Supramolecular Nanoporous Materials and Their Applications

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n porphyrin “iron heme moiety” / cytochrome P450 a naturally occurring enzyme used in the oxidative etabolism) ==> degradation (MnP-O-MnP/50 catalytic cycles)
Lifetime : (a) Catalyst lifetime : 10 mins → 3hrs ==> bound + unbound in a dynamic equilibrium (b) 1+2 : TON ↑ 10-fold (500) – K~10 6 M -1 (c) 3+2 : TON ↑ 30-fold (1500) – K~10 7 M -1 (d) Dilution for catalyst concentration (1/1000) : TON ↑ 7000 for 1+2 21000 for 3+2
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Supramolecular Nanoporous Materials
Page 4:
Supramolecular chemistry may be def
Page 10 and 11:
53 : 54 (square : triangle) 66:34 2
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4:5 / Square : triangle
Page 19 and 20:
Hong et al, Tetrahedron Lett. 1998,
Page 21:
Lehn et al, Angew. Chem. Int. Ed. 1
Page 24 and 25:
Cotton et al, J. Am. Chem. Soc. 199
Page 26 and 27:
Hupp et al, Chem. Mater. 2001, 13,
Page 28 and 29:
Why Nanoscale Porosity • Separati
Page 30 and 31:
Molecular Squares M. Fujita, et.al.
Page 32 and 33:
Synthesis of Molecular Squares Re..
Page 34:
Crystal Structures of Molecular Squ
Page 37 and 38: Modification of Square Cavity Size/
Page 39 and 40: N N N N N CN N NH 2 N N N N N N O N
Page 41 and 42: [Re(CO) 3 (Cl)(µ-pyrazine)] 4
Page 43 and 44: Applications of Thin Films Based on
Page 45 and 46: Molecular Sieving by Thin Films Bas
Page 47 and 48: Snurr et al, Adv. Mater. 2001, 13,
Page 49 and 50: Molecular Recognition and Sensors +
Page 51 and 52: QCM Study of Benzene Inclusion in [
Page 53: Substituent Effect on VOC Inclusion
Page 56 and 57: ORTEP of the Re-BiBzIm/bpy Rectangl
Page 58 and 59: Affinity Constants of Thin Films of
Page 61 and 62: Sun and Lees, J. Am. Chem. Soc. 200
Page 63 and 64: Diffraction! I 0 n film I 1 I 0 n s
Page 65 and 66: Direct Patterning of Sensor Element
Page 67 and 68: Control Box
Page 69 and 70: EtOH uptake by porpZn square functi
Page 71 and 72: SIZE EXCLUSION : 1,3,5-tripyridyl-2
Page 73 and 74: VOC uptake poly(4-vinylphenol) film
Page 75: Incident Wavelength Effects η( λ)
Page 78 and 79: Sensor Materials Based on Functiona
Page 80 and 81: M n+ (20:80 H 2 O/EtOH) binding of
Page 82 and 83: Toward Artificial Enzymes and Membr
Page 85 and 86: Enzyme are exquisite catalysts for
Page 87: R 2 R 3 R 1 R 4 + Oxidant R 2 O R 3
Page 93 and 94: The enhanced stability and enhanced
Page 95 and 96: Supramolecular complex with a funct
Page 97 and 98: Conclusion Demonstrated Electrochem
Page 99 and 100: Molecular Cages
Page 101 and 102: The key step of the exclusive forma
Page 103 and 104: There are two possible pathways to
Page 105: Fujita et al, Science 2006, 312, 25
Page 112 and 113: Fujita et al, J. Am. Chem. Soc. 200
Page 116 and 117: How might such assemblies be exploi
Page 119 and 120: ~ 740 nm due to TTF (e-rich) → tr
Page 122: Fujita et al, Angew. Chem. Int. Ed.
Page 129: Fujita et al, J. Am. Chem. Soc. 200
Page 133: [(ZnI 2 ) 3 (1) 2 ]⋅5.5(nitrobenz
Page 136 and 137: Single-crystal-to-single-crystal-gu
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