SON(rcHEMICAI, SYNIIIISIS AIID CIIARACTERIZATION OF PR.ECT ...

ise2o: Fou ptube le$ enp. Pbh. I & 4 ca..y cuMr (D 2 ed I s5
ncs6 voltrsc (!)
Fi8@ 21: Sch.matic vi.w &d bl@k di.gm of a TGA-FTIR syscD 57
Figw 22: Thc fig@ illuFarg [ow rh. coppd/gold p.n.fu lNw fonncd 94
Figuc23: SometrAical coppo/goldpauem plared @rmic sub$rate 95
Figr24: UAACVD S.t-Up fortni! nlndAosition 96
FigN 25: Sch4Etic di.g@ of T{o Prcbe r.!rin8 €hmbd fo. 98
Fsis&ne n swDdr
FiSw 26: Pi.iorial yiev of .sfubty us.d ro snrdy gs ssing prop.fiy lO0
ofthin fird
Fis@ 27r The srmcrdc uir oI tcu(dmaexoAc)(Hro)l: shoMnS tnc I 12
ld€lin8 ehmc used in ihe tqi ed ta!l€$ .romic
dirpla@i. @ at tb. l0% Iaet
figw28: Th. Istrice srere of tcu(dm&xoAcxHror, sbowing ll!
dinenc uil! linLing rtrougn bridging acdsL goups dd a
nelwort of H- bon b io fom polymqic Elrcrk
Figw 29: Crysl'l ss.r@ of tzn(&&)r(eE. Thmd .ltipeids @ I 14
dtah sr l[. 5070 Ip€I, hydrogd aron sphds e.r dbitnry
iadii. Only th. najor dierd.Ed Doidid e shom
Fige3o: Moleulu structe of [dt@)Zdl llE
Fi8@31: Th. @-plae Mrc of rh€ Z!4Ot rirg with iodirc llons ll8
dispoed i! a ,rar-l|r.@r ,mss rhe nng
FiglE 32: Th. aroD nhbcrine sLd. of c@pLx,lz(!@)r(dn&H)1. l2l
dirpl@md( cllipeid. e drah at ln. 5el. probalitity l*l
Fisel3i Th. cry$al-p&kins dia€m of[zn(a.acL(dh&H)]. Hydrcg.n 122
bonds @ snoM d doied lid6
FiguF 34: Motcculr slncruF of (zr,O{d@)r(OAc)rd sho*ils Oc 124
atom nmber sh.me
Fisft 35: Thc .sFsadc ujr of tz(&&)r(H1o)zlct showin8 the t27
lab.li.e shd. Lred in th. t xr .!d r.bt6; .lomic
displgm@l' e d llc 3d,i ld.t
trsue36: Ilr lsie srucni€ of lzie(rrrHpDlcl showins wirs D8
Iinlirg rhrcugh lrinucded chlorim arom ed a nen@* ofH-