Química orgánica, 6ta Edición - Francis A. Carey

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RECONOCIMIENTOS xxxiii Carl Bumgardner, North Carolina State University Paul Buonora, University of Scranton Kevin Burgess, Texas A & M University— College Station Sybil K. Burgess, University of North Carolina—Wilmington Magnus Campbell, Lansing Community College Suzanne Carpenter, Armstrong Atlantic State University Jin K. Cha, University of Alabama— Tuscaloosa Jeff Charonnat, California State University—Northridge Dana Chatellier, University of Delaware Clair J. Cheer, San Jose State University John C. Cochran, Colgate University Don Colborn, Missouri Baptist College Rob Coleman, Ohio State University Wheeler Conover, Southeast Community College Wayne B. Counts, Georgia Southwestern State University Brian E. Cox, Cochise College—Sierra Vista Thomas D. Crute, Augusta State University Timothy P. Curran, College of the Holy Cross S. Todd Deal, Georgia Southern University Gary DeBoer, Le Tourneau University Max Deinzer, Oregon State University Leslie A. Dendy, University of New Mexico—Los Alamos Ray Di Martini, NYC Technical College Charles Dickson, Catawba Valley Community College Edward Dix, Assumption College Ajit S. Dixit, A B Technical Community College Marvin Doerr, Clemson University Charles M. Dougherty, Lehman College Veljko Dragojlovic, MST Nova Southeastern University Karen Walte Dunlap, Sierra College Stella Elakovich, University of Southern Mississippi—Hattiesburg Janice Ems-Wilson, Valencia Community College—West Campus Dorothy N. Eseonu, Virginia Union University Michael F. Falcetta, Anderson University Mitchell Fedak, Community College Allegheny County K. Thomas Finley, SUNY—Brockport Jan M. Fleischer, The College of New Jersey Malcolm Forbes, University of North Carolina Laura Lowe Furge, Kalamazoo College Ana M. Gaillat, Greenfield Community College Roy Garvey, North Dakota State University—Fargo Edwin Geels, Dordt College Graeme C. Gerrans, University of Virginia Mary S. Gin, University of Illinois Ted Gish, St. Mary’s College Rainer Glaser, University of Missouri Brett Goldston, North Seattle Community College Manuel Grande, Universidad de Salamanca Gary Gray, University of Minnesota Gamini Gunawardena, Utah Valley State College—Orem Sapna Gupta, Park University—Parkville Frank Guziec, Southwestern University Kevin P. Gwaltney, Bucknell University Christopher Hadad, Ohio State University Midge Hall, Clark State Community College Philip D. Hampton, University of New Mexico—Albuquerque Carol Handy, Portland Community College—Sylvania Ryan Harden, Central Lakes College Kenn Harding, Texas A & M Steve Hardinger, University of California— Los Angeles J. Howard Hargis, Auburn University Sidney Hecht, University of Virginia Carl Heltzel, Transylvania University Alvan Hengge, Utah State University— Logan Reza S. Herati, Southwest Missouri State University James R. Hermanson, Wittenberg University Paul Higgs, Barry University Brian Hill, Bryan College Richard W. Holder, University of New Mexico—Albuquerque Robert W. Holman, Western Kentucky University Gary D. Holmes, Butler County Community College Roger House, Moraine Valley College William C. Hoyt, St. Joseph’s College Jeffrey Hugdahl, Mercer University— Macon Lyle Isaacs, University of Maryland T. Jackson, University of South Alabama— Mobile George F. Jackson, University of Tampa Richard Jarosch, University of Wisconsin— Sheboygan Ronald M. Jarret, College of the Holy Cross George T. Javor, Loma Linda University School of Medicine John Jefferson, Luther College Anton Jensen, Central Michigan University Teresa Johnson, Bevill State Community College—Sumiton Todd M. Johnson, Weber State University Graham Jones, Northeastern University Taylor B. Jones, The Masters College Robert O. Kalbach, Finger Lakes Community College John W. Keller, University of Alaska— Fairbanks Floyd W. Kelly, Casper College Dennis Kevill, Northern Illinois University Tony Kiessling, Wilkes University Charles Kingsbury, University of Nebraska Lynn M. Kirms, Southern Oregon University Susan Klein, Manchester College Beata Knoedler, Springfield College in Illinois Albert C. Kovelesky, Limestone College Lawrence J. Krebaum, Missouri Valley College Paul J. Kropp, University of North Carolina Mahesh K. Lakshman, University of North Dakota www.FreeLibros.com
