Photochemistry and Photophysics of Coordination Compounds

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272 Subject Index Exciplexes 15 Excited-state decay, intramolecular 8 Excited-state distortion 86 Extension cable 28 Fe(III) porphyrin 13 Formaldehyde 3,4 Grids 153 Halide-to-metal charge transfer (XMCT) 70, 102 Intraligand charge transfer (ILCT) 221 Jablonski diagram, [Cr(acac)3] 42 –, light absorption 5 Lanthanide ions, long-lived luminescence 26 LEC devices 99, 100 Ligand-centered (LC) transitions 6, 120, 218 Ligand-to-metal charge-transfer (LMCT) transitions 6, 76 Light absorption 8 Light-initiated time-resolved X-ray absorption spectroscopy (LITR-XAS) 70 Light-powered molecular machines 117 Luminescence 69, 117 Machines, light-powered molecular 117 Marcus inverted region 12 Marcus theory 16 Metal complexes 5 Metal-centered (MC) transitions 6, 120, 217 Metalloproteins, copper 75 Metal-to-ligand charge-transfer (MLCT) transitions 6, 70, 73, 119 4 ′ -Methoxyflavylium ion 29 MLCT excited states 128 –, multiple low-lying, polypyridine ligand 138 Molecular machines, light-powered 117 Molecular wires 24 Multihole storage, photoinduced, mixed Ru–Mn 177 Nanomotor, sunlight-powered 30 Naphthalene 10 Nitric oxide (NO) 60 Nitrido complexes, Cr(III) coordinated azide, photogeneration 61 Nitrido-Cr(V) 62 NO, Cr(III)-coordinated nitrite, photolabilization 60 Nuclear motions, photoactive molecular machines 183 OLED devices 69, 99, 100, 133 Oligophenylene bridges 145 Optical electron transfer 20 Os(II) bipyridine-type complexes 11 9,10-Phenanthrenequinonediimine 241 Phenanthroline 69 Phosphorescence microwave double resonance (PMDR) 221 Photocatalytic processes, supramolecular species 180 Photochemistry, molecular 3 –, supramolecular 12 Photogeneration, hydrogen 180 Photoinduced processes, supramolecular systems 15 Photonuclease 63 Photoracemization, [Ru(bpy)3] 2+ 127 Photoredox 37 Photosubstitution 37, 43 Photosynthesis, Z-scheme 77 Plastocyanin, blue copper site 75 Polyacetylenic bridges 148 Polyads, oligoproline assemblies 170 Polynuclear complexes 215 Polystyrene, multi-ruthenium assemblies 172 POP 95 Porphyrin-Rh(III) conjugates, photoinduced electron transfer 234 Pseudorotaxanes 28 Quantum mechanical theory 19 Racks, Ru(II) 153 Rh(III) complexes, as acceptors in electron transfer reactions 245 –, DNA-mediated long-range electron transfer 245
Subject Index 273 Rh(III) cyclometalated complexes 223 Rh-DNA 248 Rhodium 215 –, complexes, DNA intercalators 241 –, cyclometalated complexes 223 –, homobinuclear complexes 226 –, mononuclear species 218 –, polynuclear/supramolecular species 226 Rhodium polypyridine complexes 215, 218 [Ru(bpy)3] 2+ 120, 123 Ru(II) complexes, tridentate polypyridine ligands 136 Ru(II) dendrimers, luminescent 155 Ru(II) polypyridine complexes 117, 119 –, nonradiative decay 133 Ru(II) racks 154 Ru(II)-Rh(III) polypyridine dyads, photoinduced electron transfer 228 Ru–Os dyads, tridentate ligands 145 Ruthenium 117 –, complexes, biological systems 185 –, species, photoactive multinuclear 153 –, supramolecular photochemistry 141 Solar cells, photoelectrochemical, dye-sensitized 188 –, photoelectrochemical, ruthenium-sensitized 191 State energy levels/conversion 38, 117 Sunlight-powered nanomotor 30 Supramolecular species/sensitizers 12, 180, 193 Tb(III) complexes 95 Thermal excited state relaxation 37 Ultrafast dynamics 37 Wires, molecular 24 XMCT 70, 102 XOR logic gate 29 Zn(II) porphyrin 13
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280 Topics in Current Chemistry Edi
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Photochemistry and Photophysics of
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Volume Editors Prof. Vincenzo Balza
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Topics in Current Chemistry Also Av
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X Preface nation Compounds. The ven
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Contents Photochemistry and Photoph
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