br />

wind erosion and because they are sometimes entirely covered<br />

by sand, they are not systematically cleared away after use. In<br />

order to develop a more ecofriendly product, biodegradation<br />

studies on this woven geotextile have been carried out on a<br />

beach since January <strong>2019</strong>. A compostable beach access and<br />

soil protect carpet is also being developed.<br />

Compostable trammel fishing nets<br />

It was recently reported that a 12m French gillnetter (fishing<br />

boat) produces about 8000 kg of waste per year, most of which<br />

takes the form of fishing nets. In order to find an alternative<br />

end-of-life solution to landfill or incineration, a compostable<br />

trammel fishing net prototype was developed in <strong>2019</strong>.<br />

A trammel net is composed of three layers: the two outside<br />

layers are made from a 0.60 mm monofilament and the inside<br />

layer (fishing layer) is produced from a 0.33 mm monofilament.<br />

These trials allowed the prototypes to be assessed for flaws in<br />

order to improve the net quality.<br />

Figure 4 shows a piece of the produced fishing layer. At the<br />

moment, Seabird’s R&D office is working on the enhancement<br />

of some of the properties of the monofilaments, such as the<br />

abrasion resistance. Net production and fishing trials in real<br />

conditions are scheduled for 2020.<br />

Others perspective products<br />

The technical potential of Sea212 compound and its<br />

monofilaments improves with each challenge encountered<br />

in the projects. Seabird works with other partners to develop<br />

ropes, mussel gillnets and oyster pockets. Also, Seabird is<br />

reaching out to other application sectors such as household,<br />

packaging and medical textiles.<br />

www.seabird.fr<br />

By:<br />

Vincent Mathel<br />

Bioplastic engineer and project manager.<br />

ICCI SEA (“Seabird”)<br />

Lorient, France.<br />

Figure 3: Fence to protect the dunes<br />

Figure 4: Piece of trammel fishing net<br />

from the bio-monofilaments<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 19


Fibers & Textiles<br />

Monofilament melt spinning<br />

of biopolymer-blends<br />

By:<br />

Pavan Kumar Manvi, Jonas Hunkemöller and, Thomas Gries<br />

Institut für Textiltechnik ITA, RWTH University<br />

Aachen, Germany<br />

Several efforts have been made to produce biobased<br />

multifilament yarn for textile applications. While these<br />

have generated considerable interest, monofilament<br />

applications of biopolymers have not yet been sufficiently<br />

researched to allow their use in textile applications. In the<br />

present research, a monofilament spinning process is developed<br />

for biopolymer blends with the aim of producing<br />

biobased monofilaments for use in agrotextile applications.<br />

Arboblend 3327 V is a renewable resource-based product<br />

manufactured by Tecnaro (Ilsfeld, Germany). The potential<br />

of this polymer blend for multifilament melt spinning was<br />

studied within the scope of the projects “Tailor-made melt<br />

the speed of Duo 1 between 20 m/min and 100 m/min<br />

was experimented with, but to no avail. Other efforts were<br />

made to decrease the throughput to make the filament<br />

thinner and more flexible. This decreased the frequency of<br />

filament breaks, but failed to eliminate them completely.<br />

During the experiments, a brittle fracture (break) of the<br />

filament was observed, which, it was thought, could be due<br />

to intensive cooling and the brittle nature of polylactic acid<br />

(a component in Arboblend 3327 V) at room temperature.<br />

The water cooling of the molten filament was therefore<br />

removed and replaced by a single godet. As the cooling rate<br />

of the filament was expected to be slower with air cooling,<br />

brittle fracture of the filament would be less likely to occur.<br />

Hopper<br />

Extruder<br />

Spinning<br />

head<br />

Water<br />

bath<br />

Filament<br />

DUO 1 DUO 2<br />

Heated drawing chamber<br />

Fig. 1: Set-up of monofilament<br />

spinning machine with water bath<br />

Winder<br />

spinnable biopolymer compound for textured filament<br />

yarn, elastic combination yarn and other fibrous materials<br />

(BioKombiGarn)”, a two year project running from 2015 –<br />

2017 and “Starch-based textiles: Cost-effective textiles<br />

made from biopolymers (Star-Tex)”, which ran from 2015<br />

– 2018. The blend was shown to offer good spinnability. It<br />

was therefore chosen to use Arboblend 3327 V to develop a<br />

monofilament melt spinning process.<br />

For the development of a melt spinning process, a melt<br />

spinning set-up with single screw extruder, a spinning<br />

head, a water bath, two duo godets, one heating chamber<br />

and a winder was used, as shown in Fig. 1.<br />

The initial parameters shown in Tab. 1 were chosen on<br />

the basis of previous experiments with multifilament melt<br />

spinning of Arboblend 3327 V.<br />

Observations and results: Experiments were started<br />

with the machine set-up shown in Fig. 1 and the process<br />

parameters listed in Tab. 1. During the experiments,<br />

intensive filament breakage was observed at the first galette<br />

duo (Duo 1). To stop the filament break at Duo 1, varying<br />

Tab. 1: Initial process parameters<br />

for monofilament melt spinning of<br />

Arboblend 3327 V<br />

Parameter Unit Value<br />

Extruder temperature zone 1 °C 180<br />

Extruder temperature zone 2 °C 200<br />

Extruder temperature zone 2 °C 220<br />

Spinning pump temperature °C 220<br />

Spinning head temperature °C 220<br />

Through put of spinning pump g/min 5.9<br />

Speed of drawing godet set 1 (Duo1) m/min 50<br />

Speed of drawing godet set 2 (Duo2) m/min 100<br />

Temperature of heating chamber °C 180<br />

Speed of winder m/min 201<br />

Aimed fineness dtex 70.4<br />

A schematic view of the machine set-up with a mono<br />

take-up godet is shown in Fig. 2.<br />

20 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Fibers & Textiles<br />

Hopper<br />

Extruder<br />

Spinning<br />

head<br />

Filament<br />

Fig. 2: Set-up of monofilament<br />

spinning machine mono godet<br />

Winder<br />

Take-up<br />

godet<br />

DUO 1 DUO 2<br />

Heated drawing chamber<br />

It was observed that after replacing the water bath<br />

with the godet, the filament could be passed through the<br />

first godet duo successfully. This led to the conclusion<br />

that monofilaments containing brittle polymers should<br />

preferably be cooled by air to prevent an increase in<br />

brittleness.<br />

Subsequent experiments were conducted using the setup<br />

shown in Fig. 2. Further challenges were observed when<br />

passing the filament through a heated drawing chamber. As<br />

soon as the filament passed through the heated chamber<br />

and the second godet duo, filament break occurred. After<br />

several trials, this problem remained, meaning it could<br />

not be considered an artefact of the experiment. Further<br />

improvement in the set-up and the process parameters<br />

became necessary.<br />

One hypothesis to explain the phenomenon was that a<br />

sudden increase in the filament temperature resulted in too<br />

little tension on the filament. This in turn caused slugging,<br />

leading to breakage of the filament in contact with the<br />

bottom of heating chamber. By decreasing the temperature<br />

of the heated drawing chamber it was thought that the<br />

problem could be solved. This was tested by lowering the<br />

temperature by 10 °C steps. As the temperature of the<br />

heated drawing chamber dropped, the number of filament<br />

breaks also decreased. The temperature was therefore<br />

lowered to 100°C, at which point a significant improvement<br />

in the process stability was observed.<br />

Another approach to solving the problem was to increase<br />

the draw ratio, which would increase the tension on the<br />

filament and thus avoid or reduce the slugging of the<br />

filament. To test this, the draw ratio between Duo 1 and<br />

Duo 2 was increased by decreasing the speed of Duo 1<br />

and increasing the speed of Duo 2. This approach again<br />

improved the process stability.<br />

The optimization of the process parameters led to a stable<br />

process. However, some sudden breaks were still observed<br />

in the heated drawing chamber during a continuous run<br />

of the filament. It was concluded that a movement of the<br />

filament on Duo1 and Duo 2 caused sudden contact of the<br />

monofilament with the wall of the heated chamber, leading<br />

to filament break. To avoid this, two filament guides were<br />

placed at the entrance and at the exit of the heated drawing<br />

chamber to ensure a continuous pass of the monofilament<br />

through the heated drawing chamber without contact with<br />

the hot surface.<br />

The changes in the process and the machine set-up<br />

outlined above enabled a stable monofilament melt spinning<br />

process with Arboblend 3327 V polymer. The process<br />

parameters for a stable monofilament melt spinning<br />

process with Arboblend 3327 V polymer are shown in Tab. 2.<br />

A successful monofilament melt spinning process with<br />

biobased Arboblend 3327 V polymer could be established<br />

and a melt spun monofilament is shown in Fig. 3.<br />

The melt spun Arboblend 3327 V monofilament was also<br />

tested for its mechanical and shrinkage properties. These<br />

properties are shown in Tab. 3.<br />

Tab. 2: Process parameters for a stable monofilament melt<br />

spinning process with Arboblend 3327 V polymer<br />

Parameter Unit Value<br />

Extruder temperature Zone 1 °C 180<br />

Extruder temperature Zone 2 °C 190<br />

Extruder temperature Zone 2 °C 200<br />

Spinning pump temperature °C 200<br />

Spinning head temperature °C 200<br />

Through put of spinning pump g/min 8.8<br />

Speed of mono godet m/min 27<br />

Speed of Duo 1 m/min 30<br />

Speed of Duo 2 m/min 150<br />

Temperature of heating chamber °C 100<br />

Speed of Winder m/min 153<br />

Fig. 3: Arboblend 3327 V monofilament bobbin<br />

Tab. 3: Properties of Arboblend 3327 V monofilament<br />

Property<br />

Unit<br />

Arboblend 3327 V<br />

monofilament<br />

Monofilament fineness dtex 141<br />

Tensile strength cN/tex 28,28<br />

Breaking elongation % 26,51<br />

Hot air shrinkage % 27,49<br />

www.ita.rwth-aachen.de<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 21


Fibers & Textiles<br />

Alternative materials for<br />

mussel socks<br />

By:<br />

Bas Krins<br />

Technical Manager<br />

Senbis Polymer Innovations<br />

Emmen, The Netherlands<br />

Mussel cultivation involves a number of different<br />

steps. In The Netherlands mussel seed is collected<br />

on ropes hanging in the Waddenzee. The seed is<br />

harvested from these ropes and collected. Subsequently<br />

this seed is used for the cultivation of mussels. This can be<br />

done on the bottom of the sea. But more than 95 % of all<br />

mussels produced worldwide are grown on ropes. In that<br />

case, mussel seed is attached to a rope hanging in the sea.<br />

While there are various ways to ensure the mussel seed becomes<br />

attached to the rope, a common one is by using a<br />

so-called mussel sock. This sock is placed around the rope<br />

and the space between the rope and the sock is filled with<br />

mussel seed. This allows the mussels to grow and adhere<br />

to the rope. After about one month, the mussel sock is no<br />

longer required to support the mussels and should then<br />

start degrading. If the sock does not degrade in time, it will<br />

hamper the further growth of the mussels.<br />

The mussel sock<br />

Usually the mussel sock is produced from cotton by a<br />

knitting technique. This material has several disadvantages.<br />

The multifilament yarn developed was successfully<br />

processed on existing knitting machines for mussel socks.<br />

These mussel socks are now being tested in live mussel<br />

cultivation conditions at Blackshell Farm in Westport,<br />

Ireland. The degradation time is about a month in sea water<br />

and can be tuned by the diameter of the filaments and the<br />

composition of the compound. In the next months Senbis<br />

will optimize the yarn and set-up the requirements for<br />

market entry.<br />

www.senbis.com<br />

The degradation time can be adjusted somewhat by<br />

varying the thickness of the yarn. This means that in<br />

areas where mussels grow slower because of the low<br />

temperature of the water, for example off the coast of<br />

Iceland, the sock will degrade too fast. As a consequence,<br />

the part of the mussel seed not attached to the rope when<br />

the net degrades will be lost.<br />

A second issue relates to the environmental consequences<br />

of the use of cotton. Cultivating cotton requires larger<br />

amounts of water. Pesticides are also used. Hence<br />

customers seeking to market mussels under a biologically<br />

farmed label will suppliers of mussels not to use cotton.<br />

The challenge<br />

Senbis (Emmen, The Netherlands) is cooperating with<br />

Machinefabriek W. Bakker (Yerseke, The Netherlands), a<br />

supplier of equipment for the mussel industry, in order to<br />

develop a yarn that can serve as an alternative for cotton<br />

in this application. The degradation time in sea water<br />

must be similar to that of cotton, i.e. about a month.<br />

Very few biopolymers can fulfil this requirement as most<br />

do not biodegrade sufficiently quickly in sea water. In<br />

addition, the mechanical properties have to be sufficient<br />

for this application. This combination, fast degradation<br />

and mechanical properties, could not be realized with<br />

existing polymers. But by making a compound based on<br />

thermoplastic starch and other polymers, Senbis has been<br />

able to develop a material that can be converted into a<br />

multifilament yarns with sufficient tenacity and elongation.<br />

22 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Fibers & Textiles<br />

Cellulose based fibers fully<br />

biodegradable in water, soil<br />

and compost<br />

The Lenzing Group (Lenzing, Austria) received confirmation<br />

of the full biodegradability of its fibers in fresh<br />

water by the independent research laboratory Organic<br />

Waste Systems (OWS) (Ghent, Belgium). The new and existing<br />

international certifications conducted by OWS and issued<br />

by TÜV Austria (Kraainem, Belgium) verify that LENZING<br />

Viscose fibers, LENZING Modal fibers and LENZING Lyocell<br />

fibers are biodegradable in all natural and industrial<br />

environments: in the soil, compost as well as in fresh and<br />

in marine water.<br />

The biodegradability of cellulosic products and the<br />

synthetic fiber polyester was tested in fresh water at<br />

OWS according to valid international standards, e.g. ISO<br />

14851. At the end of the trial period, Lenzing wood-based<br />

cellulosic fibers, cotton and paper pulp were shown to be<br />

fully biodegradable in fresh water in contrast to synthetic<br />

polyester fibers. The fact that synthetic materials are not<br />

biodegradable leads to major problems in wastewater<br />

treatment plants and potentially marine litter. In turn, this<br />

not only harms fish and birds living in and close to the<br />

oceans but also all marine organisms and us humans.<br />

“The Lenzing Group operates a truly circular business<br />

model based on the renewable raw material wood to<br />

produce biodegradable fibers returning to nature after use.<br />

This complete cycle comprises the starting point of the core<br />

value of sustainability embedded in our company strategy<br />

sCore TEN and is the ‘raison d’etre’ of our company”, says<br />

Stefan Doboczky, Chief Executive Officer of the Lenzing<br />

Group. “In living up to this positioning, we not only enhance<br />

the business of our suppliers, customers and partners<br />

along the value chain but also improve the state of the<br />

entire textile and nonwovens industries.”<br />

Both the textile and nonwovens industries face huge<br />

challenges with respect to littering. Therefore, legislative<br />

bodies worldwide can no longer ignore the issue and have<br />

moved towards plastics legislation aimed at limiting the<br />

vast amount of waste. In response, European lawmakers<br />

issued the Single-Use Plastics Directive currently being<br />

transposed into national legislation in the EU member<br />

states.<br />

Conventional wet wipes and hygiene products mostly<br />

contain plastic and were thus identified as one of the product<br />

categories to be singled out. Less polluting alternatives<br />

are generally encouraged by NGOs and legislators, e.g.<br />

products made of biodegradable wood-based cellulosic<br />

fibers. Plastic waste including microplastic can persist in<br />

the environment for centuries. In contrast, biodegradable<br />

materials are the best alternative to single-use plastics<br />

because they fully convert back to nature by definition and<br />

thus do not require recycling. MT<br />

www.lenzing.com<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 23


Fibers & Textiles<br />

PLA-fibres<br />

in medical<br />

applications<br />

New composite material for<br />

non-acidic degradation of<br />

medically used PLA<br />

PLA<br />

3D-printing<br />

+<br />

Microgel<br />

Solution<br />

spinning<br />

Electrospinning<br />

Fig. 2: In the framework of the pHMed project<br />

different processes for achieving PLA structures on<br />

various scales are developed<br />

Fig. 1: Wet spinning<br />

equipment for PLAfilament<br />

spinning<br />

By:<br />

Georg-Philipp Paar<br />

Dept. of Biohybrid & Medical Textile (BioTex)<br />

Institut für Textiltechnik der RWTH Aachen University<br />

Aachen, Germany<br />

Biodegradable materials, such as polyglycolic acid<br />

(PGA) and polylactic acid (PLA), are used commercially<br />

in medicine for sutures, osteosynthesis systems<br />

and drug delivery systems. The degradation of these materials<br />

inside the body offers a big advantage in implants,<br />

like meshes and support structures (scaffolds), as a second<br />

operation for removal is not necessary and long-term foreign<br />

body reactions are prevented. Furthermore, a gradual<br />

reduction of the mechanical support function is possible,<br />

which allows load transfer from the temporary structure to<br />

the healing tissue, unlike when using metal implants.<br />

However, the degradation of PLA and PGA in the body is<br />

problematic, as acidic degradation products are released,<br />

which can cause a local acidosis. This may lead to<br />

inflammation or even tissue death.<br />

To compensate the acidic environment and local drop of<br />

the pH in the tissue buffering salts were incorporated in<br />

PGA filaments in the cooperation of the Dept. of Biohybrid<br />

& Medical Textiles (BioTex) and the Institut für Textiltechnik<br />

ITA (both RWTH Aachen University). Unfortunately, the<br />

buffering capacity was insufficient and the salts caused<br />

instabilities in the spinning process. A promising alternative<br />

are amine based microgels, developed by the DWI - Leibniz<br />

Institute for Interactive Materials (also RWTH Aachen<br />

University). These colloidal polymers show a high buffering<br />

capacity while being suitable for the use in medical products<br />

because of a good biocompatibility.<br />

PLA filaments with microgels were dry spun, as the<br />

microgels function is preserved only at low temperatures.<br />

The buffering of the pH value was successful, but the<br />

filaments showed a low tensile strength with a high<br />

variation in values. Current research results show that<br />

a wet spinning process is a promising alternative, as it<br />

allows production of PLA filaments with increased tensile<br />

strength. First experiments indicate that the filaments can<br />

be processed further by braiding and knitting technology to<br />

produce sutures and scaffolds.<br />

In addition to the production of textile filaments also other<br />

manufacturing processes are developed within the project<br />

pHMed. For example, the DWI integrated the microgels into<br />

electrospun nonwovens, which could be used for skin or<br />

cartilage replacement. The EnvisionTec GmbH (Gladback,<br />

Germany) tries to incorporate microgels into 3D printed<br />

PLA structures. With this flexible process it is possible to<br />

build up three-dimensional structures, which can be used<br />

for stabilizing materials after a bone fracture. An important<br />

aspect for industrialization of the material – the upscaling<br />

of the microgels synthesis – is investigated as well by DWI<br />

within the framework of the project.<br />

Acknowledgement: The Project pHMed is supported by<br />

the European Regional Development Fund North Rhine-<br />

Westphalia (EFRE.NRW).<br />

www.biotex-aachen.de | www.ita.rwth-aachen.de<br />

24 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


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bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 25


Report<br />

Inauguration of the world’s<br />

second largest PLA plant<br />

Total Corbion PLA’s first 75,000 tons per year bioplastics<br />

plant officially opened in Rayon/Thailand<br />

By:<br />

Michael Thielen<br />

T<br />

otal Corbion PLA, a 50/50 joint venture between Total and<br />

Corbion, officially inaugurated its 75,000 tonnes per year<br />

PLA (Poly Lactic Acid) bioplastics plant in Rayong, Thailand<br />

on Sept. 09, <strong>2019</strong>. The world’s second largest PLA plant is located<br />

on the same premises, right next to a lactic acid plant of Corbion.<br />

It was finished in mid 2018 and commissioned end of 2018. As of<br />

yet, the PLA plant has produced more than 20,000 tonnes of PLA.<br />

The Grand Opening ceremony was chaired by Ms. Duangjai<br />

Asawachintachit, Secretary General of the Thailand Board of<br />

Investment (BOI). The event was opened with a traditional religious<br />

ceremony in which the plant was blessed by Buddhist monks.<br />

Honorable guests included Dr. Somchint Pilouk from the<br />

Industrial Estate Authority of Thailand, Mr. Jirasak Tapajot,<br />

Banchang District Chief, H.E. Jacques Lapouge, the French<br />

Ambassador, and H.E. Kees Rade, the Dutch Ambassador (in<br />

absentia). bioplastics MAGAZINE participated in the Grand Opening<br />

and spoke to different representatives on Total Corbion PLA and<br />

Corbion.<br />

“This opening is an important milestone for us and the circular<br />

economy,“ said Stéphane Dion, CEO of Total Corbion PLA. “The<br />

strategic fit between Corbion and Total is no less than perfect.<br />

Benefitting from the lactic acid supply of Corbion and benefitting<br />

from Total’s expertise in polymer technology and its sales network<br />

we are poised to become a major player in the PLA industry.<br />

With this plant we demonstrate how passionate we are about<br />

contributing to a circular economy.”<br />

“The creation of sustainable growth with PLA bioplastics truly<br />

fits with our ambition to build new business platforms, applying<br />

disruptive technologies. PLA bioplastics will also drive further<br />

development and growth of Lactic Acid, which is at the centre<br />

of Corbion’s strategy to develop sustainable ingredient solutions<br />

to improve the quality of life for people today and for future<br />

generations,” said Marc den Hartog, Executive Vice President<br />

Innovation platforms of Corbion.<br />

“I’m very pleased to inaugurate Total<br />

Corbion PLA’s plant today, which has started<br />

up rapidly and now serves customers all<br />

around the globe” said Valérie Goff, Senior<br />

Vice President Polymers at Refining &<br />

Chemicals, Total. “PLA bioplastics<br />

will help meeting the rising<br />

demand for polymers<br />

while contributing to<br />

reducing end-of-life<br />

concerns.”<br />

Les 2 Vaches’<br />

yoghurt pot. Les 2<br />

Vache is an organic<br />

brand within the<br />

Danone family. The<br />

product launched<br />

in April this year<br />

The official ribbon<br />

cutting was performed<br />

by Ms. Duangjai Asawachintachit, the French Ambassador,<br />

Stéphane Dion, as well as the two parent companies of the joint<br />

venture, represented by Valérie Goff, together with Marc den<br />

Hartog. Thereafter, attendees were given a guided tour of the<br />

facility.<br />

Total Corbion’s Luminy PLA<br />

The new 75,000 tonnes per year facility currently produces ten<br />

different grades of Luminy ® PLA. “This is the widest range of<br />

PLA grades available on the market today,” said François de Bie,<br />

Senior Marketing Director of Total Corbion PLA, “covering all kind<br />

of grades from pure PDLA through pure PLLA”. Total Corbion PLA<br />

is the only resin manufacturer producing pure PDLA. “This is one<br />

of our key products and it allows us also to produce the high heat<br />

resistant stereocomplex PLA types,” François added.<br />

The new plant started production in December 2018 and has<br />

so far produced over 20,000 tonnes of different PLA grades. “The<br />

PLA went to a mix of different applications,” François continued.<br />

“The biggest part of our production goes for flexible packaging<br />

applications. Another significant amount is being compounded<br />

with e.g. PBAT and/or starch for different bag applications.”<br />

Depending on the required strength of the bags or the desired<br />

The plant was first blessed by monks in a religious ceremony<br />

Stéphane Dion, CEO Total Corbion PLA<br />

26 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Report<br />

100,000 tonne/annum lactide plant<br />

composting speed, the amount of PLA in the blends is higher or<br />

lower. For more rigid bags for multiple usage the PLA amount is<br />

higher, whereas for home-compostability for instance, it is lower.<br />

Another big field of applications is catering serviceware, such<br />

as thermoformed cups, plates and trays and injection moulded<br />

cutlery. Some smaller customers receive PLA for 3D-printing<br />

filaments. Spun into fibres, the PLA is also delivered for<br />

applications like nonwovens for e.g. teabags or hygiene products<br />

such as wet wipes.<br />

Blends of PLA and PHA are being used for example for a<br />

compostable PLA/PHA-based potato chip packaging developed by<br />

Pepsico and Danimer, now supplied to Chile as a test market. PLA/<br />

PHA-based drinking straws from Danimer are another innovation<br />

that help reduce the environmental impact of plastics.<br />

Being 100 % biobased Total Corbion’s PLA offers an alternative<br />

solution to traditional, comparable products made from fossil<br />

oil and its derivatives. The significant sustainability benefits over<br />

their fossil-based counterparts, like a reduced CO 2<br />

footprint and<br />

a reduced dependency on fossil resources contribute to solutions<br />

within the framework of today’s climate policy discussions.<br />

Geographically the biggest market of Total Corbion PLA is<br />

Europe, followed by Asia/Pacific and the Americas.<br />

“The demand for PLA is significantly higher than we can meet at<br />

the moment,” said François de Bie. One bottleneck at the moment<br />

is the capacity of Corbion’s latic acid plant, which is currently being<br />

increased. Strategically speaking François added “This is our first<br />

PLA plant, but with the market demand we are seeing and two<br />

strong parent companies we are certainly looking into further<br />

expansions.”<br />

Locally sourced sugar<br />

The Luminy PLA resins are made from renewable, non-GMO<br />

sugarcane sourced locally in Thailand. Of the total raw sugar<br />

production of Thailand of annually about 35 million tonnes, Total<br />

Corbion needs just 150,000 tonnes. And for Corbion and Total<br />

Corbion PLA it is quite important where the sugar comes from.<br />

“We seriously look at the quality of the sugar,” Marc den Hartog<br />

told bioplastics MAGAZINE. “This, together with how the sugar<br />

is grown and harvested including social responsibility, is more<br />

important than sourcing the sugar from the shortest distances.“<br />

One of the major local sugar supply partners of Corbion in Thailand<br />

is the company Mitr Phol, headquartered in Khlong Toei, Bangkok.<br />

In fact, the selection and the subsequent sustainable sourcing<br />

of these feedstocks is driven by a number of sustainability aspects.<br />

Corbion’s approach to a sustainable supply chain and responsible<br />

sourcing is founded on principles of ethical business practices,<br />

human and labor rights and environmental protection. For this<br />

reason the company has developed its Cane Sugar Code. Corbion’s<br />

code is based on the definitions for sustainable sugarcane and<br />

derived products as set out by Bonsucro. Bonsucro is a global,<br />

non-profit, multi-stakeholder organization founded by WWF in<br />

20<strong>05</strong>. Part of Bonsucro’s activities is the creation of the “Bonsucro<br />

