Supramolecular Nanoporous Materials and Their Applications

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The conceptual topological similarity of cytochrome P450 <strong>and</strong> a supramolecular encapsulated catalyst assembly ([1+2]).
Conclusion Demonstrated Electrochemical sieving for a Molecular- Square Based Thin-Film Material Demonstrated Affinity to VOCs for a Thin-Film Material Based on Molecular Squares Detected by QCM Demonstrated Potential Chemosensing <strong>Applications</strong> to VOCs, Halocarbons or Heavy Metal Ions Detected by Diffractive Photonic Lattices Toward Artificial Enzymes & Membrane Catalytic Reactors
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Supramolecular Nanoporous Materials
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Supramolecular chemistry may be def
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53 : 54 (square : triangle) 66:34 2
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4:5 / Square : triangle
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Hong et al, Tetrahedron Lett. 1998,
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Lehn et al, Angew. Chem. Int. Ed. 1
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Cotton et al, J. Am. Chem. Soc. 199
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Hupp et al, Chem. Mater. 2001, 13,
Page 28 and 29:
Why Nanoscale Porosity • Separati
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Molecular Squares M. Fujita, et.al.
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Synthesis of Molecular Squares Re..
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Crystal Structures of Molecular Squ
Page 37 and 38:
Modification of Square Cavity Size/
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N N N N N CN N NH 2 N N N N N N O N
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[Re(CO) 3 (Cl)(µ-pyrazine)] 4
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Applications of Thin Films Based on
Page 45 and 46: Molecular Sieving by Thin Films Bas
Page 47 and 48: Snurr et al, Adv. Mater. 2001, 13,
Page 49 and 50: Molecular Recognition and Sensors +
Page 51 and 52: QCM Study of Benzene Inclusion in [
Page 53: Substituent Effect on VOC Inclusion
Page 56 and 57: ORTEP of the Re-BiBzIm/bpy Rectangl
Page 58 and 59: Affinity Constants of Thin Films of
Page 61 and 62: Sun and Lees, J. Am. Chem. Soc. 200
Page 63 and 64: Diffraction! I 0 n film I 1 I 0 n s
Page 65 and 66: Direct Patterning of Sensor Element
Page 67 and 68: Control Box
Page 69 and 70: EtOH uptake by porpZn square functi
Page 71 and 72: SIZE EXCLUSION : 1,3,5-tripyridyl-2
Page 73 and 74: VOC uptake poly(4-vinylphenol) film
Page 75: Incident Wavelength Effects η( λ)
Page 78 and 79: Sensor Materials Based on Functiona
Page 80 and 81: M n+ (20:80 H 2 O/EtOH) binding of
Page 82 and 83: Toward Artificial Enzymes and Membr
Page 85 and 86: Enzyme are exquisite catalysts for
Page 87 and 88: R 2 R 3 R 1 R 4 + Oxidant R 2 O R 3
Page 89: Lifetime : (a) Catalyst lifetime :
Page 93 and 94: The enhanced stability and enhanced
Page 95: Supramolecular complex with a funct
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Page 101 and 102: The key step of the exclusive forma
Page 103 and 104: There are two possible pathways to
Page 105: Fujita et al, Science 2006, 312, 25
Page 112 and 113: Fujita et al, J. Am. Chem. Soc. 200
Page 116 and 117: How might such assemblies be exploi
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Page 122: Fujita et al, Angew. Chem. Int. Ed.
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Page 133: [(ZnI 2 ) 3 (1) 2 ]⋅5.5(nitrobenz
Page 136 and 137: Single-crystal-to-single-crystal-gu
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