Supramolecular Nanoporous Materials and Their Applications
Supramolecular Nanoporous Materials and Their Applications
Supramolecular Nanoporous Materials and Their Applications
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PorphZn Square Modification before Film Casting<br />
Square/TPP K b<br />
= 4 x 10 7 M -1 in CH 2<br />
Cl 2<br />
(Slone et al Inorg. Chem. 1997, 36, 5422.)<br />
Zn<br />
N<br />
Zn<br />
G<br />
Zn<br />
G<br />
=<br />
N<br />
N N<br />
Zn<br />
N N<br />
N<br />
bare electrode<br />
Zn<br />
N<br />
film-covered electrode<br />
d ~ 2.4 Å<br />
I -<br />
200 µ A<br />
d~2.4 A<br />
N<br />
H 3 N<br />
Ru<br />
H 3 N<br />
H 3 N<br />
NH 3<br />
NH 3<br />
d ~ 6.7 Å<br />
1.00<br />
0.75<br />
0.50<br />
0.25<br />
0.00<br />
-0.25<br />
-0.50<br />
E vs SSCE (V)