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58<br />
NCKRI Special Paper No. 1<br />
Evidence for hydrothermal hydrogeologic and karst<br />
features is abundant from carbonate-composed folded<br />
structures in many regions of Romania, particularly in the<br />
Codru Moma and Bihor Mountains. In the former region,<br />
thermal waters rise through Mesozoic limestones, along<br />
thrust-related faults and basin-limiting faults, from the<br />
underlying dolomites and quartzitic sandstones, producing<br />
thermal springs (Oraseanu and Mather, 2000). In the Bihor<br />
Mountains, Onac (2002) described skarn-hosted and<br />
classical hydrothermal caves, passages, and rooms with<br />
specific mineralization encountered by ore mines.<br />
Individual caves vary in size and total up to 500 m in<br />
length. The skarn-hosted caves are supposed to form<br />
during contact metamorphism of limestones, which<br />
involves decarbonation and release of CO2. Later on, caves<br />
were formed within the overlying limestones by rising<br />
thermal flow, either by retrograde solubility along cooling<br />
paths or by mixing of ascending hydrothermal fluids with<br />
oxygenated waters of a shallow flow system.<br />
The famous Movile Cave in the Miocene oolitic<br />
limestones of the Dobrogea Plateau, the Black Sea area, is<br />
assumed to have an epigenic origin related to the drop in<br />
sea level of the Black Sea during middle Pleistocene<br />
(Lascu, 2004), but the presence of a confined aquifer in the<br />
deeper sections of the carbonate sequence with low-grade<br />
thermal sulfidic waters, and a highly specific assemblage<br />
of cave fauna indicative of an isolated cave environment,<br />
suggest the possibility of a hypogenic origin for this cave.<br />
This is also supported by the presence of a 4 km long maze<br />
cave nearby.<br />
One of the most outstanding examples of deep-seated<br />
hypogene speleogenesis is a giant cavity encountered by<br />
boreholes in Precambrian marbles in the Rodopy<br />
Mountains, Bulgaria (Dubljansky V., 2000). The top of the<br />
cavity is intercepted at 560-800 m below the surface, and<br />
the greatest measured vertical dimension of the cavity is<br />
more than 1340 m (the borehole did not reach the bottom).<br />
The cavity has an estimated volume of 237.6 million m 3<br />
and is filled with thermal waters. The highest measured<br />
water temperature was 129.6 o C at a depth of -1279 m (359<br />
m below sea level). Hydraulic head is several hundred<br />
meters higher than the top of the cavity. Many smaller<br />
cavities of hydrothermal origin are known in this area.<br />
Outstanding hypogenic caves, formed by rising<br />
thermal H2S waters, are known in central and south Italy<br />
(Umbria and Marche regions), in Jurassic and Paleogene<br />
carbonates of the Neogene fold-and-thrust belt (Galdenzi<br />
and Menichetti, 1995). Jurassic carbonates are variable in<br />
initial porosity, with well-developed sedimentary facies in<br />
4-5 m thick cyclothemic sequences. Some hypogenic caves<br />
occur in Pleistocene travertine. They are large 3dimensional<br />
maze systems, in which patterns of basal input<br />
zones and points are recognized through fractures and<br />
vuggy porosity networks at the bottom of the carbonate<br />
sequence where mineralized water rises up from the<br />
Triassic evaporitic beds. Their morphology displays<br />
characteristic features of uprising flow, including rising<br />
shafts, wall and ceiling half-tubes, roof pendants, cupolas<br />
and blind domepits, through network and spongework<br />
passages situated at different levels. These caves contain<br />
massive gypsum deposits, like those found in the caves of<br />
the Guadalupe Mountains, USA. Galdenzi and Menichetti<br />
(1995) noted the remarkable similarity of internal<br />
morphologies in the caves that have different patterns and<br />
local geological contexts. Relict hypogenic caves are<br />
represented by Monte Cucco caves (31.3 km long and 930<br />
m deep 3-D maze system; Figure 24) and Pozzi della Piana<br />
(3.5 km long network maze in two levels within a vertical<br />
range of 25 m); whereas sections in some caves, such as<br />
those in Frasassi Gorge and Acquasanta Terme, are still<br />
active, presently at the water table, with H2S waters rising<br />
from depth. The principal chemical mechanism for<br />
hypogenic speleogenesis in the region is sulfuric acid<br />
dissolution due to mixing of deep and shallow flow<br />
systems.<br />
Figure 23. Plan view and profile of Frasassi caves. Note inclined<br />
cave stories in the profile (from Hose and Macalady, 2006).<br />
Some caves that display quasi-horizontal levels (e.g.<br />
the Frasassi caves; Figure 23) were interpreted to form in<br />
the shallow phreatic zone near the water table, where H2S<br />
oxidation is most intense in the present setting. However,<br />
Galdenzi and Menichetti (1995) have noted difficulties in<br />
explaining the upper levels of the Frasassi caves by<br />
analogy with the present water table/shallow