Supramolecular Nanoporous Materials and Their Applications
Supramolecular Nanoporous Materials and Their Applications
Supramolecular Nanoporous Materials and Their Applications
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2<br />
Synthetic Route to Bisbenzimidazolate-Based<br />
Rectangles<br />
(Third Generation)<br />
OC<br />
OC<br />
O<br />
C<br />
M<br />
Br<br />
C O<br />
CO<br />
+<br />
N<br />
N<br />
K<br />
K<br />
N<br />
N<br />
RT<br />
CH 2 Cl 2 , N 2<br />
O<br />
C<br />
O<br />
C<br />
OC M CO<br />
N N<br />
N N<br />
OC M C O<br />
C<br />
O<br />
C<br />
O<br />
+ 2KBr<br />
O O O O<br />
C C<br />
C C<br />
OC M N<br />
N M− CO<br />
N N<br />
N N<br />
N N<br />
N N<br />
OC M N<br />
N M C O<br />
C C<br />
C C<br />
O O<br />
O O<br />
THF, N 2<br />
M=Re, Mn<br />
N<br />
N<br />
-<br />
Benkstein et al, Angew. Chem. Int. Ed. 2000, 39, 2891.