SON(rcHEMICAI, SYNIIIISIS AIID CIIARACTERIZATION OF PR.ECT ...

-.
\ -/
"\-i---.-.' \
I ddq
-rl
-L-c-*, "-J.--.- -,
"r_=,".-._',-" J'
srtrnE or Nd@),.2H,o
The @nplcx* 6le bebave a @valmt dDpou*Ls &d Ihe mrdiDrion nwbq of
rcrd iowards oxygd is gaenlly 6.
r.!.21 Ch.bL.l R€.crio4 of n irl FdtLior.id
'nE prepd.tion, physical pbp€rtiB md slrlclu€ of l&g€ rMbd of p{ikdomtc
@npl€x$ have @eiv.d @middbl. atlotion; lhe study of their ch€Dical crite s for
elving studual probl€E and .lso io explos od pFpetive n€thods for a vei.ty of
nclrl d€rivltiv$ of Fdit€1ona&s $ oc not..sily fomed by tund @ion lout s.
EleEoptilic $bsrilulion @tion
In son@h.mical @tion Fdiketomt4 ligdd gcn r.lly ud€rgo redistribulion r€edon,
r.pleenor @rior dd addnct lomaiion, & the chenistry of sh r€dction qill bc
Fdil@todt s of c(D, AIGD, l(lID, c(lv), r(Iv), z(lv). H(Iv),vov), rc0ll).
Cdlll) od NioD und€Bo Edjst ibution *tion with a nubd of oelll chclard !o
fom mix.d lieard @npld6 If th. .@b.E of crchdgsble ligandr e s. thc
@tion b.r@n r*o rclal cbeldg m bc win n a followine.
M-4'{4&.r+MArrB*q + 2tvld.xBr
wlErcM = neidatoD.n - nMberof ligDd!(equltohalf 0E@ordinationnmbo)
md x = 1,2,--------. (n-l).
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