Production Standard”, which covers five key principles: obey the<br />

law, respect human rights and labor standards, manage input,<br />

production and processing efficiencies to enhance sustainability,<br />

actively manage biodiversity and ecosystem services and lastly,<br />

continuously improve key areas of the social, environmental and<br />

economic sustainability. In 2017, Total Corbion PLA became the<br />

first company to offer PLA bioplastic resins made from Bonsucro<br />

ceritified sugar to the market.<br />

100,000 tonnes/annum lactide plant<br />

In addition to the PLA plant, Total Corbion PLA operates a 100,000<br />

tonnes per year lactide plant, which produces the monomer<br />

required for the production of PLA, a 1,000 tonnes per year PLA<br />

pilot plant for product development, and a chemical recycling<br />

facility, currently used for recycling of production waste. Combined<br />

with Corbion’s lactic acid plant, located on the same site, this<br />

enables a fully integrated production chain from sugar to PLA.<br />

www.total-corbion.com<br />

Ribbon Cutting<br />

François de Bie<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 27


ioplastics MAGAZINE<br />

and European<br />

Bioplastics<br />

The joint booth of<br />

bioplastics MAGAZINE and<br />

the industry association<br />

European Bioplastics,<br />

will again be a hub for all<br />

visitors interested in these<br />

trendsetting materials.<br />

More than 175 companies<br />

will present their bioplastics<br />

products and services in<br />

Düsseldorf. So the joint<br />

booth will assist everyone<br />

to find the right company<br />

for their needs. In addition,<br />

bioplastics MAGAZINE will<br />

present the trade journal, the<br />

smartphone and tablet app,<br />

their books and consulting<br />

services and finally their<br />

conference programme. The<br />

latter includes the Bioplastics<br />

Business Breakfast, now<br />

organized already for the<br />

fourth time (see pp 10 for<br />

details).<br />

www.bioplasticsmagazine.com<br />

www.european-bioplastics.org<br />

7a / B10<br />

Show<br />

Preview<br />

K <strong>2019</strong>, known as “The World’s No. 1<br />

Trade Fair for Plastics and Rubber” and<br />

scheduled to take place in Düsseldorf<br />

from 16 to 23 October <strong>2019</strong>, is fully booked.<br />

Over 3,000 exhibitors from more than 60<br />

countries have registered to participate,<br />

and more than 200,000 trade visitors from<br />

all over the world are expected to come to<br />

the event. And this year again, bioplastics<br />

will play a major role at the K-show.<br />

K is the performance barometer for the<br />

entire industry and its global marketplace<br />

for innovations. For eight days, the “Who’s<br />

Who” of the entire plastics and rubber<br />

world will meet here to demonstrate the<br />

industry’s capabilities, discuss the latest<br />

trends and set the course for the future. K<br />

<strong>2019</strong> also addresses the current challenges<br />

of our era and especially of its sector, first<br />

and foremost in regard to “plastics for<br />

sustainable development” and the “circular<br />

economy”.<br />

The idea of the circular economy concept<br />

is quite simple: once used, valuable raw<br />

material can be processed at the end of<br />

its service life and be reused to create a<br />

new product – in an infinite loop. A vast<br />

array of polymer materials are perfectly<br />

suitable for this approach. A circular<br />

economy dramatically reduces waste and<br />

also protects the resource of crude oil.<br />

However, the implementation of a circular<br />

economy is still very much in its infancy.<br />

Many prerequisites still have to be met.<br />

Product design is important: recyclability<br />

should become an important aspect that<br />

comes in the early product development<br />

stages. A waste collecting system has to<br />

be implemented as well as recycling. We<br />

need technologies that allow cleaning,<br />

segregation, shredding and pelletizing of<br />

used plastics to ensure that it is ready to<br />

reuse in the production of plastic parts.<br />

Networking waste management and<br />

recycling with production is a core aspect<br />

of the circular economy concept. And so<br />

are bioplastics.<br />

These issues will play a major role not<br />

only at the exhibitors’ stands but also in<br />

the supporting programme of K <strong>2019</strong>, e.g.<br />

the 4 th Bioplastics Business Breakfast<br />

conferences hosted by bioplastics<br />

MAGAZINE (see pp 10 for details) as well<br />

as the special exhibition “Plastics Shape<br />

the Future” and “VDMA Circular Economy<br />

Forum” the joint appearance of the VDMA<br />

(Verband Deutscher Maschinen- und<br />

Anlagenbau – The Mechanical Engineering<br />

Industry Association) and its member<br />

companies.<br />

(Foto: Messe Düsseldorf / ctillmann)<br />

On the following pages a number of<br />

companies present their exhibits at K <strong>2019</strong>.<br />

This will be rounded off by a comprehensive<br />

K-show-review in issue 06/<strong>2019</strong>.<br />

Kompuestos<br />

Kompuestos (Palau Solità i Plegamans,<br />

Spain) will be presenting its latest<br />

innovations. Between other cutting-edge<br />

products designed to reduce environmental<br />

impact, Kompuestos has developed<br />

Biokomp, a range of fully compostable<br />

resins, duly certified according to EN 13432.<br />

Biokomp grades are based on proprietary<br />

thermoplastic starch and other renewable<br />

sources. Biokomp offers the ideal solution<br />

for products with a short life cycle such as<br />

single-use products.<br />

Kompuestos has been providing tailor<br />

made solutions for the plastic industry<br />

for over 30 years. Driven by innovation,<br />

Kompuestos has been able to develop<br />

and implement new products while<br />

maintaining a sustainable and continuous<br />

growth of over 15 % per years.<br />

www.kompuestos.com<br />

7.1 / A10<br />

28 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


K‘<strong>2019</strong> Preview<br />

FKuR<br />

FKuR (Willich, Germany) will be showcasing its expanded<br />

portfolio of biobased thermoplastics for a growing range<br />

of applications including packaging, consumer products,<br />

sporting goods and technical parts.<br />

Current additions to the portfolio include two glassreinforced<br />

grades within the Bio-Flex ® and Terralene ® product<br />

family, both with high rigidity, and three Terraprene ® TPE<br />

grades, one of which is characterized by its high bio-content,<br />

while the other two are oil-free.<br />

Bio-Flex GF30 is a PLA based compound with a glass fiber<br />

content of 30 wt % and a biobased carbon content (BBC) of over<br />

70% (calculated). This combines a relatively high stiffness of<br />

around 8,400 MPa with an equally high tensile strength of 70 MPa<br />

(ISO 527) and a good notched impact strength of 6.4 kJ/m².<br />

Applications examples include housings, castors, gears,<br />

sports equipment, orthotic devices, pipes and pipe systems.<br />

Terralene GF30 is a Green PE compound with a glass fiber<br />

content of 30 wt % and a calculated BCC of more than 94 %.<br />

The stiffness of 4.800 MPa is significantly higher than that<br />

of the mineral-filled grades with a wear resistance which<br />

is superior to the unfilled grades. It offers a wide range of<br />

applications, ranging from engineering parts to tubes and<br />

tube systems, dowels and brackets for the construction<br />

industry, orthotic devices and design products.<br />

New within the biobased Terraprene TPE compounds<br />

family are the grades SI 701 and SI 801 (calculated BBC 55%<br />

- 75%). They are available in Shore A40 to A80 grades and<br />

their properties are largely similar to those of conventional<br />

TPE-S grades. Typical applications include two-component<br />

injection molding, especially with polyolefins, which provide<br />

good adhesion.<br />

Terraprene CI 250 84A and Terrapene CI 450 93A are two oilfree<br />

TPEs with Shore A hardness of 84 or 93. With their softtouch<br />

surface, high resistance to kinking and deformation,<br />

they can substitute TPE-O and PVC in many injection molding<br />

applications.<br />

www.fkur.com<br />

6 / E48<br />

Ventilation covers (as shown in this example) are a possible<br />

application for the new glass fiber reinforced Bio-Flex and Terralene<br />

compounds from FKuR. (www.istockphoto.comSadeugra)<br />

ADBioplastics<br />

ADBioplastics (Valencia, Spain) is a startup dedicated to the<br />

development and commercial exploitation of custom-made<br />

bioplastics. Their material is biobased and biodegradable/<br />

compostable. From the origin because they are produced<br />

by corn, sugar cane, and sugar beet to renewable and<br />

biodegradable. The material goes down by 90 % within six<br />

months in an industrial composting process. A process that<br />

will help our target, packaging manufacturers in the food<br />

sector to fulfill the EU´s Strategy of plastic reduction by 2030<br />

as well as contribute to make the world a better place to live,<br />

our leitmotiv.<br />

With their background (ITENE spin-off) they are able to<br />

modify PLA into a PLA-Premium and improve its properties<br />

such as higher barrier OTR/WVTR than conventional PLA,<br />

thermal stability and improved mechanical properties,<br />

tunable transparency an good processability. All these meet<br />

the requirements demanded in the food sector.<br />

www.adbioplastics.com<br />

Albis / Dr. BOY<br />

5 / E01<br />

Dr. BOY, manufacturer of injection moulding machines from<br />

Neustadt-Fernthal, Germany, is planning an extensive live<br />

show at K <strong>2019</strong>. The company will spray produce 2-component<br />

(2K) ice scrapers, design trays and magnifiers continuously<br />

and at high frequency on various machines. The biobased<br />

plastic solutions for this demonstration will be supplied by<br />

Albis Plastic (Hamburg, Germany).<br />

"We want to offer our visitors something, so they can see for<br />

themselves the high quality of our injection moulding machines<br />

live," says Michael Kleinebrahm, Head of BOY Application<br />

Technology. "At the same time, we want to take responsibility<br />

and rely on biobased plastics. ALBIS products combine the<br />

highest quality with sustainability, that convinced us".<br />

CELLIDOR ® CP 410-10 BK 32/082 is used for the<br />

design trays. Cellidor is a plastic based on cellulose from<br />

sustainable, natural sources of raw materials, which ALBIS<br />

is compounding. It is characterised by an excellent gloss,<br />

a very good depth effect and self-polishing property. The<br />

magnifying glass contains Cellidor CP 400-10 CC, which is<br />

characterized by high transparency (comparable to PMMA)<br />

and a self-polishing surface. ALBIS supplies an ALFATERXL ®<br />

ECO with Shore A75 hardness as a soft component for the 2K<br />

ice scraper (2K with PP/LyondellBasell´s Adstif HA 840 R). It<br />

is recommended for this application due to good 2K adhesion<br />

on polyolefins in combination with 100% PP recyclate and<br />

biobased EPDM.<br />

And finally, on the booth of bioplastics MAGAZINE and<br />

European Bioplastics (7a/B10) paperclips made with<br />

Mitsubishi Chemical's Durabio TM are produced on a BOY XXS<br />

machine.<br />

www.albis.com | www.dr-boy.de<br />

8b/A61( Albis) 13/A43 (Dr. Boy) B03-03<br />

Please visit<br />

www.bioplasticsmagazine.com<br />

for updated information<br />

about K‘<strong>2019</strong>.<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 29


