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2.4. BCS THEORY<br />

Using the substitution ξ = x0+<br />

√<br />

2 1+x0 √ , we can write these integrals in<br />

2 2 1+x0 the closed form<br />

√<br />

2<br />

G(ξ) =<br />

(2E(ξ) − K(ξ)) (2.41)<br />

π((1 − ξ)ξ) 1/4<br />

1<br />

N(ξ) =<br />

3 √ ((2ξ − 1)E(ξ) + (1 − ξ)K(ξ)) (2.42)<br />

2((1 − ξ)ξ) 3/4<br />

where K and E are the complete elliptic integrals of the first and second<br />

kind, respectively. They are readily avai<strong>la</strong>ble in most computer algebra<br />

systems.<br />

2.4.5 Results<br />

The BCS theory gives a good qualitative <strong>de</strong>scription of the whole crossover.<br />

In figure 2.7, we show the behavior of the chemical potential µ<br />

and the gap ∆ at zero temperature in the crossover. While for a <strong>de</strong>ep<br />

BCS state with weak interactions the chemical potential coinci<strong>de</strong>s with<br />

the Fermi energy, it <strong>de</strong>creases while crossing the resonance and even<br />

becomes negative on the BEC si<strong>de</strong>, and eventually becomes asymptotically<br />

equal to the binding energy of the molecules. The Fermi edge<br />

washes out, as can be seen in figure 2.8, and once the chemical potential<br />

crosses zero it disappears completely. This illustrates that the pairs are<br />

not governed by the Fermi-Dirac distribution anymore, but follow the<br />

Bose-Einstein statistic and thus can be consi<strong>de</strong>red bosons. The gap,<br />

normally small in superconductors, opens up.<br />

The critical temperature can also be <strong>de</strong>duced from BCS theory,<br />

usually by calcu<strong>la</strong>ting the temperature T ∗ at which the gap vanishes, see<br />

references [65, 66]. This is the dashed curve in figure 2.9. As we already<br />

stated, the pair creation and con<strong>de</strong>nsation do not coinci<strong>de</strong> for strong<br />

interactions [59]. This becomes clear once we are on the BEC si<strong>de</strong> of<br />

the crossover: the molecules exist even at higher temperatures and only<br />

con<strong>de</strong>nse into a BEC below a critical temperature Tc [60]. A simi<strong>la</strong>r<br />

effect is seen in high temperature superconductors and is known as the<br />

pseudogap [67, 68].<br />

This critical temperature was first studied by Nozières and Schmitt-<br />

Rink (NSR) [62]. They realized that the BCS approximation to only take<br />

pairs with zero momentum into account will fail at strong interactions,<br />

and consi<strong>de</strong>red thermal motion of bound molecules. A recent theoretical<br />

calcu<strong>la</strong>tion, which agrees well with NSR, is shown in figure 2.9 together<br />

with experimental measurements. Further studies, which took beyond<br />

35

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