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Automotive Foam Basics: Public Procurement
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ISSN 1862-5258<br />
Jan/Feb<br />
<strong>01</strong> | 2<strong>01</strong>6<br />
Basics<br />
ISSN 1862-5258<br />
Public Procurement | 34<br />
May 2006<br />
Highlights<br />
Automotive | 12<br />
Foam | 30<br />
bioplastics MAGAZINE Vol. 11<br />
bioplastics magazine<br />
Vol. 1<br />
Top Talk:<br />
Interview with Helmut Traitler,<br />
VP Packaging of Nestlé | 10
Editorial<br />
dear<br />
readers<br />
Ten years of bioplastics MAGAZINE… whew – how the time has flown. I remember well<br />
how it all began. I first came into contact with bioplastics when I took on an assignment<br />
from IBAW (today European Bioplastics) to act as a PR-consultant for the “Innovationparc<br />
– bioplastics in packaging” at interpack 2005 in Düsseldorf. And,<br />
like so many other people, I was impressed. Throughout the summer after<br />
the trade fair, I couldn’t sleep, obsessed by the thought that bioplastics<br />
were the future – and that I wanted to be a part of it. I had been badly bitten<br />
by the bioplastics virus, you might say. So, I asked the experts “What’s the<br />
name of your industry’s trade journal? I want a subscription!” But there<br />
was none... And that’s how it all started.<br />
This 10 th anniversary also means a year in which we’re rolling out a few<br />
special projects:<br />
First of all, we are promoting our new App for smartphones and tablets.<br />
The App itself is free of charge and can be downloaded from the Apple<br />
appstore and from the Android Google playstore. During our anniversary<br />
year, all our content can also be downloaded for free. This means that<br />
you can read bioplastics MAGAZINE and follow us on twitter on your mobile<br />
devices – wherever you are.<br />
Of course, we’ll also have a booth at K’2<strong>01</strong>6, the world’s number one<br />
trade show for the plastics and rubber industry in October in Düsseldorf,<br />
Germany. Here, we’re planning a celebration party with music, cool<br />
drinks and snacks – and you, faithful reader, are invited. More details will<br />
follow in a later issue of the magazine.<br />
Now, about the current issue: we’re kicking off the new year with highlights on<br />
automotive applications and on foam. In the Basics section, we discuss the possibilities<br />
and challenges of public procurement. Can government stimulate and support<br />
the use of bioplastics by mandating their purchase and use in products for the public<br />
sector?<br />
We’d also like to introduce a new series in which we’re marking our anniversary<br />
year with a blast from the past. Here we’ll be re-publishing interesting articles from<br />
the early years of bioplastics MAGAZINE. Apart from the cover, have a look at page 32.<br />
Lastly, we’d like to invite you again to our 4 th PLA World Congress in Munich, Germany<br />
on May 25 th and 26 th . The Green Bag Conference, however, has regretfully had to<br />
be postponed to an as yet unknown date, due to insuperable challenges.<br />
For current news, be sure to check the latest reports, breaking news and daily news<br />
updates at www.bioplasticsmagazine.com.<br />
We hope you enjoy reading bioplastics MAGAZINE.<br />
Sincerely yours<br />
bioplastics MAGAZINE Vol. 11<br />
ISSN 1862-5258<br />
Basics<br />
bioplastics magazine<br />
Vol. 1<br />
ISSN 1862-5258<br />
Public Procurement | 34<br />
Highlights<br />
Automotive | 12<br />
Foam | 30<br />
Jan/Feb<br />
Top Talk:<br />
Interview with Helmut Traitler,<br />
VP Packaging of Nestlé | 10<br />
May 2006<br />
<strong>01</strong> | 2<strong>01</strong>6<br />
Follow us on twitter!<br />
www.twitter.com/bioplasticsmag<br />
Like us on Facebook!<br />
www.facebook.com/bioplasticsmagazine<br />
Michael Thielen<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 3
Content<br />
Imprint<br />
<strong>01</strong>|2<strong>01</strong>6<br />
Jan / Feb<br />
Automotive<br />
12 Lightweighting is key<br />
14 Carbon/Flax hybrid automotive roof<br />
15 Smart bioplastics for automotive<br />
applications<br />
16 Biocomposites in the automotive industry<br />
Materials<br />
18 The gluten solution<br />
20 Making Levulinic Acid happen<br />
24 Breakthrough platform technology for<br />
new building block<br />
Opinion<br />
26 Bioplastics industry struggling to meet<br />
expected demand<br />
38 Biopolymers will weather the crash in<br />
petroleum prices<br />
3 Editorial<br />
5 News<br />
22 Material News<br />
28 Application News<br />
Foam<br />
30 PLA foam expanding into new areas<br />
Basics: Public Procurement<br />
34 “The biobased office” for the procurement<br />
of the future<br />
34 Mandatory Federal purchasing of<br />
biobased products<br />
10 Years Ago<br />
32 Polyamide from bio-amber<br />
42 Glossary<br />
46 Suppliers Guide<br />
49 Event Calendar<br />
50 Companies in this issue<br />
Publisher / Editorial<br />
Dr. Michael Thielen (MT)<br />
Karen Laird (KL)<br />
Samuel Brangenberg (SB)<br />
Head Office<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach, Germany<br />
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info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Media Adviser<br />
Florian Junker<br />
phone: +49(0)2161-6884467<br />
fax: +49(0)2161 6884468<br />
junker@showju-systems.de<br />
Chris Shaw<br />
Chris Shaw Media Ltd<br />
Media Sales Representative<br />
phone: +44 (0) 1270 522130<br />
mobile: +44 (0) 7983 967471<br />
Layout/Production<br />
Ulrich Gewehr (Dr. Gupta Verlag)<br />
Max Godenrath (Dr. Gupta Verlag)<br />
Print<br />
Poligrāfijas grupa Mūkusala Ltd.<br />
1004 Riga, Latvia<br />
bioplastics MAGAZINE is printed on<br />
chlorine-free FSC certified paper.<br />
Total print run: 3,600 copies<br />
bioplastics magazine<br />
ISSN 1862-5258<br />
bM is published 6 times a year.<br />
This publication is sent to qualified<br />
subscribers (149 Euro for 6 issues).<br />
bioplastics MAGAZINE is read in<br />
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Every effort is made to verify all<br />
Information published, but Polymedia<br />
Publisher cannot accept responsibility<br />
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All articies appearing in bioplastics<br />
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bioplastics MAGAZINE welcomes contributions<br />
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Envelopes<br />
A part of this print run is mailed to the<br />
readers wrapped in bioplastic envelopes<br />
sponsored by Flexico Verpackungen<br />
Deutschland, Maropack GmbH & Co.<br />
KG, and Neemann<br />
Erratum<br />
For mailing our last issue we used envelopes<br />
that were we no longer permitted<br />
to use, as the new company name is<br />
Coveris Flexibles Deutschland GmbH. We<br />
sincerely apologize for this mistake.<br />
Cover<br />
Photo: Michael Thielen<br />
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daily upated news at<br />
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News<br />
SPC published position paper against oxo-additives<br />
The Sustainable Packaging Coalition (SPC), Charlottesville, Virginia, USA, has released a formal position paper against<br />
biodegradability additives for petroleum-based plastics, which are marketed as enhancing the sustainability of plastic by<br />
rendering the material biodegradable. The SPC has evaluated the use of biodegradability additives for conventional petroleumbased<br />
plastics, and has found that these additives do not offer any sustainability advantage and they may actually result in more<br />
environmental harm.<br />
The position paper lists the following reasons for the stance against these additives:<br />
• They don’t enable compostability, which is the meaningful indicator of a material’s ability to beneficially return nutrients to<br />
the environment.<br />
• They are designed to compromise the durability of plastic and the additive manufacturers have not yet demonstrated an<br />
absence of adverse effects on recycling.<br />
• The creation of a litter friendly material is a step in the wrong direction, particularly when the material may undergo<br />
extensive fragmentation and generation of micro-pollution before any biodegradation occurs.<br />
• The biodegradation of petroleum-based plastics releases fossil carbon into the atmosphere, creating harmful greenhouse<br />
gas emissions.<br />
Concerning litter and micro-pollution, the position paper says: “Most additives are designed to fragment petroleum-based<br />
plastics into small pieces in order to make it sufficiently available to the microorganisms that perform biodegradation.”<br />
However, bioplastics MAGAZINE has been waiting for 10 years now for satisfactory, scientifically backed evidence that a complete<br />
biodegradation by microorganisms will happen, in whatever timeframe. The SPC paper continues that the “fragmented micropieces<br />
remain invisible to the naked eye, yet their effects as micro-litter can be detrimental. Beyond the well-documented<br />
environmental impacts of micro-pollution, the marketing of biodegradable petroleum-based plastics as being less detrimental<br />
to the environment may contribute to improper end-of-life disposal and pollution.”<br />
In her December 30, 2<strong>01</strong>5 article at Plastics Today (bit.ly/1OM7BeC) Clare Goldsberry expresses that she doesn’t think<br />
“that most people want plastics to disappear. What we’d like to see disappear is the litter in our communities and in the<br />
world’s waterways. And that’s not a plastics problem – that’s a people problem. An additive that makes plastic litter degrade to<br />
fragments in 180 days is not exactly what I’d call a solution.” MT<br />
The complete SPC position paper can be downloaded for free from http://bit.ly/200Nv8U<br />
Jumbo merger in the chemical industry<br />
DuPont (Wilmington, Delaware, USA) and The Dow Chemical Company (Midland, Michigan, USA) announced in mid December<br />
2<strong>01</strong>5 hat their boards of directors unanimously approved a definitive agreement under which the companies will combine<br />
in an all-stock merger of equals. The combined company will be named DowDuPont. The parties intend to subsequently<br />
pursue a separation of DowDuPont into three independent, publicly traded companies through tax-free spin-offs. This would<br />
occur as soon as feasible, which is expected to be 18 – 24 months following the closing of the merger, subject to regulatory<br />
and board approval.<br />
The companies will include a leading global pure-play Agriculture company; a leading global pure-play Material Science<br />
company; and a leading technology and innovation-driven Specialty Products company. Each of the businesses will have clear<br />
focus, an appropriate capital structure, a distinct and compelling investment thesis, scale advantages, and focused investments<br />
in innovation to better deliver superior solutions and choices for customers.<br />
It is expected that the well known biobased plastic products will be continued under the the newly to be created Material<br />
Science Company: This company will be a pure-play industrial leader, consisting of DuPont’s Performance Materials segment,<br />
as well as Dow’s Performance Plastics, Performance Materials and Chemicals, Infrastructure Solutions, and Consumer<br />
Solutions (excluding the Dow Electronic Materials business) operating segments. The combination of complementary<br />
capabilities will create a low-cost, innovation-driven leader that can provide customers in high-growth, high-value industry<br />
segments in packaging, transportation, and infrastructure solutions, among others with a broad and deep portfolio of costeffective<br />
offerings. Combined pro forma 2<strong>01</strong>4 revenue for Material Science is approximately USD 51 billion.<br />
Upon completion of the transaction, Andrew N. Liveris, President, Chairman and CEO of Dow, will become Executive<br />
Chairman of the newly formed DowDuPont Board of Directors and Edward D. Breen, Chair and CEO of DuPont, will become<br />
Chief Executive Officer of DowDuPont. In these roles, both Liveris and Breen will report to the Board of Directors. In addition,<br />
when named, the chief financial officer will report to Breen. MT<br />
www.dupont.com | www.dow.com | www.dowdupontunlockingvalue.com<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 5
News<br />
daily upated news at<br />
www.bioplasticsmagazine.com<br />
Newlight, Innogas and FGV collaborate in Malaysia<br />
on biodegradable polymers from palm oil waste<br />
The world’s largest crude palm oil producer - Malaysia-based Felda Global Ventures Berhad – is collaborating with Newlight<br />
Technologies and Innogas Technologies on a project aimed at the development of biodegradable polymers from palm oil biomass<br />
waste in Malaysia. A Memorandum of Understanding was signed by the three companies late December 2<strong>01</strong>5. The MoU will<br />
remain valid for six months or such extended period as will be agreed in writing by the parties FGV-Newlight-Innogas MoU.<br />
Based in California, Newlight Technologies has developed a carbon capture technology that combines air with methanebased<br />
greenhouse gas emissions to produce a thermoplastic material called AirCarbon. Innogas Technologies is a Malaysiabased<br />
consulting company specialized in process plant engineering and technology for chemical and renewable energy.<br />
FGV Group President and CEO Dato’ Mohd Emir Mavani Abdullah said as part of the company’s commitment to sustainability,<br />
it is always looking for innovative ways to manage its palm oil waste effectively. The collaborative sustainable biomass project<br />
is also aimed at diversifying and further developing the company’s new revenue streams, in line with a core pillar in its five-year<br />
transformation strategy of revenue enhancement. “This waste to wealth project will elevate the sustainability standards of the<br />
palm oil industries in Malaysia and the region as a whole, significantly reducing carbon emissions emitted,” said Dato Emir.<br />
“FGV is keen to partner with Newlight Technologies and Innogas Technologies through this MOU to bring the first cost<br />
effective technology in the world to produce biodegradable plastic by processing 100 % of bio-waste from our palm oil mills.”<br />
Newlight Technologies will convert biogas from FGV’s palm oil mills into AirCarbon thermoplastics. “Together, FGV and<br />
Newlight Technologies have the opportunity to make important economic and environmental progress, and we look forward to<br />
working together in this project,” said CEO Mark Herrema.<br />
The project will launch in Q2 2<strong>01</strong>6. Construction of the first plant will take around 14 months and is slated to begin in Q4 2<strong>01</strong>6.<br />
The partners plan to expand the project to ten palm oil mills over the next five years.<br />
Innogas Technologies CEO Denny Yeoh said; “Innogas Technologies holds an exclusive license for a patented state-of-the<br />
art technology to process ligno-cellulosic biomass material such as palm oil mill waste which generates a significant amount<br />
of biogas, compared to conventional technologies. “The Company will transfer this license to the joint-venture company, which<br />
will then have the exclusive use of this license in Malaysia.” KL<br />
