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Conditioning Agents for Hair and Skin

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316<br />

(c)<br />

10 20<br />

Figure 7 Continued.<br />

Jachowicz<br />

C, D, <strong>and</strong> E, designed <strong>for</strong> damaged/dyed, regular, <strong>and</strong> fine hair (42). The data<br />

presented in the figures are consistent with the above-delineated criteria of<br />

per<strong>for</strong>mance. Conditioner C, based on most substantive ingredients, produced<br />

the greatest change in zeta potential of hair <strong>and</strong> also precipitated the thickest<br />

conditioning layer. On the other h<strong>and</strong>, the use of conditioner E resulted in the<br />

least extensive surface modification, as evidenced by a gradual decrease of zeta<br />

potentials during rinsing with the test solution <strong>and</strong> a relatively thin layer of<br />

conditioning agents on the hair surface. Conditioner D showed behavior intermediate<br />

between that of conditioners C <strong>and</strong> E.<br />

DEPA experiments with multiple applications of a conditioner followed by<br />

shampooing can provide in<strong>for</strong>mation about the removability of conditioner<br />

residues from hair <strong>and</strong> can be used <strong>for</strong> the evaluation of buildup parameters.<br />

The results of such an experiment are presented in Figure 8 as plots of zeta<br />

potential, flow rate, <strong>and</strong> conductivity as a function of time. The conditioner<br />

employed in this study was based on substantive components such as bephenyltrimethylammonium<br />

chloride <strong>and</strong> silicone emulsion DC 929 <strong>and</strong> resulted in a<br />

significant modification of hair as reflected by high positive values of zeta potential<br />

<strong>and</strong> a thick, 3.56-)Ltm layer of the conditioning agent. Subsequent shampooing<br />

washed away most of the adsorbed species, lowering the zeta potentials<br />

<strong>and</strong> reducing the thickness of the conditioning layer to 0.71 fim. The data from<br />

this experiment can be used to calculate the extent of removability of conditioning<br />

residues in a shampooing step <strong>and</strong> their buildup as a result of two

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