Synthesis, Characterization, and Gas Permeation Properties

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Publications Not Included in the Thesis 1. Synthesis, Characterization, and Gas Permeation Properties of the Silyl Derivatives of Cellulose Acetate Morita, R.; Khan, F. Z.; Sakaguchi, T.; Shiotsuki, M.; Nishio, Y.; Masuda, T. J. Membr. Sci. 2007, 305, 136–145. 2. Synthesis and Properties of Poly(phenylacetylene)s Carrying Siloxy, Hydroxy and Carbonate Groups Saeed, I.; Shida, Y.; Khan, F. Z.; Shiotsuki, M.; Masuda, T. Macromolecules Submitted. 3. Cellulose-Based Organic Radical Battery: Synthesis and Charge/Discharge Properties of Free Radical Carrying Cellulose Derivatives Qu, J.; Khan, F. Z.; Satoh, M.; Wada, J.; Hayashi, H.; Mizoguchi, K.; Masuda, T. Polymer Submitted. 4. Amino- and Carbamate-Substituted Poly(phenylacetylene)s: Synthesis and Properties Saeed, I.; Khan, F. Z.; Shiotsuki, M.; Masuda, T. To be Submitted. 5. Synthesis, Characterization, and Gas Permeation Properties of Amino Acid-Functionalized Ethyl Cellulose Ikeuchi, Y.; Khan, F. Z.; Shiotsuki, M.; Sanda, F.; Nishio, Y.; Masuda, T. To be Submitted. 155
Acknowledgments While submitting this doctoral thesis and looking back at the events which have gone by, I realize that my supervisor, Professor Toshio Masuda earns most of the credit given the fact that he gave me such an amazing research project which brought forth the best in me. His candid advice, suggestions and behavior injected this faith in me that I can surmount such a challenging task. I am indeed indebted to Assistant Professor Masashi Shiotsuki, whom I found exceptionally patient for inculcating the fundamental techniques for my project, which were outstandingly conducive during the research. Associate Professor Fumio Sanda also deserves my heartiest gratitude for his helpful suggestions and enriching discussions. I am also very grateful to all the members of the Masuda research group for their cheerful company and cooperation, whose words have always been a source of encouragement, which kindled my heart and aroused in me the will to make rapid strides. My earnest feelings of reverence are due to Professor Yoshiyuki Nishio without whose valuable suggestions, comments and discussions, I would not have been able to explore multiple dimensions of my research theme. He is the one who accompanied me in making my way through various obstacles which I confronted during the completion of my doctoral degree. I would also like to express my sincere regards for the group members in his lab, especially Mr. Takahiro Ohno, Mr. Dan Aoki, and Mr. Ryosuke Kusumi who made me feel at home by sharing their ideas which developed into an in-depth understanding and knowledge about my research topic. I am highly obligated to Professor Yoshiki Chujo and Professor Shunsaku Kimura for their pragmatic suggestions and enriching comments. One of my seniors, Mr. Toshikazu Sakaguchi, also deserves my heart-felt regards. I thank him for his patience as I always turned to him, at times repeatedly, for the problems I encountered in the initial yet the most stressful stages of my research work. 157
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Synthesis, Characterization, and Ga
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Table of Contents General Introduct
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General Introduction cellulose deri
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General Introduction biogenetically
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General Introduction chemistry offe
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General Introduction solution-diffu
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General Introduction A simplified t
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General Introduction been observed
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polymers. 41,46 General Introductio
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General Introduction Keeping in vie
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General Introduction the derivatize
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General Introduction strategy (G1-a
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General Introduction In conclusion,
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General Introduction 5. (a) Kobayas
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General Introduction 15. (a) Goetma
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General Introduction American Chemi
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General Introduction Macromolecules
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Silylation of Ethyl Cellulose Intro
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Silylation of Ethyl Cellulose milli
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Silylation of Ethyl Cellulose chlor
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Silylation of Ethyl Cellulose Resul
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Silylation of Ethyl Cellulose Solub
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Silylation of Ethyl Cellulose 1.034
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Silylation of Ethyl Cellulose poly(
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Silylation of Ethyl Cellulose the r
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Silylation of Ethyl Cellulose D.; Y
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Chapter 2 51 Chapter 2 Synthesis, C
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53 Chapter 2 are few and far betwee
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55 Chapter 2 constant volume/variab
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57 Chapter 2 Membrane Density. Memb
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59 Chapter 2 IR spectrum of 1 (Figu
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61 Chapter 2 1,3-bis(trifluoromethy
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63 Chapter 2 The increase in the po
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65 Chapter 2 other fluorinated poly
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67 Chapter 2 of the gas permeabilit
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69 Chapter 2 Gas Diffusivity and So
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71 Chapter 2 mobility of the perflu
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73 Chapter 2 1325-1329. (b) Hamza,
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Chapter 3 75 Chapter 3 Synthesis an
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77 Chapter 3 cost, and above all ap
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79 Chapter 3 molecular weights (Mn
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81 Chapter 3 1.99-2.07 (m, 2H, (CH3
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83 Chapter 3 25 °C, ppm): 11.9, 13
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85 Chapter 3 38.1, 44.7, 46.8, 47.9
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87 Chapter 3 CH2CH2C(=O)O), 2.50-4.
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89 Chapter 3 1091, 1053, 853, 806,
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91 Chapter 3 dendrons (G1-a-ІІ-G1
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93 Chapter 3 (DMAP) as a base, as s
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Figure 3. FTIR spectra of 1, 2c, an
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97 Chapter 3 (partly soluble) and 3
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99 Chapter 3 increased polarity of
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101 Chapter 3 that of 1, and approx
Page 105 and 106: 103 Chapter 3 derivatization per th
Page 107 and 108: 105 Chapter 3 (2a-c) were in the or
Page 109 and 110: 107 Chapter 3 2709-2719. (b) Schenn
Page 111 and 112: 109 Chapter 3 17. van Krevelen, D.
Page 113 and 114: Chapter 4 111 Chapter 4 Synthesis,
Page 115 and 116: 113 Chapter 4 Since, no significant
Page 117 and 118: 115 Chapter 4 Materials. Ethyl cell
Page 119 and 120: DStotal = DSEt + DSCarb (for 1a and
Page 121 and 122: 119 Chapter 4 Figure 2. 1 H NMR spe
Page 123 and 124: 121 Chapter 4 ruling out the possib
Page 125 and 126: 123 Chapter 4 t-butyl moiety. A str
Page 127 and 128: 125 Chapter 4 reported to lead to t
Page 129 and 130: 127 Chapter 4 Table 4. Gas Permeabi
Page 131 and 132: 129 Chapter 4 augmentation in eithe
Page 133 and 134: 131 Chapter 4 indicate the signific
Page 135 and 136: 133 Chapter 4 M.-R. J. Appl. Polym.
Page 137 and 138: Chapter 5 135 Chapter5 Synthesis an
Page 139 and 140: 137 Chapter5 acid- and peptide-cont
Page 141 and 142: 139 Chapter5 Specific rotations ([
Page 143 and 144: 141 Chapter5 1.66 (brs, 1.1H, NHCH(
Page 145 and 146: 143 Chapter5 as shown in Scheme 1,
Page 147 and 148: 145 Chapter5 in Table 1. The molecu
Page 149 and 150: 147 Chapter5 almost same pattern of
Page 151 and 152: Conclusions Table 3. Thermal Proper
Page 153 and 154: 151 Chapter5 W.; Jing, X. J. Polym.
Page 155: Chapter 5 Synthesis and Properties
Page 159: Synthesis, Characterization, and Ga
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