www.feldaglobal.com<br />
Anellotech brings 100 % biobased PET<br />
another step closer<br />
Anellotech, Pearl River, New York, USA, a sustainable technology company focused on producing<br />
cost-competitive renewable chemicals from non-food biomass, has announced that it has entered<br />
into the next phase of its strategic partnership with Osaka, Japan-based Suntory Holdings Limited,<br />
one of the world’s leading consumer beverage companies<br />
This marks a major milestone in making 100 % biobased polyester and biobased PET bottles a<br />
reality.<br />
The partnership, which began in 2<strong>01</strong>2 under a collaboration agreement that has provided<br />
more than USD 15 million in funding to date, is focused on advancing the development and<br />
commercialization of cost-competitive 100 % biobased plastics for use in beverage bottles as part<br />
of Suntory’s commitment to sustainable business practices.<br />
Suntory currently uses 30 % plant-derived materials (sugar cane derived monoethylene glycol<br />
MEG) for their Mineral Water Suntory Tennensui brands and is pursuing the development of a<br />
100 % biobottle through this partnership. Approximately 54 million tonnes of PET are manufactured<br />
globally each year. Despite strong industry demand, there is no commercially-available, biobased<br />
paraxylene, the key component needed to make terephthalic acid, und thus 100 % biobased<br />
polyethylene terephthalate (PET) for use in beverage bottles, on the market today.<br />
The Anellotech alliance with Suntory supports the development of bio-aromatics including<br />
bio-paraxylene. As an integral component in the biobased value chain, Anellotech’s proprietary<br />
thermal catalytic biomass conversion technology (Bio-TCat) cost-competitively produces drop in<br />
green aromatics, including paraxylene and benzene, from non-food biomass. MT<br />
www.anellotech.com | www.suntory.com<br />
6 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
News<br />
BioAmber and<br />
Reverdia sign nonassertion<br />
agreement<br />
BioAmber Inc., which is headquartered in Montreal and<br />
Reverdia, the Netherlands-based joint venture between Royal<br />
DSM an d Roquette Frères, are both involved in the production<br />
and commercialization of bio-based succinic acid using their<br />
own unique proprietary yeast-based technologies.<br />
Pursuant to the key provisions of this agreement, BioAmber<br />
will benefit from non-assertion covenants with respect to<br />
certain intellectual property rights of Reverdia in the field<br />
of bio-based succinic acid, in exchange for undisclosed<br />
financial consideration. Furthermore, the agreement provides<br />
comfort to both BioAmber and Reverdia to continue the<br />
implementation of their respective businesses using their<br />
own unique, proprietary yeast-based technologies.<br />
“In today’s increasingly complex intellectual property<br />
environment, the conclusion of this agreement illustrates<br />
how two proactive companies operating in the same field can<br />
find a constructive solution that allows them to focus on the<br />
execution of their respective business plans rather than seeking<br />
confrontation and conflict,” said JF Huc, BioAmber’s Chief<br />
Executive Officer. “It allows BioAmber to eliminate the risk of<br />
litigation and uncertainty at a predictable cost,” he added.<br />
”This Agreement demonstrates that Reverdia’s<br />
Biosuccinium low pH yeast technology is a leading technology<br />
in the field of bio-based succinic acid and that by working with<br />
partners in the industry, we will speed up the adoption of biobased<br />
materials and validate bio-based succinic acid as a<br />
key building block for the bio-based economy,” said Marcel<br />
Lubben, Reverdia’s President. “It is our belief that the yeastbased<br />
technologies have a significant competitive advantage<br />
over bacterial-based technologies for the production of biobased<br />
succinic acid,” he added.<br />
Both Marcel Lubben and Jean-Francois Huc believe that<br />
the market for succinic acid will benefit from having strong<br />
players able to deliver on the rapidly growing demand in<br />
bio-plastics, polyurethanes, solvents, coatings and other<br />
applications. KL<br />
www.bio-amber.com | www.reverdia.com<br />
Bioplastic from<br />
biodiesel co-product<br />
glycerol<br />
An agreement signed today by Bio-on and S.E.C.I. S.p.A.<br />
(part of Gruppo Industriale Maccaferri Holding), will see<br />
Italy’s and the world’s first facility for the production<br />
of PHA bioplastics from a co-product from biodiesel<br />
production, namely glycerol.<br />
The two companies will collaborate on the construction<br />
of a production site with an initial output of 5 thousand<br />
tonnes/year, scalable to 10 thousand tonnes/year.<br />
S.E.C.I. is investing EUR 55 million in the facility,<br />
which will be located at an Eridania Sadam (also part<br />
of Maccaferri Holding) site and will be the world’s most<br />
advanced plant producing PHAs biopolymers from<br />
glycerol.<br />
PHAs, or polyhydroxyalkanoates, are bioplastics that<br />
can replace a number of traditional polymers currently<br />
made with petrochemical processes using hydrocarbons.<br />
The PHAs developed by Bio-on guarantee the same<br />
thermo-mechanical properties with the advantage of<br />
being completely naturally biodegradable.<br />
“We are investing EUR 4 million in purchasing the<br />
license for this new technology developed by Bio-on,” says<br />
Eridania Sadam Chairman Massimo Maccaferri, “because<br />
this all-natural bioplastic represents a technological<br />
challenge that can contribute towards the growth of our<br />
group in the new “green” chemistry industry, with an ecocompatible<br />
and eco-sustainable approach”.<br />
“We will create Italy’s first PHAs production plant from<br />
glycerol with one of Europe’s most important industrial<br />
groups,” explains Marco Astorri, Chairman of Bio-on<br />
“We have granted the first technological license from<br />
glycerol in line with our expectations and will be entering<br />
into a new collaboration to develop the promising highperforming<br />
biopolymers business developed by Bio-on.<br />
and produced in Italy from glycerol by S.E.C.I.” KL<br />
www.maccaferri.it | www.bio-on.it<br />
Magnetic<br />
for Plastics<br />
www.plasticker.com<br />
• International Trade<br />
in Raw Materials, Machinery & Products Free of Charge.<br />
• Daily News<br />
from the Industrial Sector and the Plastics Markets.<br />
• Current Market Prices<br />
for Plastics.<br />
• Buyer’s Guide<br />
for Plastics & Additives, Machinery & Equipment, Subcontractors<br />
and Services.<br />
• Job Market<br />
for Specialists and Executive Staff in the Plastics Industry.<br />
Up-to-date • Fast • Professional<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 7
Events<br />
The world’s largest<br />
conference on<br />
biocomposites<br />
By:<br />
Asta Partanen and Michael Carus<br />
nova-Institute<br />
Hürth, Germany<br />
From 16 – 17 December 2<strong>01</strong>5, the world’s largest conference<br />
on Wood-Plastic Composites (WPC) and Natural<br />
Fibre Composites (NFC) with more than 220 participants<br />
took place for the sixth time in Cologne, Germany. The<br />
conference was sponsored by Beologic, Corbion-Purac and<br />
Plasthill. Coperion sponsored the Wood and Natural Fibre<br />
Composite Award 2<strong>01</strong>5.<br />
The range of topics that addressed the whole variety of<br />
bio-composites was presented by top speakers from the<br />
industry and research. Construction and automotive are the<br />
biggest markets for WPC and NFC today, these materials<br />
offer huge replacement potential in plastics and composites<br />
if one looks at application fields beyond decking and<br />
automotive interior applications. Biobased raw materials<br />
lead to local added value through innovative production<br />
processes and products, but require a great amount of<br />
know-how for raw materials, processes, properties, recipes<br />
and application fields. The conference provided an up-todate<br />
picture of different technologies and most promising<br />
applications.<br />
Dr. Asta Partanen, project leader of the conference, gave<br />
the outline of “Status and Future Markets for Biobased<br />
Composites in Europe until 2020”. The presentation gave<br />
insight into the new market and trend report, which was<br />
published in June 2<strong>01</strong>5: “Wood-Plastic Composites (WPC)<br />
and Natural Fibre Composites (NFC): European and<br />
Global Markets 2<strong>01</strong>2 and Future Trends in Automotive and<br />
Construction”. According to the study the share of WPC<br />
and NFC in the total composite market – including glass,<br />
carbon, wood and Natural Fibre Composites – is already<br />
an impressive 15 %. The production volume of WPC was<br />
260,000 t in the EU in 2<strong>01</strong>2, for NFC 92,000 t. The full study<br />
can be downloaded at http://bio-based.eu/markets/.<br />
Ten years ago the WPC & NFC Conference started as<br />
First German WPC-Conference. Good reason for Dr. Hans<br />
Korte from Dr. Hans Korte Innovationberatung Holz &<br />
Fasern, Wismar, to summarize what happened in the<br />
technical development starting at the end of 1990s in the<br />
field of WPC. The German WPC market is continuously<br />
growing, as was reported by Dr. Peter Sauerwein from the<br />
“Association of the German Wood-Based Panel Industry<br />
(VHI)”. An analyses of commercially available European<br />
decking samples was presented by Dr. Andreas Haider<br />
from Wood K plus, Austria. Some products in the market<br />
show an overall better performance compared to 2008 – in<br />
particular regarding water absorbance and colour fading<br />
but also the mechanical properties. Dr. Wayne Song, WPCC<br />
(Wood-Plastic Composite Council of China) presented the<br />
latest market news and trends, especially in interior walls<br />
in the Chinese markets, that does not grow as much as<br />
was predicted by Chinese representatives in previous<br />
conferences.<br />
As every year, the Wood and Natural Fibre Composite<br />
Award was a highlight of the conference. The participants<br />
chose by far the natural fibre-reinforced, 100 % biobased<br />
coffin as their winner (Onora, s-Hertogenbosch, The<br />
Netherlands.<br />
Second highlight was the trend in WPC and NFC<br />
granulates. So far, also mainly small producers and traders<br />
were offering WPC and NFC granulates with a limited<br />
technical support and often missing data for simulations.<br />
But also this is changing since big global players are<br />
offering their new developed materials, such as PolyOne<br />
(see article on p. 12).<br />
Developments in the use of biobased polymers in the<br />
automotive industry were shown by a number of companies<br />
(see detailed report on p. 16f).<br />
Michael Carus, managing director of nova-Institute,<br />
summed up: “It was impressive to see the dynamic in the<br />
WPC and NFC sector: Improved bio-composite properties,<br />
a broad range of professional players and the penetration<br />
of new markets such as consumer goods. The participants<br />
enjoyed the high quality of the presentations and exhibition<br />
and meeting the who-is-who of the whole sector. Many<br />
reported excellent business opportunities.”<br />
The award winning coffin in the left corner of the picture.<br />
See a more detailed report on this product in<br />
bioplastics MAGAZINE issue 06/2<strong>01</strong>5, p 36.<br />
Information:<br />
All presentations are now available at http://bio-based.eu/proceedings.<br />
In order to keep track of the the growing trends in the market and high<br />
demand the next conference will be held by nova-Institute in Cologne in<br />
Autumn 2<strong>01</strong>7.<br />
8 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
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Events<br />
4 th PLA World Congress<br />
24 – 25 MAY 2<strong>01</strong>6 MUNICH › GERMANY<br />
bioplastics MAGAZINE presents:<br />
3 rd PLA World Congress<br />
The PLA World Congress in Munich/Germany, organised by bioplastics MAGAZINE<br />
27 + 28 MAY 2<strong>01</strong>4 MUNICH ›<br />
now for the 4 GERMANY<br />
th time, is the must-attend conference for everyone interested in PLA,<br />
its benefits, and challenges. The conference offers high class presentations from<br />
top individuals in the industry and also offers excellent networkung opportunities<br />
along with a table top exhibition. Please find below the preliminary programme.<br />
Find more details and register at the conference website<br />
www.pla-world-congress.com<br />
4 th PLA World Congress, preliminary programme<br />
Constance Ißbrücker, European Bioplastics<br />
Michael Carus, nova-Institute<br />
Mariagiovanna Vetere, NatureWorks<br />
Patrick Zimmermann, FKuR<br />
Björn Bergmann, Fraunhofer ICT<br />
Udo Mühlbauer, Uhde Inventa-Fischer<br />
Vittorio Bortolon, Plantura Italia<br />
Jan Henke, ISCC<br />
Amparo Verdú Solís, AIMPLAS<br />
Tanja Siebert, Fraunhofer IVV<br />
Daniel Ganz, Sukano<br />
Hugo Vuurens, Corbion Purac<br />
Ramani Narayan, Michigan State University<br />
Jan Noordegraaf, Synbra<br />
Bert Lagrain, KU Leuven<br />
Gerald Schennink, Wageningen UR<br />
Panel discussion: t.b.d.<br />
Keynote Speech: t.b.d.<br />
The role of PLA in the Bio-based Economy<br />
Ingeo – developing new applications in a circular economy perspective<br />
t.b.d.<br />
InnoREX: European project reveals processing options for intensified PLA production<br />
New features of Uhde Inventa-Fischer’s PLAneo ® process<br />
Plantura, ecofriendly automotive biopolymer<br />
Sustainable supply chains for PLA production<br />
New PLA based fibres for automotive interior applications<br />
Present and potential future recycling of PLA waste – Chances and opportunities<br />
Sustainability without compromises – Discover a toolbox of solutions for PLA<br />
Latest application innovations in PLA bioplastics<br />
Understanding the PLA molecule – From stereochemistry to applicability<br />
An expanding update on BioFoam E-PLA foam applications<br />
PLA: a perfect marriage between bio- and chemical technology<br />
PLA for durable applications comparing PLA hybrids with nucleated PLA (t.b.c.)<br />
PLA market development: chances, obstacle and challenges (t.b.c.)<br />
Call for papers is still open.<br />
Please send your abstract to mt@bioplasticsmagazine.com<br />
Info<br />
See a video-clip of the<br />
3 rd PLA World Conference 2<strong>01</strong>4<br />
at https://youtu.be/5o-6Ej7Q0_0<br />
10 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
4 th PLA World Congress<br />
24 – 25 MAY 2<strong>01</strong>6 MUNICH › GERMANY<br />
is a versatile bioplastics raw<br />
PLA material from renewable resources.<br />
It is being used for films and rigid packaging,<br />
for fibres in woven and non-woven applications.<br />
Automotive industry<br />
and consumer electronics are thoroughly<br />
investigating and even already applying PLA.<br />
New methods of polymerizing, compounding<br />
or blending of PLA have broadened the range<br />
of properties and thus the range of possible<br />
applications.<br />
That‘s why bioplastics MAGAZINE is now<br />
organizing the 4 th PLA World Congress on:<br />