xxxiv RECONOCIMIENTOS Andrew Langrehr, Jefferson College Elizabeth M. Larson, Grand Canyon University Melanie J. Lesko, Texas A & M University—Galveston Nicholas Leventis, University of Missouri—Rolla Brian Love, East Carolina University John Lowbridge, Madisonville Community College Rachel Lum, Regis University Raymond Lutz, Portland State University Elahe Mahdavian, South Carolina State University William Mancini, Paradise Valley Community College Alan P. Marchand, University of North Texas David F. Maynard, California State University—San Bernardino John McCormick, University of Missouri— Columbia Alison McCurdy, Harvey Mudd College Nancy McDonald, Athens State University Michael B. McGinnis, Georgia College and State University Harold T. McKone, St. Joseph College Ed McNelis, New York Univesity Tyler D. McQuade, Cornell University Jerrold Meinwald, Cornell University David Mendenhall, Michigan Technology University K. Troy Milliken, Broward Community College—North Qui-chee Mir, Pierce College—Puyallup Anthony A. Molinero, State University College—Potsdam SUNY Gary Mong, Columbia Basin College Cary Morrow, University of New Mexico Mel Mosher, Missouri Southern College Richard Musgrave, St. Petersburg Junior College—St. Petersburg Jennifer Muzyka, Centre College of Kentucky David Myers, Simons Rock College Richard Narske, Augustana College Thomas A. Newton, University of Southern Maine—Portland Maria Ngu-Schwe, Southern University— Baton Rouge Olivier Nicaise, St. Louis University Bradley Norwood, Coastal Carolina University George O’Doherty, University of Minnesota Thomas O’Hare, Willamette University Kimberly A. Opperman, Erskine College Oladayo Oyelola, Lane College Anne Padias, University of Arizona Michael J. Panigot, Arkansas State University E. P. Papadopoulos, University of New Mexico—Albuquerque Edward J. Parish, Auburn University— Auburn Cyril Parkanyi, Florida Atlantic University—Boca Raton G. Anthony Parker, Seton Hill/St. Vincent’s College Abby Parrill, University of Memphis Gitendra Paul, Ohio University—Athens Donald R. Paulson, California State University—Los Angeles David Peitz, Wayne State College Thomas C. Pentecost, Aims Community College—Main Campus Phillip J. Persichini III, University of Minnesota—Duluth Gary O. Pierson, Central State University Suzette Polson, Kentucky State University Steve Pruett, Jefferson Community College Ann Randolph, Rosemont College Casey Raymond, Kent State University Preston Reeves, Texas Lutheran College Jill Rehmann, St. Joseph’s College Thomas Reitz, Bradford College Mitchell A. Rhea, Pensacola Junior College Stacia Rink, Pacific Lutheran University Randall E. Robinson, Luther College Harold R. Rogers, California State University—Fullerton Ellen Roskes, Villa Julie College Thomas Russo, Jacksonville University Thomas Ruttledge, Ursinus College Vyacheslav V. Samoshin, University of the Pacific Susan M. Schelble, University of Colorado—Denver Judith E. Schneider, SUNY—Oswego Keith Schray, Lehigh University Allen J. Scism, Central Missouri State University John Searle, College of San Mateo Alexander Seed, Kent State University William R. Shay, University of North Dakota Dale F. Shellhamer, Point Loma University Angela Rap Sherman, College of Notre Dame of Maryland Barry R. Sickles, Durham Technical Community College Jack Sidler, Mansfield University Steven B. Silbering, CUNY York College Phil Silberman, Scottsdale Community College Eric E. Simanek, Texas A & M University—College Station Carmen M. Simone, Casper College Bradley Smith, University of Notre Dame Cynthia Somers, Red Rocks Community College Melinda M. Sorenson, University of Louisiana—Lafayette Tami Spector, University of San <strong>Francis</strong>co Gary O. Spessard, St. Olaf College Richard Steiner, University of Utah—Salt Lake City James D. Stickler, Allegheny College of Maryland Heinz Stucki, Kent State University Sam Subramania, Miles College Sam Sun, Norfolk State University Paris Svoronos, Queensborough Community College Erach R. Talaty, Wichita State University Jamal Tayh, Scott Community College— Bettendorf Richard T. Taylor, Miami University— Oxford Stephen S. Templin, Cardinal Stritch University Patricia C. Thorstenson, University of the District of Columbia Tammy Tiner, Texas A & M University Tony Toste, Southwest Missouri State University Denise Tridle, Highland Community College Eric Trump, Emporia State University F. Warren Villaescusa, Our Lady of the Lake University www.FreeLibros.com
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Page 7 and 8: Director Higher Education: Miguel
Page 11 and 12: CONTENIDO Lista de presentaciones i
Page 13 and 14: xii CONTENIDO CAPÍTULO 5 ESTRUCTUR
Page 15 and 16: xiv CONTENIDO 10.7 Estabilidades re
Page 17 and 18: xvi CONTENIDO CAPÍTULO 15 ALCOHOLE
Page 19 and 20: xviii CONTENIDO 20.13 Amidas 869 20
Page 21 and 22: xx CONTENIDO 26.4 Fosfolípidos 108
Page 23 and 24: LISTA DE PRESENTACIONES IMPORTANTES
Page 25 and 26: xxiv LISTA DE PRESENTACIONES IMPORT
Page 27 and 28: xxvi LISTA DE PRESENTACIONES IMPORT
Page 29 and 30: 10.1 EL GRUPO ALILO . . . . . . . .
Page 31 and 32: xxx PREFACIO p g p p En la figura 2
Page 33: xxxii RECONOCIMIENTOS Akira Kawamur
Page 39 and 40: Introducción La raíz de toda la c
Page 41 and 42: 4 Introducción En una estampilla a
Page 43 and 44: 6 Introducción fármacos, plástic
Page 45 and 46: La estructura determina las propied
Page 47 and 48: 10 CAPÍTULO UNO La estructura dete
Page 73 and 74: H H 36 CAPÍTULO UNO La estructura
Page 81 and 82: H H 44 CAPÍTULO UNO La estructura
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48 CAPÍTULO UNO La estructura dete
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Estructura de hidrocarburos. Alcano
