Supramolecular Nanoporous Materials and Their Applications

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Diffractive Photonic Lattices : The approach is based on the diffraction efficiency concept n>1 2 n1 = 1 n 2’ > n 2 ’ n2 analyte= n1 = 1
Direct Patterning of Sensor Elements Micromolding in Capillaries (MIMIC) Creation of PDMS stamp PDMS Master Solution casting of sensor material PDMS Sensing Material Mold filling by capillary action PDMS Removal of PDMS stamp leaving behind micromolded film Hupp et al, Angew. Chem. Int. Ed. 2001, 41, 154. 75 µm AFM image
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Supramolecular Nanoporous Materials
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Supramolecular chemistry may be def
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53 : 54 (square : triangle) 66:34 2
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4:5 / Square : triangle
Page 19 and 20: Hong et al, Tetrahedron Lett. 1998,
Page 21: Lehn et al, Angew. Chem. Int. Ed. 1
Page 24 and 25: Cotton et al, J. Am. Chem. Soc. 199
Page 26 and 27: Hupp et al, Chem. Mater. 2001, 13,
Page 28 and 29: Why Nanoscale Porosity • Separati
Page 30 and 31: Molecular Squares M. Fujita, et.al.
Page 32 and 33: Synthesis of Molecular Squares Re..
Page 34: Crystal Structures of Molecular Squ
Page 37 and 38: Modification of Square Cavity Size/
Page 39 and 40: N N N N N CN N NH 2 N N N N N N O N
Page 41 and 42: [Re(CO) 3 (Cl)(µ-pyrazine)] 4
Page 43 and 44: Applications of Thin Films Based on
Page 45 and 46: Molecular Sieving by Thin Films Bas
Page 47 and 48: Snurr et al, Adv. Mater. 2001, 13,
Page 49 and 50: Molecular Recognition and Sensors +
Page 51 and 52: QCM Study of Benzene Inclusion in [
Page 53: Substituent Effect on VOC Inclusion
Page 56 and 57: ORTEP of the Re-BiBzIm/bpy Rectangl
Page 58 and 59: Affinity Constants of Thin Films of
Page 61 and 62: Sun and Lees, J. Am. Chem. Soc. 200
Page 63: Diffraction! I 0 n film I 1 I 0 n s
Page 67 and 68: Control Box
Page 69 and 70: EtOH uptake by porpZn square functi
Page 71 and 72: SIZE EXCLUSION : 1,3,5-tripyridyl-2
Page 73 and 74: VOC uptake poly(4-vinylphenol) film
Page 75: Incident Wavelength Effects η( λ)
Page 78 and 79: Sensor Materials Based on Functiona
Page 80 and 81: M n+ (20:80 H 2 O/EtOH) binding of
Page 82 and 83: Toward Artificial Enzymes and Membr
Page 85 and 86: Enzyme are exquisite catalysts for
Page 87 and 88: R 2 R 3 R 1 R 4 + Oxidant R 2 O R 3
Page 89: Lifetime : (a) Catalyst lifetime :
Page 93 and 94: The enhanced stability and enhanced
Page 95 and 96: Supramolecular complex with a funct
Page 97 and 98: Conclusion Demonstrated Electrochem
Page 99 and 100: Molecular Cages
Page 101 and 102: The key step of the exclusive forma
Page 103 and 104: There are two possible pathways to
Page 105: Fujita et al, Science 2006, 312, 25
Page 112 and 113: Fujita et al, J. Am. Chem. Soc. 200
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How might such assemblies be exploi
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~ 740 nm due to TTF (e-rich) → tr
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Fujita et al, Angew. Chem. Int. Ed.
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Fujita et al, J. Am. Chem. Soc. 200
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[(ZnI 2 ) 3 (1) 2 ]⋅5.5(nitrobenz
Page 136 and 137:
Single-crystal-to-single-crystal-gu
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