24 – 25 May 2<strong>01</strong>6 in Munich / Germany<br />
Experts from all involved fields will share their<br />
knowledge and contribute to a comprehensive<br />
overview of today‘s opportunities and challenges<br />
and discuss the possibilities, limitations<br />
and future prospects of PLA for all kind of<br />
applications. Like the three congresses<br />
the 4 th PLA World Congress will also offer<br />
excellent networking opportunities for all<br />
delegates and speakers as well as exhibitors<br />
of the table-top exhibition.<br />
The conference will comprise high class presentations on<br />
The team of bioplastics MAGAZINE is looking<br />
forward to seeing you in Munich.<br />
› Latest developments<br />
› Market overview<br />
EARLY BIRD DISCOUNT<br />
Register now to benefit from the<br />
Early Bird fee of just EUR 799<br />
(after Feb 28, 2<strong>01</strong>6 it will be 899).<br />
› High temperature behaviour<br />
› Barrier issues<br />
› Additives / Colorants<br />
› Applications (film and rigid packaging, textile,<br />
automotive,electronics, toys, and many more)<br />
› Fibers, fabrics, textiles, nonwovens<br />
Contact us at: mt@bioplasticsmagazine.com<br />
for exhibition and sponsoring opportunities<br />
www.pla-world-congress.com<br />
› Reinforcements<br />
› End of life options<br />
(recycling,composting, incineration etc)<br />
organized by<br />
Gold Sponsor:
Automotive<br />
Lightweighting<br />
is key<br />
Reaching lightweighting goals<br />
with new natural fiber reinforced<br />
solutions<br />
Charpy<br />
unnotched<br />
Flexural<br />
modulus<br />
100 %<br />
80 %<br />
60 %<br />
40 %<br />
20 %<br />
0 %<br />
Tensile<br />
strength<br />
Flexural<br />
strength<br />
Tensile<br />
modulus<br />
Tensile<br />
elongation<br />
Coupling Technologie 1 Coupling Technologie 2<br />
Graph 1: Performance comparison between the two coupling<br />
technologies on Natural Engineered Fiber 1<br />
Graph 2: Comparison of reSound NF 40% natural fiber reinforced<br />
solution vs. ultimate target profile<br />
Specific gravity<br />
100 %<br />
HDT A<br />
HDT B<br />
Charpy unnotched<br />
impact strength<br />
80 %<br />
60 %<br />
40 %<br />
20 %<br />
0 %<br />
Flexural modulus<br />
Ultimate target<br />
Results<br />
Tensile strength<br />
at break<br />
Tensile modulus<br />
Flexural strength<br />
at break<br />
Manufacturers of semi-structural automotive applications<br />
now have the option to reduce part weight by<br />
5 % or more, maintain mechanical performance, and<br />
even use more sustainable materials. A triad of developments<br />
makes this possible.<br />
Automobile manufacturers need to improve their vehicles’<br />
fuel efficiencies, as required by global regulations. Reducing a<br />
vehicle’s weight is one of the most direct ways to improve fuel<br />
efficiency. Not only do lower-weight vehicles use less fuel, but<br />
they also generate lower carbon dioxide (CO 2<br />
) emissions. For<br />
carmakers marketing their vehicles in Europe, failure to reach<br />
incremental CO 2<br />
limits imposed by the European Commission<br />
would force OEMs to pay a significant penalty of up to 95 € per<br />
gram of CO 2<br />
over the limit and for each new car sold.<br />
PolyOne recognized the challenges these new regulations<br />
placed on manufacturers in the automotive industry and set<br />
out to develop a solution that could meet the mechanical<br />
properties of parts made with short glass fiber reinforced<br />
polypropylene (GFR-PP), but with a density at least 5 % less<br />
than that of GFR-PP. The Company targeted more than 20<br />
demanding automotive applications; many of these are large<br />
parts, such as instrument panel carriers and lighting systems,<br />
so a 5 – 10 % reduction in density could lead to significant<br />
overall weight reduction.<br />
A reduction of this magnitude is what automotive customers<br />
said was necessary for them to consider alternate materials<br />
to those already proven suitable for commercial use.<br />
PolyOne’s search for a solution to the lightweighting challenge<br />
led to the development of a new natural fiber reinforced<br />
thermoplastic (NFR-TP) that supports lightweighting goals in<br />
the automotive and other industries, while also maintaining<br />
the necessary mechanical performance characteristics.<br />
Develop a novel compounding process<br />
The Company is one of the world’s leading developers of<br />
thermoplastic compounds, with research and development<br />
experts at laboratories around the world. As the process to<br />
develop a lightweight replacement for GFR-PP began, the experts<br />
there recognized that a new type of compounding process showed<br />
promise for the manufacture of strong, stable compounds even<br />
with materials of different polarities. R&D teams at PolyOne had<br />
been working for two years to optimize the process, and believed<br />
this new compounding technology could be key to manufacturing<br />
NFR-TP solutions with excellent mechanical properties. It seemed<br />
a critical part of the solution to the long-recognized challenge of<br />
the ability of a non-polar thermoplastic material to couple with a<br />
polar reinforcing material.<br />
12 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Automotive<br />
This new compounding technology proved to be the first leg<br />
in the triad of developments that led to success.<br />
Find the best fiber for the job<br />
When it comes to reinforcing polypropylene with natural<br />
fiber, many routes, variables, and choices can have a<br />
significant influence on the final solution:<br />
• type of PP (homo- or copolymer)<br />
• melt index<br />
• type of reinforcing fiber<br />
• coupling technology<br />
• manufacturing process<br />
A design of experiment (DOE) helped reduce these input<br />
variables down to three: the type of fiber, coupling technology<br />
for the fiber and the PP, and manufacturing process<br />
(compound extrusion). PolyOne’s R&D experts already<br />
had developed what the researchers felt might be the best<br />
manufacturing process, but they needed to find the right<br />
materials. A PP homopolymer was determined to be the<br />
optimal matrix material with the appropriate melt index.<br />
So the best fiber for the applications targeted needed to<br />
be found, and a coupling technology to enable these fibers<br />
to bond well with the thermoplastic matrix material. Natural<br />
fibers made sense because of their low density; but to serve<br />
the automotive industry, fibers need to be available globally,<br />
with consistent sizing and quality.<br />
Testing of many types of natural fiber led to an engineered<br />
fiber, available globally as a modified product of an established<br />
wood fabrication industry. These fibers are supplied with<br />
consistent length and thickness, facilitating production<br />
of a compound with consistent properties – if the new<br />
compounding technology was able to evenly distribute the<br />
fibers throughout the matrix material, and helped create a<br />
powerful bond between fiber and matrix material.<br />
A powerful bond<br />
The best fibers would be worth little if they could not be<br />
properly mixed into and bonded with the thermoplastic matrix.<br />
PolyOne’s search for solutions to these challenges led them to<br />
a coupling technology that forged the necessary bond, as seen<br />
in Graph 1. Coupling Technology 1 is an advanced technology<br />
while Coupling Technology 2 is a more classical technology.<br />
Coupling Technology 1 was tested on multiple fibers but<br />
ultimately PolyOne settled on the natural engineered fiber<br />
mentioned earlier.<br />
Testing began to determine whether the positive results<br />
seen in lab testing could be maintained at commercial<br />
scale. In addition, it needed to be investigated whether the<br />
new compounding process had an influence on the property<br />
profile at various reinforcing fiber amounts (30 % and 40 %<br />
in weight).<br />
The properties of the material manufactured on industrial<br />
scale machinery are very similar to the original target, and<br />
realize a density reduction versus short glass fiber alternatives<br />
of at least 5 % (Graph 2). The new formulations were named<br />
reSound NF natural fiber reinforced solutions; reSound is<br />
PolyOne’s brand name for formulations that contain 30 % or<br />
more of renewably resourced materials. u<br />
By:<br />
Marc Mézailles<br />
Global Automotive Industry Manager,<br />
PolyOne Corporation<br />
Lyon, France<br />
Photo 1: Lightweight and strong: Tests have proven the mechanical<br />
performance of parts molded from reSound NF natural fiber<br />
reinforced solutions.<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 13
Automotive<br />
Drop-in solution for your existing equipment and<br />
processes<br />
Injection molding of tensile bars and then larger parts<br />
(Photo 1) proved the mechanical performance and easy<br />
processability of reSound NF formulation. Like most natural<br />
fiber reinforced thermoplastics, reSound NF material should<br />
be processed at temperatures below 200 °C in order to<br />
maintain the integrity of the naturally-originating fibers.<br />
Using low temperatures also offers potential energy savings<br />
and short cooling times, providing an efficient yield for<br />
manufacturers.<br />
Further testing revealed that reSound NF material is<br />
compatible with and shows robust property retention when<br />
molded on machinery outfitted with the MuCell ® foaming<br />
technology from Trexel. The retention is as robust as PP‐SGF<br />
for tensile properties, is even more robust for flexural<br />
properties, and clearly more stable for impact properties.<br />
The reSound NF solutions also are compatible with chemical<br />
foaming technologies, and exhibit strong bonding with<br />
selected thermoplastic elastomers, also found in PolyOne’s<br />
solutions portfolio. Separate trials also proved that customers<br />
could select a reSound NF concentrate, rather than a fully<br />
compounded formulation with a predetermined percentage<br />
of fiber loading, if they wanted to adjust final reinforcement<br />
levels vs. application needs.<br />
Finally, tests also were conducted to determine the<br />
recyclability of reSound NF material. Tensile bars were<br />
molded, reground, and molded again with the regrind material<br />
only. This was repeated three times.<br />
These results show a very stable performance towards<br />
regrinding for reSound NF versus PP-SGF. It seems the<br />
limitation in the on-line re-introduction of reground PP-SGF<br />
into the manufacturing process does not apply to reSound<br />
NF material, which offers a potential “no scrap” process for<br />
manufacturers.<br />
Time for a change<br />
Advanced material and manufacturing technologies have<br />
been combined to create reSound NF, a NFR-TP solution<br />
with a low specific gravity but offering excellent mechanical<br />
properties. Manufacturers can select reSound NF natural fiber<br />
reinforced solutions to reduce parts’ weights 5 – 10 % lower<br />
than ones made using comparable glass fiber formulations.<br />
Compared to other natural fiber reinforced solutions,<br />
reSound NF solutions offer mechanical property improvements<br />
of more than 20 % for tensile and flexural properties, 10 °C<br />
to 20 °C higher heat deflection temperature, and more than<br />
50 % in impact strength.<br />
Customers can process reSound NF material on existing<br />
machinery and tooling at low injection molding temperatures,<br />
resulting in short cycle times. These new natural fiber<br />
reinforced polymer formulations enable automotive OEMs and<br />
their suppliers to meet goals for lightweighting, sustainability,<br />
production efficiency and performance.<br />
Customers from non-automotive industries that value<br />
lightweighting and sustainable solutions in technical<br />
applications can benefit from reSound NF formulations too.<br />
www.polyone.com<br />
Carbon/Flax hybrid automotive roof<br />
The CARBIO project has developed a carbon/flax hybrid automotive roof using Composite Evolution’s Biotex Flax material.<br />
The project, which involves Jaguar Land Rover, is developing novel carbon/flax hybrid composites to produce automotive<br />
structures with reduced weight, cost, environmental impact and improved noise, vibration and harshness (NVH).<br />
The adoption of carbon fibre-epoxy composites to reduce vehicle weight is presenting significant challenges to the volume<br />
automotive industry. Compared to carbon, flax fibres are renewable, lower in cost, CO 2<br />
neutral and have excellent vibration<br />
damping properties. In addition, bio-epoxy resins based on cashew nut shell liquid (CNSL) can offer enhanced toughness,<br />
damping and sustainability over synthetic epoxies.<br />
By creating a hybrid structure using flax-bioepoxy to replace some of the carbon, enhanced properties such as lower weight,<br />
cost, NVH and environmental impact can be gained.<br />
A 50/50 carbon/flax hybrid biocomposite, made from Biotex Flax supplied by Composites Evolution and prepregged by SHD<br />
Composite Materials, has significantly contributed to achieving the objectives of the project. With equal bending stiffness to<br />
carbon fibre, the hybrid biocomposite has:<br />
• 15 % lower cost<br />
• 7 % lower weight<br />
• 58 % higher vibration damping<br />
The prototype roof, designed by Delta Motorsport and manufactured<br />
by KS Composites, was displayed at the Advanced Engineering show, last<br />
November in Birmingham, UK.<br />
The CARBIO project is part-funded by Innovate UK. The partners are<br />
Composites Evolution, SHD Composite Materials, KS Composites, Delta<br />
Motorsport, Jaguar Land Rover and Cranfield University. MT<br />
http://carbioproject.com<br />
14 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Automotive<br />
Smart bioplastics for<br />
automotive applications<br />
By:<br />
Francesca Brunori<br />
Advanced Development Engine Systems<br />
Röchling Automotive<br />
Laives, Italy<br />
Röchling Automotive reports promising results on the development<br />
of automotive parts made of Plantura PLA<br />
based biopolymers.<br />
In collaboration with Plantura Italia Srl (Italy) and Corbion<br />
Purac (The Netherlands), Röchling Automotive is working<br />
towards greener products offering similar or enhanced<br />
technical functionality.<br />
Plantura has a CO 2<br />
equivalent emission of approximately<br />
0.5 tonnes for each ton of produced raw material. This is<br />
around 70 % lower than PP, and close to 90 % less than PA6.<br />
There are currently four standard grades available that are<br />
suitable for low to medium demanding automotive underthe-hood<br />
applications and – using the glass fiber filled<br />
grade – in underbody applications. The talc filled standard<br />
grade, as well as natural fiber filled grades, are suitable for<br />
automotive interior applications. As these different standard<br />
grades, which boast a biocontent of up to 95 %, can be finetuned<br />
to meet specific customer needs and final application<br />
requirements, the material has already been used in series<br />
production in sectors other than the automotive market. The<br />
compounds can be processed and recycled with conventional<br />
