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2012 - Europe Direct Iasi

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EUROINVENT <strong>2012</strong><br />

(pressure and composition of gas phase), and a device for<br />

phasing of solutions in micro-reactor. The installation allows the<br />

experimental modelling in solid-liquid, solid-liquid-gas, liquidgas<br />

multi-phases –multi-components systems, at pressures of<br />

0.5–1.75 atm., temperatures of 5–45 o C, and is easily adaptable in<br />

relation to an appreciable number of physic-chemical operational<br />

parameters.<br />

Financial support for the studies was provided by the Romanian<br />

Academy, Filial of Iaşi, Collective of Geography - III project /<br />

issue 3 / 2013 phase.<br />

X. 42.<br />

Title Advanced recovery of precious metals from secondary sources<br />

Authors Dumitru Bulgariu 1,3 , Laura Bulgariu 2 , Mihai Brânzilă 1<br />

Institution<br />

Description<br />

1<br />

“Al.I.Cuza” University of <strong>Iasi</strong>, Faculty of Geography;<br />

2<br />

“Gheorghe Asachi” Technical Univeristy of <strong>Iasi</strong>, Faculty of<br />

Chemical Engineering and Environmental Protection<br />

3<br />

Romanian Academy, Filial of <strong>Iasi</strong>, Collective of Geography<br />

This invention relates to the description of advanced recovery<br />

procedure of precious metals from secondary (sediments, alluvial<br />

deposits, mining dumps) by extraction in aqueous two- phase<br />

systems, formed from an organic polymer (polyethylene glycol,<br />

PEG) and an inorganic salt (ammonia sulphate). The utilization<br />

of aqueous PEG-based two-phase systems for the advanced<br />

recovery of precious metals, has a great potential due to their<br />

non-toxicity, durability and relatively low cost of preparation. In<br />

such extraction systems, the precious metals (Au, Ag, Pt) can be<br />

selectively separated after materials dissolution in presence of<br />

chloride ions, as extracting agents. The procedure described in<br />

this invention included: (i) the methodology for preparation of<br />

aqueous two-phase system adequate for precious metals<br />

extraction: type and characteristics (pH, concentration) of phaseforming<br />

salt, optimum concentration and molecular mass of<br />

polyethylene glycol, mixing ration of the phases and contact<br />

Innovative Researches<br />

192

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