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Chapter 11 Chemical Bonds: The Formation of Compounds from ...

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<strong>11</strong>.8 Complex Lewis structures<br />

for some molecules or polyatomic ions, no single<br />

Lewis structure consistent with all characteristics<br />

and bonding information can be written<br />

ex. nitrate ion NO<br />

-<br />

3<br />

step 1 total valence electrons<br />

= 5 + 3 × 6 + 1 = 24<br />

step 2 O O· ·<br />

O N O O : N : O<br />

step 3 24 - 6 = 18<br />

step 4 · ·<br />

: O electron deficient<br />

·· ·· ··<br />

: O : N : O :<br />

·· ·· ··<br />

step 5 · · - · · - · · -<br />

: O : O : : O :<br />

·· || ·· ·· ·· ·· ·· ·· ··<br />

: O : N : O : : O =N : O : : O : N= O :<br />

·· ·· ·· ··<br />

there are three possible Lewis structures<br />

a molecule or ion that has multiple correct<br />

Lewis structures shows resonance<br />

each <strong>of</strong> these Lewis structures is called a<br />

resonance structure<br />

19

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