plastics processing and recycling technologies.<br />
In comparison to standard PLA, Plantura showed significant<br />
improvements in thermal stability and chemical resistance.<br />
Long term thermal stability was tested according to thermal<br />
cycle tests performed from -40 °C to 140 °C according to an<br />
OEM’s specification. When tested at temperatures as low as<br />
-30 °C, the material demonstrated an outstanding impact<br />
resistance for shockproof parts, showing that Plantura 30 %<br />
GF can offer values of up to 50 % higher Charpy impact<br />
strength compared to a PA6 GF+M30. The materials also<br />
exhibit excellent hydrolysis resistance.<br />
Prototype filter boxes (cf. fig. 1) as well as interior parts<br />
were tested according to the OEM’s complete specifications,<br />
with very promising results<br />
The use of Plantura for the air flaps (fig. 3) of an Active Grille<br />
Shutter (fig. 2) was investigated and the initial results bode<br />
well for the future. The injection molded Plantura component<br />
has a higher stiffness compared to the component produced<br />
with the standard material (PA6 GF30). Because of this,<br />
deflection is lower during use, which can be used to reduce<br />
air leakage. Moreover, thanks to the lower shrinkage of the<br />
material, it is also possible to reduce the deformation of the<br />
final component. Another big advantage to using Plantura for<br />
this application is that the dimensional stability will increase<br />
over the lifetime of the component, due to the fact that no<br />
humidity is absorbed. The scratch resistance behavior of PLA,<br />
an extremely important aspect when it comes to aesthetic<br />
components in general, and in this case for aesthetic Active<br />
Grille Shutters In particular, is well known and taken into<br />
consideration in the Plantura formulations.<br />
The continuous development of the material has led to<br />
higher, and increasingly interesting cost efficiency. With its<br />
significant contribution to an improved CO 2<br />
balance, Plantura<br />
could become an important concept in the automotive world.<br />
www.roechling.com<br />
Fig. 1: Filter box made of Plantura 30 % Wood Fibers<br />
Fig. 2: Assembled Active Grille Shutter<br />
Fig. 3: Air flaps of Active Grille Shutter made of<br />
Plantura 30 % Glass Fiber reinforced<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 15
Automotive<br />
Biocomposites in the<br />
automotive industry<br />
By:<br />
Michael Carus and Asta Partanen<br />
Nova-Institute<br />
Hürth, Germany<br />
“Nature 50 – long fibre” for injection moulding with a cold-press<br />
method. These long fibre pellets with more than 50 % hemp<br />
fibre content, polypropylene and additives are produced with<br />
pellet technology. They can be used for injection moulded parts<br />
with standard machines and standard tools as a substitution<br />
of PC/ABS with 20 % glass fibre content. Their fibre structure<br />
gives them a unique look and makes them suitable also for<br />
use outside the automotive industry. (courtesy HIB TRIM PART<br />
SOLUTIONS)<br />
The second biggest application sector for biocomposites<br />
is the automotive interior sector. The main application is<br />
the construction sector and third is consumer goods. At<br />
the world’s largest conference on Wood-Plastic Composites<br />
(WPC) and Natural Fibre Composites (NFC) with more than<br />
220 participants in December 2<strong>01</strong>5 in Cologne, Germany (see<br />
p. 8), one extended session informed about the latest status of<br />
biocomposites in the automotive industry.<br />
Biocomposites contain wood or natural fibres or/and<br />
biobased polymers. So far, almost all biocomposites contain<br />
wood or natural fibres, but only a few using biobased<br />
polymers. Experts speak about Wood-Plastic Composites<br />
(WPC) and Natural Fibre Composites (NFC). Especially in<br />
the interior applications in middle and high class cars, NFC<br />
are well established and a growing market. The dominating<br />
technology is compression moulding, with a natural fibre nonwoven<br />
fleece. One of the leading experts is Werner Klusmeier<br />
(Yanfeng Europe Automotive Interior Systems (formerly JCI))<br />
and speaker at the conference summarized: “There is a<br />
diversity of reasons for the use of natural fibres: Advantages<br />
in the ecological footprint, affordable production costs as well<br />
as good acoustic and mechanical properties. Furthermore,<br />
natural fibre reinforced plastics convince with their low<br />
weight. They enable savings in mass of up to 30 % – which is<br />
a decisive plus in times of lightweight construction. Natural<br />
fibre composites have been and are still further developed<br />
in terms of lightweight construction and strength. They have<br />
become integral parts of the automotive industry.”<br />
The combination of compression moulding and simultaneous<br />
back injection moulding can bring further weight reduction,<br />
as Tayfun Buzkan and Motoki Maekawa from Toyota Boshoku<br />
Europe demonstrated in their presentation. The material<br />
performance completely meets automotive requirements and<br />
reduces production time.<br />
Developments in the use of biobased polymers in the<br />
automotive industry were shown by Global Marketing Director<br />
bioplastics at Corbion Purac, François de Bie, together<br />
Biocomposites with Natural Fibres, Wood Fibres and Recycled Cotton in the European Automotive Production in 2<strong>01</strong>2<br />
Biocomposites<br />
Natural Fibre<br />
Composites<br />
Wood-Plastic<br />
Composites<br />
Recycled Cotton<br />
Reinforced Plastics<br />
Volume fibres in<br />
tonnes in 2<strong>01</strong>2<br />
Volume<br />
biocomposites in<br />
tonnes in 2<strong>01</strong>2<br />
30,000 60,000<br />
30,000 60,000<br />
Processing technologies<br />
95 % compression moulding,<br />
5 % injection moulding & others<br />
45 % extrusion & thermoforming,<br />
50 % compression moulding & others<br />
5 % injection moulding<br />
Matrice<br />
55 % thermoplastics,<br />
45 % thermosets<br />
Extrusion:<br />
100 % thermoplastics,<br />
compression moulding:<br />
>90 % thermoset<br />
20,000 30,000 mainly compression moulding >90 % thermoset<br />
Total 80,000 150,000<br />
16 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Automotive<br />
with Francesca Brunori from Röchling Automotive. They<br />
presented their latest cooperation results on high heat PLA<br />
100% biobased natural fibre filled compounds with injection<br />
and compression moulding. The material is ready to use and<br />
Röchling is already in contact with different OEMs (see also<br />
page 15).<br />
Experts expect a growth in injection moulding for WPC and<br />
NFC: So far, also mainly small producers and traders were<br />
offering WPC and NFC granulates with a limited technical<br />
support and often missing data for simulations. But also<br />
this is changing since big global players are offering their<br />
new developed materials: “Sustainable Light weighting<br />
Thermoplastic Solutions for Automotives” (see also page<br />
12) was presented by Marc Mézailles from PolyOne Global<br />
Engineered Materials. This innovation from PolyOne breaks<br />
the conventional material property balance and opens<br />
the industrial use of natural fibres reinforced solutions in<br />
many demanding end applications and markets, including<br />
automotive, with a 5 to 10% light weighting potential vs.<br />
standard solutions. The material has a typical 30% fibre<br />
content, the fibre is an engineered industrial wood fibre, and<br />
a new coupling technology as well as a specific compounding<br />
process is used. PolyOne a first official OEM approval on a<br />
critical semi-structural application, and continues to be<br />
evaluated by several key OEMs and their Tier One suppliers.<br />
Today, as the last survey from nova-Institute showed,<br />
about 4 kg natural and wood fibres per vehicle in average<br />
are used European automotive production; but vehicles with<br />
considerably larger amounts of 20 kg natural and wood fibres<br />
have been successfully produced in series for years and could<br />
credit these amounts in the future.<br />
Most experts expect a continuously growth in the use of<br />
WPC and especially NFC in the automotive industry because<br />
of the high light weight potential of these materials, the<br />
continuously improvement of technologies and properties<br />
and new professional players. The combination with biobased<br />
polymers to realize fully biobased biocomposites is just<br />
starting and could become an additional market for biobased<br />
polymers such as PLA or PBS.<br />
www.nova-institute.com<br />
This table is showing the main reason, why Natural Fibre<br />
Composites (NFC) are such an exciting material for the automotive<br />
industry<br />
NF compression moulded – superior lightweight properties<br />
Automotive interior parts Area weight in g/m 2<br />
WPC – extruded and moulded 2,500<br />
Injection moulded pure plastc or glass fibre<br />
reinforced plastics<br />
>2,200<br />
Compression moulded PP-NF 1,800<br />
Compression moulded PP-NF with bonding<br />
agent MAPP<br />
1,500<br />
Compression moulded thermosets-NF 1,400 – 1,500<br />
Compression moulded thermosets-NF<br />
In development, production expected after<br />
2<strong>01</strong>8<br />
800 – 1,000<br />
All figures and tables are teken from the study<br />
“Wood-Plastic Composites (WPC) and Natural<br />
Fibre Composites (NFC): European and Global<br />
Markets 2<strong>01</strong>2 and Future Trends in Automotive and<br />
Construction“. The full study can be downloaded at<br />
http://bio-based.eu/markets<br />
All presentations of the conference are now available at<br />
http://bio-based.eu/proceedings<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 17
Materials<br />
The gluten solution<br />
New TPVs derived from wheat gluten<br />
By Karen Laird<br />
While gluten has got a lot of bad press over the past<br />
few years, there is still good news to report. Gluten,<br />
it turns out, can actually serve as the basis for a new<br />
type of biobased plastic material, say scientists at the KU<br />
Leuven in Belgium. These researchers are working on the development<br />
of a new type of thermoplastic vulcanisate – based<br />
on gluten.<br />
But what is gluten? Very simply put, is the seed storage<br />
protein in mature cereal seeds. More specifically, it is a protein<br />
composite, meaning it is a substance made up of several<br />
different proteins, in this case gliadin and a glutenin. The<br />
cross-linking of gliadin molecules and glutenin molecules<br />
creates the primary properties associated with gluten.<br />
According to Lien Telen, a postdoctoral researcher at KU<br />
Leuven who has spent the past five years exploring the the<br />
use of wheat gluten to produce thermoplastic elastomers,<br />
there are a number of aspects that make gluten an attractive<br />
starting point for novel biobased materials. In the first place,<br />
there is a lot of it: as a co-product of industrial gluten-starch<br />
separation or bioethanol production, gluten is available in<br />
Europe in quantities of up to 1 million tonnes on an annual<br />
basis. Only part of this gluten is used as a high-value bakery<br />
ingredient, while the excess is mostly used in animal feed.<br />
Secondly, unlike most other proteinaceous resources,<br />
gluten contains high molar mass constituents and unique<br />
network forming properties, which means it can readily be<br />
converted into a variety of biobased materials.<br />
The development that has received the most attention of the<br />
gluten team at KU Leuven, said Telen, has been the glutenbased<br />
TPVs (TPV stands for thermoplastic vulcanizates).<br />
These new materials are colorable and can be processed on<br />
conventional processing equipment. Unlike the olefin-based<br />
rubbers in conventional TPVs, wheat gluten intrinsically<br />
crosslinks under the influence of heat, eliminating the need<br />
for an additional chemical crosslinker. Gluten-based TPVs<br />
combine the typical properties and functional performance<br />
of rubbers with the melt processability of thermoplastic<br />
polymers, resulting in recyclable materials. Telen explains:<br />
“The gluten TPV consists of (non-recyclable) crosslinked<br />
gluten particles within a thermoplastic matrix. The main<br />
advantage of these TPVs is that they have elastomeric<br />
characteristics at room temperature combined with the<br />
melt processability of thermoplastic materials. The rubber<br />
particles are very small (a few µm) and will flow in the melt<br />
of the thermoplastic matrix making the entire material<br />
recyclable using standard thermoplastic polymer processing<br />
equipment such as extrusion and injection molding.”<br />
The gluten team is also working on improving the<br />
properties of the new TPVs, which, said Telen, “fall short on<br />
water-resistance, oil and chemical resistance and operational<br />
temperature range”. Yet what also sets gluten-based TPVs<br />
apart is the possibility of combining elastomeric behavior and<br />
biodegradability in a single material, a combination not seen in<br />
conventional oil-based TPVs. Depending on the thermoplastic<br />
component, the gluten TPV’s can be designed to be fully<br />
biodegradable. TPVs with a polyethylene or polyamide matrix<br />
are not completely biodegradable, as the matrix remains<br />
intact, making them unsuitable for composting.<br />
“However, completely biodegradable and (home)<br />
compostable TPVs have also been developed using a<br />
biodegradable and (home) compostable matrix,” said Telen.<br />
Applications for these materials could include indoor soft<br />
touch materials, or functional biodegradation applications in<br />
the agricultural and horticultural sectors.<br />
Next to gluten-based TPVs, the researchers at KU Leuven<br />
are looking at other materials as well. “In the absence of<br />
a plasticizer, the heat induced crosslinking results in a<br />
glassy, rigid material with material properties comparable<br />
to Polystyrene (PS)”, said Telen. “Gluten composites: rigid<br />
gluten bioplastic reinforced with flax fibers are another focus.<br />
Research on these materials is ongoing and very promising.”<br />
http://chem.kuleuven.be<br />
60 – 80 % biobased non biodegradable 100 % biobased biodegradable<br />
anaerobic<br />
TPV 1 2 3 4<br />
Tensile modulus (MPa) 333 197 265 494<br />
Tensile elongation (%) 247 240 120 18<br />
Tensile strength (MPa) 16 12 9 12<br />
Shore D hardness 42 48 43 51<br />
Melting temperature (°C) 129 118 125 140<br />
Crystallization temperature (°C) 113 60 50 85<br />
18 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Market study on<br />
Bio-based Building Blocks and Polymers in the World<br />
Capacities, Production and Applications: Status Quo and Trends towards 2020<br />
Bio-based polymers: Will the positive growth trend continue?<br />
Bio-based polymers: Worldwide production<br />
capacity will triple from 5.7 million tonnes in<br />
2<strong>01</strong>4 to nearly 17 million tonnes in 2020. The<br />
data show a 10% growth rate from 2<strong>01</strong>2 to 2<strong>01</strong>3<br />
