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Maple Solutions to the Chemical Engineering Problem Set

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ToKelvin:=x->x+273.15;<br />

T(K) := map(ToKelvin,T(C));<br />

ToKelvin := x → x + 273.15<br />

TK ( ) := [ 236.45, 253.55, 261.65, 270.55, 280.75, 288.55, 299.25, 315.35, 333.75, 353.25 ]<br />

We must take <strong>the</strong> reciprocal of <strong>the</strong>se values<br />

> r := x-> 1/x;<br />

Tover := map(r,T(K));<br />

1<br />

r := x →<br />

x<br />

Tover := [ .004229223937 , .003943995267 , .003821899484 , .003696174459 , .003561887801 , .003465603881<br />

,<br />

.003341687552 , .003171079753 , .002996254682 , .002830856334<br />

]<br />

We are now ready <strong>to</strong> fit <strong>the</strong> transformed data<br />

> CCfit:=fit[leastsquare[[Tau,rho], CC2, {A,B}]]([Tover,lnpdata]): CCfit;<br />

ρ = 8.752009662 − 2035.330939 Τ<br />

This result can be expressed in terms of our orginal variables<br />

> CC3:=subs(v1,v2,CCfit): CC3;<br />

2035.330939<br />

log10( P )<br />

= 8.752009662 −<br />

T + 273.15<br />

We make a function of <strong>the</strong> right hand side for plotting purposes<br />

> CCF:=unapply(10^rhs(CC3),T);<br />

⎛<br />

2035.330939 ⎞<br />

⎜8.752009662<br />

−<br />

⎟<br />

⎝<br />

T + 273.15 ⎠<br />

CCF := T → 10<br />

and display this new result along with <strong>the</strong> polynomial fits and <strong>the</strong> data.<br />

> n:='n':<br />

p1:=plots[logplot]([seq(rhs(eqn[n]),n=2..5),CCF(T)],T=-40..100,color=[red,yellow,green,black,blue,purple]):<br />

> plots[display]({p1,lplot2,lplot1});<br />

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