SON(rcHEMICAI, SYNIIIISIS AIID CIIARACTERIZATION OF PR.ECT ...

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u&E taxltclE3 arlPrmttt! in ! p.rticdate .n@ hdiu Thu!, cavilation sfles as ! n.8 of @MDl[tils lle difta. *rsy of soud irto a uiqE s.t ofoiditi@ to ptodu.. unaul m!&ri.h toD diselv.d (&d gcmnlly voldil.) $lurion oerso.t ltic p|qrsor'. B06, @LLpo. of d@ bub6Ls &d @stic wit lioE Focss duirg dtrmic .n!&cc ttc cL@iclt pr.€s i! vti.ty of chmicd licl& i €. inorlllic,r*' orsdic sy hesir,z'5 polFaeriatiorLta ald clcci.och€bisi.l'Jr .t ldge *dc &d dbo plays 6 iEponut reI. in prcpdilg th. *id. iang€ of dgsoD€tallic c@!ol|!d! invobirg @{rdiD.& @npldir8 p.niculdly th* of Mg, c'! Ni. &d !.i@l t6Biti@ rrds ar l4 rdrpd.nN ulda ubre .n with his! Pd@n tteld od in shon rinc thd @nvdtioMl m.tbo
Lilc wir !Fta! lelyla@ioe| @nplq6 lwtr wilb .ltali n rds sdochcni.dly dd sivc @tivc m.bl sp@is (M) ..g., Ro.tivc ri.!.| pDducld ton ulrMic dcrio! of niclcl ectyl&aonare ud sodjb, tuE in situ wiih 1,5 cycloFnradi.nc (COD) |o yicld NdcoD),.rr r(adc) + f& -\ Ni JF(Q" ln @nvdlioml synlhesis pN€dw rcLl sbonyl 6mplex6 e @$ibl. by this p$.de tom tosilion belal hdidca, edju .rd clrbon nonoxid., bul rht r.actio. Gquird t mp@turc of 10G300"C u&r high pelsue. den who uing frcshly pepded tuckds mciab, 'Ihe e of sn@h.misrry f&ilirab the ductior st€ps to yGld the €quir€d prod@t udq mitd .onditioB.s *,^, Ni.co.(l be). ))). THf. lOC .,, .^w(r. -.-" ; i*".-i j j:r-: j--:' w,(cutl .,^.__. Na. CO. (4.4 bdl. l,). THr. tOC vc|Jfiftr) _ j:==lidtYt6H:: j-r:-:+ v(.o)6 MocL -4-4919+ Mo,(co),o' Anothd linph orSrdotuelallic @lioa dhibiling hdl@d ihpDv€nent undd snicaiion i.e. B&bicr Ea.iioq ihc couplins of b€trzdd.hy& dd l-brcmoh@tan in thc pescncc of Li givs 90% prcd@t by enication.t 50 lllz in 25 milut€ ed ody 8vc prcdud .n r ? hoN !r Mn t.hpcr.lw Mrhorn sicai@.'' 1.3 SotrochembtryEquipocois A vsicty of rldi6 bavc bea u!.d for ultenic ilEdiatior of $luriod. Th.E @ lne gdcal d6igB in N pres y: tbe ultlloijc ddine ba ! the tErducqn ad ultsodc pbb., Th. ulirenic dtuins bath is cl.dly thc nost essible s@ of labo8tory ult@ud ed h4 ber ued su@$iirlly in prsent ludies for ue stnthess of neialorsdic complqcs, So w. willdieB iri worLing in dclailheF.
Page 1 and 2: SON(rcHEMICAI, SYNIIIISIS AIID CIIA
Page 3 and 4: DECI,/\NATION I i! crd6d |h.[ li..n
Page 5 and 6: ACKNOWLEDGEMENTS It b my piivilcge
Page 7 and 8: LIST OF CONTENTS CHAPTER-I: INTRODU
Page 9 and 10: 1.9,1 Themognvimereric ealysis (TcA
Page 11 and 12: Fi8u! ll: Iigurc 13: ligw 18: LIST
Page 13 and 14: Fige 3E: Fi$e 4l: FiSuc 50: FiSuF 5
Page 15 and 16: Table 2l Tablc I l: Table l2: Tdble
Page 17 and 18: LIST OF ABBREVIATIONS 2.4-p. &di@L
Page 19 and 20: Chapter I
Page 21 and 22: IltoduriN Stuxhatittry a ot€ c./c
Page 23 and 24: HolmFvadleont-Witiig @ctio! bcilrr!