and even 11% from 2<strong>01</strong>3 to 2<strong>01</strong>4. However,<br />
growth rate is expected to decrease in 2<strong>01</strong>5.<br />
Consequence of the low oil price?<br />
million t/a<br />
Bio-based polymers: Evolution of worldwide production capacities<br />
from 2<strong>01</strong>1 to 2020<br />
20<br />
actual data<br />
forecast<br />
The new third edition of the well-known 500<br />
page-market study and trend reports on<br />
“Bio-based Building Blocks and Polymers<br />
in the World – Capacities, Production and<br />
Applications: Status Quo and Trends Towards<br />
2020” is available by now. It includes consistent<br />
data from the year 2<strong>01</strong>2 to the latest data of 2<strong>01</strong>4<br />
and the recently published data from European<br />
Bioplastics, the association representing the<br />
interests of Europe’s bioplastics industry.<br />
Bio-based drop-in PET and the new polymer<br />
PHA show the fastest rates of market growth.<br />
Europe looses considerable shares in total<br />
production to Asia. The bio-based polymer<br />
turnover was about € 11 billion worldwide<br />
in 2<strong>01</strong>4 compared to € 10 billion in 2<strong>01</strong>3.<br />
http://bio-based.eu/markets<br />
©<br />
15<br />
10<br />
5<br />
2<strong>01</strong>1<br />
-Institut.eu | 2<strong>01</strong>5<br />
2% of total<br />
polymer capacity,<br />
€11 billion turnover<br />
2<strong>01</strong>2<br />
Epoxies<br />
PE<br />
2<strong>01</strong>3<br />
PUR<br />
PBS<br />
2<strong>01</strong>4<br />
CA<br />
PBAT<br />
2<strong>01</strong>5<br />
PET<br />
PA<br />
2<strong>01</strong>6<br />
PTT<br />
PHA<br />
2<strong>01</strong>7<br />
PEF<br />
2<strong>01</strong>8<br />
Starch<br />
Blends<br />
EPDM<br />
PLA<br />
2<strong>01</strong>9<br />
2020<br />
Full study available at www.bio-based.eu/markets<br />
The nova-Institute carried out this study in<br />
collaboration with renowned international<br />
experts from the field of bio-based building<br />
blocks and polymers. The study investigates<br />
every kind of bio-based polymer and, for the<br />
second time, several major building blocks<br />
produced around the world.<br />
What makes this report unique?<br />
■ The 500 page-market study contains<br />
over 200 tables and figures, 96 company<br />
profiles and 11 exclusive trend reports<br />
written by international experts.<br />
■ These market data on bio-based building<br />
blocks and polymers are the main source<br />
of the European Bioplastics market data.<br />
■ In addition to market data, the report offers a<br />
complete and in-depth overview of the biobased<br />
economy, from policy to standards<br />
& norms, from brand strategies to<br />
environmental assessment and many more.<br />
■ A comprehensive short version<br />
(24 pages) is available for free at<br />
http://bio-based.eu/markets<br />
To whom is the report addressed?<br />
■ The whole polymer value chain:<br />
agro-industry, feedstock suppliers,<br />
chemical industry (petro-based and<br />
bio-based), global consumer<br />
industries and brands owners<br />
■ Investors<br />
■ Associations and decision makers<br />
Content of the full report<br />
This 500 page-report presents the findings of<br />
nova-Institute’s market study, which is made up<br />
of three parts: “market data”, “trend reports”<br />
and “company profiles” and contains over 200<br />
tables and figures.<br />
The “market data” section presents market<br />
data about total production capacities and the<br />
main application fields for selected bio-based<br />
polymers worldwide (status quo in 2<strong>01</strong>1, 2<strong>01</strong>3<br />
and 2<strong>01</strong>4, trends and investments towards<br />
2020). This part not only covers bio-based<br />
polymers, but also investigates the current biobased<br />
building block platforms.<br />
The “trend reports” section contains a total of<br />
eleven independent articles by leading experts<br />
Order the full report<br />
The full report can be ordered for 3,000 €<br />
plus VAT and the short version of the report<br />
can be downloaded for free at:<br />
www.bio-based.eu/markets<br />
Contact<br />
Dipl.-Ing. Florence Aeschelmann<br />
+49 (0) 22 33 / 48 14-48<br />
florence.aeschelmann@nova-institut.de<br />
in the field of bio-based polymers. These trend<br />
reports cover in detail every important trend<br />
in the worldwide bio-based building block and<br />
polymer market.<br />
The final “company profiles” section includes<br />
96 company profiles with specific data<br />
including locations, bio-based building blocks<br />
and polymers, feedstocks and production<br />
capacities (actual data for 2<strong>01</strong>1, 2<strong>01</strong>3 and<br />
2<strong>01</strong>4 and forecasts for 2020). The profiles also<br />
encompass basic information on the companies<br />
(joint ventures, partnerships, technology and<br />
bio-based products). A company index by biobased<br />
building blocks and polymers, with list of<br />
acronyms, follows.
Materials<br />
Making Levulinic Acid happen<br />
A new (?) building block not only for bioplastics<br />
No. Levulinic acid (LA) is not exactly a new building block<br />
or better a new platform chemical. It has been known<br />
of since 1840. “Everybody knows the benefits of levulinic<br />
acid, but few are using it yet – because it has been too<br />
expensive so far”, Maxim Katinov, CEO of Caserta, Italy based<br />
GFBiochemicals told bioplastics MAGAZINE during a plant visit<br />
in early December.<br />
GFBiochemicals is the first and only company to produce<br />
levulinic acid at commercial scale directly from biomass. The<br />
10,000 tonnes/annum commercial-scale production plant in<br />
Caserta started production in July 2<strong>01</strong>5. The plant uses new<br />
and modified conversion, recovery and purification technology<br />
owned by GFBiochemicals. The company also has offices in<br />
Milan, Italy and Geleen, the Netherlands. In-house application<br />
and R&D is supported by a highly skilled and prolific<br />
management team with decades of experience in innovation,<br />
production and business development of biobased chemicals.<br />
“We have the best people and they are passionate about what<br />
they do”, as Maxim proudly told us. “Many of them left leading<br />
world renowned chemical companies in the Netherlands to<br />
join a startup“, he added.<br />
Levulinic acid is a biobased platform chemical with<br />
applications in the chemical and biofuel sectors. “Levulinic<br />
acid is an essential building block for a green future,” as<br />
Marcel van Berkel, CCO of GFBiochemicals pointed out. In<br />
2004, the US Department of Energy (DoE) identified LA as one<br />
of the 12 most important platform chemicals [1].<br />
Levulinic acid for affordable prices<br />
Fundamentally lower price ranges are now possible for<br />
derivatives using GFBiochemicals technology. “We don’t need<br />
outputs of 150,000 tonnes to be successful,” said Maxim<br />
Katinov. “We can do it economically with three, five or ten<br />
thousand tonnes. And so we can produce and deliver levulinic<br />
acid for prices the market can afford”. The current price level<br />
is at about USD 4 – 5 per kg, but this company is targeting<br />
substantially lower prices, “in the range of one Dollar, when<br />
we reach maturity and produce at large scale,” Marcel van<br />
Berkel commented.<br />
Possible bioplastic applications<br />
Among the possible applications for LA we find quite<br />
a number of biopolymer-products or pre-products for<br />
bioplastics such as Me-BDO (Methyl butanediol for biobased<br />
polyesters or as building block for polyurethanes), Gamma<br />
valerolactone, an amino acid to make Nylons or specialty<br />
acrylates, DPA (Diphenolic acid to replace BPA, Bisphenol A,<br />
in Epoxies or Polycarbonate. BPA is cheaper but toxic),<br />
Co-nutrients during PHB production with metabolically<br />
engineered strains, and many more.<br />
Markets for levulinic acid and its derivatives include<br />
furthermore green solvents, coatings and resins, plasticizers,<br />
but also flavours and fragrances, personal care and<br />
pharmaceutical products, agrochemicals, fuel additives and<br />
biofuels.<br />
LA from renewable resources<br />
Traditionally levulinic acid is produced from petroleum via<br />
butane/benzene. “The first biobased routes went through<br />
furfural and furfuryl alcohole”, said Aris de Rijke, Director<br />
Technology & Engineering. “We however, go a direct route<br />
from biomass in a continuous process. Today we are using<br />
industrial corn starch, but in the long run we aim at using<br />
wood waste or other cellulosic waste streams such as straw<br />
or bagasse”.<br />
And a share of the energy used to run the process comes<br />
from char, a by-product of the LA-production from biomass.<br />
All in all, levulinic acid is a product of which we can expect<br />
interesting developments. Or maybe even “the transition to a<br />
new economy”, as Maxim Kativov said. MT<br />
[1] www.nrel.gov/docs/fy04osti/35523.pdf<br />
www.gfbiochemicals.com<br />
Pre-treatment Reactor Flash<br />
Energy recovery<br />
Cellulosic Biomass<br />
Steam<br />
Proprietary technology<br />
Solid/liquid<br />
separatrion<br />
Product<br />
recovery &<br />
concentration<br />
Final<br />
purification<br />
Biochar<br />
Steam<br />
O<br />
CH 3<br />
HO<br />
O<br />
Levulinic acid<br />
20 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
MARCH 30 – APRIL 1, 2<strong>01</strong>6<br />
Orlando World Center Marriott<br />
A Collaborative Biopolymers Forum<br />
for the Global Ingeo Community<br />
@NatureWorks #ITR2<strong>01</strong>6 www.innovationtakesroot.com
Material news<br />
New amorphous PHA<br />
grades as performance<br />
additives for PVC and PLA<br />
Metabolix (Cambridge, Massachusetts, USA) is launching its<br />
new line of amorphous polyhydroxyalkanoate (PHA) grades to be<br />
used as performance additives for PVC and PLA. Production of the<br />
new materials is underway at a U.S. pilot plant and will ramp up to<br />
270 tonnes (600,000 pounds) annual nameplate capacity during 2<strong>01</strong>6.<br />
“The commercial launch of these new grades of amorphous PHA<br />
represents an important development for Metabolix as we advance<br />
our business strategy focused on specialty biopolymers,” said Johan<br />
van Walsem, Metabolix’s chief operating officer. “This expanded pilot<br />
capacity is strategic for us to support existing customers and opens<br />
new market development opportunities in our target application<br />
spaces.”<br />
Amorphous PHA (a-PHA) is a softer and more rubbery (low<br />
glass transition temperature or T g) version of PHA that offers a<br />
fundamentally different performance profile from crystalline forms<br />
of PHA. Metabolix’s a-PHA is produced by fermentation and extracted<br />
using a patented solvent recovery process. The production process has<br />
been reviewed by EPA and recently cleared the Premanufacture Notice<br />
(PMN) requirement for new materials placed into commerce. Several<br />
certifications are pending on a-PHA as a biobased material and for the<br />
full range of biodegradation scenarios enabled when a-PHA is used<br />
alone or with other complementary materials. Metabolix plans to seek<br />
FDA clearance for a-PHA in food contact applications, which would<br />
further expand the range of PHA compositions available for use in food<br />
contact materials. Metabolix previously received FDA clearance for use<br />
of its semi-crystalline PHA grades in food contact applications.<br />
At low loading levels, a-PHA can serve as a process aid and<br />
performance modifier for PVC. It increases productivity during<br />
processing and enhances mechanical performance, with the potential<br />
to also deliver cost savings in PVC material systems. In highly filled<br />
composite systems, the use of a-PHA enables increased use of wood<br />
pulp, mineral fillers and PVC recyclate to replace virgin PVC and<br />
achieve improved mechanical properties. Metabolix is working closely<br />
with customers on a wide range of applications utilizing a-PHA as a<br />
modifier for PVC. These applications include a floor backing material<br />
that utilizes PVC recyclate, a highly-filled vinyl flooring system, wire and<br />
cable insulation, roofing membranes, PVC/wood polymer composites<br />
and other construction and building materials (see p. 23).<br />
Amorphous PHA also complements the bio-content and<br />
compostability profile of the biopolymer PLA while delivering significant<br />
improvements in mechanical properties such as increased toughness,<br />
strength and ductility. Based on these product advantages, Metabolix<br />
is working with customers interested in achieving better performance<br />
with PLA biopolymers. Many of these customers are focused on<br />
developing a-PHA-modified PLA materials for sustainable, bio-based,<br />
and compostable packaging solutions. In addition to conducting<br />
numerous trials for transparent packaging films, Metabolix is working<br />
with customers interested in a-PHA-modified PLA for thermoformed<br />
transparent clamshells used in food service and consumer packaging<br />
as well as a-PHA-modified PLA for non-wovens used in personal care<br />
applications. MT<br />
www.metabolix.com<br />
Biobased and<br />
biodegradable<br />
thermoelastomers<br />
TerraVerdae BioWorks, Edmonton, Alberta,<br />
Canada, an industrial biotechnology company<br />
developing advanced bioplastics and biomaterials<br />
from environmentally sustainable, single-carbon<br />
(C1) feedstocks, has announced that<br />
it has entered into a strategic partnership agreement<br />
with PolyFerm, Kingston, Ontario, Canada.<br />
PolyFerm is a biopolymer company that<br />
is focused on developing renewable and<br />
biodegradable alternatives to petrochemicalbased<br />
elastomers. The partnership expands<br />
TerraVerdae’s product and technology portfolio<br />
into the high growth market of biodegradable<br />
thermoelastomers.<br />
PolyFerm has developed the only line of<br />
biodegradable thermoelastomers in the<br />
industry made entirely from renewable<br />
feedstocks. PolyFerm’s product line, marketed<br />
as VersaMer, is a medium-chain-length PHA<br />
material with enhanced elastomeric properties<br />
that can be engineered to multiple applications.<br />
This addresses a large unmet need within<br />
the biopolymer industry, with applications for<br />
adhesives and sealants, plastic additives, inks and<br />
toners, paints and coatings, and medical devices.<br />
“This strategic partnership allows us to offer<br />
our customers the most comprehensive product<br />
portfolio of high-value biodegradable polymers and<br />
opens up significant opportunities in new, highgrowth<br />
markets,” said William Bardosh, CEO and<br />
founder of TerraVerdae BioWorks. “<br />
“With TerraVerdae, we have found an ideal<br />
partner to help us penetrate new markets with<br />
our high-performance polymer and elastomer<br />
products,” said Bruce Ramsay, Founder and CTO of<br />
PolyFerm Canada. “TerraVerdae’s demonstrated<br />
ability to scale up complex bioprocesses to meet<br />
the performance specifications demanded by<br />
industry is a great fit with our technology.”<br />
Elastomeric PHAs represent one of the<br />
