46 GEOLOGY AND MINERAL RESOURCES OF PARAGUAYFIGURE 36. Shonkinite (specimen P-54a) from Mbocayaty. Note the large rounded hydronephelite, h, crystals at left. At the center right are "graphic"remnants <strong>of</strong> nepheline or hydronepheline, g, that have been partly replaced by sanidine. Light-green monoelinic pyroxene, p, showing good cleavage,<strong>and</strong> dark-brown biotite, b, are abundant; olivine, o, in the lower right edge, is enclosed in biotite. Pale-bluish apatite <strong>and</strong> black iron oxide are accessoryminerals. X 15.strongly pleochroic brown biotite grains, sphene, <strong>and</strong> apatiteare also present.P 54c, shonkinite. Specimen P 54c is similar to specimenP-54a, described above. Numerous olivine crystals are seenin figure 38 (just upper left <strong>of</strong> center, just left <strong>of</strong> middle loweredge, <strong>and</strong> elsewhere). Large pyroxene crystals, showing goodcleavage, are also abundant. In the middle <strong>of</strong> the left half <strong>of</strong>the field is a large crystal <strong>of</strong> hydronephelite. The white areasare sanidinic feldspar.P-54d <strong>and</strong> P-S4e, shonkinite. Specimens P-54d <strong>and</strong> P-54eare similar. Both are rather coarse-grained medium-dark rockswith prominent tabular feldspars. They are variants <strong>of</strong> specimensP-54a <strong>and</strong> P-54c <strong>and</strong> differ essentially in having no olivine,<strong>and</strong> very little titaniferous amphibole. Titaniferous amphiboleshows normal absorption in deep brown parallel to c, unlike thekataphorite amphibole found in the other rocks from thislocality. Specimen P-54d has been analyzed (table 5).Figure 39 (specimen P-54d) shows the abundant tabular(laths in cross section) feldspar, <strong>and</strong> titaniferous augite. Undercrossed nicols, many <strong>of</strong> the clear feldspars show turbid cores,indicating perhaps replacement <strong>of</strong> an earlier generation <strong>of</strong>feldspar.Specimen P-54e contains some analcite, with clear feldsparapparently replacing nepheline. Many <strong>of</strong> the feldspar crystalshave turbid inner zones.P-64f <strong>and</strong> P-S4g, shonkinite. Specimens P-54f <strong>and</strong> P-54gare similar, <strong>and</strong> differ from the others somewhat. No definitelath-shaped feldspars are seen; instead there are abundant roundedwhitish areas, as much as 0.5 centimeter across, which arereplacements <strong>of</strong> nepheline. Figure 40 shows specimen P-54f, inwhich two such replacements (with more or less hexagonal outline)are seen in the upper half <strong>of</strong> the field. The smaller <strong>and</strong> clearerone is isotropic, <strong>and</strong> may be analcite; the other appears to behydrouephelite. In the center <strong>of</strong> the field, to the right <strong>of</strong> alarge augite, is more <strong>of</strong> the hydronephelite aggregate enclosingclear feldspar. There is an abundance <strong>of</strong> mafic minerals,including olivine, in this rock. Hornblende, though, is absent.Specimen P 54g, shown in figure 41, contains abundantwell-formed crystals <strong>of</strong> colorless fresh olivine, augite colorlessinside but usually with a thick outer green zone (aegirineaugite)fresh red-brown biotite, <strong>and</strong> some kataphorite amphibole. This mineral shows a strong <strong>and</strong> unusual pleochroism:X, pale yellow, Y, wine-red brown, Z, yellow; a small opticangle; strong dispersion, v>p; <strong>and</strong> the amphibole type <strong>of</strong>cleavage, against which an extinction <strong>of</strong> about 15° can bemeasured.This amphibole resembles a kataphoritic amphibole namedmagnophorite by R. T. Prider (1939) from a leucite-bearing
IGNEOUS AND METAMOEPHIC ROCKS 47, ',* , * - *^ S . Jf , ? ^..1^-filFIGTJEE 37. Nepheline syenite (specimen P-54b) from Mbocayaty. Coarsely crystallized orthoclase, /, with hydronephelite, ft, after nepheline, which isslightly darker, <strong>and</strong> sphene, s. The darker small areas are green pyroxene, a, <strong>and</strong> black ore grains, o, <strong>of</strong> magnetite-ilmenite. Much <strong>of</strong> the hydronepheliteretains the characteristic stubby hexagonal prism shape <strong>of</strong> the original nepheline; however, it is uniaxial positive with appreciably higher birefringencethan nepheline. X 15.TABLE 5.Chemical analyses <strong>of</strong> alkalic rocks[Analyses <strong>of</strong> A, B, <strong>and</strong> E by Trumbull with densities by L. N. Tarrant; analysis <strong>of</strong>C, by Goldschlag; D, by Lindner]SiO 2 - - -Al2OsFeO.. . ......MgO ... ...Cao...-_ ______Na2O -. ... _.K20 .__....H.O- -H20+.. .... _.TiOs .....-.-.CO.. .........PsOs. -SOs.S....MnO ...BaO. ___ ____Less O . ..Norm...NOTE.AP-54d53.2916.104.502.982.323.783.459.42.201.231.11.02.71.50.03.13.1999.96.0299.942.68II-5-1-2BP-54g50.4111. 173.505.059.237.732.317.10.12.761.61.00.41.12.03.14.2099 89!0299.872.87III-6-1-2C48.5511. 975.734.414. 7710.064.864.30} 2.623.04Tr.100. 31III-6-1-3See explanation <strong>of</strong> specimen designations below.52.2020. 673.261.38.484.436.614.90f .36\ 3.56.141.54.12.04D. 09(Mn2O 3).0999. 872.463I-6-2-3EP-58a51. 2715. 728.611.533.725.983.714.15.871.821.64.01.43.17.1899.812.731I-5-2-3SpecimenNo.A (P-54d)_._T! CP-'Hfr}D ____ .E (P-58a) ........doRockLocalityDo.2.3 km west-southwest <strong>of</strong> Centurion.Sapucai, Ibytymi district.rock from Western Australia. Prider gives an analysis. Asecond paper by Wade <strong>and</strong> Prider (1941) gives a further description,with illustration <strong>of</strong> a peculiar "herringbone" structurewhich is also present in the Mbocayaty mineral. Figure 42shows this amphibole, with "herringbone" structure.The amphibole also resembles an amphibole from Wyoming,described by Cross (1897), which Cross states is almost uniaxial,<strong>and</strong> with a color scheme X, a pale yellow, b, red similar tohypersthene, Z, a bright yellow.ANALYSES OF AIKAIIC ROCKSFive chemical analyses <strong>of</strong> the alkalic rocks <strong>of</strong> <strong>Paraguay</strong>are available, three new ones (<strong>of</strong> nepheline syenite