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An Introduction to Neutron Scattering - Spallation Neutron Source

An Introduction to Neutron Scattering - Spallation Neutron Source

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~650Å<br />

~1350Å<br />

Reflectivity<br />

Non-Fickian Boron Self-Diffusion at an Interface*<br />

10<br />

0.1<br />

0.001<br />

10 -5<br />

10 -7<br />

10 -9<br />

10 -11<br />

0 0.02 0.04 0.06 0.08 0.1 0.12<br />

11 B<br />

10 B<br />

Si<br />

Boron Self Diffusion<br />

Q (Å -1<br />

)<br />

Unnanealed sample<br />

2.4 Hours<br />

5.4 Hours<br />

9.7 Hours<br />

22.3 Hours<br />

35.4 Hours<br />

*Data courtesy of G. Smith (LANSCE)<br />

-2 )<br />

<strong>Scattering</strong> Length Density (Å<br />

8 10 -6<br />

7 10 -6<br />

6 10 -6<br />

5 10 -6<br />

4 10 -6<br />

3 10 -6<br />

2 10 -6<br />

1 10 -6<br />

Non-Standard Fickian Model<br />

10 -4<br />

10 -5<br />

10 -6<br />

10 -7<br />

10 -8<br />

10 -9<br />

10 -10<br />

10 -11<br />

Data requires density<br />

step at interface<br />

0<br />

-800 -600 -400 -200 0 200 400 600 800<br />

Distance from<br />

11 B- 10 B Interface (Å)<br />

0.045 0.05 0.055 0.06 0.065 0.07 0.075 0.08<br />

-2 )<br />

<strong>Scattering</strong> Length Density (Å<br />

8 10 -6<br />

7 10 -6<br />

6 10 -6<br />

5 10 -6<br />

4 10 -6<br />

3 10 -6<br />

2 10 -6<br />

1 10 -6<br />

Fickian diffusion<br />

doesn’t fit the data<br />

Standard Fickian Model<br />

0<br />

-600 -400 -200 0 200 400 600 800<br />

Distance from<br />

11 B- 10 B Interface (Å)

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