Page 25: 1.2 SonochemicalSynth€sis To expl
Page 29 and 30: 1.4 Cerrmic Msterirl$ Cmic hatcials
Page 31 and 32: 1.4.1 Ccr|nic Cortiry As A Grs S.No
Page 33 and 34: TiO! hdt d al l000ec to 150 M or 50
Page 35 and 36: httro.lutiN Stuize Metwiw E"in 5o/o
Page 37 and 38: Setechon of Lisand. Jot UAACVD noE
Page 39 and 40: R3 L-2 -l .L ,K * \i!\c' J: d Mh ch
Page 41 and 42: UlUCYD f.chniaws d*tib.d th. prtp.n
Page 43 and 44: UtaCYDTahnl sMicd- In additioo th.y
Page 45 and 46: x-my e.bstu of Ni(acac)r B! irdicar
Page 47 and 48: ltuodurion UMcvDTechmqres I!'fr!r.d
Page 49 and 50: lnto.lutiu U.IACVD Tatuioues 'ft. c
Page 51 and 52: dcposilion to fm .cmic oxides, md 6
Page 53 and 54: elubiliry of $-dit€lomles or alto
Page 55 and 56: ROH + R'COjH + RCO^'+ HO n!. rc&tio
Page 57 and 58: UAACvDI!.httS!3! McLl .&on&! i! d!.
Page 59 and 60: C\'D b nom.lly pqfom.d in a low prs
Page 61 and 62: I {a. bbl&.€b,H -fL-) l- Flg@ 9 H
Page 63 and 64: Il.tr=H.(l-d) Prctusor CtuKl.tizati
Page 65 and 66: Figurc 12: Mol.cul& strmr@ of tpd(C
Page 67 and 68: 1.8 Tbin Film Chracteriation, Struc
Page 69 and 70: O@ of th. gMtcsr str.qlhs of th. SE
Page 71 and 72: Tlbh! 2 Po*ddx-E cry3hl dah of $c d
Page 73 and 74: El ecnical resbtate ne8neke its Des
Page 75 and 76: 1.9 Thermal Studies T1| sreup oftec
Page 77 and 78:
I! wpl6 @ heLd st a givd Latirg hrc
Page 79 and 80:
Chaltqja':3t prcpose d iethemal ner
Page 81 and 82:
su.d a !@tsBi!s r*lio! *l@ ! @tad,
Page 83 and 84:
obtai&d.'rr Irl ldvet g6 i5 itat it
Page 85 and 86:
o la@ wU Mth orha licBnre !du6. How
Page 87 and 88:
polycdbonales eith s@ succes. IlE e
Page 89 and 90:
REFERENCES l. Sul'ck, K. S.i CM,L.
Page 91 and 92:
2E, 29. 30, 31. 12. 14. 35. 36. 37.
Page 93 and 94:
Relerenees 62. Modien, R S. ".S'i.,
Page 95 and 96:
94. Tmg., L. M.; PJchsn, D, S,; M!.
Page 97 and 98:
137 , Chedla, D, C.r Ro8er, C.; HMp
Page 99 and 100:
n824-6826. Retqqces l6t. D@o4 C. B.
Page 101 and 102:
Grovth 20{5,280,495. r93. Piffi\ H.
