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EPP Europe P2.2022

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Bild: Microcare<br />

Particulate contamination comes from the air,<br />

from the abrasion of moving parts, from clothing,<br />

or from dirty, unfiltered etching fluids<br />

(Metal Oxide Semiconductor Field-Effect<br />

Transistors) or other semiconductor components<br />

are immersed in the heated fluid<br />

for cleaning. Often, agitation helps enhance<br />

the cleaning fluid’s effectiveness.<br />

This is done by leveraging the boiling action<br />

of the cleaning fluid, adding vibrating<br />

ultrasonic energy or using a spray<br />

wand to loosen the particulate off the<br />

substrate. Once cleaned, the parts mechanically<br />

transfer to the rinse sump. The<br />

parts rinse in pure, uncontaminated fluid<br />

or inside the fluid vapors themselves. The<br />

components come out cool so they are<br />

immediately ready for use or for the next<br />

stage of processing. Unlike the commoner<br />

aqueous cleaning, vapor degreasing combines<br />

cleaning, rinsing and drying in one<br />

step to maximize takt time. It takes as<br />

little as 6–20 minutes per batch.<br />

Moreover, vapor degreasers typically<br />

have a smaller footprint than aqueous<br />

cleaners. The systems take up less valuable<br />

production space and, because vapor<br />

degreasing cleaning is a simple, predictable<br />

and repeatable process, it is easy to<br />

qualify and validate for cleanroom use.<br />

Good particle displacement<br />

The displacement cleaning fluids used<br />

inside vapor degreasers have chemical<br />

and physical properties that are advantageous<br />

to particle displacement and help<br />

accelerate the cleaning process. Small<br />

particles can be difficult to remove from<br />

wafers since strong electrostatic forces<br />

exist between the particles and the wafer<br />

substrate. A particle adheres to the substrate<br />

through adhesion forces, whether<br />

it is an electrostatic charge or Van der<br />

Waals force. This adhesion creates a friction<br />

force parallel with the surface: static<br />

friction if the particle is not moving, dynamic<br />

friction if it is. To remove the contaminant,<br />

the cleaning fluid must reduce<br />

the thickness of the laminar boundary<br />

layer, break the bond and allow the particles<br />

to release from the substrate.<br />

Some displacement fluids are a mixture<br />

of hydrofluoro-olefin (HFO) and ethanol<br />

that removes fine particulate down to the<br />

micron or even sub-micron range. The alcohol<br />

component forms hydrogen bonds<br />

at the fluid-substrate interface, reducing<br />

the intermolecular forces between the<br />

particle and the substrate. This allows the<br />

particulate to lift more easily from the<br />

substrate.<br />

Plus, the fluorocarbon-based fluids are<br />

synthetically derived, allowing for a<br />

higher purity level than traditional hydrocarbon-based<br />

cleaning fluids. These<br />

ultra-pure fluids dry quickly and completely<br />

without leaving spots or residue<br />

behind.<br />

High density & low viscosity<br />

Particulate displacement fluids are<br />

dense: typically, 20–40% heavier than<br />

water and 50% heavier than alcohol.<br />

They also have a lower viscosity than IPA<br />

(Isopropyl Alcohol), water or water with<br />

surfactant additives. The combination of<br />

the higher density and the lower viscosity<br />

About the author<br />

Elizabeth Norwood is a<br />

Senior Chemist at MicroCare,<br />

which offers precision cleaning<br />

solutions. She has been in<br />

the industry more than 25<br />

years and has a BS in Chemistry<br />

from the University of St.<br />

Joseph. Norwood researches,<br />

develops and tests cleaningrelated<br />

products. She currently<br />

has one patent issued<br />

and two pending for her<br />

work. For more information,<br />

visit www.microcare.com.<br />

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<strong>EPP</strong> <strong>Europe</strong> » 11 | 2022 23

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