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62 CAPÍTULO DOS Estructura de hidr
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100 CAPÍTULO DOS Estructura de hid
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Conformaciones de alcanos y cicloal
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108 CAPÍTULO TRES Conformaciones d
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H W N 134 CAPÍTULO TRES Conformaci
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Alcoholes y halogenuros de alquilo
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146 CAPÍTULO CUATRO Alcoholes y ha
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Estructura y preparación de alquen
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192 CAPÍTULO CINCO Estructura y pr
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Reacciones de los alquenos: reaccio
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236 CAPÍTULO SEIS Reacciones de lo
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O O O 268 CAPÍTULO SEIS Reaccion
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Estereoquímica Esbozo del capítul
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288 CAPÍTULO SIETE Estereoquímica
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Sustitución nucleofílica Esbozo d
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332 CAPÍTULO OCHO Sustitución nuc
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Alquinos Esbozo del capítulo 9.1 F
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370 CAPÍTULO NUEVE Alquinos materi
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372 CAPÍTULO NUEVE Alquinos FIGURA
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Vea, por ejemplo, la distancia del
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376 CAPÍTULO NUEVE Alquinos drocar
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378 CAPÍTULO NUEVE Alquinos A cont
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380 CAPÍTULO NUEVE Alquinos PROBLE
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382 CAPÍTULO NUEVE Alquinos El hec
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384 CAPÍTULO NUEVE Alquinos te de
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386 CAPÍTULO NUEVE Alquinos El bro
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388 CAPÍTULO NUEVE Alquinos O HC C
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390 CAPÍTULO NUEVE Alquinos TABLA
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392 CAPÍTULO NUEVE Alquinos TABLA
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394 CAPÍTULO NUEVE Alquinos h) Clo
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396 CAPÍTULO NUEVE Alquinos 9.35 E
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Conjugación en alcadienos y sistem
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400 CAPÍTULO DIEZ Conjugación en
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H H O 404 CAPÍTULO DIEZ Conjugaci
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Arenos y aromaticidad Esbozo del ca
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434 CAPÍTULO ONCE Arenos y aromati
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Sección 11.11 Un ejemplo de una re
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Reacciones de arenos: sustitución
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484 CAPÍTULO DOCE Reacciones de ar
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Espectroscopia Esbozo del capítulo
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530 CAPÍTULO TRECE Espectroscopia
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± 562 CAPÍTULO TRECE Espectroscop
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Transmitancia (%) Transmitancia (%)
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Transmitancia (%) 570 CAPÍTULO TRE
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Compuestos organometálicos Esbozo
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590 CAPÍTULO CATORCE Compuestos or
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P 608 CAPÍTULO CATORCE Compuestos
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Alcoholes, dioles y tioles Esbozo d
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634 CAPÍTULO QUINCE Alcoholes, dio
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Éteres, epóxidos y sulfuros Esboz
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676 CAPÍTULO DIECISÉIS Éteres, e
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Aldehídos y cetonas: adición nucl
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714 CAPÍTULO DIECISIETE Aldehídos
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Transmitancia (%) 750 CAPÍTULO DIE
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Enoles y enolatos Esbozo del capít
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766 CAPÍTULO DIECIOCHO Enoles y en
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H± H± ` ` ` H± ` H± ` 770 CAPÍ