most versatile classes of engineered materials<br />
for a number of commercial uses. These<br />
biodegradable materials combine the look, feel<br />
and elasticity of conventional thermoset rubber<br />
with improved processing efficiencies and are<br />
capable of withstanding large deformations<br />
while regaining their original shape. They also<br />
exhibit unique performance characteristics<br />
such as toughness, resilience, stretchability, and<br />
stiffness. KL<br />
www.polyfermcanada.com | www.terraverdae.com<br />
22 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
www.pu-magazine.com<br />
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Plasticizers<br />
Processing Aids, Activators<br />
Silanes, Desiccants<br />
Antitack Agents<br />
Heat Transfer Fluids<br />
Material news<br />
Volume 7, September 2<strong>01</strong>5<br />
PHA in PVC-WPC applications<br />
In a recent blog posted by Metabolix Vice President of Marketing and Corporate Communications, Lynne Brum, the use<br />
of Metabolix I6003 PHAs in WPC was touted as a “cost effective solution which imparts superior mechanical properties and<br />
process benefits in wood filled PVC building materials.”<br />
Wood fiber polymer composites (WPC), wrote Brum, are materials made by combining wood particles or other fibrous materials with<br />
polymer resins and additives to improve performance. WPCs, which require little maintenance have become popular replacements<br />
for solid wood. Common applications for these composites are in products such as decking, fences, railings and outdoor landscaping<br />
features. PVC is one of the key base polymers used in wood polymer composites for decking and railing systems.<br />
Miscibility between PVC and plasticizer is essential for good performance. PHA and PVC materials are highly miscible and<br />
moreover, have similar processing windows. Because of their miscibility with PVC, the PHA additives will not migrate out of the<br />
PVC and are easy to handle and process under the same conditions as PVC.<br />
Exploring the use of Metabolix I6003 PHAs in WPC, it was found that I6003, a<br />
multifunctional process aid, acted as an efficient fusion promoter, improved wood filler<br />
incorporation and dispersion, and significantly reduced torque in the extrude.<br />
Metabolix has worked with customers to develop new PVC-WPC formulations<br />
for decking and railing systems. Incorporating Metabolix PHA material into these<br />
formulations at a low loading level, made it possible to increase the proportion of wood<br />
flour used and at the same time to decrease the amount of PVC needed. The data<br />
generated by Metabolix showed that during processing, the addition of PHA, even at<br />
a low level, reduced torque and improved processing of the wood polymer composite<br />
material. For railing applications, the end-product also exhibited significantly improved<br />
mechanical properties and surface finish.<br />
This work demonstrates that PHA materials can offer significant performance benefits<br />
– and consequently costs advantages, as well – in PVC wood polymer composite systems.<br />
Brum said the company is looking forward to working with PVC wood polymer composite<br />
manufacturers to develop new solutions for decking and railing systems. KL<br />
www.metabolix.com | http://bit.ly/1Rsqp4w<br />
SEEING POLYMERS<br />
WITH DIFFERENT EYES...<br />
Weltautomarkt 2<strong>01</strong>6<br />
Rubber and greenhouse effect<br />
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Magazine for the Polymer Industry<br />
Sulphenamides and network structure<br />
Ultra-clear silicone<br />
Optimising tear resistance<br />
Compound development<br />
sensorial material selection<br />
low output applications<br />
tpu in cardiac device leads<br />
Thermoplastic<br />
Elastomers<br />
magazine<br />
international<br />
POLYURETHANES MAGAZINE INTERNATIONAL<br />
Interview with J. MacCleary, Covestro<br />
CPI Polyurethanes Technical Conference review<br />
Spray polyurethane foam<br />
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Additives for low-emission foams<br />
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Simulation von Schaumspritzgießprozessen<br />
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bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 23
Materials<br />
Breakthrough<br />
platform technology for<br />
new building block<br />
In mid-January, science and agricultural leaders DuPont<br />
Industrial Biosciences, Wilmington Delaware, USA and<br />
Archer Daniels Midland Company (ADM), Chicago, Illinois,<br />
USA announced a new breakthrough process with the<br />
potential to expand the materials landscape in the 21 st<br />
century with exciting and truly novel, high-performance<br />
renewable materials. The technology has applications in<br />
packaging, textiles, engineering plastics and many other<br />
industries.<br />
The companies have developed a method for producing<br />
furan dicarboxylic methyl ester (FDME) from fructose.<br />
FDME is a high-purity derivative of furandicarboxylic acid<br />
(FDCA), one of the 12 building blocks identified by the<br />
U.S. Department<br />
of Energy that<br />
can be converted<br />
into a number of<br />
high-value, biobased<br />
chemicals<br />
or materials that<br />
can deliver high<br />
performance in<br />
a number of applications.<br />
It<br />
has long been<br />
sought-after and<br />
researched, but<br />
has not yet been<br />
available at commercial<br />
scale and<br />
at reasonable<br />
cost. The new<br />
FDME technology<br />
is a more efficient<br />
and simple process<br />
than traditional conversion approaches and results<br />
in higher yields, lower energy usage and lower capital expenditures.<br />
generic bottle picture (no PTF)<br />
This partnership brings together ADM’s world-leading<br />
expertise in fructose production, and carbohydrate<br />
chemistry with DuPont’s biotechnology, chemistry,<br />
materials and applications expertise, all backed by a<br />
strong joint intellectual-property portfolio.<br />
“This molecule is a game-changing platform technology.<br />
It will enable cost-efficient production of a variety of 100 %<br />
renewable, high-performance chemicals and polymers<br />
with applications across a broad range of industries,” said<br />
Simon Herriott, global business director for biomaterials<br />
at DuPont. “ADM is an agribusiness powerhouse with<br />
strong technology development capabilities. They are the<br />
ideal partner with which to develop this new, renewable<br />
supply chain for FDME.”<br />
One of the first polymers under development utilizing<br />
FDME is polytrimethylene furandicarboxylate (PTF), a novel<br />
polyester also made from DuPont’s proprietary plant based<br />
Bio-PDO (1,3-propanediol). PTF is a 100 % renewable<br />
and recyclable polymer that, when used to make bottles<br />
and other beverage packages, substantially improves<br />
gas-barrier properties compared to other polyesters.<br />
This makes PTF<br />
a great choice<br />
for customers<br />
in the beverage<br />
packaging<br />
industry looking<br />
to improve the<br />
shelf life of their<br />
products.<br />
“We are excited<br />
about the potential<br />
FDME has to<br />
help our customers<br />
reach new<br />
markets and develop<br />
better-performing<br />
products,<br />
all made from<br />
sustainable, biobased<br />
starting<br />
materials,” said<br />
Kevin Moore, president, renewable chemicals at ADM.<br />
“With their strong leadership in the biomaterials industry,<br />
DuPont is a great partner that can help us bring this product<br />
to market for our customers.”<br />
ADM and DuPont are taking the initial step in the<br />
process of bringing FDME to market by moving forward<br />
on the scale-up phase of the project. The two companies<br />
are planning to build an integrated 60 tonnes/year<br />
demonstration plant in Decatur, Illinois, USA, which<br />
will provide potential customers with sufficient product<br />
quantities for testing and research. MT<br />
www.dupont.com | www.adm.com<br />
24 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Drive Innovation<br />
Become a Member<br />
Join university researchers and industry members<br />
to push the boundaries of renewable resources<br />
and establish new processes and products.<br />
www.cb2.iastate.edu<br />
See us at K 2<strong>01</strong>6<br />
October 19-26, 2<strong>01</strong>6<br />
Düsseldorf, Germany<br />
Hall 5, US Pavilion
Opinion<br />
Bioplastics industry struggling<br />
to meet expected demand<br />
Avantium and Mitsui announced in December their<br />
plan to bring 100 % bio-based PEF (Polyethylene<br />
Furanoate) packaging to the Tokyo Olympics in<br />
2020. This press release captures the importance of both<br />
partnerships and professional marketing in today’s bioplastic<br />
business.<br />
Today, bioplastics are generally sold at a premium<br />
compared to conventional plastics, and the current low<br />
prices of crude oil are not making the competition any<br />
easier. It is therefore of the utmost importance to build<br />
maximum exposure for the new products. The higher price<br />
of bioplastics for instance in packaging is compensated<br />
by added brand or product value. Major sports events are<br />
the candy shops for marketing professionals. The London<br />
Olympic Games in 2<strong>01</strong>2 were broadcast to 220 different<br />
countries with over 3.6 billion viewers. The bioplastic<br />
industry has been able to get its fair share of the publicity.<br />
McDonald’s decided to use Novamont’s Mater-Bi bioplastic<br />
for the disposable foodservice packaging in their Olympic<br />
park restaurant during London Olympic Games. Rio 2<strong>01</strong>6<br />
has published sustainability guidelines encouraging the<br />
use of biodegradable compostable packaging for fast<br />
food outlets, and recyclable bioplastics for other types of<br />
packaging. The choice of event for Avantium’s and Mitsui’s<br />
launch was an expected yet very smart move.<br />
Along with the increasing media exposure, more and<br />
more brand owners are considering bioplastics as part of<br />
their sustainability programme. Shiseido plans to switch<br />
over 70 % of the polyethylene used in their domestic<br />
cosmetics containers from petroleum-based to bio-based<br />
by 2020. Procter & Gamble has announced replacing 25 %<br />
of their petroleum-based raw materials with renewable<br />
materials in all products and packaging by 2020. Also<br />
the Swedish furniture giant IKEA is planning to have all<br />
plastics used in the company’s home furnishings made<br />
from 100 % renewable and/or recyclable materials with<br />
the same schedule as Shiseido and P&G. These global<br />
brands are considered to be innovators in the adoption<br />
curve of bioplastics. We at Pöyry believe this trend of<br />
brand owner targets will expand from innovators to early<br />
adopters in the next ten years. Will there be enough supply<br />
to meet these targets?<br />
The market data of European Bioplastics forecasts<br />
that the production capacities of bioplastics will reach<br />
almost 8 million tonnes in 2<strong>01</strong>9 with non-biodegradable<br />
bioplastics representing the major part of the growth.<br />
As a combined management consulting and engineering<br />
company we keep a tight eye on the development and<br />
realisation of investment projects. Today, we see some<br />
major challenges with the build-up of new bioplastic<br />
production. Much of the volume growth is counting on new<br />
bio-based PE, PET, PEF and PLA production.<br />
Braskem is still the only producer of sugar-based PE<br />
on the market with no announcements of new entrants.<br />
In addition, Mitsui decided to bury their bio-ethylene<br />
joint venture with Dow Chemical last October by selling<br />
all its shares of the company. On the positive side, SABIC<br />
launched a portfolio of renewable PE and PP in 2<strong>01</strong>4 but<br />
the actual production volumes remain unknown. There is<br />
also an on-going debate whether these ISCC Plus certified<br />
renewable polyolefins can be marketed as bio-based<br />
products.<br />
The development of bio-based PET and PEF is going<br />
forward, but the production output is lagging behind<br />
The Chasm<br />
Innovators Early adopters Early majority Late majority Laggards<br />
26 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Opinion<br />
By:<br />
Henna Poikolainen and Juulia Kuhlman<br />
Pöyry Management Consulting<br />
Vantaa, Finland<br />
market projections. For instance, the largest biobased<br />
monoethylene glycol project to date – 500,000<br />
t/a in Brazil by JBF Industries – has been put on hold<br />
and some sources expect it to be cancelled. There is<br />
a lot of activity in developing catalytic processes for<br />
bio-MEG but there will be little production available<br />
for P&G, IKEA and alike by 2020.<br />
The future supply looks more promising for PLA.<br />
Corbion succeeded in signing letters of intent for<br />
one-third of the 75,000 t/a capacity planned for their<br />
new facility in Thailand and decided to go forward<br />
with the investment. NatureWorks awarded the<br />
engineering contract of a new production plant in<br />
Southeast Asia to Jacobs back in 2<strong>01</strong>3 but we are<br />
still waiting for news on the location.<br />
Press releases of new bioplastic projects paint<br />
a distorted picture of the supply volumes. Only<br />
few projects reach full capacity with the initially<br />
announced timing. New technologies, developing<br />
markets and exclusive partnerships make the<br />
bioplastics industry demanding, risky and timeconsuming<br />
to enter. Sustainable biomass sourcing<br />
with transparent traceability is a prerequisite for<br />
any collaboration with the major brand owners.<br />
Similarly to Corbion, many producers seek to<br />
secure major offtake of planned capacity prior to a<br />
final investment decision which prolongs time-tomarket.<br />
Project financing is rarely straightforward.<br />
Many bioplastics projects are risky investments<br />
even at high crude oil prices. It is challenging to<br />
convince investors of the profitability of capital<br />
intensive projects when the return on investment is<br />
dependent on a biopremium.<br />
The supply of bioplastics is expected to show<br />
double-digit growth for the next ten years, but the<br />
curve is unlikely to depict as exponential a growth<br />
as project announcements would indicate. Securing<br />
an adequate supply of bioplastics will be a major<br />
issue for the brands aiming to reach their targets<br />
by 2020. Most brands are unwilling to commit to a<br />
single supplier. There should be at least two or three<br />
certified suppliers to secure supply, but this is rarely<br />
the case in today’s bioplastic market. There is great<br />
variation in polymer grades and switching costs are<br />
still too high. Hence, bioplastic producers should<br />
not see new entrants as unwelcome competitors,<br />
but rather as a necessity for market formation. We<br />
foresee more and more partnerships with bioplastic<br />
producers and brand owners. Tight collaboration<br />
with brand owners can speed-up market entry and<br />
take the bioplastics industry to the next level.<br />