Novamont<br />

In collaboration with a number of leading machine<br />

manufacturers, Novamont, the world’s leading company in<br />

the sector of bioplastics and the development of bioproducts<br />

obtained from the integration of chemistry, environment<br />

and agriculture, will be presenting extrusion testing and the<br />

complete production cycle of MATER-BI fruit and vegetable<br />

bags. It will be an occasion to see first-hand the transparency<br />

and mechanical characteristics of biodegradable and<br />

compostable bags produced with a 50 % renewable content.<br />

The Italian company from Novara has always been driven<br />

by innovation and investment in R&D. It develops new<br />

proprietary technologies with which to constantly improve the<br />

performance and environmental profile of its products.<br />

The development model adopted starts with the local areas.<br />

It creates integrated biorefineries by rehabilitating industrial<br />

sites that have fallen into disuse, respecting the specific<br />

characteristics of the local areas, in partnership with all the<br />

stakeholders in the value chain.<br />

In an approach that is both cultural and industrial, jobs<br />

are created and competitiveness restored, while local skills<br />

are enhanced and training programmes rolled out at various<br />

levels.<br />

www.novamont.com<br />

Carbiolice<br />

6 / A58<br />

CARBIOLICE (Riom, France) has developed a unique and<br />

disruptive technology to fight white pollution, using enzymes<br />

to accelerate at least by 30 % (measured by OWS) the<br />

compostability and biodegradability of PLA-based materials.<br />

Under the trade name EVANESTO ® , this innovative patented<br />

concentrate is universal and compatible with any PLA-based<br />

compounds, best suited for applications such as single-use<br />

plastics, but also films, bags for biowaste collection, food<br />

packaging, coffee-pod… In fact, all applications in which<br />

composting is a meaningful end-of-life and where reuse or<br />

recycling have reached their limits.<br />

PLA is naturally compostable, but its decomposition takes<br />

too long according to norms to be certified OK Compost Home,<br />

i.e. in domestic conditions. Thanks to Evanesto upgrading<br />

PLA, it is now possible to compost PLA-based products at<br />

home, and improve its positive impact on the environment.<br />

In compost, PLA will be disintegrated in less than 6 months,<br />

according to norms EN 13432 and NF T51-800.<br />

Developed as a Masterbatch, Evanesto can be used<br />

on conventional plastic transforming processes without<br />

adaptation or investments.<br />

Carbiolice latest technological advances will simplify<br />

composting certification procedure for all the PLA industry..<br />

www.carbiolice.com 5 / D04-03<br />

Agiplast<br />

Agiplast (Casalbuttano, Italy) is a world leader group in<br />

polymer compounding and regeneration since 1994.<br />

The company has developed a large range focused<br />

on the polyamides as well as fluoropolymers and other<br />

thermoplastics. They are distributed through 2 business units<br />

and 4 brands including RGN by Agiplast, the feeding brand<br />

guaranteeing the sustainable origin of the raw material.<br />

Thanks to its intensive international activity, Agiplast exports<br />

worldwide its high quality products in most of European,<br />

American, Asian and African countries.<br />

The mission of Agiplast, plastic compound manufacturer,<br />

is to be a protagonist in the engineering plastic market in<br />

offering sustainable solutions to the companies interested<br />

in decreasing the planet resources use and improving their<br />

proposals to the consumers.<br />

That is why the brand RGN by Agiplast has been created<br />

in order to offer to the consumers confidence in using<br />

regenerated raw materials with first choice quality.<br />

www.agiplast-group.com<br />

Omya<br />

Omya (Cologne, Germany) is presenting Omya Smartfill ®<br />

55 - OM, a new functionalized Calcium Carbonate for use in<br />

biopolymers and in particular Polylactic Acid (PLA).<br />

Conventional Calcium Carbonate products lead to PLA<br />

degradation because of hydrolysis during processing. Omya<br />

Smartfill 55 - OM demonstrates almost no hydrolysis when<br />

processed at filler loads of up to 40 %. At the same time,<br />

the addition of Omya Smartfill 55 – OM in films, sheets and<br />

injection molded items improves product stiffness, impact<br />

resistance, elongation, heat transfer, and it contributes to an<br />

overall reduction in formulation cost.<br />

Omya Smartfill 55 - OM is food contact compliant according<br />

to (EU) Regulation No 10/2011 and FDA approved. It also<br />

passes the compostable evaluation criteria for heavy metals,<br />

fluorine and ecotoxicity, outlined in the European norm EN<br />

13432.<br />

This new product reflects the company’s commitment to<br />

offer sustainable and innovative solutions for the plastics<br />

industry.<br />

www.omya.com<br />

6 / D75<br />

7.0 / B25<br />

30 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


K‘<strong>2019</strong> Preview<br />

Polykum<br />

Two Polykum members – Yizumi and Exipnos – celebrate<br />

a world premiere on the Booth of POLYKUM (Merseburg,<br />

Germany), that will find especially the interest of biopolymer<br />

processors. The new Direct Compounding Injection Molding<br />

(DCIM) system allows gentle, continuous processing with<br />

lowest shear and heat stress. Burdensome impacts like<br />

heating up, cooling down and granulating are eliminated. It<br />

saves energy, time and money. The CO 2<br />

-savings of up to 264 kg<br />

per ton of processed material minimize the ecological<br />

footprint of the final products significantly.<br />

On the Polykum booth visitors can follow the live production<br />

of design coffee cups of 100 % biobased and biodegredable<br />

compound. The exhibition unit consists of a standard injction<br />

moulding machine and the brand new Yizumi DCIM Compound<br />

Delivery System (CDS 35, on the photo on the right).<br />

The DCIM CDS module mixes the ingredients just where<br />

and when the compound is needed to be processed. Docked<br />

directly on the injection molding machine the CDS delivers it<br />

instantly to the injection unit.<br />

The joint project of Yizumi and Exipnos is 100 % in line<br />

with the Polykum politics. The german non-profit association<br />

hosts the congress „Biopolymer – Processing & Moulding“<br />

and offers the „Biopolymer Innovation Award“.<br />

www.polykum.de<br />

Gema Polimer<br />

12 / A27<br />

Gema Polimer ® (Izmir, Turkey) is the leading manufacturer<br />

of Masterbatch & Compounds in Turkey. Gema offers product<br />

solutions to various industries such as Hygiene, Packaging,<br />

White goods, Disposables, Construction and Automotive etc.<br />

GEMABiO ® is the brand name of Gema Polimer’s<br />

compostable Bioplastic Compounds. Gemabio grades of<br />

Bioplastic compounds are suitable for Flexible Packaging<br />

Film applications, Injection moulding, Thermoforming and<br />

other extrusion applications. The major end use are shopping/<br />

carrier bags, mailing bags, textile bags, cups/plates, cutlery,<br />

teaspoon, and many more. The products made from Gemabio<br />

are suitable for food contact and compostable according to EN<br />

13432 and ASTM D 6400. This year at K <strong>2019</strong>, Gema Polimer<br />

will be presenting its new certified Bioplastic compounds<br />

GEMABiO F 2910, GEMABiO E 2869, GEMABiO P 2884.<br />

www.gemapolimer.com<br />

7.1 / C21<br />

Foto Exipnos<br />

United Biopolymers<br />

United Biopolymers (Figueira da Foz, Portugal) through<br />

the BIOPAR ® Technology enables the production of nextgeneration<br />

starch-based bioplastics, with added capabilities<br />

& functionalities.<br />

The Biopar Technology enables blending two or more<br />

functional polymers to produce CoRez´s new material.<br />

CoRez is a compound Compostable Resin product achieved<br />

by the action of a compatibilizer that creates a unique bico-continues<br />

phase structure. This one brings several<br />

competitive advantages over any of the disperse technologies<br />

currently available in the market.<br />

Corez new material, under designation of Biopar allows<br />

formulation up 90 % green carbon content, it has the industrial<br />

compost and home compost Certification and is recyclable.<br />

The aim is to make CoRez the industry reference for the<br />

new material generation replacing Plastic as it is known.<br />

www.guiltfreeplastics.com<br />

Total Corbion PLA<br />

7.2 / G32<br />

Total Corbion PLA will be co-exhibiting together with parent<br />

company Total, and will highlight its Luminy ® Poly Lactic Acid<br />

(PLA) portfolio and the most recent application innovations.<br />

The Luminy PLA portfolio includes both high heat and<br />

standard grades and is used in a wide range of markets, from<br />

packaging to durable consumer goods and electronics.<br />

At K <strong>2019</strong>, Total Corbion PLA will be showcasing a number<br />

of partner applications based on PLA to illustrate the range of<br />

possibilities offered by this versatile biopolymer such as PLA<br />

pots from organic yoghurt brand Les 2 Vaches (Danone) will<br />

be on display, which replace traditional PS yoghurt pots.<br />

To showcase the high heat capabilities of PLA, visitors are<br />

welcome to enjoy a fresh cup of coffee at the Total Corbion<br />

PLA booth, served in a PLA thermoformed cup. The cups are<br />

available under the naturesse product range by Pacovis. The<br />

cups are biobased, made from renewable materials and have<br />

a reduced carbon footprint compared to PS cups.<br />

Total Corbion PLA is a global technology leader in Poly<br />

Lactic Acid (PLA) and lactide monomers. Total Corbion PLA,<br />

headquartered in the Netherlands, operates a 75,000 tonnes<br />

per year PLA production facility in Rayong, Thailand. The<br />

company is a 50/50 joint venture between Total and Corbion.<br />

www.total-corbion.com<br />

6 / E23<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 31


6 th PLA World Congress<br />

19 + 20 MAY 2020 MUNICH › GERMANY<br />

organized by<br />

www.pla-world-congress.com<br />

02-03 Sep 2020<br />

Cologne, Germany<br />

Save the dates!<br />

organized by<br />

www.pla-world-congress.com<br />

1D12<br />

Hall 1<br />

Fostag Formenbau<br />

Hall 3<br />

3F23 Eurolaser<br />

3C70-02 Lincore Depestele<br />

Hall 5<br />

5D04-08 Actiplast<br />

5E01 Adbio Composites<br />

5D04-13 Addiplast Group<br />

5C21–<br />

D21<br />

BASF<br />

5B18 Biesterfeld Plastic<br />

5A25 Blow Moulding Technologies<br />

5D04-03 Carbiolice<br />

5C07-01<br />

Center for Bioplastics<br />

and Biocomposites<br />

5E08 EcoForte<br />

5D<strong>05</strong> Ensinger<br />

5C06-01 FRX Polymers<br />

5B40 Gabriel-Chemie<br />

5E01 ITENE<br />

5F30-04 Kruschitz<br />

5D04-10 Lactips<br />

5D41 Montello<br />

5B39 Polyscope Polymers<br />

5D04-01 Polytechs<br />

5E08 The Compound Company<br />

5E08 Transmare Compounding<br />

5B09 Victrex Europa<br />

5C43 WKI Kunststoffe<br />

5E08 Yparex<br />

6A11<br />

6B42<br />

6C57<br />

6B42<br />

6D27 /<br />

6.1W01<br />

5E26<br />

6B11<br />

6B11<br />

6C43<br />

6C10<br />

6E61<br />

6D50<br />

6B28<br />

6E48<br />

6D76<br />

6E75\..<br />

E77<br />

6D76<br />

6D76<br />

6A23<br />

6D43<br />

6E80<br />

6A20<br />

6E27<br />

6A58<br />

6D75<br />

6C11<br />

6B55<br />

6C50<br />

6C50<br />

6D11<br />

6E16<br />

6C50<br />

Hall 6<br />

Adeka Polymer Additives Europe<br />

Akro-Plastic<br />

Arkema France<br />

Bio-Fed<br />

Braskem<br />

Cabopol - Polymer Compounds<br />

DSM Engineering Plastics Europe<br />

DSM Engineering Plastics Europe<br />

DuPont<br />

Elastron Kimya Sanayi ve Ticaret<br />

EMS-CHEMIE Deutschland<br />

Epsan Plastik<br />

Evonik Industries AG<br />

FKuR Kunststoff<br />

Fraunhofer-UMSICHT<br />

Grafe Advanced Polymers<br />

Grässlin Nord<br />

Hoffmann + Voss<br />

IMCD Deutschland<br />

Interpolimeri<br />

IRPC Public Company<br />

Kaneka Belgium<br />

Meraxis<br />

Novamont<br />

Omya<br />

Petrochemical Commercial<br />

Polimarky<br />

Polyblend<br />

Polymer-Chemie<br />

Reliance Industries<br />

Sidiac<br />

TechnoCompound<br />

6C58-01 Teknor Apex<br />

6E23 Total Corbion PLA<br />

6E23 Total Petrochemicals & Refining<br />

6E08 UBE Europe<br />

6A10 Wacker Chemie<br />

6E16 Weber & Schaer<br />

Hall 7<br />

7.0B25 Agiplast<br />

7.0B30 Daikin Chemical Europe<br />

7.0B08 Finproject<br />

7.0C23 Forplas Plastik<br />

7.0SC01 Fraunhofer IGB<br />

7.0B30 Heroflon<br />

7.0A37 Meltem Kimya ve Tekstil<br />

7.0C21 Nanox - Antimicrobial Protection<br />

7.0B03 Silon<br />

7.1A23 A.J. Plast Public Company<br />

7.1B21 Biotec<br />

7.1E03-13 Chnv Technology<br />

7.1A38 Doill Ecotec<br />

7.1D10 Elachem<br />

7.1D10 Epaflex Polyurethanes<br />

7.1C21 Gema Elektro Plastik<br />

7.1E03-28 Guangzhou Lushan<br />

7.1C06 Ingenia Polymers<br />

7.1B45 Jiangsu Torise Biomaterials<br />

7.1D01 Kandui Industries<br />

7.1A10 Kompuestos<br />

7.1B50 Merit Polyplast (Partnership)<br />

7.1D39 Parsa Polymer Sharif<br />

7.1C12 Ravago<br />

7.1E44 Shandong Dawn Polymer<br />

7.1C09 Soltex Petro Products.<br />

7.1D24 Toyobo Chemicals Europe<br />

7.1B19 UBQ Materials<br />

7.2A07 Art Plast<br />

7.2G11 Bajaj Superpack India<br />

7.2E10 Gianeco<br />

7.2C21 Greenage Industries<br />

7.2A06 Jinhui Zhaolong High Technology<br />

7.2E13 Laborplast<br />

7.2C27 Mesgo<br />

7.2G18 Stora Enso Timber<br />

7.2A14 Sumika Polymer Compounds (Eu)<br />

7.2C17 Technocom<br />

7.2G21 Tecnofilm<br />

7.2G31 United Biopolymers<br />

7aC24<br />

7aB10<br />

7aD<strong>05</strong><br />

7aB10<br />

7aD06<br />

7aD25<br />

7aD21<br />

7aC30<br />

7aD40<br />

Bassermann Minerals<br />

bioplastics MAGAZINE<br />

Croda Europe<br />

European Bioplastics<br />

Kuraray Europe<br />

Marubeni Europe Plc.<br />

Nurel<br />

Sojitz Europe<br />

West-Chemie<br />

Hall 8a<br />

8aH20 Add-Chem Germany<br />

8aE12-08 AIMPLAS<br />

8aB12 Alok Masterbatches<br />

8aF12 Benvic Europe<br />

8aE35 Beologic<br />

8aJ11 Clariant<br />

8aF20 Constab<br />

8aF37 Cromex<br />

8aH10 Dufor Resins<br />

8aH34 Fortum Waste Solutions<br />

8aK27 GCR Group<br />

8aK27 Gestora Catalana de Residuos<br />

8aH18 Hexpol TPE<br />

8aF40 Imerys Talc Europe<br />

8aB09 Inno-Comp<br />

8aF20 Kafrit Industries<br />

8aD12 LyondellBasell<br />

8aF50 Metaclay<br />

8aG41 Plastika Kritis<br />

8aK<strong>05</strong> Polyram Plastic Industries.<br />

8aG41 Romcolor 2000<br />

8aB28 Romira<br />

8aH28 Sukano<br />

8aE42 Tecni-Plasper<br />

8aD01 Tosaf Group<br />

8aK20 TPV Compound<br />

Hall 8b<br />

8bA61 Albis Plastic<br />

8bD60 almaak international<br />

8bH54 Coating P. Materials<br />

8bE68 Euro Commerciale<br />

8bA31 Forever Plast<br />

8bF22 Granulat<br />

8bH70 Indochine Bio Plastiques<br />

8bA52 Koksan Pet Ve Plastik Ambalaj<br />

8bH83 Loxim Industries<br />

8bE71-02 Maskom Plastik<br />

8bF80 Mexichem Specialty Compounds<br />

8bH28 MGG Polymers<br />

8bE11-<strong>05</strong> Nanjing Lesun Screw<br />

8bC68 Nanocyl<br />

8bC55 Pebo


8bH79-06<br />

8bC66<br />

8bH70<br />

8bC32<br />

8bH70<br />

8bF63<br />

8bH48<br />

8bC37-02<br />

Rák Antenna<br />

Raw Materials Recycling<br />

Respack Manufacturing<br />

SCJ Plastics<br />

Sheng Foong Plastic Industries<br />

Sirmax<br />

Taro Plast<br />

Woodplastic Group<br />

16F71<br />

FG Halle<br />

4 / 04.1<br />

FG04.1<br />

FG04.1<br />

Hall<br />

Sulzer Chemtech<br />

Outdoor area<br />

Nippon Gohsei Europe<br />

Mitsubishi Chemical - MCPP<br />

Mitsubishi Polyester<br />

10C67<br />

Hall 10<br />

Ww Ekochem<br />

Hall12a<br />

12A48 Aquafil Engineering<br />

12C45 Bayern Innovativ<br />

12A52-29 Intype Enterprise<br />

12C45 Neue Materialien Bayreuth<br />

12A27 Polykum<br />

12E19 Tecnaro<br />

Hall 813<br />

13A79 ICEE Containers Pty.<br />

Show<br />

Guide<br />

14A68<br />

Hall 14<br />

Biofibre<br />

Note: All companies listed in this guide<br />

were found in the official K’<strong>2019</strong><br />

catalogue under bioplastics.<br />

About companies listed in bold you find<br />

a short K-Show preview on pp 28-35<br />

bioplastics MAGAZINE,<br />

Polymedia Publisher GmbH<br />

Hall 07a, B10<br />

1<br />

BIOPLASTICS<br />

BUSINESS<br />

BREAKFAST<br />

B 3<br />

17. - 20.10.<strong>2019</strong><br />

You can use this double page as your<br />

personal show guide.<br />

As there are usually a lot of last minute<br />

changes, you’ll find up-to-date<br />

information at<br />

www.bioplasticsmagazine.com<br />

PLA Bioplastics for a brighter future<br />

Visit us:<br />

Hall 6 / booth E23<br />

Learn more about<br />

• Luminy® PLA Portfolio<br />

• Our 1st 75,000 tons p.a. plant<br />

• PLA applications


Beologic<br />

Beologic (Sint Denijs, Belgium) a compounding company<br />

with more than 20 years experience, is dedicated to the<br />

production of sustainable compounds. They develop,<br />

manufacture and market compounds for the plastic industry.<br />

Together with their R&D company Innologic, they are able<br />

to optimize and improve our materials depending on the<br />

application.<br />

At K <strong>2019</strong>, the company will launch different and innovative<br />

solutions to improve sustainability. For instance, a biobased<br />

ASA compound with good weathering properties, a 100 %<br />

fully biobased roto moulding powder and our latest range of<br />

Beograde materials.<br />

Over the years this has resulted in four product brands;<br />

either being biobased (Beobase – adding natural fibres),<br />

biodegradable or compostable (Beograde), fully recycled<br />

(Beocycle) or ecologic (Beosmart). The Beograde family is<br />

made of thermoplastic compounds containing renewable<br />

resources and designed to degrade under compost<br />

conditions. The materials can be processed with a wide range<br />

of tchnologies: extrusion, injection moulding, rotomoulding,<br />

thermoforming, or blow moulding. Adding wood creates a look<br />

and feel that emphasizes<br />

the biodegradable<br />

characteristics. It’s the<br />

company‘s ambition to<br />

replace traditional polymers<br />

but maintain their technical<br />

characteristics, whilst<br />

at the same time being<br />

sustainable.<br />

www.beologic.com<br />

AIMPLAS<br />

8A / E35<br />

AIMPLAS, the Plastics Technology Centre (Paterna, Spain)<br />

will display its main technological developments in the<br />

circular economy, active and smart packaging, sustainable<br />

mobility, medicine and decarbonization of the economy.<br />

Most of the projects to be presented will be on the circular<br />

economy. New sorting and treatment systems for waste of<br />

different origin (e.g. agri-food, packaging, bulky, automotive<br />

and PVC waste) so it can be recovered and used to generate<br />

new products and chemical compounds, thus reducing<br />

dependence on fossil sources.<br />

Aimplas will also exhibit its new developments in active<br />

and smart packaging designed to keep food fresh and also<br />

preserve completely different products such as audiovisual<br />

heritage. This new packaging contains sensors, improved<br />

barrier properties, additives and absorbents to extend the<br />

contents’ shelf life.<br />

The centre will also present projects on decarbonization of<br />

the economy, CO 2<br />

capture and storage for subsequent reuse<br />

as a raw material, and range solutions for electric cars that<br />

will lead to real progress in sustainable mobility. This is the<br />

case of new air conditioning methods that are more efficient<br />

because they reduce power consumption and increase vehicle<br />

range.<br />

www.aimplas.net<br />

08A / E-12-08<br />

Sukano<br />

At K <strong>2019</strong>, SUKANO (Schindellegi, Switzerland) will<br />

showcase new developments in functional additives and<br />

color masterbatches to expand the use of PLA and PBS in<br />

packaging applications and beyond. Several case studies will<br />

be presented to highlight advances in material modification<br />

using Sukano compostable masterbatches to achieve the best<br />

performance for biodegradable plastics. Sukano is a global<br />

leader in the development and production of additive and<br />

color masterbatches for biodegradable polymers such as PLA<br />

and PBS.<br />

All Sukano products are certified compostable according to<br />

EN13432. Their biobased carbon content is certified according<br />

to ASTM 6866. Sukano © Masterbatches are intended for<br />

packaging applications that are used in compostable<br />

certified products, and customers will be supported to attain<br />

certification for products where Sukano’s solutions are<br />

included. Sukano also assists our customers in their strategies<br />

and goals towards a circular economy; and contribute to the<br />

European roadmap towards a bioeconomy.<br />

www.carbiolice.com 5 / D04-03<br />

Biofibre<br />

Biofibre (Altdorf, Germany) shows the new product portfolio<br />

at their mother´s company Steinl Group.<br />

The complete product portfolio comprises Biofibre ® Silva,<br />

Biofibre Sustra, Biofibre Solva and Biofibre Lenta. Real<br />

show cases with our business partners and customized<br />

developments will be presented as well.<br />

Biofibre Lenta, as the newest development, is a compound<br />

that has been developed to substitute or replace HDPE (High<br />

Density Polyethylene) on an organic basis.<br />

Processing capabilities and product properties are almost<br />

equivalent to HDPE. The name Lenta is derived from the Latin<br />

origin lenta, i.e. tough and indicates the very stable material<br />

properties of this product group.<br />

In addition at the Circular Economy Pavillion of VDMA (open<br />

area outside halle 16) Biofibre presents new 90 % biobased<br />

material Biofibre Lenta - In use as a shoe tree!<br />

Biofibre client nico NORBERT SCHMID GMBH + CO. KG<br />

replaces a part of their product range by bioplastic based<br />

material solutions. In this particular case, a shoe tree.<br />

There are some challenging aspects for the development<br />

of a suitable substitute material in order to fully fulfill the<br />

required flexibility, strength, durability in that special footwear<br />

environment. The resulting material is over 90 % biobased<br />

recyclable, and colorable.<br />

www.biofibre.de/en<br />

14 / A68<br />

34 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


K‘<strong>2019</strong> Preview<br />

Evonik<br />

The German sports equipment manufacturer VAUDE uses<br />

the biobased polyamides of Evonik's ® Terra brand in its new<br />

collection of bags and backpacks.<br />

High-performance material with multiple benefits biobased<br />

VESTAMID Terra (PA 610) offers excellent impact resistance<br />

in cold temperatures. That makes the material ideally suited<br />

for all-weather buckles and other durable elements in<br />

equipment for demanding mountaineering and other leisure<br />

activities. Thanks to their low water absorption, buckles made<br />

of PA 610 are less likely to become brittle when used in the<br />

sports equipment of Vaude. This reduces the risk of tearing<br />

and improves product safety. Moreover, the low density of<br />

Vestamid Terra allows for manufacturing lighter sports<br />

equipment with a natural feel.<br />

Bio-based high-performance fibers in textiles Vaude plans to<br />

expand the successful use of Vestamid Terra to other product<br />

ranges in the future. For example, textile fibers made from Evonik's<br />

biopolyamides are lightweight, stretchable and breathable. The<br />

fabrics stand out for low moisture absorption, they dry quickly and<br />

don’t need ironing. The unique innovative high-performance fibers<br />

can be processed in all textile applications.<br />

Vestamid Terra is made up to 100 % from the seeds of<br />

the castor bean plant, but its sustainability concept goes<br />

beyond environmental benefits. Since castor bean plants can<br />

survive prolonged drought, they are typically cultivated in arid<br />

regions with no other agricultural use. As a result, the highperformance<br />

polymer does not have a negative impact on the<br />

human food chain.<br />

www.evonik.com<br />

6 / B28<br />

Arkema<br />

As a global player in specialty chemicals and advanced<br />

materials, Arkema (Colombes, France) strives to generate<br />

sustainable growth by providing its customers with innovative<br />

and environmentally sound solutions. Among these visitors will<br />

find some engineering plastics made from renewable resources.<br />

Over more than 70 years, Arkema’s Rilsan ® biosourced<br />

polyamide 11 flagship range has been renowned for its<br />

outstanding wide-ranging performance including resistance<br />

to high temperatures, chemical stability, and durability in the<br />

most demanding applications. It is used primarily in underhood<br />

applications as a substitute to metal and rubber.<br />

With its unique properties of energy return, light weight,<br />

elasticity, flexibility and impact resistance, Pebax ® elastomer<br />

remains the choice material for football boots. In the <strong>2019</strong><br />

Women’s World Cup, it was featured in 61 % of the sole of<br />

the shoes of the players during the competition. Arkema has<br />

also brought out an innovation with Pebax Rnew, the first<br />

biosourced thermoplastic elastomer.<br />

High performance Sarbio ® liquid resins from Sartomer ® ,<br />

derived from renewable raw materials, are unique and<br />

accommodate thermal curing as well as UV-curing for<br />

high output yield. They offer a sustainable approach to the<br />

development of consumer goods, and impart high performance<br />

plastic coatings to components used in smartphones,<br />

television sets, cosmetics packaging, household appliances,<br />

etc.<br />

www.arkema.com<br />

6 / B28<br />

14 –15 NOVEMBER <strong>2019</strong>, MATERNUSHAUS, COLOGNE, GERMANY<br />

BIOCOMPOSITES CONFERENCE COLOGNE is the world‘s largest conference<br />

and exhibition on the topic. This event offers the unique opportunity to gain a<br />

comprehensive overview of the world of biocomposites. See you in Cologne.<br />

Organiser:<br />

www.nova-institute.eu<br />

Sponsor Innovation Award:<br />

www.coperion.com<br />

Vote for the Innovation Award<br />

“Biocomposite of the Year <strong>2019</strong>”!<br />

© PICTURE: AMORIM CORK COMPOSITES<br />

www.biocompositescc.com<br />

www.biocompositescc.com<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 35


Application News<br />

CaixaBank launches new biodegradable cards<br />

CaixaBank (Valencia, Spain) recently started releasing<br />

its first biodegradable cards, 150,000 units of which will<br />

be distributed per year. It is a new type of card that can be<br />

acquired in any branch of the CaixaBank network, in the<br />

format of a gift card. In fact, from now on, all gift cards<br />

issued by CaixaBank will be biodegradable.<br />

The launch of this product represents a significant<br />

step forward in a plan specifically designed to reduce the<br />

environmental impact of the Company’s cards, a business<br />

in which CaixaBank is the leading company in Spain, with a<br />

total of 17.4 million cards and a market share of 23.38 % in<br />

terms of turnover.<br />

The plan includes both<br />

replacing the manufacturing<br />

material of the range of gift<br />

cards, and creating a new<br />

recycling programme for all<br />

card types. The cards will now be<br />

fully made from a biodegradable<br />

material, primarily formed of<br />

PLA. All other components of<br />

the card are biomass derived as<br />

well.<br />

Cards that use this material last<br />

for approximately two years, which<br />

makes it an ideal material for the<br />

gift cards, which expire within a<br />

maximum period of two years. As well as being biodegradable,<br />

the new CaixaBank cards use a different manufacturing process,<br />

which halves the carbon footprint of their production and entails<br />

the reduction of practically half the CO 2<br />

emitted.<br />

In order for customers to clearly recognise the biodegradable<br />

cards, CaixaBank is presenting a new design, with a more<br />

environmentally-friendly and minimalist feel, including a logo<br />

that indicates that it is a biodegradable product. In parallel to<br />

the launch of these new biodegradable cards, CaixaBank is<br />

continually analysing the materials that offer better durability to<br />

reduce the number of card replacements and thus reduce their<br />

carbon footprint.<br />

CaixaBank has also joined the United<br />

Nations Environment Programme<br />

- Finance Initiative (UNEP FI), which<br />

has three main goals: commitment<br />

to sustainable development, sustainability<br />

management and public<br />

awareness. MT<br />

www.caixabank.com<br />

New electric motorbike made with<br />

hemp biocomposite<br />

Cake (Stockholm, Sweden), which recently launched a<br />

groundbreaking electric motorbike, will now collaborate<br />

with Trifilon, an exciting Swedish startup from Nyköping<br />

that designs and sells sustainable materials with advanced<br />

biocomposite technology.<br />

The partnership was born of Cake’s mission to explore<br />

new sustainable technologies while producing exciting<br />

high-performance motorbikes. Trifilon’s biocomposites,<br />

which are produced with fibers from hemp and flax plants,<br />

can help the company improve its sustainability merits<br />

while maintaining the performance of its motorbikes.<br />

The current project will seek to replace<br />

current plastic components with Trifilon’s<br />

plant-based biocomposites. With Cake’s<br />

ethos of sustainability and clean<br />

transportation, the company has found<br />

a good match in the green-tech startup<br />

Trifilon, which helps companies<br />

systematically lower CO 2<br />

emissions<br />

and integrate renewable materials.<br />

Trifilon’s hemp-based biocomposite BioLite reduces the CO 2<br />

footprint from its manufacture by at least one third.<br />

“This is a great match because our companies are both<br />

about performance and sustainability. I think fans of Cake<br />

motorbikes will respond positively to having our plant-fiber<br />

composites in their motorbikes. It will mean that some<br />

ingredients in their motorbikes come from European farms.<br />

That makes these exciting motorbikes even cooler and more<br />

sustainable,” said Trifilon’s CEO and co-founder Martin<br />

Lidstrand.<br />

The technology behind Trifilon’s biocomposites<br />

was initially intended for the automotive<br />

segment, as a substitute for lightweight,<br />

strong carbon fiber. Trifilon had previously<br />

developed and built the body of a car<br />

for Volkswagen Rally with its hempbased<br />

biocomposite, BioLite. MT<br />

www.ridecake.com | www.trifilon.com<br />

36 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


green@hexpolTPE.com<br />

www.hexpolTPE.com<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 37


Natural Rubber © -Institut.eu | 2018<br />

Starch-based Polymers<br />

Lignin-based Polymers<br />

Cellulose-based Polymers<br />

©<br />

PBAT<br />

PET-like<br />

PU<br />

APC<br />

PTT<br />

PLA<br />

PU<br />

PA<br />

PTF<br />

PHA<br />

-Institut.eu | 2017<br />

PMMA<br />

HDMA<br />

DN5<br />

PVC<br />

Isosorbide<br />

1,3 Propanediol<br />

Caprolactam<br />

UPR<br />

PP<br />

Propylene<br />

Vinyl Chloride<br />

Ethylene<br />

Sorbitol<br />

Lysine<br />

MPG<br />

Epoxy resins<br />

Epichlorohydrin<br />

EPDM<br />

Ethanol<br />

Glucose<br />

PE<br />

MEG<br />

Terephthalic<br />

acid<br />

Isobutanol<br />

PET<br />

p-Xylene<br />

Starch Saccharose<br />

Fructose<br />

Lignocellulose<br />

Natural Rubber<br />

Plant oils<br />

Hemicellulose<br />

Glycerol<br />

PU<br />

Fatty acids<br />

NOPs<br />

Polyols<br />

PU<br />

PU<br />

LCDA<br />

THF<br />

PBT<br />

1,4-Butanediol<br />

Succinic acid<br />

3-HP<br />

5-HMF/<br />

5-CMF<br />

Aniline<br />

Furfural<br />

PA<br />

SBR<br />

Acrylic acid<br />

2,5-FDCA/<br />

FDME<br />

PU<br />

PFA<br />

PU<br />

PTF<br />

ABS<br />

PHA<br />

Full study available at www.bio-based.eu/reports<br />

Full study available at www.bio-based.eu/reports<br />

PEF<br />

PBS(X)<br />

©<br />

-Institut.eu | 2017<br />

Full study available at www.bio-based.eu/markets<br />

■<br />

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■<br />

■<br />

■<br />

7 th<br />

Bio-based Polymers & Building Blocks<br />

The best market reports available<br />

Commercialisation updates on<br />

bio-based building blocks<br />

7 th 1<br />

Data Data for for<br />

2018 2018<br />

UPDATE<br />

<strong>2019</strong><br />

UPDATE<br />

<strong>2019</strong><br />

Bio-based Building Blocks<br />

Bio-based Building Blocks<br />

and Polymers – Global Capacities<br />

and Polymers – Global Capacities<br />

and Trends 2018-2023<br />

and Trends 2017-2022<br />

Carbon dioxide (CO 2 ) as chemical<br />

feedstock for polymers – technologies,<br />

polymers, developers and producers<br />

Succinic acid: New bio-based<br />

building block with a huge market<br />

and environmental potential?<br />

Million Tonnes<br />

6<br />

5<br />

4<br />

3<br />

2<br />

1<br />

2011<br />

Bio-based polymers:<br />

Evolution of worldwide production capacities from 2011 to 2022<br />

Lactic<br />

acid<br />

Adipic<br />

acid<br />

Methyl<br />

Metacrylate<br />

Itaconic<br />

acid<br />

Furfuryl<br />

alcohol<br />

Levulinic<br />

acid<br />

2012 2013 2014 2015 2016 2017 2018 <strong>2019</strong> 2020 2021 2022<br />

Dedicated<br />

Drop-in<br />

Smart Drop-in<br />

Superabsorbent<br />

Polymers<br />

Pharmaceutical/Cosmetic<br />

Acidic ingredient for denture cleaner/toothpaste<br />

Antidote<br />

Calcium-succinate is anticarcinogenic<br />

Efferescent tablets<br />

Intermediate for perfumes<br />

Pharmaceutical intermediates (sedatives,<br />

antiphlegm/-phogistics, antibacterial, disinfectant)<br />

Preservative for toiletries<br />

Removes fish odour<br />

Used in the preparation of vitamin A<br />

Food<br />

Bread-softening agent<br />

Flavour-enhancer<br />

Flavouring agent and acidic seasoning<br />

in beverages/food<br />

Microencapsulation of flavouring oils<br />

Preservative (chicken, dog food)<br />

Protein gelatinisation and in dry gelatine<br />

desserts/cake flavourings<br />

Used in synthesis of modified starch<br />

Succinic<br />

Acid<br />

Industrial<br />

De-icer<br />

Engineering plastics and epoxy curing<br />

agents/hardeners<br />

Herbicides, fungicides, regulators of plantgrowth<br />

Intermediate for lacquers + photographic chemicals<br />

Plasticizer (replaces phtalates, adipic acid)<br />

Polymers<br />

Solvents, lubricants<br />

Surface cleaning agent<br />

(metal-/electronic-/semiconductor-industry)<br />

Other<br />

Anodizing Aluminium<br />

Chemical metal plating, electroplating baths<br />

Coatings, inks, pigments (powder/radiation-curable<br />

coating, resins for water-based paint,<br />

dye intermediate, photocurable ink, toners)<br />

Fabric finish, dyeing aid for fibres<br />

Part of antismut-treatment for barley seeds<br />

Preservative for cut flowers<br />

Soil-chelating agent<br />

Authors:<br />

Raj Authors: Chinthapalli, Raj Chinthapalli, Dr. Pia Skoczinski, Michael Carus, Michael Wolfgang Carus, Wolfgang Baltus, Baltus,<br />