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OH 788 CAPÍTULO DIECIOCHO Enoles y
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Ácidos carboxílicos Esbozo del ca
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806 CAPÍTULO DIECINUEVE Ácidos ca
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´ ´ 828 CAPÍTULO DIECINUEVE Áci
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842 Derivados de los ácidos carbox
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844 CAPÍTULO VEINTE Derivados de l
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HO 864 CAPÍTULO VEINTE Derivados
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Enolatos de éster Esbozo del capí
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896 CAPÍTULO VEINTIUNO Enolatos de
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Aminas Esbozo del capítulo 22.1 NO
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922 CAPÍTULO VEINTIDÓS Aminas vit
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924 CAPÍTULO VEINTIDÓS Aminas CH
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926 CAPÍTULO VEINTIDÓS Aminas En
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928 CAPÍTULO VEINTIDÓS Aminas TAB
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930 CAPÍTULO VEINTIDÓS Aminas La
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932 CAPÍTULO VEINTIDÓS Aminas Las
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934 CAPÍTULO VEINTIDÓS Aminas 22.
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946 CAPÍTULO VEINTIDÓS Aminas CH
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950 CAPÍTULO VEINTIDÓS Aminas Al
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952 CAPÍTULO VEINTIDÓS Aminas Ya
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956 CAPÍTULO VEINTIDÓS Aminas A l
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958 CAPÍTULO VEINTIDÓS Aminas De
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960 CAPÍTULO VEINTIDÓS Aminas FIG
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962 CAPÍTULO VEINTIDÓS Aminas ami
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976 CAPÍTULO VEINTIDÓS Aminas Com
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Halogenuros de arilo Esbozo del cap
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980 CAPÍTULO VEINTITRÉS Halogenur
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1000 CAPÍTULO VEINTITRÉS Halogenu
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1002 CAPÍTULO VEINTITRÉS Halogenu
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Fenoles Esbozo del capítulo 24.1 N
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1006 CAPÍTULO VEINTICUATRO Fenoles
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Transmitancia (%) CH 3 CH 3 CH 3 10
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Transmitancia (%) 1036 CAPÍTULO VE
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Carbohidratos Esbozo del capítulo
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1040 CAPÍTULO VEINTICINCO Carbohid
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www.FreeLibros.com H CHO OH HO CHO
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Lípidos Esbozo del capítulo 26.1
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1082 CAPÍTULO VEINTISÉIS Lípidos
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1124 CAPÍTULO VEINTISIETE Aminoác
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Nucleósidos, nucleótidos y ácido
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1180 CAPÍTULO VEINTIOCHO Nucleósi
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U A U U A A U A 1200 CAPÍTULO VEIN
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1218 CAPÍTULO VEINTINUEVE Polímer
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± ± 1230 CAPÍTULO VEINTINUEVE Po
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H± 1234 CAPÍTULO VEINTINUEVE Pol
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A-2 APÉNDICE 1 TABLA A Propiedades
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A-4 APÉNDICE 1 TABLA C Propiedades
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A-6 APÉNDICE 1 TABLA E Propiedades
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APÉNDICE 2 RESPUESTAS A LOS PROBLE
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A-10 APÉNDICE 2 d) Ambas estructur
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A-12 APÉNDICE 2 2.13 9O 2 6CO 2
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A-14 APÉNDICE 2 4.6 El enlace carb
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A-16 APÉNDICE 2 CH 3 (CH 2 ) 7 (CH
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A-18 APÉNDICE 2 CAPÍTULO 6 6.1 2-
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A-20 APÉNDICE 2 CH 3 CH 3 CH 3 CH
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A-22 APÉNDICE 2 c) H 2 C CH H NH
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A-24 APÉNDICE 2 10.5 El 2,3,3-trim
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A-26 APÉNDICE 2 11.11 C C C 11.