www.poyry.com<br />
About the authors:<br />
Henna Poikolainen and Juulia<br />
Kuhlman are both consultants at Pöyry<br />
Management Consulting. Pöyry is one<br />
of the leading advisors to the world’s<br />
energy, forest and bio-based industries.<br />
In the past 5 years, the authors have<br />
been supporting clients e.g. in market<br />
entry, product portfolio and partnering<br />
strategies; in supply, demand and cost<br />
analyses; and in technology evaluation<br />
and pre-feasibility assessments. In<br />
2<strong>01</strong>5, Pöyry published a multiclient<br />
report “BioSight up to 2025” analysing<br />
the supply, demand and dynamics of<br />
the bio-based chemical business: www.<br />
poyry.com/biosight<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 27
Application News<br />
New biobased<br />
sustainable eyewear<br />
Eyewear company Charmant USA has announced<br />
the launch of Awear, a line of eco-friendly eyeglasses.<br />
Composed of recyclable plant-based biobased plastics,<br />
plus biodegradable demo lenses. Its inaugural collection<br />
of ergonomic eyewear was designed to be lightweight,<br />
fashion-forward and completely eco-friendly.<br />
The brand boasts an unyielding commitment to<br />
environmentally conscious practices, from design to<br />
production. All of the glasses’ frames and sun lenses<br />
are made with sustainable materials – the frames<br />
themselves are created from recyclable plant-based<br />
biobased polyamide. And since the bio-polyamide is<br />
made from a plant-based material, each ergonomically<br />
fitted frame boasts reduced carbon-dioxide emissions<br />
and water use compared with conventional eyewear.<br />
Production is another important factor for the company.<br />
The temple pieces for each pair of glasses (made of a<br />
biobased elastomer material) are hand-assembled,<br />
ultimately making the process more energy efficient. The<br />
frames are also designed with a high-chemical resistant<br />
material that eliminates the need for spray coating pieces,<br />
a factor that reduces overall water usage in production.<br />
Even the demo lenses are biobased and biodegradable<br />
and are made from PLA.<br />
“Awear is different and exceptional from any other<br />
eyewear collection,” Michele Ziss, director of product<br />
and marketing at Charmant, said in a statement. “The<br />
materials and production processes have distinctive<br />
properties and a unique story because they are<br />
environmentally friendly.”<br />
Aimed at style-conscious and environmentally savvy<br />
millennials, Awear debuts this month with seven optical<br />
frames and two styles of sunglasses for men and women.<br />
Yosuke Shimano, the collection’s lead designer,<br />
credited the vivacity of life in the landscapes that<br />
surround him for inspiring the range of translucent yet<br />
saturated colors.<br />
“It is with this concept, that Awear can make an equally<br />
bold style and eco-savvy statement,” the company added. KL<br />
www.awearcharmant.com<br />
PHA for safer toys<br />
Italy-based Bio-on laboratories have created a new type<br />
of bioplastic, designed to make safe and eco-sustainable<br />
children’s toys. Dubbed Minerv PHA Supertoys, the new<br />
material has now been used for the first time for the<br />
manufacture of building bricks.<br />
Based on Bio-on’s biodegradable biopolymer (PHA),<br />
which has already been tested in applications ranging<br />
from automotive to design to biomedical, biobased<br />
Supertoys is safe, and hygienic, and it meets and exceeds<br />
the provisions of the recent European Directive 2009/48/<br />
EC, known as the TDS (Toy Safety Directive), implemented<br />
into the standard international procedure for toy safety<br />
evaluation EN 71.<br />
Bio-On has developed an exclusive process for the<br />
production of a family of PHA polymers from agricultural<br />
waste (including molasses and sugar cane and sugar<br />
beet syrups). Bio-On PHA is certified by Vincotte and by<br />
USDA (United States Department of Agriculture) as 100 %<br />
biobased and completely biodegradable.<br />
The Minerv PHA Supertoys project was launched<br />
by Bio-on with no commercial goal, aiming solely to<br />
demonstrate whether or not specific, eco-sustainable and<br />
completely biodegradable formulations could be created<br />
to manufacture child-safe, environmentally friendly toys,<br />
without compromising on the functionality or aesthetic<br />
appeal of the end product.<br />
“The presence of toxic substances in toys is still a very<br />
serious problem today,” says Bio-on S.p.A. Chairman<br />
Marco Astorri. “We are convinced that this new discovery<br />
can make a decisive contribution to the health of our<br />
children.”<br />
The first product chosen as the demonstrator for the<br />
new material was a LEGO ® -style building bricks. Astorri<br />
explained that the company had chosen this product,<br />
because of the relative difficulty in producing it. “It has a<br />
tolerance of 2 µm and the fact that we have succeeded in<br />
guaranteeing such a high quality level gives us confidence<br />
for future developments,” he said.<br />
The research project is open to all laboratories and<br />
companies around the world working on toy design. The<br />
goal is to create two types of bioplastic by the end of 2<strong>01</strong>7:<br />
Minerv PHA Supertoys type R, a rigid, strong grade, and<br />
Minerv PHA Supertoys type F, which will be ductile and<br />
flexible. KL/MT<br />
www.bio-on.it<br />
28 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Application News<br />
New Ice-cream container<br />
At the SIGEP Exhibition in Rimini, Italy (23 – 27 January 2<strong>01</strong>6) a new line of ice-cream containers made from BioFoam ® has<br />
been introduced by the companies Erreme (Foligno, Italy) and Domogel (Costa di Mezzate, Italy). They are two of the leading<br />
producers of ice-cream packaging in Italy. The BioFoam containers are produced by Synprodo, Wijchen, The Netherlands. The<br />
ice containers are put into the market under the name Greeny and come in two models 500 ml and 1000 ml. The insulating<br />
properties of the containers keep the ice cool<br />
for several hours allowing the consumers to<br />
take it home for consumption. Assuming an<br />
external temperature of 25 °C, the temperature<br />
of the ice cream stored in a BioFoam container<br />
will vary by 2 °C per hour. With a thermoformed<br />
layer of PLA on the inside the entire container<br />
is still completely bio-based and compostable<br />
(certified as industrially compostable according<br />
to EN13432). In Italy officially allowed by law since<br />
last year, consumers can dispose of the empty<br />
containers in their biowaste bin.<br />
After an official Press Conference and during the<br />
following days on the exhibition the revolutionary<br />
new concept for Italy gained a lot of interest and<br />
the producers are confident that the coming years<br />
the Greeny box will grow and take market share<br />
on the Italian and other markets.<br />
www.greeny.it<br />
www.synprodo.com<br />
9. Biowerkstoff-Kongress<br />
HIGHLIGHTS OF THE WORLDWIDE BIOECONOMY:<br />
1 st Day (5 April 2<strong>01</strong>6)<br />
• Policy & markets<br />
• New bio-based building blocks<br />
• Biorefineries<br />
• Innovation Award<br />
“Bio-based Material of the Year 2<strong>01</strong>6”<br />
2 nd Day (6 April 2<strong>01</strong>6)<br />
• Building blocks and polymers<br />
• Polyhydroxyalkanoates (PHA)<br />
• Lignin utilisation<br />
Organiser<br />
Venue & Accomodation<br />
Maternushaus Cologne, Germany<br />
Kardinal-Frings-Str. 1–3, 50668 Cologne<br />
+49 (0)221 163 10 | info@maternushaus.de<br />
Book now<br />
10% reduction – enter code bpm10<br />
during your booking process<br />
www.nova-institute.eu<br />
Contact<br />
Dominik Vogt<br />
Conference Manager<br />
+49 (0)2233 4814-49<br />
dominik.vogt@nova-institut.de<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 29
Foam<br />
PLA foam expanding<br />
<br />
into new areas<br />
By:<br />
Sarah Heine, CEO<br />
Biopolymer Network<br />
Rotorua, New Zealand<br />
The Biopolymer Network Limited (BPN) team from Rotorua,<br />
New Zealand, who developed Zealafoam ® , a PLA based alternative<br />
to expanded polystyrene (EPS), continues to develop<br />
new opportunities for bio-based foam. Leveraging off their<br />
patented process which uses CO 2<br />
as a green blowing agent to<br />
produce low density particle PLA foam, BPN has developed a variety<br />
of prototypes of varying shape and dimension. These include<br />
cups, films or other articles depending on the target application.<br />
PLA foamed cups have been developed to target the growing<br />
demand for bio-based disposable cups for both hot and cold<br />
beverages. The foaming process increases the glass transition<br />
temperature (T g<br />
) and/or crystallinity of the PLA, depending on<br />
the grade of PLA used, resulting in better thermal stability than<br />
non-foamed PLA cups. Thermal conductivity measurements<br />
show that the foamed cups have good insulation properties,<br />
while mechanical testing indicates the prototypes have good<br />
impact resistant properties. While work is ongoing to target hot<br />
beverage applications, the current technology is ideal for cold<br />
beverages.<br />
Similarly, the team has created a thin PLA foamed film using<br />
this process. Currently there is interest from industry in the use<br />
of PLA film for packaging and labelling applications. Printing on<br />
clear PLA film can however prove a challenge, with a white base<br />
coat required prior to printing. The BPN process results in an<br />
opaque, smooth and shiny surface that is ideal for printing and<br />
the product is light weight. The manufacturing process can be<br />
manipulated to significantly improve the elastic modulus and the<br />
yield stress of the product, over solid PLA film, while decreasing<br />
the strain percentage at break. These properties make the<br />
material an excellent product for the targeted applications.<br />
BPN has also studied the incorporation of different biomass in<br />
all their foamed products, from particle foam to foamed film. The<br />
focus has been on available low value biomass such as pine bark,<br />
canola meal or dried distiller grains and excellent foam has been<br />
achieved with biomass loadings as high as 15 %. The resulting<br />
foam exhibits altered properties, depending on the biomass<br />
loading and therefore can target different applications, with a<br />
reduced product cost achieved by the substitution of a processed<br />
plastic with a low cost biomass.<br />
Traditionally, Zealafoam particle foam has been moulded using<br />
existing expanded polystyrene (EPS) equipment to produce low<br />
density foam with similar mechanical and thermal insulation<br />
properties to that of EPS. Zealafoam is a closed cell foam<br />
with properties primarily determined by the properties and<br />
morphology of the polymer, the foam or cellular structure, and<br />
the bulk density. Using these principles, BPN have produced a<br />
more diverse range of products incorporating their technology<br />
for new applications, combining the functionality of excellent<br />
insulating properties and light weight with the many advantages<br />
of a bio-based plastic.<br />
This research was funded by New Zealand’s Ministry of<br />
Business, Innovation and Employment.<br />
www.biopolymernetwork.com<br />
30 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
organized by<br />
supported by<br />
20. - 22.10.2<strong>01</strong>6<br />
Messe Düsseldorf, Germany<br />
Bioplastics in<br />
Packaging<br />
BIOPLASTICS<br />
BUSINESS<br />
BREAKFAST<br />
B<br />
3<br />
PLA, an Innovative<br />
Bioplastic<br />
Bioplastics in<br />
Durable Applications<br />
Subject to changes<br />
Call for Papers now open<br />
www.bioplastics-breakfast.com<br />
Contact: Dr. Michael Thielen (mt@bioplasticsmagazine.com)<br />
At the World‘s biggest trade show on plastics and rubber:<br />
K‘2<strong>01</strong>6 in Düsseldorf bioplastics will certainly play an<br />
important role again.<br />
On three days during the show from Oct 20 - 22, 2<strong>01</strong>6<br />
bioplastics MAGAZINE will host a Bioplastics Business<br />
Breakfast: From 8 am to 12 noon the delegates get the<br />
chance to listen and discuss highclass presentations and<br />
benefit from a unique networking opportunity.<br />
The trade fair opens at 10 am.<br />
BIO-BASED START-UP DAY<br />
7 April 2<strong>01</strong>6 · Maternushaus · Cologne · Germany<br />
Organiser<br />
www.nova-institute.eu<br />
Venue & Accomodation<br />
Maternushaus Cologne, Germany<br />
Kardinal-Frings-Str. 1–3, 50668 Cologne<br />
+49 (0)221 163 10 | info@maternushaus.de<br />
Contact<br />
Dominik Vogt<br />
Conference Manager<br />
+49 (0)2233 4814-49<br />
dominik.vogt@nova-institut.de<br />
HIGH-POTENTIAL START-UPS FROM BIO-BASED<br />
CHEMISTRY, POLYMERS AND BIOTECHNOLOGY<br />
The Bio-based Start-up Day will bring start-ups, investors and industry<br />
together by giving the floor to everyone and providing great opportunities of<br />
networking. The day will start with a keynote speech followed by presentations<br />
of start-ups. Related clusters such as CLIB2021 and IBB Netzwerk will also<br />
have the chance to present their own young start-ups. In a special meeting<br />
session the audience will have the opportunity to meet the start-ups and<br />
investors in person. Investors will afterwards provide<br />
an insight into their incentives and experiences working<br />
with start-ups in the bio-based and biotech sector. The<br />
day will end with a discussion and a coming together.<br />
Great networking opportunities all day long!<br />
More information: www.bio-based.eu/startup
Polyamides are made by polycondensation of dicarbonic acids with diamines or by polyaddition<br />
of lactames. e.g. PA 66 or PA 6. Succinic acid and its derivates 1,4 –di-amino butane or<br />
in academic research have been magnetic and crystallographic data. Furthermore, there is<br />
no clarity regarding melting point and temperature stability to be found in the literature, an<br />
important subject to enable its practical use. The Fraunhofer-UMSICHT scientists synthesized<br />
high melting point of 329 °C indicates high density of hydrogen bonding of the amide groups.<br />
10 years ago<br />
Published in bioplastics MAGAZINE<br />
10 YEARS AGO<br />
new<br />
series<br />
In January 2<strong>01</strong>6, Dr. Stephan Kabasci (Fraunhofer UMSICHT) comments:<br />
“Succinic acid fermentation was improved considerably with respect to concentration<br />
and yield in the course of the project. PA44, however, proved to be highly sensitive to<br />
temperature so that thermoplastic melt processing was not feasible.”<br />
Materials<br />
Succinic acid: versatile platform chemical<br />
The Fraunhofer-Institut für Umwelt, Sicherheits- und Energietechnik UMSICHT<br />
in Oberhausen, Germany has recently published some basic findings about the<br />
synthesis of polyamide from succinic acid, a substance that can be derived from<br />
renewable sources. A poster, presented at the International Conference on Renewable<br />
Resources and Biorefineries in Ghent, Belgium (Sept. 19 – 21, 2005) won<br />
the conference’s “Poster Award”.<br />