Doris Doris de de Guzman, Harald Harald Käb, Käb, Achim Achim Raschka, Jan Jan Ravenstijn,<br />

April 2018<br />

<strong>2019</strong><br />

This and other reports on the bio-based economy are available at<br />

This www.bio-based.eu/reports<br />

and other on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Achim Raschka, Dr. Pia Skoczinski, Jan Ravenstijn and<br />

Michael Carus<br />

nova-Institut GmbH, Germany<br />

February <strong>2019</strong><br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Raj Chinthapalli, Dr. Pia Skoczinski, Achim Raschka,<br />

Michael Carus, nova-Institut GmbH, Germany<br />

Update March <strong>2019</strong><br />

This and other reports on the bio-based economy are available<br />

at www.bio-based.eu/reports<br />

Standards and labels for<br />

bio-based products<br />

Bio-based polymers, a revolutionary change<br />

Comprehensive trend report on PHA, PLA, PUR/TPU, PA<br />

and polymers based on FDCA and SA: Latest developments,<br />

producers, drivers and lessons learnt<br />

million t/a<br />

Selected bio-based building blocks: Evolution of worldwide<br />

production capacities from 2011 to 2021<br />

3,5<br />

actual data<br />

forecast<br />

3<br />

2,5<br />

Bio-based polymers, a<br />

revolutionary change<br />

2<br />

1,5<br />

Jan Ravenstijn 2017<br />

1<br />

0,5<br />

Picture: Gehr Kunststoffwerk<br />

2011<br />

2012<br />

2013<br />

2014<br />

2015 2016 2017 2018 <strong>2019</strong> 2020<br />

2021<br />

L-LA<br />

Epichlorohydrin<br />

MEG<br />

Ethylene<br />

Sebacic<br />

acid<br />

1,3-PDO<br />

MPG<br />

Lactide<br />

E-mail:<br />

j.ravenstijn@kpnmail.nl<br />

Succinic<br />

acid<br />

1,4-BDO<br />

2,5-FDCA<br />

D-LA<br />

11-Aminoundecanoic acid<br />

DDDA<br />

Adipic<br />

acid<br />

Mobile: +31.6.2247.8593<br />

Author: Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />

July 2017<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />

nova-Institut GmbH, Germany<br />

May 2017<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />

April 2017<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Policies impacting bio-based<br />

plastics market development<br />

and plastic bags legislation in Europe<br />

Asian markets for bio-based chemical<br />

building blocks and polymers<br />

Market study on the consumption<br />

of biodegradable and compostable<br />

plastic products in Europe<br />

2015 and 2020<br />

Share of Asian production capacity on global production by polymer in 2016<br />

100%<br />

A comprehensive market research report including<br />

consumption figures by polymer and application types<br />

as well as by geography, plus analyses of key players,<br />

relevant policies and legislation and a special feature on<br />

biodegradation and composting standards and labels<br />

80%<br />

60%<br />

Bestsellers<br />

40%<br />

20%<br />

0%<br />

PBS(X)<br />

APC –<br />

cyclic<br />

PA<br />

PET<br />

PTT<br />

PBAT<br />

Starch<br />

PHA<br />

PLA<br />

PE<br />

Blends<br />

Disposable<br />

tableware<br />

Biowaste<br />

bags<br />

Carrier<br />

bags<br />

Rigid<br />

packaging<br />

Flexible<br />

packaging<br />

Authors: Dirk Carrez, Clever Consult, Belgium<br />

Jim Philp, OECD, France<br />

Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />

Lara Dammer & Michael Carus, nova-Institute, Germany<br />

March 2017<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Wolfgang Baltus, Wobalt Expedition Consultancy, Thailand<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />

Lara Dammer, Michael Carus (nova-Institute)<br />

April 2016<br />

The full market study (more than 300 slides, 3,500€) is available at<br />

bio-based.eu/top-downloads.<br />

www.bio-based.eu/reports<br />

1<br />

38 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Application News<br />

Revolutionary dog plush toy line with<br />

starch based stuffing<br />

The Good Stuffing Company announced the launch of its first line of plush dog toys, which<br />

will be exclusively available at Petco and Petco.com through the end of the year. What makes<br />

the Good Stuffing offerings unique is that, unlike almost any other canine plush toy that is<br />

filled with poly-fill, the Good Stuffing line is filled with SafeFill Stuffing. SafeFill Stuffing is<br />

a proprietary alternative fill made from natural plant starch. If a dog tears open a plush toy<br />

filled with poly-fill, there is a real choking hazard. Conversely, the SafeFill Stuffing will dissolve<br />

harmlessly in the dog’s mouth like cotton candy does in people.<br />

While the principle ingredient used in the manufacturing of poly-fill is ethylene, which<br />

is derived from petroleum, SafeFill Stuffing is derived from natural plant starch. SafeFill<br />

Stuffing, manufactured without any crude oil component or toxic byproducts, is eco-friendly,<br />

biodegradable, sustainable, fire-resistant, and hypoallergenic. The line at Petco is launching<br />

