Supramolecular Nanoporous Materials and Their Applications

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Supramolecular chemistry may be defined as “chemistry beyond the molecule”, bearing on the organized entities of higher complexity that result from the association of two or more chemical species held together by intermolecular forces : metal-ion coordination, electrostatic forces, hydrogen bonding, van der Waals interacions, donor acceptor interactions, etc. - Supramolecular Chemistry – Concepts and Perspectives (J.-M. Lehn, VCH)
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Page 9 and 10: Fujita et al, Chem. Commun.1996, 38
Page 11 and 12: 4 4 5 Fujita et al, Chem. Commun. 1
Page 18 and 19: Cotton et al, J. Am. Chem. Soc. 199
Page 20 and 21: Stang et al, J. Am. Chem. Soc. 1998
Page 23 and 24: Stang et al, J. Am. Chem. Soc., 199
Page 25 and 26: Lu et al, Inorg. Chem. 2000, 39, 20
Page 27 and 28: Mirkin et al, J. Am. Chem. Soc. 199
Page 29 and 30: Aluminosilicates (zeolites) : catal
Page 31 and 32: Applications of Thin Films Based on
Page 33 and 34: Characteristics of Rhenium Squares
Page 36 and 37: Crystal Structures of “Corners”
Page 38 and 39: Chemically Tailored Molecular Nanot
Page 40 and 41: Chemically Tailored Molecular Nanot
Page 42 and 43: [Re(CO) 3 (Cl)(µ-porphZn)] 4
Page 44 and 45: Permeation Through a Thin Film of t
Page 46 and 47: PorphZn Square Modification before
Page 48 and 49: Applications of Thin Films Based on
Page 50 and 51: VOC Detection Via Quartz Crystal Mi
Page 52 and 53: Aromatic vs. Aliphatic Vapor Inclus
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2 Synthetic Route to Bisbenzimidazo
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Space Filling Representation of the
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Applications of Thin Films Based on
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Diffractive Photonic Lattices : The
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AFM image Fraunhofer Diffraction Ef
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Refractive Index n(x,λ) = n(x,λ)
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∆ θ Plo
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Direct Patterning of Sensor Element
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Concentration-dependent uptake stud
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Direct Patterning of Sensor Element
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M 2+ (20:80 H2O/EtOH) binding by po
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A Target Reaction: Olefin Epoxidati
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Supramolecular coordination chemist
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n porphyrin “iron heme moiety”
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Encapsulation of epoxidation cataly
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Selectivity (size): (a) 4-5 : 5 is
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The conceptual topological similari
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Cage Formation & Their Applications
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Nanoreactor
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(285 nm)
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To clarify the reaction pathway, th
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Once the reaction is complete, the
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Fujita et al, Science 2006, 313, 12
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(2) The next logical step would be
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[(TTF)2] +. [(TTF +. ) 2 [(TTF) 2 ]
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A-D-A (450 nm) A-D-D-A (475 nm) A-D
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Fujita et al, J. Am. Chem. Soc. 200
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Triphenylene (3a) Anthracene (3b) P
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In summary, we demonstrate the effi
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