SON(rcHEMICAI, SYNIIIISIS AIID CIIARACTERIZATION OF PR.ECT ...

tntrcdtcrion Ut 4CvD Tecluiq,et
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Bddging,It Bridging,Fl
I! sh tt?. oftddgi!& bond ldglhs vary i! thc oda M4R l.minsl < M+roR < M-
ll!.OR. IlEe stlucts @ So.nlly r.t incd in non-pold oredic nedi6, In this way ii
hs lhe prcbability of lirking two or th@ n rlb in th. fod of oligonaic uirs$nr
rnd lLB hclp€ in &sigirs of hmo or hcr.o nulti@mopoiot shsre $ue p@lN6.
Mctal alkoxid6 M(OR)" @l .$ily wiih th. poroB of 6 lsse vdi.ty or holrculcs
.r!.cially with doior tunctionNliad al@hol &d l!3 6y ch.@cal nodification e
Drd. pcsibl. to &him lurlblc pbFni"s ofotg&ic hydmty ddivativa $itabL for
cvD.
In e atr€mF to obtain solublc nick l dkoxidc conPl*es. do@r nmdoDiiad olkoxid.
gmup6, sEh s diD.lhyl@ilo-isopropoxid. [OCH{M.)CH:NMo] h.v. b*n uriliFd.
but th. Grhiig producl b e iElpaobl. nix$s of tNi(OCH(Me)CHrNM.rhl sd
tL(PdOrDN(OCH(Me)cs?NMo)Cll:.rrs 9-diketonatoalkoxidB of Ni(ll), such as
tNia(OMeXP{iL).(Mcor0d h!rc al$ ben synth.sisd,'" but thee 4 iruolublc jn
Simibdy polldoric Cu(ll) .lkoxid6 ICu(OR)rl"
(R = Mq Pr, Bu), show such hehav,or
in which alohot dcbesc @ns giv. iMluble @pp.(lD 2'naloxvdhond.
tcq(rctloMcL} wt.6 mimal*orftL of @prq lik tc(ocr&NMe?rl is a
nononr, volatle ed $lublc. Coppq (U) dkoxides a.c nad€ sohbl. bv sing
.ll@xlrl@hols wilh E add,lion! O{onor sic (ltoc?HaOCTH.OM€) or siih a lonsa
.r.bonchlinfo.lhcctt .6lchi?vcd*ilh'BuOC2ILOH-
Aninoal@hol r!!€*nts &othq clss ofdlcohoh us.d to . ld€e qi41 in Fent cvD
.rd sl-get prce$ilg- Vriou elheoldiB hNe als b@n u.d $ a meds lo
inDoE bicdEEtue of co.ri!gs.'{ Mdd minodl@hol.ta h.w b.cn inre$iElt
studi.d ed h.v. @i!ed incsing andto! d@ to thcir role for th. srnthBis of
hore dd h.r.o'mebllic mimal@holat DFusoB rlhs for chdical vapou
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