with over two-dozen fun and attractive animals for all sized dogs MT<br />

www.goodstuffingcompany.com<br />

Natural Farm<br />

pet food packaging<br />

Braskem and Natural<br />

Farm, a leading provider<br />

of 100% natural pet food<br />

based in Atlanta, recently<br />

announced the adoption<br />

of Braskem’s I’m green TM<br />

Polyethylene (PE) bioplastic for<br />

the consumer packaging of its<br />

Natural Farm’s TM line of highquality<br />

pet food products.<br />

Marcus Maximo, Founder<br />

and CEO of Natural Farm stated,<br />

“Natural Farm was founded on a passion for dogs and the<br />

love we share with our pets. We’re delighted that as well<br />

as preparing the highest quality dog treats, we’re equally<br />

focused on being responsible environmental stewards.<br />

We’re excited to have found the perfect partner with<br />

Braskem and its bio-PE allowing Natural Farm so ensure<br />

we’re being socially responsible with our packaging.”<br />

Natural Farm is one of the few companies in the pet<br />

retail space who own and operate their own facility and<br />

The Natural Farm commitment stretches from its fields<br />

to its packaging, consistently supporting its people and<br />

the local communities where they live and operate. This<br />

spirit of “Care, Quality, and Transparency” extends to<br />

everything Natural Farm creates through its 360 Degree<br />

Plan towards sustainability. This includes integrating 51%<br />

bio-based, fossil fuel-free and fully recyclable, I’m greenT<br />

Polyethylene (PE) bioplastic into its packaging. Natural<br />

Farm also donates a portion of its proceeds to helping<br />

animals in local community shelters. MT<br />

Cushion for<br />

artificial turf<br />

Braskem and ProdTek, a product development and<br />

manufacturing company serving the artificial turf, flooring<br />

and textile industries with innovative solutions announced the<br />

integration of Braskem’s biobased Polyethylene in ProdTek’s<br />

new Turf Cushion line of turf underlay products.<br />

ProdTek’s revolutionary new Turf Cushion is installed under<br />

artificial turf for a wide range of applications including play<br />

grounds, play areas, sports fields, roof tops, indoor play<br />

areas and other areas where shock attenuation is critical for<br />

users. The Turf Cushion underlay is composed of recycled<br />

polyethylene and Eco Raw, which utilizes Braskem’s bio-<br />

PE and qualifies for High Recycled Content (HRC) status.<br />

In utilizing Braskem’s bio-PE as a renewable alternative<br />

to petroleum based polyethylene, ProdTek’s Turf Cushion<br />

can make a significant contribution to reducing the level of<br />

greenhouse gas emissions in the product value creation chain<br />

John Karr, President at ProdTek, stated, “We feel very<br />

good about our new Turf Cushion Pad. Not only is it carbon<br />

neutral and 100 % recyclable, it provides enhanced safety<br />

for children in playground environments and is economically<br />

advantageous for turf installation companies. We feel like we<br />

have a product that creates value for everyone and serves<br />

society as well.” MT<br />

www.turfcushion.com<br />

www.naturalfarmpet.com<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 39


Opinion<br />

Bioplastics in the<br />

Circular Economy<br />

R.O.J. Jongboom, Director Business Development, Biotec<br />

Founded in 1992, BIOTEC (Emmerich, Germany) is one<br />

of the oldest and most experienced companies worldwide<br />

in the area of compostable and biodegradable<br />

plastics. Looking back at nearly 30 years of history in this<br />

field, it is remarkable how some trends and focus points<br />

seem to change, whereas - even after almost 3 decades -<br />

others remain stubbornly the same.<br />

In the early nineties of the previous century, the number<br />

of companies using starch as a feedstock for alternative<br />

plastic materials was very limited. In those days,<br />

biodegradable starch plastics were considered an exotic<br />

novelty providing an elegant way to help farmers to find<br />

new outlets for their surplus production of crops such as<br />

potatoes and corn - and make a contribution to a cleaner<br />

world for future generations. Organic waste collection<br />

and composting were still in their infancy and landfill was<br />

a commonly accepted waste disposal method. Worries<br />

about climate change or plastic soup were far away in the<br />

distant future. Global plastic consumption was roughly 30 %<br />

of current volumes and plastics recycling was something<br />

that - at best - occurred inside the factory with production<br />

scraps.<br />

The image and reputation of plastics have shifted over<br />

the last few decades: from materials representing hope,<br />

growth, progress and wealth, they have become a scourge,<br />

increasingly associated with pollution, climate change and<br />

irreparable environmental damage.<br />

Many governments and multinationals are focusing<br />

in their long term sustainability policies on the Circular<br />

Economy. Much of the inspiration is coming from the<br />

work of the Ellen MacArthur Foundation. Unfortunately,<br />

the translation of this well-elaborated vision on a Circular<br />

Economy into legislation and policies has in many cases<br />

simply been distilled into a focus on plastics recycling, while<br />

ignoring the added value of compostable and biodegradable<br />

plastics in specific applications.<br />

Is focusing purely on plastic recycling a responsible<br />

strategy or policy? At first sight, it seems a charming<br />

concept: keep plastics materials in circulation, preferably<br />

for eternity, and minimize dependency on crude oil as<br />

feedstock. In the perception of the public at large, recycling<br />

is a positive approach, supported by decades of positive<br />

experiences with the recycling of glass, metal and paper.<br />

For these materials, recycling, however, is well established.<br />

Once recycled, these materials have a positive value and<br />

there is a market or outlet for them.<br />

The situation for most plastics, however, is much more<br />

complicated, as anyone that ever played with clay in different<br />

colors as a child knows: once the bright colors are mixed,<br />

you cannot separate them back again. Likewise, mixed<br />

plastics are extremely difficult to separate, and as many<br />

products available in the<br />

market consist of different<br />

materials, colorants,<br />

printing inks, labels and<br />

numerous contaminations,<br />

recycling becomes a<br />

challenge. Separating,<br />

cleaning, upgrading, and<br />

recycling is currently only<br />

possible for mono-stream<br />

products for which a proper<br />

collection system is in place,<br />

such as e.g. (most) PET<br />

bottles. Some polyolefins, like PE or PP, can, up to a certain<br />

point, be used to produce various products.<br />

It is currently an illusion to think that plastics will be able<br />

to be mechanically recycled on the same scale as glass,<br />

paper and metals anytime in the near future. Suggesting<br />

this as a policy would be thoroughly misleading and a<br />

serious oversimplification.<br />

Yet, what does the general public hear? “Plastics are<br />

bad, and recycling is good” is the highly oversimplified and<br />

incorrect message which is being communicated over and<br />

over again in the news. As a result, people see no need for<br />

other steps, even though these would actually be much<br />

better in the long run.<br />

Recycling is not something that is exclusively done<br />

by humans. Nature has developed biological processes<br />

over millions of years, keeping creation and degradation<br />

in balance and harmony. As a result, nature is able to<br />

“recycle” enormous amounts of organic material. Look,<br />

for example, at what happens in autumn, when the leaves<br />

fall from the trees. Nature is able to effectively break the<br />

mass of different leaves, other plant materials and dead<br />

insects back down into simple building blocks. The CO 2<br />

that green plants bind during growth via photosynthesis, is<br />

released back into the atmosphere without contributing to<br />

the formation of greenhouse gasses.<br />

Nature is actually much better at organic recycling<br />

than mankind, as nature can handle complex mixtures of<br />

organic materials, whereas technical/mechanical recycling<br />

processes can only work effectively when there is a very low<br />

degree of contamination. Washing, cleaning, and separating<br />

is fine for glass, metal and paper, but is very difficult for<br />

plastics. There is a need for recycling processes that can<br />

handle heterogenic feedstock. Both chemical recycling and<br />

organic recycling are able to do so. Chemical recycling is<br />

still in its infancy, but compostable products and industrial<br />

composting are well established, with demonstrated<br />

products and technologies.<br />

40 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Opinion<br />

There are many applications in which plastics run a<br />

high risk of being contaminated with food waste or other<br />

undesirable materials that make regular recycling of these<br />

plastics virtually impossible. Typical examples are coffee<br />

capsules, food trays, yoghurt or mayonnaise cups and alike.<br />

Cleaning these plastic products is costly and negatively<br />

influences the technical and economic feasibility of plastic<br />

recycling. And vise versa as well: consumers can have a<br />

tendency to (wrongfully) assume that such products can be<br />

disposed of via organic waste collection and that removing<br />

plastics after composting or biogas production is a simple<br />

step.<br />

Either way, contamination is undesirable and leads<br />

both to additional costs and a lower quality of output (of<br />

both recycled plastic and compost). Compost should not<br />

be contaminated with plastics, and plastics should not<br />

be contaminated with food. And in cases where the risk<br />

of cross contamination is high, alternatives that can be<br />

processed via organic recycling, i.e., composting or biogas<br />

production, should be sought.<br />

Biotec strongly supports the objectives of the Circular<br />

Economy. With numerous different Bioplast grades,<br />

different high quality applications can be achieved for blown<br />

films, sheet material, thermoformed or injection molded<br />

trays, fibers, and laminated products. To achieve the<br />

objectives of the Circular Economy, the general public must<br />

become more aware, which would force multinationals<br />

and governments to pursue higher ambition levels and<br />

to fully embrace the suggestions of the Ellen MacArthur<br />

Foundation, rather than simply cherry picking the initiatives<br />

relating to plastics recycling only.<br />

www.biotec.de<br />

Compostable plastics can strongly support the objectives<br />

of the Circular Economy, ensuring that less (food)<br />

contaminated materials end up in the plastics recycling<br />

stream and that more AND cleaner organic waste is<br />

collected. This organic waste can be effectively converted<br />

into compost for improving the carbon binding capacity of<br />

the soil, or into biogas for decentral energy generation (gas<br />

or electricity).<br />

It would really help a lot if companies that are involved in<br />

post-consumer waste processing were not paid per ton of<br />

waste processed, but instead per ton of high quality recycled<br />

plastic or clean compost that is applied in the market. The<br />

currently existing profit incentives for post-consumer waste<br />

processors act as a legal stimulation for them to optimize<br />

their profits. This does not take into account the price<br />

that future generations will be paying for cleaning up the<br />

garbage we are dumping in the soil and the oceans.<br />

All industrial composting facilities are perfectly able to<br />

convert certified compostable products into water, CO 2<br />

and<br />

humus. What they need to do is to stop focusing on the high<br />

speed processing of large volumes of contaminated organic<br />

waste that has no agricultural value, and instead to aim<br />

more at producing high quality compost with significant<br />

agricultural benefits. The currently existing financial<br />

incentives for these companies do not justify investments<br />

in delivering quality but are optimized for converting the<br />

highest possible volumes in the shortest possible time,<br />

thus creating the highest value for their shareholders and<br />

leaving the bill that the future generations will need to take<br />

care of unpaid.<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 41


Barrier materials<br />

Ultra high barrier for<br />

bio-packaging<br />

S<br />

olving the world’s problems of plastic<br />

and food waste is right at the forefront<br />

of Plantic Technologies business.<br />

To fight food waste Plantic supplies<br />

ultra-high barrier films made from renewable<br />

and recycled materials throughout the<br />

world. The recycled content in the materials<br />

is providing a source for food grade<br />

waste plastics that would otherwise be<br />

going to land fill.<br />

As part of Kuraray (headquartered<br />

in Chiyoda, Japan) who are the world<br />

largest supplier of barrier resins, Plantic<br />

Technologies Ltd (Altona, Victoria,<br />

Australia) has achieved a unique place<br />

in the world market for bioplastics<br />

through proprietary technology that<br />

delivers biodegradable and renewable<br />

sourced alternatives to conventional<br />

plastics based on corn and cassava;<br />

which is not genetically modified. The<br />

barrier properties of the materials start<br />

with an Oxygen Transmission Rate (OTR) below<br />

1.0 cm³/m²·day.<br />

Unlike other bioplastics companies who utilise organic<br />

materials, but whose polymers are still developed in<br />

refineries, Plantic’s polymer as well as its raw material, are<br />

grown in a field. The entire process integrates the science<br />

of organic innovation with commercial and industrial<br />

productivity in a new way. The result is both a broad range<br />

of immediate performance and cost advantages, and longterm<br />

environmental and sustainability benefits.<br />

Flexible, rigid and semi rigid materials from Plantic<br />

have shown to give extension of shelf life for the products<br />

packed, this is through the ultra-high barrier in the<br />

packaging material. With thermoformable webs for Skin,<br />

MAP and Flexible applications the benefits for retailers and<br />

brand owners are proven, this enables them to meet their<br />

packaging targets and goals.<br />

PLANTIC HP a fully biodegradable high barrier<br />

structure forms the core of all Plantic products and<br />

depending on the customer needs the outer skins can be<br />

made to seal onto conventional PE and PET sealing layers.<br />

Other materials that are being used with PLANTIC HP are<br />

PBS, rPET, Cellulose<br />

An additional benefit of these multilayer materials is the<br />

ability for them to go through a standard recycling process.<br />

A unique process of separation of polymers occurs when<br />

the materials are sent through the recycling system.<br />

Plantic has recently released a range of high barrier<br />

recyclable paper-based structures being used in<br />

applications such as coffee pouches. These paper based and<br />

paper board structures have the additional<br />

benefit of being able to go through a<br />

standard thermforming machine, giving<br />

producers the chance to use a board or<br />

paper structure on standard equipment<br />

Plantic Technologies is supplying<br />

major retailers and brand owners<br />

throughout the world in applications<br />

such as fresh case ready beef, pork,<br />

lamb and veal, smoked and processed<br />

meats, chicken, fresh pasta and<br />

cheese applications.<br />

Plantic Technologies is expanding<br />

rapidly and refining its technology<br />

to meet the ever-growing global<br />

needs for more environmentally and<br />

performance efficient materials.<br />

With global recognition through<br />

multiple award wins including DuPont<br />

Packaging, World Star, PIDA and others,<br />

Plantic has a solution for Retailers,<br />

Processors and Brand owners who want<br />

to fulfill their future packaging targets.<br />

“Plantic materials are not just about being a<br />

sustainable material, it has an ultra-high barrier that can<br />

improve the shelf life of a product, and reduce food waste.<br />

With Plantic materials you can have an enormous impact<br />

on value change and reduce the effects of climate change,<br />

both by reducing food waste and using more sustainable<br />

materials.” Brendan Morris Plantic Technologies Limited<br />

CEO and Managing Director said. MT<br />

www.plantic.com.au<br />

42 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Barrier materials<br />

New compostable barrier films<br />

Development of a biodegradable flexible film with barrier properties for<br />

food packaging application<br />

Using multilayer films for food packaging<br />

in which the layers consist of different<br />

types of material makes<br />

it possible to combine different<br />

properties of different materials,<br />

such as oxygen and water<br />

vapour protection into a single<br />

packaging solution. However,<br />

the use of different materials<br />

to achieve these different<br />

properties makes the multilayer<br />

packaging developed to<br />

date impossible to recycle at the<br />

end of life. And as biodegradable or<br />

compostable materials do not offer<br />

sufficient barrier properties to<br />

be applied in packaging for fresh foodstuffs<br />

like cheese, compostable packaging<br />

cannot be used, either.<br />

To improve the environmental sustainability of multilayer<br />

film, the MULTIBIOBARRIER project is working on the<br />

development of a new biodegradable and compostable<br />

multilayer film for cheese that will offer good oxygen and<br />

water vapour barrier properties. The objectives of the project<br />

are listed below:<br />

• To develop new biodegradable materials to produce flexible<br />

and fully compostable packaging according to EN 13432<br />

• To develop a new biodegradable and compostable<br />

multilayer film with an oxygen barrier (< 2cm³/m²·day·bar)<br />

and water vapour barrier (< 4g/m²·day) suitable for cheese<br />

packaging. The new film will be able to be composted<br />

together with the food residues as the composition of the<br />

film is 100% compostable<br />

• Flexible and easily recyclable film, because the layers of<br />

the film can be separated easily<br />

• To obtain sustainable packaging complying with the<br />

legislative changes related to single-use products in<br />

countries where biodegradables are exempted from bans<br />

• To convince legislators to allow the use of biodegradable<br />

and compostable materials for manufacturing single-use<br />

products<br />

The development of biodegradable materials with an oxygen<br />

barrier, the task for which AIMPLAS (Paterna, Spain) is mainly<br />

responsible, will be based on a mixture of non-thermoplastic<br />

PVOH, additives and plasticizers. It will be processed through<br />

blown film extrusion technology<br />

During the project, the researchers will be working on the<br />

optimization of a formulation to keep oxygen barrier below<br />

2 cm³/m²·day·bar at the lowest possible thickness.<br />

On the other hand, biodegradable materials with a water<br />

vapour barrier are being developed by Nurel (Zaragoza, Spain).<br />

By:<br />

Nuria López Aznar<br />

Senior polymer researcher<br />

AIMPLAS<br />

Paterna, Spain<br />

These will be based on a mixture<br />

of biopolymers derived from<br />

starch, biopolyesters and additives,<br />

which will allow the water vapour barrier<br />

to be improved. The main goal is to obtain<br />

a biopolymer with a moisture vapour<br />

transmission rate below 4 g/m²·day, measured at<br />

85 % RH and 23°C.<br />

In addition, the focus will also be on the compatibility of<br />

both materials to avoid using a tie layer.<br />

Based on the biopolymers developed by Aimplas and Nurel,<br />

a coextruded biodegradable multilayer film will be produced<br />

by Gaviplas (Alfarrasí, Spain). The cheese packaging will<br />

be manufactured from this film, after which the functional<br />

validation of the packaging developed will be studied.<br />

Taking advantage of the soluble character of the PVOH,<br />

a recyclability study of the external layers of the film will be<br />

undertaken at the end of the project.<br />

MULTIBIOBARRIER is a three-year project funded by<br />

the RETOS – COLABORACIÓN 2018 national call with file<br />

number RTC-2017-6034-2. Aimplas, the Plastics Technology<br />

Centre, is the technical coordinator of the project. The other<br />

participants in the consortium are Nurel and Gaviplas who will<br />

also contribute to the development of the new biodegradable,<br />

compostable and flexible food packaging.<br />

The project<br />

has been running<br />

for one year<br />

and the first<br />

biodegradable<br />

grades have<br />

been already<br />

developed from<br />

which film will<br />

be produced at<br />

pilot plant level<br />

using blown<br />

film extrusion<br />

technology.<br />

www.aimplas.es<br />

www.nurel.com<br />

www.gaviplas.es<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 43


Barrier materials<br />

Emerging circular biobased<br />

barrier solutions<br />

Multilayer plastic packaging films are commonly used<br />

to pack sensitive food products. Their share on the<br />

packaging market is increasing as they enable lightweighting<br />

and increase resource efficiency in their primary<br />

use in comparison to rigid packaging. However, multilayer<br />

packaging concepts are currently not recyclable. Indeed,<br />

high purity fractions are needed for reprocessing and the<br />

vast majority of them end up in land fill or in energy recovery<br />

systems. In addition, most of the barrier materials such as<br />

Ethylene Vinyl Alcohol (EVOH) or polyamides (PA), are fossil<br />

based. In this article, emerging solutions in recent research<br />

and innovation initiatives will subsequently be reviewed,<br />

first in terms of new biobased feedstocks from which barrier<br />

materials can be sourced and second on how using them<br />

can positively affect the end of life of the derived laminates.<br />

An array of potential sources in nature<br />

Many biopolymers made of polysaccharides or proteins<br />

offer good barrier properties against oxygen permeation<br />

and can be used as edible coatings such as chitosan,<br />

proteins from dairy, fish, potatoes or legumes. In addition,<br />

those can be extracted from non-edible food fractions or<br />

agro-food industry by products.<br />

For example, in the project DAFIA [1], marine rest rawmaterials<br />

such as salmon skin and backbones are harnessed<br />

to develop cost-efficient isolated and purified gelatin and<br />

hydrolysates. Gelatin is a denatured polypeptide extracted<br />

by hydrolysis from pre-treated collagen sources, mainly<br />

animal skins and bones, which is mostly affected by its amino<br />

acid composition and molecular weight distribution. The<br />

fractionation and lipids separation pre-treatment protocols<br />

have been optimized in mild conditions. The coating was<br />

formulated comparing different natural plasticizers, pH<br />

and temperature as well as drying condition. Furthermore,<br />

the mechanically separated salmon muscle has been<br />

hydrolysed with proteases as potential active compound.<br />

The addition of hydrolysates has shown positive antioxidant<br />

activity (Gallic acid equivalent GAeq of 66 +/-7 ppm<br />

and Ferric Reducing Ability of Plasma FRAP of<br />

189 +/-17 µmol/L), but no antibacterial effects were<br />

observed. The coating application and lamination have<br />

been successfully carried out at pilot scale by AIMPLAS<br />

resulting in laminates with promising oxygen barrier<br />

(1.58 OTR (cm³/(m²·day) at 23°C, 1 atm and 50 % relative<br />

humidity for a 10 µm coating). This shows that biomacromolecules<br />

from marine sub-products have a great<br />

potential to be used as high added value active barrier coatings for<br />

multilayer packaging or edible coatings directly applied on food.<br />

Previously reported Wheylayer ® barrier materials have<br />

also been obtained from whey protein [2] (which can be<br />

extracted from a cheese by-product). Further development<br />

also allowed obtaining thermoformable versions of the<br />

same (Thermowhey) [3]. In the recent project OptiNanoPro<br />

[4], nano-enhancement of the whey protein coating was<br />

performed adding food contact approved nanoclays. Those<br />

were converted into a so-called “ready-to-use” formulation<br />

by means of a solid-state pre-dispersion process using<br />

ball-milling. The process yielded a nearly dust-free, freeflowing<br />

powder containing agglomerated particles, which<br />

can easily be mixed with water. The preparation of a coating<br />

Oxygen transmission rate °C/50% RH<br />

(cm 3 · 100µm (STP) m -2 d -1 bar -1 )<br />

Fig 1. top: microscopic picture of the cross-section picture of<br />

a laminate including PET 23 µm and 4 µm of whey proteins<br />

nanocomposite coatings produced semi-industrial-scale,<br />

and bottom: Scanning electron microscopy (SEM) images at a<br />

magnification of 50,000 on the nanocomposite coating<br />

Fig. 2: Permeability values for different whey coatings vs. standard<br />

and biobased polymers (all normalized to 100 μm)<br />

10000<br />

1000<br />

100<br />

10<br />

1<br />

0.1<br />

PE-HD<br />

PP (oriented)<br />

PA 12<br />

PE-LD<br />

PC<br />

PUR-elastomer<br />

Celluloseacetate<br />

Wax/paper<br />

PA 11<br />

PS (oriented)<br />

PVC-U<br />

PA 12<br />

PET (oriented) PA 66<br />

PVC-U (oriented) PA 6<br />

EVOH 44%<br />

PVDC<br />

EVOH 38%<br />

Wheylayer<br />

Cellulose-acetobutyrate<br />

Thermowhey<br />

OPTIANOPRO<br />

EVA-copolymer,<br />

VAC 20%<br />

0.01<br />

0.01 0.1 1 10 100 1000<br />

Water vapour transmission rate<br />

23°C/85 0% RH (g · 100µm · m -2 d -1 )<br />

44 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Barrier materials<br />

By:<br />

Multilayer<br />

Film<br />

Elodie Bugnicourt, Simona Neri<br />

IRIS Technology Solutions<br />

Barcelona, Spain<br />

Esra Kucukpinar<br />

Fraunhofer IVV<br />

Freising, Germany<br />

Markus Schmid<br />

Faculty of Life Sciences, Albstadt-Sigmaringen University<br />

Sigmaringen, Germany<br />

Patrizia Cinelli, Andrea Lazzeri<br />

INSTM, University of Pisa<br />

Pisa, Italy<br />

Fig. 3: Illustration of the<br />

materials recyclability of<br />

whey coated laminates<br />

Grinding Wheylayer Removal Density Separation<br />

Recycled<br />

PE<br />

Recycling<br />

Recycled<br />

PET<br />

formulation and its upscaling for roll-to-roll converting<br />

at pilot- and semi-industrial scale was also successfully<br />

implemented [5]. This process resulted in a good dispersion<br />

and orientation of the nanoparticles (Fig. 1) and an<br />

interesting barrier improvement that allowed resulting<br />

coating laminates matching the properties of EVOH (Fig. 2).<br />

Nevertheless, as seen from the graph (Fig. 2), the<br />

developed protein coatings are not able to compete with<br />

standard plastics in terms of water vapour barrier. In<br />

BIOnTop [6], to reach such performance, the previously<br />

developed whey protein coatings will be improved by<br />

nano-coatings of fatty acids applied by a resource efficient<br />

grafting technology.<br />

But what about the End Of Life?<br />

All the previously mentioned protein-based coatings<br />

are compostable by nature. Indeed, their composition<br />

makes them ideal for metabolization by microorganisms.<br />

They can be applied on a range of biodegradable or nonbiodegradable<br />

substrate films and the end of life of the later<br />

is what mainly determines that of the whole laminate.<br />

Fig. 4:<br />

Representation<br />

of the end of life<br />

scenarios that will<br />

be compatible with<br />

the new BIOnTop<br />

materials, some of<br />

them coated with<br />

barrier materials<br />

Biontop<br />

Copolymers<br />

& Compounds<br />

Coating<br />

Organic & Materials Recycling<br />

Indeed, when applied for example on PLA, the nitrogen<br />

(as amino-acid rich component) of the coating was even<br />

reported to speed up the biodegradation of the overall<br />

multilayer films [7] resulting in industrially compostable<br />

packaging solutions.<br />

When the protein coating is applied on conventional<br />

substrates, its removability using enzymatic detergent<br />

during the washing step of the packaging recycling can be<br />

exploited (Fig. 3). In that case, the cleaned layers of e.g. PE<br />

and PET can then be separated by density and reprocessed<br />

separately with a minor loss of properties [8].<br />

After showing the capability for automatic sorting<br />

of the packaging containing the new biobased barrier<br />

coatings, BIOnTop aims at upscaling the recycling process<br />

of the barrier multilayer packaging. In addition, to match<br />

virtually any controlled waste management demand, PLA<br />

copolymers suitable for home composting are also being<br />

developed. Such end of life versatility, depicted in Fig. 4,<br />

is key in the view of the difficulty to remove the organic<br />

content in specific packaging formats such as tea bags or<br />

when fruits or vegetables get rotten in their trays or nets.<br />

It is also key to be able to adjust to the most sustainable<br />

end of life option depending on the packed products and<br />

the actually feasible waste management for which available<br />

logistics are extremely variable between regions.<br />

Conclusion<br />

lead<br />

Home<br />

Composting<br />

Echoing the increasingly stringent<br />

legislations and public demands,<br />

the packaging industry is<br />

requesting more sustainable<br />

barrier solutions. This is boosting<br />

the research in renewably sourced<br />

materials which in turn also<br />

have the ability to support the<br />

circular economy transition<br />

by enabling improved organic<br />

or materials recycling routes.<br />

Different protein solutions<br />

based on cheese or fish byproducts<br />

have been discussed and<br />

to barrier properties close to their<br />

fossil counterpart while making<br />

laminates recyclable organically or<br />

in terms of materials.<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 45


Barrier materials<br />

Opinion<br />

Despite such advances, the maturity of these<br />

developments needs to grow to substitute the wellconsolidated<br />

fossil-based counterparts in terms of<br />

costs and markets. Besides, the number of progresses<br />

improving the end of life of conventional plastic<br />

packaging can also change the conditions of the<br />

competition. New emerging solutions for recycling<br />

standard multilayers packaging e.g., a preferential<br />

solvent based extraction of each of the main fractions<br />

in multi-materials laminates or composites, is being<br />

brought to semi-industrial scale in the Multicycle<br />

project [9]. All these solutions, also compatible with<br />

biobased barrier coatings, shall co-exist in a global<br />

plastic strategy to solve the different issues currently<br />

met by the plastic industry. This shows that, for circular<br />

biobased barrier solutions to get a lion’s share in this<br />

massive opportunity for change in the plastic packaging<br />

sector and lead to an actual decarbonisation of the<br />

society, further innovations embedded in a concerted<br />

action along the value chain are needed including not<br />

only materials providers but also waste management<br />

bodies and end users (including consumers).<br />

References<br />

[1] DAFIA, H2020 BIOTEC, GA 720770, Biomacromolecules from<br />

municipal solid bio-waste fractions and fish waste for high added<br />

value applications.<br />

[2] “Films with excellent barrier properties”, E. Bugnicourt, M.<br />

Schmid; Bioplastics magazine; Vol. 8, p 44; Sept. 2013.<br />

[3] Barrier… but also bio-based and thermoformable!, E. Bugnicourt,<br />

Bioplastics magazine, Vol 5, p 36. Sept. Oct 2015<br />

[4] OPTINANOPRO, H2020 NMP, GA 686116, Processing and control<br />

of novel nanomaterials in packaging, automotive and solar panel<br />

processing lines<br />

[5] Dispersion and Performance of a Nanoclay/Whey Protein<br />

Isolate Coating upon its Upscaling as a Novel Ready-to-Use<br />

Formulation for Packaging Converters. Bugnicourt, E.; Brzoska,<br />

N.; Kucukpinar, E.; Philippe, S.; Forlin, E.; Bianchin, A.; Schmid,<br />

M. Polymers <strong>2019</strong>, 11, 1410.<br />

[6] BIOnTop, H2020 BBI, GA 837761, Novel packaging films and<br />

textiles with tailored end of life and performance based on biobased<br />

copolymers and coatings<br />

[7] Whey protein layer applied on biodegradable packaging film to<br />

improve barrier properties while maintaining biodegradability”,<br />

P. Cinelli, M. Schmid, E. Bugnicourt, J. Wildner, A. Bazzichi, I.<br />

Anuillesi, A. Lazzeri, Polymer Degradation and Stability. 07/2014;<br />

DOI: 10.1016/j.polymdegradstab.2014.07.007<br />

[8] Recyclability of PET/WPI/PE Multilayer Films by Removal of Whey<br />

Protein Isolate-Based Coatings with Enzymatic Detergents”, P.<br />

Cinelli, M. Schmid, E. Bugnicourt, A. Lazzeri, Materials 9(6):473 ·<br />

June 2016, DOI: 10.3390/ma9060473<br />

[9] MULTICYCLE, H2020 SPIRE, GA 820695, Advanced and sustainable<br />

recycling processes and value chains for plastic-based multimaterials<br />

www.iris.cat | www.ivv.fraunhofer.de<br />

www.hs-albsig.de | www.instm.it<br />

ACKNOWLEDGEMENTS<br />

In addition to other past projects quoted in footnote,<br />

the authors would like to acknowledge the H2020<br />

and BBI-JU fundings for the DAFIA project under<br />

Grant Agreement No. 720770, MultiCycle project<br />

under Grant Agreement No. 820695 and BIOnTop<br />

project under Grant Agreement No. 837761.<br />

They would also like to thank the collaboration of<br />

AIMPLAS plastic technology centre.<br />

Equal footing<br />

for LCAs<br />

I<br />

n the current efforts to develop an LCA methodology<br />

for biobased polymers by the JRC (Joint Research<br />

Centre), fundamental problems must be confronted if<br />

an equal and fair comparison is to be made between the<br />

environmental effects of biobased polymers and those of<br />

petrochemical polymers, write four scientists from Germany’s<br />

nova Institute in an open letter to the JRC.<br />

The JRC is the European Commission’s science and<br />

knowledge service, tasked with carrying out research in<br />

order to provide independent scientific advice and support<br />

to EU policy. Its activities currently include the elaboration<br />

of a consistent and appropriate LCA-based method for<br />

the purpose of a “Comparative Life-Cycle Assessment of<br />

alternative feedstock for plastics production.” The final<br />

report is expected by end of this year, or early 2020. The<br />

authors of the open letter, led by Michael Carus, point<br />

to the various methodological and technical stumbling<br />

blocks that remain to be overcome and put forward a<br />

number of proposals in aid of the development of LCA<br />

standards for biobased polymers.<br />

As the authors write, biobased technologies are subject<br />

to highly critical evaluation, while the petrochemical<br />

industry, which uses non-renewable resources and which<br />

has been and still is involved in many environmental<br />

disasters, is not scrutinized with the same level of detail<br />

and transparency, making a comparison on equal footing<br />

impossible. In addition, the importance of renewable<br />

carbon is not sufficiently valued in the LCA methodology<br />

developed by the JRC. The LCA methodology for<br />

biobased polymers will also differ considerably from<br />

the methodology for biofuels, “which could lead to<br />

greenhouse gas (GHG) reductions for biofuels being<br />

relatively higher than for biobased polymers, purely as a<br />

result of the different methodologies (each in comparison<br />

to their petrochemical counterpart)…. The only option:<br />

the same LCA rules must apply to all uses of biomass,<br />

whether it is for fuels or for chemicals!”, they argue.<br />

The solution proposed by the nova Institute lies in<br />

the use of a prospective LCA. To that end, a scenario<br />

could be developed and a quasi-standardised life cycle<br />

assessment conducted for the year 2<strong>05</strong>0, in addition to<br />

the present situation. “A comparison between bio- and<br />

petro-based polymers would then look entirely different,”<br />

write the authors of the open letter.<br />

“Biobased polymers are considered as a sustainable<br />

solution for the circular economy of the future. That is<br />

why, for a fair comparison, it is so important to consider<br />

how they perform not only in the present, but in particular<br />

in the future. This is not accounted for in the methods<br />

prevailing today,” the scientists conclude. MT<br />

The complete text of the open letter to the JRC can be<br />

downloaded from:<br />

https://tinyurl.com/openletter-jrc<br />

46 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Barrier materials<br />

PVOH for<br />

barrier<br />

applications<br />

Today’s expectations are very high for primary packaging<br />

for such applications as food, cosmetics and<br />

household goods, as the products packed should be<br />

kept clean, fresh and sweet-smelling. In addition, nothing<br />

from the surroundings should get into the packaging. However,<br />

the entire pack should also be sustainable as well as<br />

environmentally friendly. The matter of recycling is also an<br />

important issue.<br />

A PVOH barrier layer could be a possible solution. PVOH<br />

(polyvinyl alcohol) is a synthetically produced water-soluble<br />

polymer which is non-toxic and environmentally friendly as<br />

it biodegrades into water and CO 2<br />

. In waste incineration, it<br />

burns without residues.<br />

As a result of its good processing and printing properties,<br />

PVOH is particularly suitable to produce mono films.<br />

The common applications include laundry bags for<br />

hospitals, detergent packaging and sachets. PVOH films<br />

also demonstrate high flexibility and tensile strength. In<br />

combination with other bioplastics as a multilayer film,<br />

it can be used as an environmentally friendly alternative<br />

to EVOH or aluminum due to its outstanding gas barrier<br />

properties towards oxygen and carbon dioxide. Its resistance<br />

to chemicals, oils and greases means that it can also be<br />

used as a shield against oils, fats and solvents.<br />

FKuR Kunststoff GmbH (Willich, Germany) now has<br />

PVOH in the portfolio of their biobased and biodegradable<br />

plastics, offering their customers individual solutions,<br />

either as mono or multi-layer applications with PLA-based<br />

film materials. This guarantees films with particularly<br />

good breathability which also have good barrier properties<br />

against O 2<br />

and CO 2<br />

. If used with compostable films, organic<br />

recycling may be possible. MT<br />

www.fkur.com<br />

Material<br />

“Oxygen permeability<br />

(ml/m²day) “<br />

Hot-water soluble PVOH 0.24<br />

Warm-water soluble PVOH 0.36<br />

Cold-water soluble PVOH 1,85<br />

Ethylene-vinyl alcohol (EVOH) 0.29-2.4<br />

Nylon 6 26-38<br />

Polyethylene terephthalate (PET) 40-80<br />

PVC 50-390<br />

HDPE 1,700-2,400<br />

Polypropylene 2,000-10‚00<br />

Low Density Polyethylene 12,000<br />

Join us at the<br />

14th European Bioplastics<br />

Conference<br />

The leading business forum for the<br />

bioplastics industry<br />

3/4 December <strong>2019</strong><br />

Titanic Chaussee Hotel<br />

Berlin, Germany<br />

@EUBioplastics #eubpconf<br />

www.european-bioplastics.org/events<br />

REGISTER<br />

NOW!<br />

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bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 47


