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Microstructure-Properties: I Fracture Toughness - Materials Science ...

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27<br />

Objective<br />

Overview<br />

Crack<br />

Minimztn.<br />

Energy<br />

Absrptin.<br />

2A Transformation toughening:<br />

critical size of zirconia particles<br />

• An important consequence of the volume change on<br />

transformation is that it leads to an elastic driving force that<br />

opposes the transformation for particles embedded in a matrix<br />

of a different material.<br />

• Therefore we take advantage of having the zirconia<br />

embedded as small particles in the matrix of the ceramic to be<br />

toughened.<br />

• The particles must be small enough for the elastic energy term<br />

to be effective. The upper limit for retention of the high<br />

temperature (tetragonal) phase is ~ 0.5 µm.<br />

[Green]

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