Page 103 and 104:
227. Fbm, J. H,W.ll L. A. J X.r. ,V
Page 105 and 106:
Etp.ritudol 2.0 EXPERIMENTALDETAILS
Page 107 and 108:
t x^ *x ;t x* E9 iE sq *s Fg -a -d
Page 109 and 110:
? a E E I t $ FA ie lir x I s d, I
Page 111 and 112:
x o 9. I 'n i J* 6 5!F F3 3U :s efi
Page 113 and 114:
sinale .rtstal tat mdltsls Efr€d
Page 115 and 116:
Eq{nM a! Patu^ PIdn$ On Cc@nat Usio
Page 117 and 118:
lhin Filn D.pos|ld (uAAcvD) gs dd @
Page 119 and 120:
Elecri.al rcskt@e @at T.bl.F 5 Raut
Page 121 and 122:
REFERENCES L Sicms, SMART ud SAINT-
Page 123 and 124:
3.0 RESULTS & DISCUSSION 3.1 CoDptr
Page 125 and 126:
3.1 lR Studies So@ iblolldr R .tcor
Page 127 and 128:
D@bcad rinB of dm&H app.s at 2953-2
Page 129 and 130:
3,2 rH NMR rd '3c NMR srudie! The r
Page 131 and 132:
e E i9 F I I 90 90 -t v 3 I66 t60 N
Page 133 and 134:
o(5>c(7) |.23T2) o(r){d2)'N( D 85.3
Page 135 and 136:
Clrstal St tct0e,1tubB FiS!rc 2E. T
Page 137 and 138:
Cryttal Stuaue ,tmlts\ All hydregd
Page 139 and 140:
Fisrn 30: MolRuld sEuc@ of CroHiLNa
Page 141 and 142:
T.bler- t4 Bond lcnglhs [A] I-Zb h4
Page 143 and 144:
Cryttal Snudwe Atulysis ch.lat€ r
Page 145 and 146:
Cryttal Snudu. Awlrsx b.id8! th. Z!
Page 147 and 148:
ZtA-412 7,nr.421 02 {l o3-{t Ol--2n
Page 149 and 150:
Cry$al 9rctw. lwDtit Thc ov@ll latt
Page 151 and 152:
3.4 Tbermal Studies 3.4.1 Th€rnrl
Page 153 and 154:
SiDjl&lr, b!..d on 16r \ulrc r.mper
Page 155 and 156:
obsw€d rhis tT€ of d€Fndercy
Page 157 and 158:
f n s I z d ,E I ,5 .! 3 a 8 n 5 t
Page 159 and 160:
Howvd hic}lc! h€arins hle.tin the
Page 161 and 162:
addition to CHr stretching, dcforui
Page 163 and 164:
cru+-ctt,CU { c!+ HocHrcllr,l{ct!,
Page 165 and 166:
It is tunabl€ 10 believe rhd rh.
Page 167 and 168:
I I E Flgurc {6: ITIR srBrrum of a)
Page 169 and 170:
3.5 Thin Film Chractedzation 3.5.1
Page 171 and 172:
Flsurc52: SEM images oiSn doped /sd
Page 173 and 174:
3.5.1 XRD Studie! )
Page 175 and 176:
* I n * i J ,i l z-I-l-;' _ Pan rt.
Page 177 and 178:
Figrrc 59: XRD patreo of.lopc
Page 179 and 180:
m is cb!tu|ristic fo. thc$ lhn filn
Page 181 and 182:
ft|eilrle ald f is lhc lhickns of |
Page 183 and 184:
3.7 Gas Sensiog Studies 3.7.1 zro C
Page 185 and 186:
asr.ttlvlty ol ztto thln FIlm v. fq
Page 187 and 188:
I a T lt !2 l0 8 6 2 Efdotoryad d R
Page 189 and 190:
REFERENCES l. httpr/ ch€n. Lab. T
Page 191 and 192:
38. S.o, w. S.i Jo, H. H.: Lee, K-i
Page 193 and 194:
75. Liu, Y.; Dm8, J.; Hest€d! P.
Page 195 and 196:
Conclusions Son6hmical t€chnique
Page 197 and 198:
PPEIIDD(.I. APPENDICES P.tt m Phti4
Page 199 and 200:
A'PPENDIX-II M btmric.t ddiv.rtoD o
Page 201 and 202:
EDX ofzor ihi! fh tE0
Page 203 and 204:
.i$*n-*."i3:-.+-qi._*i-*Tr.Es_* 182
Page 205 and 206:
6 Nth Ord.r MTK Nth Ord.r 184 App6d
Page 207 and 208:
9 MTK 'l 'i I t86 :;:l *1
Page 209 and 210:
l5 zn(6d), MIK l8E
Page 211 and 212:
zr(PPh),cL z(@)3 (H2o), . cl MTK a(
Page 213 and 214:
NdGE {DL @ac} Ntlr Od.r - f,'!-=rso
Page 215 and 216:
2 2. .t. tluis$ess 5, PAPERS SUSMIT
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SON(rcHEMICAI, SYNIIIISIS AIID CIIARACTERIZATION OF PR.ECT ...

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