News<br />

10<br />

Years ago<br />

Published in<br />

bioplastics MAGAZINE<br />

from left: Patrick Gerritsen, Frank<br />

Eijkman, Jhon Bollen, Oliver Fraaije.<br />

Bio4Pack offers<br />

One-Stop Shopping<br />

Two Dutch thermoforming companies, Nedupak<br />

Thermoforming BV (of Rheden, NL) and Plastics2Pack (of<br />

Uden, NL), recently announced the forming of ‘Bio4Pack‘<br />

as a new packaging supply company. The new company is<br />

headed by Managing Director Patrick Gerritsen, who brings<br />

with him several years of know-how and expertise in the area<br />

of biobased and biodegradable packaging.<br />

Bio4Pack not only offers thermoformed packaging but<br />

also all other kinds of packaging made from biobased and/or<br />

biodegradable materials, including films, bags and netting,<br />

and through to sugar cane trays made from the bagasse, a<br />

by-product from the sugar cane industry.<br />

“We want to offer our customers a total packaging<br />

solution,“ says Oliver Fraajie, Commercial Director of<br />

Nedupack, “not just a thermoformed tray or bulk pack.“<br />

And thus the portfolio of Bio4Pack comprises the traditional<br />

thermoformed packaging made from bioplastics such as<br />

PLA or new thermoformable materials.<br />

The range also includes films and bags for all kinds of<br />

purposes, e.g shopping bags or flow wrap packaging made<br />

from starch based bioplastics such as Biolice ® , Materbi ® or<br />

Bioflex ® from FKUR, and also nets for onions, potatoes or<br />

fruit and, of course, the labelling on the packaging.<br />

“We also offer meat packaging consisting of a<br />

thermoformed PLA tray with peelable SiOx coated PLA<br />

film, having the same properties as conventional packing“<br />

adds Frank Eijkman, Managing Director of Plastics2Pack.<br />

“And for bakery goods such as cakes and cookies we have<br />

thermoformed trays and folded boxes from a more rigid PLA<br />

sheet. This kind of box is also available for the packaging of<br />

bio-chocolate for example.“<br />

Blisters for liquor gift packs or batteries round off the<br />

list of examples. “In a nutshell: We are a trading company<br />

that offers all types of packaging made from biobased or<br />

biodegradable materials,“ says Patrick Gerritsen, “Those that<br />

we don‘t produce ourselves at Nedupack or Plastics2pack,<br />

we get from partners who I know from the past“.<br />

Of course all products are certified according to EN 13432<br />

and Patrick goes even one step further: “We are investigating<br />

the possibility of having our products certified and labeled<br />

with ‘Climate Neutral‘ (www.climatepartner.de)“.<br />

Bio4Pack started operations in early August and is proud of<br />

the first orders from leading companies in the fresh produce<br />

and supermarket businesses. Even if the company initially<br />

targets the European market, clients from all over the world<br />

can be served via Nedupack‘s partners in many countries.<br />

“Another big advantage is that Nedupack Thermoforming<br />

have their own design and tool-making department, so we<br />

are more flexible and can react much quicker than many<br />

other suppliers,“ says Jhon Bollen, Technical Director of<br />

Nedupack.<br />

Although this new company was founded in a generally<br />

difficult economic situation, the entrepreneurs have full<br />

confidence in the development of this market. “We are<br />

looking forward to convincing more and more supermarkets<br />

and other suppliers to switch to bioplastic products - and<br />

not only because the traditional resources are finite,“ says<br />

Patrick Gerritsen. Oliver Fraaije is convinced that “the<br />

customers who buy bio-food are also willing to buy biopackaging.“<br />

- MT<br />

www.bio4pack.com<br />

In September <strong>2019</strong>, Patrick Gerritsen,<br />

founder and CEO of Bio4Pack said:<br />

10 years of Bio4Pack means 10 years<br />

of fighting for the opportunities of<br />

sustainable packaging.<br />

On July 15 it was exactly 10 years ago<br />

that Bio4pack was founded. At the time, 4<br />

enthusiastic entrepreneurs knew for sure:<br />

sustainable packaging is the packaging of<br />

the future. Now, 10 years later, it appears<br />

that they had a good foresight. Sustainable<br />

packaging is more popular than ever, partly<br />

due to the relentless energy that our team<br />

has put into convincing large retailers and<br />

packers to switch to this environmentally<br />

friendly packaging. Bio4Pack has benefited<br />

from this and has since grown into a leading<br />

supplier of compostable and sustainable<br />

packaging.<br />

In the initial phase of Bio4Pack the<br />

emphasis was on packaging intended for<br />

organically grown fruit and vegetables. Net<br />

packaging, film for packaging of potatoes<br />

and carrots, among other things, and PLA<br />

trays for packaging fruit were the most<br />

important products that Bio4Pack sold in<br />

the initial phase. Under the influence of<br />

the development of new sustainable raw<br />

materials and production techniques,<br />

the range has since been expanded to<br />

include packaging for a wide variety of<br />

products that do not have a biological<br />

background. Consider, for example, the<br />

packaging of peppermint. Bio4Pack<br />

recently introduced a completely<br />

new sustainable packaging made<br />

from the waste of rice plantations.<br />

This packaging is so special that the<br />

product immediately received the<br />

silver cradle-to-cradle certificate.<br />

The success of Bio4Pack has<br />

led the company to move into a<br />

completely new business premises<br />

in Nordhorn (D) at the beginning<br />

of this year with sufficient office<br />

space and a large warehouse. Here<br />

the company has room for further<br />

growth in the coming years.<br />

tinyurl.com/2009-bio4pack<br />

6 bioplastics MAGAZINE [<strong>05</strong>/09] Vol. 4<br />

48 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Opinion<br />

Biodegradation of plastics in<br />

nature: the future tasks of<br />

standardisation<br />

Francesco Degli Innocenti,<br />

Ecology of Products Director, Novamont, Italy<br />

What is the minimum timeframe for complete biodegradation<br />

for plastics designed to biodegrade?<br />

Faced everyday with these type of questions, as a<br />

biodegradation expert, I realize that there is a communication<br />

deficit in our industry that must be filled.<br />

Two tiers are necessary to characterize the biodegradation<br />

of plastics at sea.<br />

The first tier testing is to verify whether the plastic material<br />

shows intrinsic biodegradability. This is the potential of<br />

the plastic to be cleaved by enzymes and assimilated by<br />

microorganisms present in the biosphere. Achieving high levels<br />

of conversion to CO 2<br />

, comparable to those achieved by GRAB<br />

(Generally Recognized As Biodegradable) substances, is a<br />

strong indication that plastic is biodegradable. When addressing<br />

the first tier, test conditions must be optimised, because it<br />

does not make any sense to limit the growth and activity of<br />

microbes. Obviously, when a biodegradable product “leaves<br />

the laboratory” and goes into the real world its biodegradation<br />

rate can be slower if conditions are sub-optimal. This is true<br />

for any biodegradable material, whether natural or synthetic.<br />

Food stored in the fridge does not biodegrade quickly and keeps<br />

for years if stored in the freezer. Nobody will claim “food is not<br />

biodegradable!” because it does not go bad at 4°C.<br />

The second tier is about the environmental fate of<br />

products placed on the market that are littered. Here the<br />

purpose is to assess the ecological risk of littering. “Risk”<br />

is a probabilistic concept, the probability that a certain<br />

event will occur that can cause harm to flora and fauna. For<br />

example, a bag (the hazard) can be mistaken for a jellyfish<br />

by a fish causing its death by suffocation (the harm). That is,<br />

a potential hazard can become<br />

real harm. The probability of<br />

this event happening depends<br />

on the number of bags present<br />

in the environment and their<br />

residence time. The greater<br />

the number of bags, the<br />

longer their residence time,<br />

the greater the probability of<br />

harm. For the layman: if I have<br />

to cross a highway blindfolded it is better to do it at 3 a.m.<br />

(when the “concentration” of cars is very low) and running<br />

fast (i.e. with the lowest “residence time”) than at 5 p.m.<br />

(when the “concentration” of cars is very high) and walking<br />

slow (i.e. with the highest “residence time.”) From this, it<br />

follows that littering products whether they are biodegradable<br />

or not, causes a risk because it increases one factor of the<br />

multiplication: “concentration x residence time”. The other<br />

factor is the residence time to be predicted based on the<br />

physical characteristics and the biodegradation behaviour of<br />

products. Biodegradation reduces residence times and thus<br />

the risk.<br />

In conclusion, the intrinsic biodegradability, demonstrated in the<br />

laboratory under optimal conditions and using a GRAB material<br />

as a reference, characterizes the plastic material from the point of<br />

view of its propensity to degrade similarly to natural materials. The<br />

definition of the impact of any product (including biodegradable<br />

plastics) in case of littering requires methodologies for the<br />

estimation of amount of litter and the effective biodegradation<br />

rates. This will be the task of research and standardisation in the<br />

near future.<br />

Magnetic<br />

for Plastics<br />

www.plasticker.com<br />

• International Trade<br />

in Raw Materials, Machinery & Products Free of Charge.<br />

• Daily News<br />

from the Industrial Sector and the Plastics Markets.<br />

• Current Market Prices<br />

for Plastics.<br />

• Buyer’s Guide<br />

for Plastics & Additives, Machinery & Equipment, Subcontractors<br />

and Services.<br />

• Job Market<br />

for Specialists and Executive Staff in the Plastics Industry.<br />

Up-to-date • Fast • Professional<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 49


Research & Development<br />

Opportunity for developers<br />

Use or invest in (biobased) Polymerization Shared Facility –<br />

Call for Partners<br />

G<br />

reen Chemistry Campus (Bergen op Zoom), REWIN<br />

(Breda) and Wageningen University (Wageningen,<br />

all in the Netherlands) are planning the development<br />

of the first multipurpose Polymerization Shared<br />

Facility Pilot Plant in Bergen op Zoom. In this facility new<br />

and redesigned bio-polymers can be produced at a subcommercial<br />

scale. Currently the consortium is looking for<br />

companies in the field of new (biobased) polymers that are<br />

interested to either use this unique infrastructure or that<br />

want to become a shareholder.<br />

Test new & redesigned polymers at a<br />

sub-commercial scale<br />

Many developers of (bio-)polymers are ready to scale-up<br />

production from lab-scale to industrial-scale. The current<br />

lack of R&D infrastructure prevents them from optimally<br />

developing their innovations that could potentially green the<br />

chemical industry. The Polymerization Shared Facility Pilot<br />

aims to bridge this valley of death in polymer innovation by<br />

sharing costly infrastructure between multiple users.<br />

The plant embraces ring-opening and polycondensation<br />

polymerization as well as de-polymerization. With the<br />

possibility of continuous production of larger volumes of new<br />

and re-designed polymers, both the behavior of the polymer<br />

in production (upstream) and the processing (downstream)<br />

can be investigated at pre-commercial volumes (tonnesscale).<br />

The figure below shows the Polymerization Shared<br />

Facility Pilot across the value chain.<br />

Call for industrial partners to use or invest in<br />

the Polymerization Shared Facility Pilot Plant<br />

The Consortium is looking for companies who are<br />

active in the research and development of (bio)-polymers,<br />

either new polymers and/or drop-ins. This facility will help<br />

polymer developers or an end-users in materials to make<br />

the innovation process of developing new polymers and<br />

materials more efficient and sustainable.<br />

The offer is open for business partner(s) who want to use<br />

this facility in coming years or who want to be a shareholder<br />

of this facility. For any type of business partner, very<br />

attractive offerings are available, which include:<br />

• a pilot plant designed to your requirements (with broad<br />

process-operating window)<br />

• opportunity to co-invest<br />

• guaranteed use of the facility<br />

• competitive costs<br />

• located in the thriving bio-economy ecosystem of the<br />

Biobased Delta (South-West Netherlands)<br />

Consortium Partners & Context<br />

Consortium Partners Green Chemistry Campus, REWIN<br />

and Wageningen University are planning to develop this<br />

Polymerization Shared Facility at the site of the Green<br />

Chemistry Campus in Bergen op Zoom.<br />

The facility reinforces the Biobased Delta ecosystem and<br />

is additional to existing research infrastructure such as<br />

the Wageningen Food & Biobased Research, Bioprocess<br />

Pilot Facility in Delft and the Bio Base Europe Pilot Plant<br />

in Ghent. It increases the attractiveness of the region for<br />

companies in the world to establish R&D centers here. The<br />

Wageningen Food & Biobased Research will give specifically<br />

scientific and engineering support to this polymerization<br />

pilot plant.<br />

About two third of the plant will be publicly funded.<br />

More Information<br />

The Consortium would be happy to send you<br />

more information or (preferably) talk to interested<br />

parties to explore possibilities that<br />

could help your company to successfully<br />

scale-up production of new (bio-)polymers.<br />

Please contact:<br />

Marcel van Berkel<br />

CEO Polymerization Shared Facility<br />

+31 6222 03144<br />

marcel@polymerizationsharedfacility.com<br />

Up-scaling<br />

Research &<br />

Development<br />

Upscaling<br />

(pilot)<br />

Demo/<br />

Commercial<br />

scale<br />

(Cellulosic)<br />

Sugars<br />

Universities, private R&D at multinationals, -startups,<br />

Pilot plants for<br />

monomers<br />

Value Chain<br />

Monomers<br />

Polymers &<br />

Materials<br />

Polymerization Shared<br />

Facility<br />

End product<br />

Compounders,<br />

Converters & End use<br />

Feedstock suppliers Polymer producers Brand owners<br />

50 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


ORDER<br />

NOW!<br />

BOOK<br />

STORE<br />

www.bioplasticsmagazine.com/en/books<br />

email: books@bioplasticsmagazine.com<br />

phone: +49 2161 6884463<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 51


By:<br />

BIOPLASTIC<br />

patents<br />

Barry Dean,<br />

Naperville, Illinois, USA<br />

U.S. Patent 10,246,799 (April 2, <strong>2019</strong>) “Polylactic Acid Resin<br />

Composition For 3D Printing”, Min-young Kim, Jong Ryang<br />

Kim, Tae-Young Kim, Sung-wan Jeon, (SK Chemicals Co, Ltd),<br />

(Seongnam-si Korea)<br />

Ref: WO2016/043440<br />

This patent teaches a composition and a process for making<br />

a composition for 3D printing. The composition taught consists<br />

of a hard segment polylactic acid (65 – 95 weight %) and a<br />

soft segment polyol (5 – 35 weight %) connected via urethane<br />

linkages by reaction with a diisocyanate. The PLA hard<br />

segment is prepared via reaction of D/L lactide while the soft<br />

segment is derived from a polyol such as polyethyleneglycol,<br />

polybutyleneglycol or polypropyleneglycol. The hard segment<br />

offers a melting point of 170°C and a glass transition of 55°C;<br />

while the soft segment glass transition can be tailored by<br />

the selection of polyol or mixtures of polyol. The polyol soft<br />

segment provides for a greater practical toughness of the<br />

resin and hence the 3D printed article.<br />

Key to the composition and its use for 3D printing is a<br />

practical melt viscosity which is taught based on a measured<br />

viscosity of


U.S. Patent 10,351,755 (July 16, <strong>2019</strong>) “Loss Circulation<br />

Material Composition Having Alkaline Nanoparticle Based<br />

Dispersion and Water Insoluble Hydrolysable Polyester”,<br />

Vikrant Wagle, Rajendra Kalgaonkar, Abdullah Al-Yami, Zalnab<br />

Alsaihati (Saudi Arabian Oil Company), (Dhahran, Saudi Arabia)<br />

Ref. WO 2015116044<br />

This patent teaches a composition to address loss of<br />

drilling fluids in the wellbore. The composition consists<br />

of alkaline nanosilica dispersion and a water insoluble<br />

polyester where the ratio of the nanosilica: polyester is 50<br />

– 80:1. The water insoluble polyester can be polylactic acid,<br />

polyhydroxyalkanoate, polyglycolide or polycaprolactone,<br />

The combined nanosilica and insoluble polyester(powder<br />

or fiber) form a gel which when introduced into a well enter<br />

subterranean formations of low pressure and/or fractured<br />

areas. Under well temperatures the polyester hydrolyzes to<br />

form monomeric acid residues which react with the alkaline<br />

nanosilica forming a solid, physical barrier to the drilling fluids<br />

thereby increasing the efficiency and recovery of the drilling<br />

fluids.<br />

Process PLA<br />

with Improved<br />

Molecular Weight<br />

Retention<br />

LOWER MELT<br />

TEMPERATURE<br />

REDUCED ENERGY<br />

CONSUMPTION<br />

HIGHER FILL<br />

LEVELS<br />

U.S. Patent 10,314,683 (June 11, <strong>2019</strong>) “Polyhydroxyalkanoate<br />

Medical Textiles and Fibers”, David P Martin, Said Rizk,<br />

Ajay Ahuja, Simon F. Williams, (Tepha, Inc), (Lexington,<br />

Massachusetts)<br />

This patent teaches absorbable polyester fibers, braids and<br />

surgical meshes with good in vivo strength retention based<br />

on monofilament or multifilament fiber made from poly-4-<br />

hydroxybutyrate homopolymer and copolymers. Multifilament<br />

fiber tenacity is greater than 3.5 g/denier and monofilament<br />

fiber has tensile strength greater than 126 MPa. These<br />

strength properties are key for in vivo sutures and surgical<br />

meshes<br />

These absorbable fibers are suggested to offer improved<br />

performance for anti-adhesion properties and reduced risks<br />

of infection.<br />

This patent also teaches the process for forming useful<br />

4-PHB fiber while overcoming the challenges of melt fracture,<br />

low crystallization and fiber tackiness.<br />

U.S. Patent 10,351,973 (July 16, <strong>2019</strong>) “Process For The<br />

Preparation Of A Fiber, A Fiber and A Yarn Made From Such A<br />

Fiber”, Jeffrey John Kolstad, Gerardus Johannes Maria Gruter,<br />

(Furanix Technologiers B.V.), (Amsterdam, Netherlands)<br />

Ref: WO2014/204313<br />

A fiber by melt spinning of polyethylene-2.5-<br />

furandicarboxylate is taught. The PEF resin exhibits a solution<br />

viscosity of 0.45 – 0.85 dL/g. PEF fiber with draw ratios of 1:<br />

1.4 – 1.6 are shown to exhibit good fiber tenacity 200 – 1000<br />

mN/tex. It is also taught that PEF fiber can be subjected to<br />

traditional fiber techniques such as texturing, finishing and<br />

dyeing. In a comparative example with poly(trimethylene-2,5-<br />

furanoate), PEF was demonstrated to have improved fiber<br />

forming properties, e.g. reduced number of spin breaks.<br />

The PEF resin can be 100 % renewable with a biobased<br />

source of ethylene glycol.<br />

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lower melt temperatures than twin screw<br />

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bioplastics MAGAZINE [03/19] Vol. 14 53


