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Emerging contaminants in groundwater - NERC Open Research ...

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OR/11/013<br />

Log DT 50 water/sediment<br />

4<br />

3<br />

2<br />

1<br />

0<br />

‐1<br />

‐2<br />

0 1 2 3 4 5 6 7 8<br />

Log K oc<br />

Figure 4.4 Classification of leach<strong>in</strong>g probability of all compounds us<strong>in</strong>g Koc and DT50 (after Worrall<br />

et al, 2000). Compounds <strong>in</strong> red assessed as leachers<br />

Log DT 50 water/sediment<br />

4<br />

3<br />

2<br />

1<br />

0<br />

‐1<br />

‐2<br />

0 1 2 3 4 5 6 7 8<br />

Log K oc<br />

Figure 4.5 Classification of leach<strong>in</strong>g probability of f<strong>in</strong>al list compounds us<strong>in</strong>g Koc and DT50 (after<br />

Worrall et al, 2000)<br />

A classification similar to that proposed by Worrall et al. (2000) was applied, as shown <strong>in</strong><br />

Figure 4.4, where po<strong>in</strong>ts along a diagonal l<strong>in</strong>e have a similar estimated leach<strong>in</strong>g probability.<br />

The l<strong>in</strong>e shown is a cut-off between leachers and non-leachers. This was used as Test 4 (see<br />

Table 4.2). Values close to the l<strong>in</strong>e have been assessed as leachers. Compounds were assessed<br />

as non-leachers where Log Koc > 4, Log DT50 100,000 ha and/or Weight applied >20,000 kg”. This left the 65<br />

compounds shown <strong>in</strong> Figure 4.5 and listed <strong>in</strong> Table 4.3. Compounds meet<strong>in</strong>g all five criteria<br />

assessed as hav<strong>in</strong>g the highest leach<strong>in</strong>g hazard.<br />

17

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