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Recharge systems for protecting and enhancing groundwate

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TOPIC 4<br />

Pathogens <strong>and</strong> micro pollutants / Health aspects 495<br />

Mcyst concentration [g/l] at outlet<br />

2.5<br />

2<br />

1.5<br />

1<br />

0.5<br />

measured<br />

modelled<br />

1<br />

0<br />

0 5 10 15 20 25 30<br />

0<br />

Time t [h]<br />

Figure 3. Measured <strong>and</strong> modelled MCYST-concentrations in 20 cm depth<br />

during enclosure experiment E2 (diamonds: MCYST-concentration in the inlet);<br />

parameters <strong>for</strong> the given situation are: ν = 0.32 m/h, α L = 0.0063 m, R = 1.97, λ = 0.74 l/h<br />

Table 2. Retardation coefficients <strong>and</strong> degradation rates calculated <strong>for</strong> extracellular MCYST<br />

during two enclosure experiments E2 <strong>and</strong> E3<br />

retardation coefficient<br />

(R)<br />

6<br />

5<br />

4<br />

3<br />

2<br />

Mcyst concentration [g/l] at inlet<br />

degradation rate (λ)<br />

[1/d]<br />

Experiment<br />

E2 E3 E2 E3<br />

water reservoir -> 20 cm 1.97 1.76 17.8 13.0<br />

20 cm -> 40 cm 1.9 1.25 5.76 7.44<br />

40 cm -> 60 cm 1.0 1.36 18 4.56<br />

60 cm -> 80 cm 1.0 1.14 13.0 0.24<br />

80 cm -> outlet 1.58 1.3 1.68 1.68<br />

In order to compare adsorption parameters obtained from laboratory batch experiments to those calculated on the<br />

basis of field enclosure experiments k d -values were calculated on the basis of the retardation coefficients according<br />

to (1), with n e ranging from 0.16 to 0.4 <strong>and</strong> ρ s amounting to an average of 1.65 g/cm³.<br />

k<br />

d<br />

⎛ ne<br />

⎞<br />

= ⎜ ⎟ * R − 1<br />

⎝ ρ ⎠<br />

s<br />

( )<br />

Eqn. (1)<br />

The resulting average k d -value <strong>for</strong> experiments E2 <strong>and</strong> E3 amounted to 0,14 cm 3 /g <strong>and</strong> 0.07 cm 3 /g, respectively.<br />

This is less than 50% of the values obtained in the batch experiments. This might be due to the different ratio of<br />

water to sediment (batch experiment 1:1, enclosure experiment about 3:1).<br />

10 – 16 June 2005, Berlin ■ 5th International Symposium ■ AQUIFER RECHARGE ■ ISMAR 2005

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