Basics<br />

Glossary 4.4 last update issue <strong>05</strong>/<strong>2019</strong><br />

In bioplastics MAGAZINE again and again<br />

the same expressions appear that some of our readers<br />

might not (yet) be familiar with. This glossary shall help<br />

with these terms and shall help avoid repeated explanations<br />

such as PLA (Polylactide) in various articles.<br />

Bioplastics (as defined by European Bioplastics<br />

e.V.) is a term used to define two different<br />

kinds of plastics:<br />

a. Plastics based on → renewable resources<br />

(the focus is the origin of the raw material<br />

used). These can be biodegradable or not.<br />

b. → Biodegradable and → compostable<br />

plastics according to EN13432 or similar<br />

standards (the focus is the compostability of<br />

the final product; biodegradable and compostable<br />

plastics can be based on renewable<br />

(biobased) and/or non-renewable (fossil) resources).<br />

Bioplastics may be<br />

- based on renewable resources and biodegradable;<br />

- based on renewable resources but not be<br />

biodegradable; and<br />

- based on fossil resources and biodegradable.<br />

1 st Generation feedstock | Carbohydrate rich<br />

plants such as corn or sugar cane that can<br />

also be used as food or animal feed are called<br />

food crops or 1 st generation feedstock. Bred<br />

my mankind over centuries for highest energy<br />

efficiency, currently, 1 st generation feedstock<br />

is the most efficient feedstock for the production<br />

of bioplastics as it requires the least<br />

amount of land to grow and produce the highest<br />

yields. [bM 04/09]<br />

2 nd Generation feedstock | refers to feedstock<br />

not suitable for food or feed. It can be either<br />

non-food crops (e.g. cellulose) or waste materials<br />

from 1 st generation feedstock (e.g.<br />

waste vegetable oil). [bM 06/11]<br />

3 rd Generation feedstock | This term currently<br />

relates to biomass from algae, which – having<br />

a higher growth yield than 1 st and 2 nd generation<br />

feedstock – were given their own category.<br />

It also relates to bioplastics from waste<br />

streams such as CO 2<br />

or methane [bM 02/16]<br />

Aerobic digestion | Aerobic means in the<br />

presence of oxygen. In →composting, which is<br />

an aerobic process, →microorganisms access<br />

the present oxygen from the surrounding atmosphere.<br />

They metabolize the organic material<br />

to energy, CO 2<br />

, water and cell biomass,<br />

whereby part of the energy of the organic material<br />

is released as heat. [bM 03/07, bM 02/09]<br />

Since this Glossary will not be printed<br />

in each issue you can download a pdf version<br />

from our website (bit.ly/OunBB0)<br />

bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />

Version 4.0 was revised using EuBP’s latest version (Jan 2015).<br />

[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />

Anaerobic digestion | In anaerobic digestion,<br />

organic matter is degraded by a microbial<br />

population in the absence of oxygen<br />

and producing methane and carbon dioxide<br />

(= →biogas) and a solid residue that can be<br />

composted in a subsequent step without<br />

practically releasing any heat. The biogas can<br />

be treated in a Combined Heat and Power<br />

Plant (CHP), producing electricity and heat, or<br />

can be upgraded to bio-methane [14] [bM 06/09]<br />

Amorphous | non-crystalline, glassy with unordered<br />

lattice<br />

Amylopectin | Polymeric branched starch<br />

molecule with very high molecular weight<br />

(biopolymer, monomer is →Glucose) [bM <strong>05</strong>/09]<br />

Amylose | Polymeric non-branched starch<br />

molecule with high molecular weight (biopolymer,<br />

monomer is →Glucose) [bM <strong>05</strong>/09]<br />

Biobased | The term biobased describes the<br />

part of a material or product that is stemming<br />

from →biomass. When making a biobasedclaim,<br />

the unit (→biobased carbon content,<br />

→biobased mass content), a percentage and<br />

the measuring method should be clearly stated [1]<br />

Biobased carbon | carbon contained in or<br />

stemming from →biomass. A material or<br />

product made of fossil and →renewable resources<br />

contains fossil and →biobased carbon.<br />

The biobased carbon content is measured via<br />

the 14 C method (radio carbon dating method)<br />

that adheres to the technical specifications as<br />

described in [1,4,5,6].<br />

Biobased labels | The fact that (and to<br />

what percentage) a product or a material is<br />

→biobased can be indicated by respective<br />

labels. Ideally, meaningful labels should be<br />

based on harmonised standards and a corresponding<br />

certification process by independent<br />

third party institutions. For the property<br />

biobased such labels are in place by certifiers<br />

→DIN CERTCO and →TÜV Austria who both<br />

base their certifications on the technical specification<br />

as described in [4,5]<br />

A certification and corresponding label depicting<br />

the biobased mass content was developed<br />

by the French Association Chimie du Végétal<br />

[ACDV].<br />

Biobased mass content | describes the<br />

amount of biobased mass contained in a material<br />

or product. This method is complementary<br />

to the 14 C method, and furthermore, takes<br />

other chemical elements besides the biobased<br />

carbon into account, such as oxygen, nitrogen<br />

and hydrogen. A measuring method has<br />

been developed and tested by the Association<br />

Chimie du Végétal (ACDV) [1]<br />

Biobased plastic | A plastic in which constitutional<br />

units are totally or partly from →<br />

biomass [3]. If this claim is used, a percentage<br />

should always be given to which extent<br />

the product/material is → biobased [1]<br />

[bM 01/07, bM 03/10]<br />

Biodegradable Plastics | Biodegradable Plastics<br />

are plastics that are completely assimilated<br />

by the → microorganisms present a defined<br />

environment as food for their energy. The<br />

carbon of the plastic must completely be converted<br />

into CO 2<br />

during the microbial process.<br />

The process of biodegradation depends on<br />

the environmental conditions, which influence<br />

it (e.g. location, temperature, humidity) and<br />

on the material or application itself. Consequently,<br />

the process and its outcome can vary<br />

considerably. Biodegradability is linked to the<br />

structure of the polymer chain; it does not depend<br />

on the origin of the raw materials.<br />

There is currently no single, overarching standard<br />

to back up claims about biodegradability.<br />

One standard for example is ISO or in Europe:<br />

EN 14995 Plastics- Evaluation of compostability<br />

- Test scheme and specifications<br />

[bM 02/06, bM 01/07]<br />

Biogas | → Anaerobic digestion<br />

Biomass | Material of biological origin excluding<br />

material embedded in geological formations<br />

and material transformed to fossilised<br />

material. This includes organic material, e.g.<br />

trees, crops, grasses, tree litter, algae and<br />

waste of biological origin, e.g. manure [1, 2]<br />

Biorefinery | the co-production of a spectrum<br />

of bio-based products (food, feed, materials,<br />

chemicals including monomers or building<br />

blocks for bioplastics) and energy (fuels, power,<br />

heat) from biomass.[bM 02/13]<br />

Blend | Mixture of plastics, polymer alloy of at<br />

least two microscopically dispersed and molecularly<br />

distributed base polymers<br />

Bisphenol-A (BPA) | Monomer used to produce<br />

different polymers. BPA is said to cause<br />

health problems, due to the fact that is behaves<br />

like a hormone. Therefore it is banned<br />

for use in children’s products in many countries.<br />

BPI | Biodegradable Products Institute, a notfor-profit<br />

association. Through their innovative<br />

compostable label program, BPI educates<br />

manufacturers, legislators and consumers<br />

about the importance of scientifically based<br />

standards for compostable materials which<br />

biodegrade in large composting facilities.<br />

Carbon footprint | (CFPs resp. PCFs – Product<br />

Carbon Footprint): Sum of →greenhouse<br />

gas emissions and removals in a product system,<br />

expressed as CO 2<br />

equivalent, and based<br />

on a →life cycle assessment. The CO 2<br />

equivalent<br />

of a specific amount of a greenhouse gas<br />

is calculated as the mass of a given greenhouse<br />

gas multiplied by its →global warmingpotential<br />

[1,2,15]<br />

54 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Basics<br />

Carbon neutral, CO 2<br />

neutral | describes a<br />

product or process that has a negligible impact<br />

on total atmospheric CO 2<br />

levels. For<br />

example, carbon neutrality means that any<br />

CO 2<br />

released when a plant decomposes or<br />

is burnt is offset by an equal amount of CO 2<br />

absorbed by the plant through photosynthesis<br />

when it is growing.<br />

Carbon neutrality can also be achieved<br />

through buying sufficient carbon credits to<br />

make up the difference. The latter option is<br />

not allowed when communicating → LCAs<br />

or carbon footprints regarding a material or<br />

product [1, 2].<br />

Carbon-neutral claims are tricky as products<br />

will not in most cases reach carbon neutrality<br />

if their complete life cycle is taken into consideration<br />

(including the end-of life).<br />

If an assessment of a material, however, is<br />

conducted (cradle to gate), carbon neutrality<br />

might be a valid claim in a B2B context. In this<br />

case, the unit assessed in the complete life<br />

cycle has to be clarified [1]<br />

Cascade use | of →renewable resources means<br />

to first use the →biomass to produce biobased<br />

industrial products and afterwards – due to<br />

their favourable energy balance – use them<br />

for energy generation (e.g. from a biobased<br />

plastic product to →biogas production). The<br />

feedstock is used efficiently and value generation<br />

increases decisively.<br />

Catalyst | substance that enables and accelerates<br />

a chemical reaction<br />

Cellophane | Clear film on the basis of →cellulose<br />

[bM 01/10]<br />

Cellulose | Cellulose is the principal component<br />

of cell walls in all higher forms of plant<br />

life, at varying percentages. It is therefore the<br />

most common organic compound and also<br />

the most common polysaccharide (multisugar)<br />

[11]. Cellulose is a polymeric molecule<br />

with very high molecular weight (monomer is<br />

→Glucose), industrial production from wood<br />

or cotton, to manufacture paper, plastics and<br />

fibres [bM 01/10]<br />

Cellulose ester | Cellulose esters occur by<br />

the esterification of cellulose with organic<br />

acids. The most important cellulose esters<br />

from a technical point of view are cellulose<br />

acetate (CA with acetic acid), cellulose propionate<br />

(CP with propionic acid) and cellulose<br />

butyrate (CB with butanoic acid). Mixed polymerisates,<br />

such as cellulose acetate propionate<br />

(CAP) can also be formed. One of the most<br />

well-known applications of cellulose aceto<br />

butyrate (CAB) is the moulded handle on the<br />

Swiss army knife [11]<br />

Cellulose acetate CA | → Cellulose ester<br />

CEN | Comité Européen de Normalisation<br />

(European organisation for standardization)<br />

Certification | is a process in which materials/products<br />

undergo a string of (laboratory)<br />

tests in order to verify that the fulfil certain<br />

requirements. Sound certification systems<br />

should be based on (ideally harmonised) European<br />

standards or technical specifications<br />

(e.g. by →CEN, USDA, ASTM, etc.) and be<br />

performed by independent third party laboratories.<br />

Successful certification guarantees<br />

a high product safety - also on this basis interconnected<br />

labels can be awarded that help<br />

the consumer to make an informed decision.<br />

Compost | A soil conditioning material of decomposing<br />

organic matter which provides nutrients<br />

and enhances soil structure.<br />

[bM 06/08, 02/09]<br />

Compostable Plastics | Plastics that are<br />

→ biodegradable under →composting conditions:<br />

specified humidity, temperature,<br />

→ microorganisms and timeframe. In order<br />

to make accurate and specific claims about<br />

compostability, the location (home, → industrial)<br />

and timeframe need to be specified [1].<br />

Several national and international standards<br />

exist for clearer definitions, for example EN<br />

14995 Plastics - Evaluation of compostability -<br />

Test scheme and specifications. [bM 02/06, bM 01/07]<br />

Composting | is the controlled →aerobic, or<br />

oxygen-requiring, decomposition of organic<br />

materials by →microorganisms, under controlled<br />

conditions. It reduces the volume and<br />

mass of the raw materials while transforming<br />

them into CO 2<br />

, water and a valuable soil conditioner<br />

– compost.<br />

When talking about composting of bioplastics,<br />

foremost →industrial composting in a<br />

managed composting facility is meant (criteria<br />

defined in EN 13432).<br />

The main difference between industrial and<br />

home composting is, that in industrial composting<br />

facilities temperatures are much<br />

higher and kept stable, whereas in the composting<br />

pile temperatures are usually lower,<br />

and less constant as depending on factors<br />

such as weather conditions. Home composting<br />

is a way slower-paced process than<br />

industrial composting. Also a comparatively<br />

smaller volume of waste is involved. [bM 03/07]<br />

Compound | plastic mixture from different<br />

raw materials (polymer and additives) [bM 04/10)<br />

Copolymer | Plastic composed of different<br />

monomers.<br />

Cradle-to-Gate | Describes the system<br />

boundaries of an environmental →Life Cycle<br />

Assessment (LCA) which covers all activities<br />

from the cradle (i.e., the extraction of raw materials,<br />

agricultural activities and forestry) up<br />

to the factory gate<br />

Cradle-to-Cradle | (sometimes abbreviated<br />

as C2C): Is an expression which communicates<br />

the concept of a closed-cycle economy,<br />

in which waste is used as raw material<br />

(‘waste equals food’). Cradle-to-Cradle is not<br />

a term that is typically used in →LCA studies.<br />

Cradle-to-Grave | Describes the system<br />

boundaries of a full →Life Cycle Assessment<br />

from manufacture (cradle) to use phase and<br />

disposal phase (grave).<br />

Crystalline | Plastic with regularly arranged<br />

molecules in a lattice structure<br />

Density | Quotient from mass and volume of<br />

a material, also referred to as specific weight<br />

DIN | Deutsches Institut für Normung (German<br />

organisation for standardization)<br />

DIN-CERTCO | independant certifying organisation<br />

for the assessment on the conformity<br />

of bioplastics<br />

Dispersing | fine distribution of non-miscible<br />

liquids into a homogeneous, stable mixture<br />

Drop-In bioplastics | chemically indentical<br />

to conventional petroleum based plastics,<br />

but made from renewable resources. Examples<br />

are bio-PE made from bio-ethanol (from<br />

e.g. sugar cane) or partly biobased PET; the<br />

monoethylene glykol made from bio-ethanol<br />

(from e.g. sugar cane). Developments to<br />

make terephthalic acid from renewable resources<br />

are under way. Other examples are<br />

polyamides (partly biobased e.g. PA 4.10 or PA<br />

6.10 or fully biobased like PA 5.10 or PA10.10)<br />

EN 13432 | European standard for the assessment<br />

of the → compostability of plastic<br />

packaging products<br />

Energy recovery | recovery and exploitation<br />

of the energy potential in (plastic) waste for<br />

the production of electricity or heat in waste<br />

incineration pants (waste-to-energy)<br />

Environmental claim | A statement, symbol<br />

or graphic that indicates one or more environmental<br />

aspect(s) of a product, a component,<br />

packaging or a service. [16]<br />

Enzymes | proteins that catalyze chemical<br />

reactions<br />

Enzyme-mediated plastics | are no →bioplastics.<br />

Instead, a conventional non-biodegradable<br />

plastic (e.g. fossil-based PE) is enriched<br />

with small amounts of an organic additive.<br />

Microorganisms are supposed to consume<br />

these additives and the degradation process<br />

should then expand to the non-biodegradable<br />

PE and thus make the material degrade. After<br />

some time the plastic is supposed to visually<br />

disappear and to be completely converted to<br />

carbon dioxide and water. This is a theoretical<br />

concept which has not been backed up by<br />

any verifiable proof so far. Producers promote<br />

enzyme-mediated plastics as a solution to littering.<br />

As no proof for the degradation process<br />

has been provided, environmental beneficial<br />

effects are highly questionable.<br />

Ethylene | colour- and odourless gas, made<br />

e.g. from, Naphtha (petroleum) by cracking or<br />

from bio-ethanol by dehydration, monomer of<br />

the polymer polyethylene (PE)<br />

European Bioplastics e.V. | The industry association<br />

representing the interests of Europe’s<br />

thriving bioplastics’ industry. Founded<br />

in Germany in 1993 as IBAW, European<br />

Bioplastics today represents the interests<br />

of about 50 member companies throughout<br />

the European Union and worldwide. With<br />

members from the agricultural feedstock,<br />

chemical and plastics industries, as well as<br />

industrial users and recycling companies, European<br />

Bioplastics serves as both a contact<br />

platform and catalyst for advancing the aims<br />

of the growing bioplastics industry.<br />

Extrusion | process used to create plastic<br />

profiles (or sheet) of a fixed cross-section<br />

consisting of mixing, melting, homogenising<br />

and shaping of the plastic.<br />

FDCA | 2,5-furandicarboxylic acid, an intermediate<br />

chemical produced from 5-HMF.<br />

The dicarboxylic acid can be used to make →<br />

PEF = polyethylene furanoate, a polyester that<br />

could be a 100% biobased alternative to PET.<br />

Fermentation | Biochemical reactions controlled<br />

by → microorganisms or → enyzmes (e.g.<br />

the transformation of sugar into lactic acid).<br />

FSC | Forest Stewardship Council. FSC is an<br />

independent, non-governmental, not-forprofit<br />

organization established to promote the<br />

responsible and sustainable management of<br />

the world’s forests.<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 55


Basics<br />

Gelatine | Translucent brittle solid substance,<br />

colorless or slightly yellow, nearly tasteless<br />

and odorless, extracted from the collagen inside<br />

animals‘ connective tissue.<br />

Genetically modified organism (GMO) | Organisms,<br />

such as plants and animals, whose<br />

genetic material (DNA) has been altered<br />

are called genetically modified organisms<br />

(GMOs). Food and feed which contain or<br />

consist of such GMOs, or are produced from<br />

GMOs, are called genetically modified (GM)<br />

food or feed [1]. If GM crops are used in bioplastics<br />

production, the multiple-stage processing<br />

and the high heat used to create the<br />

polymer removes all traces of genetic material.<br />

This means that the final bioplastics product<br />

contains no genetic traces. The resulting<br />

bioplastics is therefore well suited to use in<br />

food packaging as it contains no genetically<br />

modified material and cannot interact with<br />

the contents.<br />

Global Warming | Global warming is the rise<br />

in the average temperature of Earth’s atmosphere<br />

and oceans since the late 19th century<br />

and its projected continuation [8]. Global<br />

warming is said to be accelerated by → green<br />

house gases.<br />

Glucose | Monosaccharide (or simple sugar).<br />

G. is the most important carbohydrate (sugar)<br />

in biology. G. is formed by photosynthesis or<br />

hydrolyse of many carbohydrates e. g. starch.<br />

Greenhouse gas GHG | Gaseous constituent<br />

of the atmosphere, both natural and anthropogenic,<br />

that absorbs and emits radiation at<br />

specific wavelengths within the spectrum of<br />

infrared radiation emitted by the earth’s surface,<br />

the atmosphere, and clouds [1, 9]<br />

Greenwashing | The act of misleading consumers<br />

regarding the environmental practices<br />

of a company, or the environmental benefits<br />

of a product or service [1, 10]<br />

Granulate, granules | small plastic particles<br />

(3-4 millimetres), a form in which plastic is<br />

sold and fed into machines, easy to handle<br />

and dose.<br />

HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />

organic compound derived from sugar dehydration.<br />

It is a platform chemical, a building<br />

block for 20 performance polymers and over<br />

175 different chemical substances. The molecule<br />

consists of a furan ring which contains<br />

both aldehyde and alcohol functional groups.<br />

5-HMF has applications in many different<br />

industries such as bioplastics, packaging,<br />

pharmaceuticals, adhesives and chemicals.<br />

One of the most promising routes is 2,5<br />

furandicarboxylic acid (FDCA), produced as an<br />

intermediate when 5-HMF is oxidised. FDCA<br />

is used to produce PEF, which can substitute<br />

terephthalic acid in polyester, especially polyethylene<br />

terephthalate (PET). [bM 03/14, 02/16]<br />

Home composting | →composting [bM 06/08]<br />

Humus | In agriculture, humus is often used<br />

simply to mean mature →compost, or natural<br />

compost extracted from a forest or other<br />

spontaneous source for use to amend soil.<br />

Hydrophilic | Property: water-friendly, soluble<br />

in water or other polar solvents (e.g. used<br />

in conjunction with a plastic which is not water<br />

resistant and weather proof or that absorbs<br />

water such as Polyamide (PA).<br />

Hydrophobic | Property: water-resistant, not<br />

soluble in water (e.g. a plastic which is water<br />

resistant and weather proof, or that does not<br />

absorb any water such as Polyethylene (PE)<br />

or Polypropylene (PP).<br />

Industrial composting | is an established<br />

process with commonly agreed upon requirements<br />

(e.g. temperature, timeframe) for transforming<br />

biodegradable waste into stable, sanitised<br />

products to be used in agriculture. The<br />

criteria for industrial compostability of packaging<br />

have been defined in the EN 13432. Materials<br />

and products complying with this standard<br />

can be certified and subsequently labelled<br />

accordingly [1,7] [bM 06/08, 02/09]<br />

ISO | International Organization for Standardization<br />

JBPA | Japan Bioplastics Association<br />

Land use | The surface required to grow sufficient<br />

feedstock (land use) for today’s bioplastic<br />

production is less than 0.01 percent of the<br />

global agricultural area of 5 billion hectares.<br />

It is not yet foreseeable to what extent an increased<br />

use of food residues, non-food crops<br />

or cellulosic biomass (see also →1 st /2 nd /3 rd<br />

generation feedstock) in bioplastics production<br />

might lead to an even further reduced<br />

land use in the future [bM 04/09, 01/14]<br />

LCA | is the compilation and evaluation of the<br />

input, output and the potential environmental<br />

impact of a product system throughout its life<br />

cycle [17]. It is sometimes also referred to as<br />

life cycle analysis, ecobalance or cradle-tograve<br />

analysis. [bM 01/09]<br />

Littering | is the (illegal) act of leaving waste<br />

such as cigarette butts, paper, tins, bottles,<br />

cups, plates, cutlery or bags lying in an open<br />

or public place.<br />

Marine litter | Following the European Commission’s<br />

definition, “marine litter consists of<br />

items that have been deliberately discarded,<br />

unintentionally lost, or transported by winds<br />

and rivers, into the sea and on beaches. It<br />

mainly consists of plastics, wood, metals,<br />

glass, rubber, clothing and paper”. Marine<br />

debris originates from a variety of sources.<br />

Shipping and fishing activities are the predominant<br />

sea-based, ineffectively managed<br />

landfills as well as public littering the main<br />

land-based sources. Marine litter can pose a<br />

threat to living organisms, especially due to<br />

ingestion or entanglement.<br />

Currently, there is no international standard<br />

available, which appropriately describes the<br />

biodegradation of plastics in the marine environment.<br />

However, a number of standardisation<br />

projects are in progress at ISO and ASTM<br />

level. Furthermore, the European project<br />

OPEN BIO addresses the marine biodegradation<br />

of biobased products.[bM 02/16]<br />

Mass balance | describes the relationship between<br />

input and output of a specific substance<br />

within a system in which the output from the<br />

system cannot exceed the input into the system.<br />

First attempts were made by plastic raw material<br />

producers to claim their products renewable<br />

(plastics) based on a certain input<br />

of biomass in a huge and complex chemical<br />

plant, then mathematically allocating this<br />

biomass input to the produced plastic.<br />

These approaches are at least controversially<br />

disputed [bM 04/14, <strong>05</strong>/14, 01/15]<br />

Microorganism | Living organisms of microscopic<br />

size, such as bacteria, funghi or yeast.<br />

Molecule | group of at least two atoms held<br />

together by covalent chemical bonds.<br />

Monomer | molecules that are linked by polymerization<br />

to form chains of molecules and<br />

then plastics<br />

Mulch film | Foil to cover bottom of farmland<br />

Organic recycling | means the treatment of<br />

separately collected organic waste by anaerobic<br />

digestion and/or composting.<br />

Oxo-degradable / Oxo-fragmentable | materials<br />

and products that do not biodegrade!<br />

The underlying technology of oxo-degradability<br />

or oxo-fragmentation is based on special additives,<br />

which, if incorporated into standard<br />

resins, are purported to accelerate the fragmentation<br />

of products made thereof. Oxodegradable<br />

or oxo-fragmentable materials do<br />

not meet accepted industry standards on compostability<br />

such as EN 13432. [bM 01/09, <strong>05</strong>/09]<br />

PBAT | Polybutylene adipate terephthalate, is<br />

an aliphatic-aromatic copolyester that has the<br />

properties of conventional polyethylene but is<br />

fully biodegradable under industrial composting.<br />

PBAT is made from fossil petroleum with<br />

first attempts being made to produce it partly<br />

from renewable resources [bM 06/09]<br />

PBS | Polybutylene succinate, a 100% biodegradable<br />

polymer, made from (e.g. bio-BDO)<br />

and succinic acid, which can also be produced<br />

biobased [bM 03/12].<br />

PC | Polycarbonate, thermoplastic polyester,<br />

petroleum based and not degradable, used<br />

for e.g. baby bottles or CDs. Criticized for its<br />

BPA (→ Bisphenol-A) content.<br />

PCL | Polycaprolactone, a synthetic (fossil<br />

based), biodegradable bioplastic, e.g. used as<br />

a blend component.<br />

PE | Polyethylene, thermoplastic polymerised<br />

from ethylene. Can be made from renewable<br />

resources (sugar cane via bio-ethanol) [bM <strong>05</strong>/10]<br />

PEF | polyethylene furanoate, a polyester<br />

made from monoethylene glycol (MEG) and<br />

→FDCA (2,5-furandicarboxylic acid , an intermediate<br />

chemical produced from 5-HMF). It<br />

can be a 100% biobased alternative for PET.<br />

PEF also has improved product characteristics,<br />

such as better structural strength and<br />