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A-28 APÉNDICE 2 12.3 H 3 C H 3 C S
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A-30 APÉNDICE 2 H SO 3 H H SO 3 H
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A-32 APÉNDICE 2 14.8 b) CH 3 MgI
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A-34 APÉNDICE 2 15.11 O 2 NOCH 2 C
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A-36 APÉNDICE 2 17.7 H 2 C CC N CH
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A-38 APÉNDICE 2 CH 2 17.16 b) CH 3
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A-40 APÉNDICE 2 18.11 La conjugaci
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A-42 APÉNDICE 2 c) C 6 H 5 CHCO 2
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A-44 APÉNDICE 2 Paso 4: Protonaci
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A-46 APÉNDICE 2 Paso 6: Procesos d
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A-48 APÉNDICE 2 21.6 b) C 6 H 5 CH
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A-50 APÉNDICE 2 22.11 La isobutila
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A-52 APÉNDICE 2 23.7 N Cl NH 3 C
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A-54 APÉNDICE 2 25.8 67% , 33% CH
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A-56 APÉNDICE 2 26.8 O CO 2 H CH 3
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A-58 APÉNDICE 2 27.8 O O OH OH H 2
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A-60 APÉNDICE 2 27.20 Una O-acilis
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A-62 APÉNDICE 2 28.9 O NH 2 N N N
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G-2 GLOSARIO Adición 1,4 (sección
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G-4 GLOSARIO Areno (sección 2.1):
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G-6 GLOSARIO Cianohidrina (sección
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G-8 GLOSARIO Deshidratación (secci
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G-10 GLOSARIO Enlace peptídico (se
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G-12 GLOSARIO Genoma (sección 28.7
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G-14 GLOSARIO intermediarios en la
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G-16 GLOSARIO en el que están unid
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G-18 GLOSARIO Polipéptido (secció
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G-20 GLOSARIO distribución electr
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G-22 GLOSARIO estereoisómero treo
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C-2 CRÉDITOS CAPÍTULO 25 25.6: ©
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I-2 Índice Ácido fosfórico catal
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I-4 Índice espectros de infrarrojo
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I-8 Índice Catalizador de Ziegler-
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I-10 Índice Complejo activado, 111
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I-12 Índice 3,3-Dimetil-2-butanol
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I-14 Índice Epímeros, 1068 Epinef
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I-16 Índice reacción con epóxido
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I-18 Índice enlaces en, 149-150 na
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I-20 Índice cantidad, 73 ceto-enó
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I-22 Índice 2-Metil-2-propanol, 15
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I-24 Índice Picrocrocina, 1113 hid
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I-26 Índice Reacciones de sustituc
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I-28 Índice reacciones S N 2, 339-
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ELEMENTOS DE TRANSICIÓN ELEMENTOS
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C-2 a) b) c) d) FIGURA 1.6 Modelos
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C-4 FIGURA 2.4 Representación del
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C-6 FIGURA 4.5 Puentes de hidrógen
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C-8 2p a) b) c) d) FIGURA 10.1 En
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C-10 Electronegatividad 4.0 3.0 2.0
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C-12 FIGURA 17.9 Mapa del potencial
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C-16 Aminoácidos con cadenas later
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C-18 FIGURA 27.19 Grupo hem, repres
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U A U U A A U A C-20 3 O OCCHCH 2 C
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Química orgánica, 6ta Edición - Francis A. Carey

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