improved barrier behaviour, which will allow<br />

for the use of PEF bottles in additional applications.<br />

[bM 03/11, 04/12]<br />

PET | Polyethylenterephthalate, transparent<br />

polyester used for bottles and film. The<br />

polyester is made from monoethylene glycol<br />

(MEG), that can be renewably sourced from<br />

bio-ethanol (sugar cane) and (until now fossil)<br />

terephthalic acid [bM 04/14]<br />

PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />

thermoplastic polymer and the<br />

simplest linear, aliphatic polyester. Besides<br />

ist use in the biomedical field, PGA has been<br />

introduced as a barrier resin [bM 03/09]<br />

PHA | Polyhydroxyalkanoates (PHA) or the<br />

polyhydroxy fatty acids, are a family of biodegradable<br />

polyesters. As in many mammals,<br />

including humans, that hold energy reserves<br />

in the form of body fat there are also bacteria<br />

that hold intracellular reserves in for of<br />

of polyhydroxy alkanoates. Here the microorganisms<br />

store a particularly high level of<br />

56 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Basics<br />

energy reserves (up to 80% of their own body<br />

weight) for when their sources of nutrition become<br />

scarce. By farming this type of bacteria,<br />

and feeding them on sugar or starch (mostly<br />

from maize), or at times on plant oils or other<br />

nutrients rich in carbonates, it is possible to<br />

obtain PHA‘s on an industrial scale [11]. The<br />

most common types of PHA are PHB (Polyhydroxybutyrate,<br />

PHBV and PHBH. Depending<br />

on the bacteria and their food, PHAs with<br />

different mechanical properties, from rubbery<br />

soft trough stiff and hard as ABS, can be produced.<br />

Some PHSs are even biodegradable in<br />

soil or in a marine environment<br />

PLA | Polylactide or Polylactic Acid (PLA), a<br />

biodegradable, thermoplastic, linear aliphatic<br />

polyester based on lactic acid, a natural acid,<br />

is mainly produced by fermentation of sugar<br />

or starch with the help of micro-organisms.<br />

Lactic acid comes in two isomer forms, i.e. as<br />

laevorotatory D(-)lactic acid and as dextrorotary<br />

L(+)lactic acid.<br />

Modified PLA types can be produced by the<br />

use of the right additives or by certain combinations<br />

of L- and D- lactides (stereocomplexing),<br />

which then have the required rigidity for<br />

use at higher temperatures [13] [bM 01/09, 01/12]<br />

Plastics | Materials with large molecular<br />

chains of natural or fossil raw materials, produced<br />

by chemical or biochemical reactions.<br />

PPC | Polypropylene Carbonate, a bioplastic<br />

made by copolymerizing CO 2<br />

with propylene<br />

oxide (PO) [bM 04/12]<br />

PTT | Polytrimethylterephthalate (PTT), partially<br />

biobased polyester, is similarly to PET<br />

produced using terephthalic acid or dimethyl<br />

terephthalate and a diol. In this case it is a<br />

biobased 1,3 propanediol, also known as bio-<br />

PDO [bM 01/13]<br />

Renewable Resources | agricultural raw materials,<br />

which are not used as food or feed,<br />

but as raw material for industrial products<br />

or to generate energy. The use of renewable<br />

resources by industry saves fossil resources<br />

and reduces the amount of → greenhouse gas<br />

emissions. Biobased plastics are predominantly<br />

made of annual crops such as corn,<br />

cereals and sugar beets or perennial cultures<br />

such as cassava and sugar cane.<br />

Resource efficiency | Use of limited natural<br />

resources in a sustainable way while minimising<br />

impacts on the environment. A resource<br />

efficient economy creates more output<br />

or value with lesser input.<br />

Seedling Logo | The compostability label or<br />

logo Seedling is connected to the standard<br />

EN 13432/EN 14995 and a certification process<br />

managed by the independent institutions<br />

→DIN CERTCO and → TÜV Austria. Bioplastics<br />

products carrying the Seedling fulfil the criteria<br />

laid down in the EN 13432 regarding industrial<br />

compostability. [bM 01/06, 02/10]<br />

Saccharins or carbohydrates | Saccharins or<br />

carbohydrates are name for the sugar-family.<br />

Saccharins are monomer or polymer sugar<br />

units. For example, there are known mono-,<br />

di- and polysaccharose. → glucose is a monosaccarin.<br />

They are important for the diet and<br />

produced biology in plants.<br />

Semi-finished products | plastic in form of<br />

sheet, film, rods or the like to be further processed<br />

into finshed products<br />

Sorbitol | Sugar alcohol, obtained by reduction<br />

of glucose changing the aldehyde group<br />

to an additional hydroxyl group. S. is used as<br />

a plasticiser for bioplastics based on starch.<br />

Starch | Natural polymer (carbohydrate)<br />

consisting of → amylose and → amylopectin,<br />

gained from maize, potatoes, wheat, tapioca<br />

etc. When glucose is connected to polymerchains<br />

in definite way the result (product) is<br />

called starch. Each molecule is based on 300<br />

-12000-glucose units. Depending on the connection,<br />

there are two types → amylose and →<br />

amylopectin known. [bM <strong>05</strong>/09]<br />

Starch derivatives | Starch derivatives are<br />

based on the chemical structure of → starch.<br />

The chemical structure can be changed by<br />

introducing new functional groups without<br />

changing the → starch polymer. The product<br />

has different chemical qualities. Mostly the<br />

hydrophilic character is not the same.<br />

Starch-ester | One characteristic of every<br />

starch-chain is a free hydroxyl group. When<br />

every hydroxyl group is connected with an<br />

acid one product is starch-ester with different<br />

chemical properties.<br />

Starch propionate and starch butyrate |<br />

Starch propionate and starch butyrate can be<br />

synthesised by treating the → starch with propane<br />

or butanic acid. The product structure<br />

is still based on → starch. Every based → glucose<br />

fragment is connected with a propionate<br />

or butyrate ester group. The product is more<br />

hydrophobic than → starch.<br />

Sustainable | An attempt to provide the best<br />

outcomes for the human and natural environments<br />

both now and into the indefinite future.<br />

One famous definition of sustainability is the<br />

one created by the Brundtland Commission,<br />

led by the former Norwegian Prime Minister<br />

G. H. Brundtland. The Brundtland Commission<br />

defined sustainable development as<br />

development that ‘meets the needs of the<br />

present without compromising the ability of<br />

future generations to meet their own needs.’<br />

Sustainability relates to the continuity of economic,<br />

social, institutional and environmental<br />

aspects of human society, as well as the nonhuman<br />

environment).<br />

Sustainable sourcing | of renewable feedstock<br />

for biobased plastics is a prerequisite<br />

for more sustainable products. Impacts such<br />

as the deforestation of protected habitats<br />

or social and environmental damage arising<br />

from poor agricultural practices must<br />

be avoided. Corresponding certification<br />

schemes, such as ISCC PLUS, WLC or Bon-<br />

Sucro, are an appropriate tool to ensure the<br />

sustainable sourcing of biomass for all applications<br />

around the globe.<br />

Sustainability | as defined by European Bioplastics,<br />

has three dimensions: economic, social<br />

and environmental. This has been known<br />

as “the triple bottom line of sustainability”.<br />

This means that sustainable development involves<br />

the simultaneous pursuit of economic<br />

prosperity, environmental protection and social<br />

equity. In other words, businesses have<br />

to expand their responsibility to include these<br />

environmental and social dimensions. Sustainability<br />

is about making products useful to<br />

markets and, at the same time, having societal<br />

benefits and lower environmental impact<br />

than the alternatives currently available. It also<br />

implies a commitment to continuous improvement<br />

that should result in a further reduction<br />

of the environmental footprint of today’s products,<br />

processes and raw materials used.<br />

Thermoplastics | Plastics which soften or<br />

melt when heated and solidify when cooled<br />

(solid at room temperature).<br />

Thermoplastic Starch | (TPS) → starch that<br />

was modified (cooked, complexed) to make it<br />

a plastic resin<br />

Thermoset | Plastics (resins) which do not<br />

soften or melt when heated. Examples are<br />

epoxy resins or unsaturated polyester resins.<br />

TÜV Austria Belgium | independant certifying<br />

organisation for the assessment on the conformity<br />

of bioplastics (formerly Vinçotte)<br />

Vinçotte | → TÜV Austria Belgium<br />

WPC | Wood Plastic Composite. Composite<br />

materials made of wood fiber/flour and plastics<br />

(mostly polypropylene).<br />

Yard Waste | Grass clippings, leaves, trimmings,<br />

garden residue.<br />

References:<br />

[1] Environmental Communication Guide,<br />

European Bioplastics, Berlin, Germany,<br />

2012<br />

[2] ISO 14067. Carbon footprint of products -<br />

Requirements and guidelines for quantification<br />

and communication<br />

[3] CEN TR 15932, Plastics - Recommendation<br />

for terminology and characterisation<br />

of biopolymers and bioplastics, 2010<br />

[4] CEN/TS 16137, Plastics - Determination<br />

of bio-based carbon content, 2011<br />

[5] ASTM D6866, Standard Test Methods for<br />

Determining the Biobased Content of<br />

Solid, Liquid, and Gaseous Samples Using<br />

Radiocarbon Analysis<br />

[6] SPI: Understanding Biobased Carbon<br />

Content, 2012<br />

[7] EN 13432, Requirements for packaging<br />

recoverable through composting and biodegradation.<br />

Test scheme and evaluation<br />

criteria for the final acceptance of packaging,<br />

2000<br />

[8] Wikipedia<br />

[9] ISO 14064 Greenhouse gases -- Part 1:<br />

Specification with guidance..., 2006<br />

[10] Terrachoice, 2010, www.terrachoice.com<br />

[11] Thielen, M.: Bioplastics: Basics. Applications.<br />

Markets, Polymedia Publisher,<br />

2012<br />

[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />

FNR, 20<strong>05</strong><br />

[13] de Vos, S.: Improving heat-resistance of<br />

PLA using poly(D-lactide),<br />

bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />

[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />

MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />

[15] ISO 14067 onb Corbon Footprint of<br />

Products<br />

[16] ISO 14021 on Self-declared Environmental<br />

claims<br />

[17] ISO 14044 on Life Cycle Assessment<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 57


Suppliers Guide<br />

1. Raw Materials<br />

AGRANA Starch<br />

Bioplastics<br />

Conrathstraße 7<br />

A-3950 Gmuend, Austria<br />

bioplastics.starch@agrana.com<br />

www.agrana.com<br />

Xinjiang Blue Ridge Tunhe<br />

Polyester Co., Ltd.<br />

No. 316, South Beijing Rd. Changji,<br />

Xinjiang, 831100, P.R.China<br />

Tel.: +86 994 22 90 90 9<br />

Mob: +86 187 99 283 100<br />

chenjianhui@lanshantunhe.com<br />

www.lanshantunhe.com<br />

PBAT & PBS resin supplier<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 510663<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.kingfa.com<br />

39 mm<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

BASF SE<br />

Ludwigshafen, Germany<br />

Tel: +49 621 60-99951<br />

martin.bussmann@basf.com<br />

www.ecovio.com<br />

Gianeco S.r.l.<br />

Via Magenta 57 10128 Torino - Italy<br />

Tel.+390119370420<br />

info@gianeco.com<br />

www.gianeco.com<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel: +66(0) 2 140-3563<br />

MCPP Germany GmbH<br />

+49 (0) 152-018 920 51<br />

frank.steinbrecher@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0) 6 07 22 25 32<br />

fabien.resweber@mcpp-europe.com<br />

Microtec Srl<br />

Via Po’, 53/55<br />

30030, Mellaredo di Pianiga (VE),<br />

Italy<br />

Tel.: +39 041 5190621<br />

Fax.: +39 041 5194765<br />

info@microtecsrl.com<br />

www.biocomp.it<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.jinhuizhaolong.com<br />

ecoworldsales@jinhuigroup.com<br />

Jincheng, Lin‘an, Hangzhou,<br />

Zhejiang 311300, P.R. China<br />

China contact: Grace Jin<br />

mobile: 0086 135 7578 9843<br />

Grace@xinfupharm.comEurope<br />

contact(Belgium): Susan Zhang<br />

mobile: 0032 478 991619<br />

zxh0612@hotmail.com<br />

www.xinfupharm.com<br />

1.1 bio based monomers<br />

1.2 compounds<br />

Cardia Bioplastics<br />

Suite 6, 2<strong>05</strong>-211 Forster Rd<br />

Mt. Waverley, VIC, 3149 Australia<br />

Tel. +61 3 85666800<br />

info@cardiabioplastics.com<br />

www.cardiabioplastics.com<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36065 Mussolente (VI), Italy<br />

Telephone +39 0424 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

BIO-FED<br />

Branch of AKRO-PLASTIC GmbH<br />

BioCampus Cologne<br />

Nattermannallee 1<br />

50829 Cologne, Germany<br />

Tel.: +49 221 88 88 94-00<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

Global Biopolymers Co.,Ltd.<br />

Bioplastics compounds<br />

(PLA+starch;PLA+rubber)<br />

194 Lardproa80 yak 14<br />

Wangthonglang, Bangkok<br />

Thailand 10310<br />

info@globalbiopolymers.com<br />

www.globalbiopolymers.com<br />

Tel +66 81 9150446<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Green Dot Bioplastics<br />

226 Broadway | PO Box #142<br />

Cottonwood Falls, KS 66845, USA<br />

Tel.: +1 620-273-8919<br />

info@greendotholdings.com<br />

www.greendotpure.com<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50016 Zaragoza, Spain<br />

Tel: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

Sukano AG<br />

Chaltenbodenstraße 23<br />

CH-8834 Schindellegi<br />

Tel. +41 44 787 57 77<br />

Fax +41 44 787 57 78<br />

www.sukano.com<br />

58 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


Suppliers Guide<br />

Natureplast – Biopolynov<br />

11 rue François Arago<br />

14123 IFS<br />

Tel: +33 (0)2 31 83 50 87<br />

www.natureplast.eu<br />

TECNARO GmbH<br />

Bustadt 40<br />

D-74360 Ilsfeld. Germany<br />

Tel: +49 (0)7062/97687-0<br />

www.tecnaro.de<br />

1.3 PLA<br />

Total Corbion PLA bv<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem<br />

The Netherlands<br />

Tel.: +31 183 695 695<br />

Fax.: +31 183 695 604<br />

www.total-corbion.com<br />

pla@total-corbion.com<br />

Zhejiang Hisun Biomaterials Co.,Ltd.<br />

No.97 Waisha Rd, Jiaojiang District,<br />

Taizhou City, Zhejiang Province, China<br />

Tel: +86-576-88827723<br />

pla@hisunpharm.com<br />

www.hisunplas.com<br />

1.4 starch-based bioplastics<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

Plásticos Compuestos S.A.<br />

C/ Basters 15<br />

08184 Palau Solità i Plegamans<br />

Barcelona, Spain<br />

Tel. +34 93 863 96 70<br />

info@kompuestos.com<br />

www.kompuestos.com<br />

1.5 PHA<br />

Bio-on S.p.A.<br />

Via Santa Margherita al Colle 10/3<br />

40136 Bologna - ITALY<br />

Tel.: +39 <strong>05</strong>1 392336<br />

info@bio-on.it<br />

www.bio-on.it<br />

Kaneka Belgium N.V.<br />

Nijverheidsstraat 16<br />

2260 Westerlo-Oevel, Belgium<br />

Tel: +32 (0)14 25 78 36<br />

Fax: +32 (0)14 25 78 81<br />

info.biopolymer@kaneka.be<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

1.6 masterbatches<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Albrecht Dinkelaker<br />

Polymer and Product Development<br />

Blumenweg 2<br />

79669 Zell im Wiesental, Germany<br />

Tel.:+49 (0) 7625 91 84 58<br />

info@polyfea2.de<br />

www.caprowax-p.eu<br />

Treffert GmbH & Co. KG<br />

In der Weide 17<br />

55411 Bingen am Rhein; Germany<br />

+49 6721 403 0<br />

www.treffert.eu<br />

Treffert S.A.S.<br />

Rue de la Jontière<br />

57255 Sainte-Marie-aux-Chênes,<br />

France<br />

+33 3 87 31 84 84<br />

www.treffert.fr<br />

2. Additives/Secondary raw materials<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

3. Semi finished products<br />

3.1 films<br />

4. Bioplastics products<br />

Bio-on S.p.A.<br />

Via Santa Margherita al Colle 10/3<br />

40136 Bologna - ITALY<br />

Tel.: +39 <strong>05</strong>1 392336<br />

info@bio-on.it<br />

www.bio-on.it<br />

Bio4Pack GmbH<br />

D-48529 Nordhorn, Germany<br />

Tel.: +49 (0) 5921 818 37 00<br />

info@bio4pack.com<br />

www.bio4pack.com<br />

BeoPlast Besgen GmbH<br />

Bioplastics injection moulding<br />

Industriestraße 64<br />

D-40764 Langenfeld, Germany<br />

Tel. +49 2173 84840-0<br />

info@beoplast.de<br />

www.beoplast.de<br />

INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />

45, 0,90, 0<br />

10, 0, 80,0<br />

(ICBP) C, M, Y, KSDN BHD<br />

C, M, Y, K<br />

50, 0 ,0, 0<br />

0, 0, 0, 0<br />

12, Jalan i-Park SAC 3<br />

Senai Airport City<br />

81400 Senai, Johor, Malaysia<br />

Tel. +60 7 5959 159<br />

marketing@icbp.com.my<br />

www.icbp.com.my<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, COO<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima.com<br />

Natur-Tec ® - Northern Technologies<br />

4201 Woodland Road<br />

Circle Pines, MN 55014 USA<br />

Tel. +1 763.404.8700<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.601<br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

6. Equipment<br />

6.1 Machinery & Molds<br />

Buss AG<br />

Hohenrainstrasse 10<br />

4133 Pratteln / Switzerland<br />

Tel.: +41 61 825 66 00<br />

Fax: +41 61 825 68 58<br />

info@busscorp.com<br />

www.busscorp.com<br />

6.2 Degradability Analyzer<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6155<br />

Fax: +81-54-623-8623<br />

info_fds@saidagroup.jp<br />

www.saidagroup.jp/fds_en/<br />

7. Plant engineering<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4<strong>05</strong>2 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

D-13509 Berlin<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

sales.de@uhde-inventa-fischer.com<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31, CH-7013 Domat/Ems<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

sales.ch@uhde-inventa-fischer.com<br />

www.uhde-inventa-fischer.com<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 59


Suppliers Guide<br />

9. Services<br />

10.2 Universities<br />

10.3 Other Institutions<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

Innovation Consulting Harald Kaeb<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

9. Services (continued)<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

E-Mail: contact@nova-institut.de<br />

www.biobased.eu<br />

Bioplastics Consulting<br />

Tel. +49 2161 664864<br />

info@polymediaconsult.com<br />

10. Institutions<br />

10.1 Associations<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10019, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

10117 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

70199 Stuttgart<br />

Tel +49 711/685-62831<br />

silvia.kliem@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

Michigan State University<br />

Dept. of Chem. Eng & Mat. Sc.<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

lisa.mundzeck@hs-hannover.de<br />

www.ifbb-hannover.de/<br />

GO!PHA<br />

Rick Passenier<br />

Oudebrugsteeg 9<br />

1012JN Amsterdam<br />

The Netherlands<br />

info@gopha.org<br />

www.gopha.org<br />

Green Serendipity<br />

Caroli Buitenhuis<br />

IJburglaan 836<br />

1087 EM Amsterdam<br />

The Netherlands<br />

Tel.: +31 6-24216733<br />

www.greenseredipity.nl<br />

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60 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


1_<strong>05</strong>.2017<br />

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Kuwait Sustainable Development Symposium – <strong>2019</strong><br />

13.10.<strong>2019</strong> - 14.10.<strong>2019</strong> - Kuweit<br />

https://traiconevents.com/sustainable/kuwait/<br />

K <strong>2019</strong><br />

16.10.<strong>2019</strong> - 23.10.<strong>2019</strong> - Duesseldorf, Germany<br />

www.k-online.com<br />

Bioplastics Business Breakfast K‘<strong>2019</strong><br />

17.10.<strong>2019</strong> - 20.10.<strong>2019</strong> - Duesseldorf, Germany<br />

http://www.bioplastics-breakfast.com<br />

SPC Engage:London<br />

23.10.<strong>2019</strong> - 24.10.<strong>2019</strong> - London, Great Britain<br />

https://sustainablepackaging.org/events/spc-engage-london/<br />

WWW.MATERBI.COM<br />

North American Biopolymer Summit <strong>2019</strong><br />

06.11.<strong>2019</strong> - 07.11.<strong>2019</strong> - Chicago,IL,USA<br />

https://www.wplgroup.com/aci/event/biopolymer-summit-usa/<br />

bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />

Basics<br />

Home composting | 44<br />

Highlights<br />

Bottles / Blow Moulding | 10<br />

Biocomposites | 24<br />

r1_<strong>05</strong>.2017<br />

<strong>05</strong>/<strong>05</strong>/17 11:39<br />

Jul / Aug<br />

bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />

04 | <strong>2019</strong><br />

Cover Story<br />

Cove PHA bottles<br />

Preview:<br />

Highlights<br />

Fibers / Textiles / Nonwovens | 16<br />

Barrier Materials | 38<br />

... is read in 92 countries<br />

Sep / Oct<br />

Cover Story<br />

Lightweighting PBAT<br />

based materials<br />

Jinhui Zhaolong<br />

<strong>05</strong> | <strong>2019</strong><br />

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BioPlastEx’<strong>2019</strong><br />

08.11.<strong>2019</strong> - 09.11.<strong>2019</strong> - Bangalore, India<br />

www.BioPlastEx.com<br />

8th Biocomposites Conference Cologne<br />

14.11.<strong>2019</strong> - 15.11.<strong>2019</strong> - Cologne, Germany<br />

www.biocompositescc.com<br />

Frontiers in Polymer Chemistry and Biopolymers<br />

18.11.<strong>2019</strong> - 19.11.<strong>2019</strong> - Rome, Italy<br />

https://www.longdom.com/polymerchemistry<br />

14th European Bioplastics Conference <strong>2019</strong><br />

03.12.<strong>2019</strong> - 04.12.<strong>2019</strong> - Berlin, Germany<br />

https://www.european-bioplastics.org/events/eubp-conference/<br />

4th European Chemistry Partnering<br />

27.02.2020 - Frankfurt, Germany<br />

https://european-chemistry-partnering.com/<br />

<strong>05</strong>/<strong>05</strong>/17 11:39<br />

+<br />

or<br />

Plastics beyond Petroleum-BioMass & Recycling<br />

12.<strong>05</strong>.2020 - 13.<strong>05</strong>.2020 - New York City Area, USA<br />

http://innoplastsolutions.com/conference.html<br />

The Greener Manufacturing Show<br />

16.06.2020 - 17.06.2020 - Cologne, Germany<br />

https://www.greener-manufacturing.com/welcome<br />

Mention the promotion code ‘watch‘ or ‘book‘<br />

and you will get our watch or the book 3)<br />

Bioplastics Basics. Applications. Markets. for free<br />

(new subscribers only)<br />

1) Offer valid until 31 Dec. <strong>2019</strong><br />

3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />

bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14 61


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

Abioplastics 29<br />

Agiplast 30<br />

Agrana Starch Bioplastics 58<br />

AIMPLAS 34, 43<br />

Albis 29<br />

Allied Market Research 7<br />

AMIBM 16<br />

API 58<br />

Arkema 35<br />

BASF 7 58<br />

Beologic 34<br />

BeoPlast Besgen 59<br />

Bio4Pack 48 59<br />

Bio4Self 14<br />

Bio-Fed Branch of Akro-Plastic 58<br />

Biofribre 34<br />

Bio-On 7, 14 59<br />

Biotec 40 59, 63<br />

BPI 60<br />

Braskem 15, 39<br />

Buss 59<br />

CaixaBank 36<br />

Cake 36<br />

Caprowachs, Albrecht Dinkelaker 59<br />

Carbiolice 14, 30<br />

Cardia Bioplastics 58<br />

Corbion 26, 31<br />

Dantoy 15<br />

Dr. BOY 8, 29<br />

Dr. Heinz Gupta Verlag 60<br />

DuPont 42<br />

DWI Leibniz Inst. F. Interactive Mat. 24<br />

Erema 37, 59<br />

European Bioplastics 8, 28, 29 47, 60<br />

Evonik 35<br />

Faculty of Life Scienes, Albst Sigm. 45<br />

Farrel 53<br />

Federal Mogul Powertrian 52<br />

First Mile 6<br />

FKuR 15, 29, 47 2, 58<br />

Fraunhofer IAP 15<br />

Fraunhofer IVV 45<br />

Fraunhofer UMSICHT 60<br />

Furanix Technologies 53<br />

Gema Polimer 31<br />

Gianeco 58<br />

Global Biopolymers 58<br />

Go!PHA 6 60<br />

Grafe 58, 59<br />

Green Chemistry Campus 50<br />

Green Dot Bioplastics 58<br />

Green Serendipity 60<br />

Hexpol TPE 37<br />

ICCI SEA 18<br />

Indochine Bio Plastiques 59<br />

Inst. F. Bioplastics & Biocomposites 60<br />

Institut f. Kunststofftechnik, Stuttgart 60<br />

Institut für Textiltechnik ITA 20, 24<br />

INSTM, Univ. Pisa 45<br />

IRIS Technology Solutions 45<br />

JinHui ZhaoLong High Technology 15 1, 58<br />

Kaneka 8 59<br />

Kartell 15<br />

Kingfa 58<br />

Kompuestos 28 59<br />

Kuraray 42<br />

Lenzing 23<br />

Machinefabriek W. Bakker 22<br />

Messe Düsseldorf 28 28<br />

Michigan State University 60<br />

Microtec 58<br />

Minima Technology 59<br />

Mitr Phol 27 47<br />

Mitsubishi Chemical 8<br />

Modint 16<br />

narocon 8 60<br />

Natural Farm 39<br />

Natureplast-Biopolynov 59<br />

Natur-Tec 59<br />

Nölle Kunststofftechnik 15<br />

Norbert Schmid 34<br />

nova Institute 46 35, 38, 60<br />

Novamont 5, 30, 49 59, 64<br />

Novozymes 14<br />

Nurel 58<br />

Omya 30<br />

Plantic 42<br />

plasticker 49<br />

Polykum 31<br />

polymediaconsult 60<br />

Polymerization Shared Facility 50<br />

ProdTek<br />

PTTMCC 42 58<br />

RIKEN 8<br />

REWIN 50<br />

Saida 59<br />

Saudi Arabian Oil Company 53<br />

Saxon Textile Research Inst. 15<br />

SeaBird 18<br />

Senbis Polymer Innovation 22<br />

Sicomin 5<br />

Simcon 7<br />

SK Chemicals 52<br />

Sukano 34 17, 58<br />

TAIF Group 7<br />

Tecnaro 59<br />

Tepha 53<br />

The Good Stuffing Company 39<br />

TianAn Biopolymer 59<br />

Total 26, 31<br />

Total Corbion PLA 6, 26, 31 33, 59<br />

Treffert 59<br />

Trifilon 36<br />

Uhde Inventa-Fischer 59<br />

United Biopolymers 31<br />

Univ. Stuttgart (IKT) 60<br />

Vaude 35<br />

Vegware 6<br />

Wageningen Univ. 50<br />

Xinjiang Blue Ridge Tunhe Polyester 58<br />

Zeijiang Hisun Biomaterials 58<br />

Zhejiang Hangzhou Xinfu Pharm. 58<br />

Editorial Planner<br />

<strong>2019</strong>/2020<br />

<strong>Issue</strong><br />

Month<br />

Publ.<br />

Date<br />

edit/ad/<br />

Deadline<br />

06/<strong>2019</strong> Nov/Dec 02.12.19 01.11.19 Films/Flexibles/<br />

Bags<br />

Edit. Focus 1 Edit. Focus 2 Basics<br />

Consumer & office<br />

electronics<br />

Multilayer films<br />

Trade-Fair<br />

Specials<br />

K'<strong>2019</strong> Review<br />

01/2020 Jan/Feb 10.02.20 31.12.19 Automotive Foam t.b.c. t.b.c.<br />

02/2020 Mar/Apr 06.04.20 06.03.20 Thermoforming /<br />

Rigid packaging<br />

Additives /<br />

Masterbatches<br />

t.b.c.<br />

interpack preview<br />

Subject to changes<br />

www.bioplasticsmagazine.com<br />

Follow us on twitter!<br />

www.twitter.com/bioplasticsmag<br />

Be our friend on Facebook!<br />

www.facebook.com/bioplasticsmagazine<br />

62 bioplastics MAGAZINE [<strong>05</strong>/19] Vol. 14


MEET US AT THE K<strong>2019</strong><br />

HALL 7 LEVEL 1 / STAND B 21<br />

A COMPLETE RANGE<br />

OF SOLUTIONS.<br />

BIOPLAST®,<br />

INNOVATIVE<br />

SOLUTIONS FOR<br />

EVERYDAY PRODUCTS.<br />

Made from potato starch,<br />

BIOPLAST® resins are<br />

designed to work on<br />

existing standard<br />

equipment for blown<br />

film, flat film, cast<br />

film, injection molded<br />

and thermoformed<br />

components.<br />

100 % biodegradable,<br />

BIOPLAST® is particularly<br />

suitable for ultra-light<br />

films with a thickness of<br />

approx. 10-15 μm.<br />

S002<br />

S002<br />

TRANSPARENT ODORLESS PLASTICIZER<br />

FREE<br />

OK COMPOST<br />

HOME<br />

FOOD-<br />

CONTACT<br />

GRADE<br />

GMO FREE<br />

www.biotec.de<br />

member of the SPHERE<br />

group of companies<br />

LJ Corporate – © JB Mariou – BIOTEC HRA 1183


WWW.MATERBI.COM<br />

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r1_<strong>05</strong>.2017

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