Succinic acid [HOC(O)CH 2<br />
CH 2<br />
C(O)OH] is a platform chemical that can be used<br />
directly or as intermediate for a large number of applications such as for plastics,<br />
paints, food additives and other industrial and consumer products. Today, succinic<br />
acid is produced mainly by chemical processes from petrochemical feedstocks.<br />
“But it can also be won from renewable sources” says Dr. Stephan Kabasci, one<br />
of the authors of the poster. For the fermentation of succinic acid from glucose,<br />
From starch to polyamide –<br />
via succinic acid<br />
Polyamide from bio-amber<br />
Synthesis of polyamide<br />
two strains of anaerobic bacteria have been tested on a laboratory scale: Anaerobiospirillum<br />
succiniciproducens (DSM 6400) and Actinobacillus succinogenes<br />
(ATCC 55618). Other experiments with starch from different sources showed that<br />
the highest succinate concentration was achieved with maize starch (see Fig. 1).<br />
2-pyrrolidinone are therefore raw materials for the production of polyamide 4.4 or polyamide<br />
4.<br />
Only a few articles have been published in literature in relation to polyamide 4.4. Main topics<br />
polyamide 4.4 in a polycondensation process. The resulting product takes up water to form<br />
gelatinous mass and is a very hard material in dry state.<br />
The melting point of a sample that has not been fully refined is shown in Fig. 2. The extreme<br />
A comprehensive article about polyamides made from bio-based succinic acid, their potential<br />
for packaging and technical applications and including a discussion of the cost issue is<br />
planned for the next issue of bioplastics magazine.<br />
www.umsicht.fraunhofer.de/english<br />
Formation of Succinic acid by fermentation of starch types<br />
Start concentration of starch types :15gL -1<br />
Succinic Acid Concentration / gL -1<br />
7<br />
6<br />
5<br />
4<br />
3<br />
2<br />
1<br />
Maize Starch<br />
Potato Starch<br />
Wheat Sarch<br />
0<br />
0 40 80 120 160 200 240<br />
time / h<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
Succinate Yield<br />
[g/100 g substrate]<br />
Fig. 1: Left: Succinate production from starch types by fermentation<br />
Right: Specific Yield of succinate from different substrates<br />
Glucose<br />
Maize starch<br />
Wheat starch<br />
Potato starch<br />
Cellulose<br />
endo 0,45<br />
first heating and cooling<br />
20-250-50 °C, desorption of water<br />
0,40<br />
second heating 20 KMin -1<br />
0,35<br />
0,30<br />
0,25<br />
0,20<br />
0,15<br />
0,10<br />
329 °C<br />
80 120 160 200 240 280 320 360<br />
temperature / °C<br />
heat flow / mWmg -1<br />
Fig. 2: DSC thermogramof raw Polyamide 4.4<br />
14 bioplastics [06/<strong>01</strong>] Vol. 1<br />
32 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
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Basics<br />
“The biobased office” for the<br />
procurement of the future<br />
The German Agency for Renewable Resources<br />
promotes a viable sustainable procurement.<br />
German law lacks a legal basis for sustainable public<br />
procurement. Legislation requiring resource and environmental<br />
considerations to be taken into account<br />
when purchasing goods and services for the public sector has<br />
not yet been put in place.<br />
Hence, the implementation of sustainable public<br />
procurement in Germany has been patchy in many aspects, a<br />
fact that is also reflected in the development of a recognized<br />
environmental label. It would therefore be helpful first to<br />
formulate significant sustainability criteria and thus to gain<br />
experience with public procurement and, at the same time,<br />
to gradually develop a sustainable procurement culture. That<br />
would also give producers the opportunity to adopt a goaloriented<br />
perspective. However, many public authorities are<br />
struggling with such an approach.<br />
Clearly, sustainable procurement is a new approach – and<br />
it is one that involves more effort, as information will have to<br />
be collected, old and familiar procurement habits abandoned<br />
and market availability studied. However, the single most<br />
important reason for the slow progress in this area is the lack<br />
of encouragement and support from decision makers.<br />
Of course there are good examples as well, such as that<br />
of Berlin. Berlin not only has administrative regulations<br />
providing for the implementation of environmental protection<br />
requirements in the procurement of goods, works and services<br />
[1], but has also developed specific minimum requirements for<br />
many product groups, which serve as practical procurement<br />
guides. Another positive sign was the recent publication from<br />
the Öko-Institute of a study showing the financial savings<br />
and environmental benefits potentially resulting from the<br />
implementation of environmentally-friendly procurement<br />
processes.<br />
The Agency for Renewable Resources (Fachagentur<br />
Nachwachsende Rohstoffe, FNR) also encourages<br />
environmentally friendly procurement. On behalf of the<br />
Federal Ministry for Food and Agriculture (BMEL), a project<br />
called the “Use of biobased products in public procurement”<br />
was established at the FNR in 2<strong>01</strong>0. The project aims to<br />
promote environmental and natural resource stewardship,<br />
as well as to enhance the security of the resource supply by<br />
fostering the use of biobased products. Public institutions,<br />
in their role as pioneers, could leverage their purchasing<br />
The bio-based office<br />
34 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Basics<br />
power to further advance the use of biobased products. This<br />
commitment to biobased products is also reflected in the EUfinanced<br />
projects of the FNR.<br />
The biobased office<br />
The FNR project entitled “Use of biobased products in public<br />
procurement” is currently touring Germany with a model of a<br />
biobased office serving as an exhibition booth. Tour schedule:<br />
http://www.das-nachwachsende-buero.de/service/tourenplan/<br />
The booth showcases the products with which a biobased,<br />
environmentally-friendly office setting can be created. Given<br />
the 17 million office workspaces in Germany alone, the use<br />
of biobased office products offers enormous potential for a<br />
reduction of CO 2<br />
emissions.<br />
Nearly 100 biobased products, ranging from office furniture<br />
to office design and furnishings can be viewed and touched at<br />
the fully accessible, 12 m 2 exhibition booth. The selection of<br />
bioplastic products featured have been made available by a<br />
variety of companies, both large and small. The entire range of<br />
products featured in the exhibition booth, and the companies<br />
producing these, are listed in a complimentary brochure, but<br />
can also be found on: www.das-nachwachsende-buero.de.<br />
Sustainability in procurement law and procurement<br />
processes of biobased products<br />
Plastics play a major role in office equipment. In addition to a<br />
growing use of recycled plastic materials, products made from<br />
biobased materials are also on the rise. According to public<br />
procurement law, it may be necessary to substantiate and<br />
submit proof of the sustainability claims of biobased plastics<br />
(e.g. the environmental benefits of the product).<br />
Implementation of the European public procurement<br />
directives will require an overhaul of public procurement law and<br />
the strengthening of sustainable and innovative procurement<br />
practices. Following the incorporation of these directives<br />
into German law in April 2<strong>01</strong>6, it should be easier for public<br />
procurers to write tenders with sustainable (environmental,<br />
social and innovative) requirements, which relate to:<br />
• the terms of references / technical specifications<br />
• the qualification / selection criteria<br />
• the contract / award criteria<br />
• requirements for the implementation of a contract<br />
as long as there is an objective connection with the contract<br />
at hand.<br />
Proof of the required properties can be provided by an<br />
overall reference to a recognized label or certificate. Moreover,<br />
e-procurement will be the standard procedure.<br />
However, for the heterogeneous group of manufacturers<br />
of biobased products – mainly made up of SMEs – such<br />
certifications and e-procurement requirements pose a serious<br />
impediment to doing business with public procurers. Another<br />
problem is the wide use of framework agreements, which make<br />
it difficult for SMEs to participate. Hence, SMEs are more likely<br />
to opt for direct award procedures with volumes below the<br />
€ 10.000 threshold.<br />
With sales figures like these, however, no real market<br />
breakthrough, of the kind envisioned by the “bioeconomy”<br />
policy strategy, is possible.<br />
<br />
By:<br />
Monika Missalla-Steinmann<br />
Public relations officer<br />
Agency for Renewable Resources (FNR)<br />
Gülzow, Germany<br />
Office materials made of biobased plastic<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 35
Basics<br />
The Blauer Engel is highly accepted in Germany<br />
Environmentally-friendly procurement in Germany is<br />
strongly influenced by the ecolabel Blauer Engel (Blue<br />
Angel). The label is highly accepted among public procurers<br />
in Germany. The Blauer Engel was explicitly introduced<br />
as an environmental policy instrument by the state, which<br />
contributed to its credibility. Most product certifications,<br />
however, are based on energy saving and energy efficiency.<br />
Biobased plastics, can currently not be certified under the<br />
Blauer Engel. However, this may change in the near future,<br />
as a result of an ongoing study commissioned by the Federal<br />
Environment Agency, which is examining this issue.<br />
While the “Blauer Engel” is a respected national eco-label,<br />
the question is, what are the possibilities for certification<br />
available to businesses in the international market?<br />
In the EU, biobased plastics can be certified under the<br />
Vincotte/biobased certification system. However, this solely<br />
applies to the biobased content of a product, not to its<br />
sustainability. The Vincotte / compost certificate is not likely to<br />
play a role in the field of office supplies. Not many authorities<br />
will want to compost their biobased plastic stapler.<br />
Blauer Engel<br />
Raw materials associations and the different countries<br />
of origin complicate the verification process. A step in the<br />
right direction would be to establish criteria to determine<br />
the sustainability of individual commodities, which could<br />
then be granted a corresponding recognized quality label. A<br />
certification system of this kind would at least provide insight<br />
into the predominant raw material content (e.g. wood). The<br />
hurdles to sustainable procurement are particularly high<br />
at this point. No conventional product carries such a high<br />
burden of proof.<br />
Sustainable procurement requires creativity and<br />
dialogue<br />
Life cycle costs or life cycle assessments are also playing an<br />
increasingly important role in the sustainability assessment<br />
carried out as part of the process of evaluation and awarding<br />
of contracts. However, the difficulty is knowing how to go<br />
about a life cycle assessment of a granulate that is based<br />
on raw materials derived from different origins. Moreover,<br />
such calculations will mean very little in the case of office<br />
accessories. Nevertheless, these are questions that need to<br />
36 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Basics<br />
be raised and addressed by the biobased sector, together<br />
with the decision makers in public procurement.<br />
What are other possibilities for biobased plastics in<br />
public procurement?<br />
Procurement law not only defines the what, but also<br />
the how of purchasing. One possibility would be to require<br />
the use of products or materials designated as biobased<br />
or from renewable resources in the specifications. The<br />
invitation to tender can state clearly and transparently<br />
that this requirement constitutes an award criterion, to<br />
which a particular weighting has been assigned.<br />
Relating resource security to the award of a<br />
procurement contract is slightly more complicated, as<br />
resource security is understood to refer not only to the<br />
finite supply of fossil fuels, but also to the dependency on<br />
imports. This makes establishing an objective connection<br />
somewhat more difficult.<br />
Security of supply is an important building block for<br />
the realization of a biobased economy. The same goes<br />
for the widely documented CO 2<br />
savings over the lifetime<br />
of a biobased product. Both aspects are difficult to prove,<br />
even when using eco-labels as proof for awarding a<br />
contract.<br />
At this point, general societal responsibility in<br />
public procurement will take the form of promoting<br />
an open and creative dialogue between producers and<br />
public procurers, with a view to achieving an effective<br />
breakthrough of biobased products in the market.<br />
Nevertheless, this does not excuse the sector from<br />
thinking about how a scientifically proven, independent<br />
and transparent and possibly globally applicable<br />
certification scheme or label could be launched.<br />
On the other hand, the tax-financed public sector has<br />
a duty to use the opportunities created by procurement<br />
law to support societal goals such as energy and<br />
resource security or climate protection measures for the<br />
benefit of the general public.<br />
The Agency for Renewable Resources, with its “Use<br />
of biobased products in public procurement” project,<br />
is open for a dialogue concerning the procurement of<br />
biobased products.<br />
The FNR is also involved in Europe-wide projects on<br />
biobased products and services in public procurement<br />
with the EU projects InnProBio “Forum for Bio-Based<br />
Innovation in Public Procurement” and OpenBio<br />
“Opening bio-based markets via standards, labelling and<br />
procurement”.<br />
[1] Verwaltungsvorschrift für die Anwendung von Umweltschutzanforderungen<br />
bei der Beschaffung von Liefer-, Bau- und<br />
Dienstleistungen - VwVBU<br />
http://beschaffung.fnr.de<br />
www.das-nachwachsende-buero.de<br />
www.innprobio.eu<br />
www.open-bio.eu<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 37
Opinion<br />
Biopolymers<br />
will weather<br />
the crash in<br />
petroleum<br />
prices<br />
By:<br />
Ron Buckhalt<br />
Before you read this column, you should know that I retired<br />
on December 31, 2<strong>01</strong>5 as Manager of the (USDA)<br />
BioPreferred Program. So anything I say here is as a<br />
private citizen, not a government employee. However I was<br />
involved with bioproducts for nearly 40 years and have some<br />
institutional knowledge.<br />
I would like to first thank, Michael Thielen for allowing me<br />
a few paragraphs to reflect on advancements made in the<br />
bioproducts industry over the last few decades.<br />
But before we discuss the recent advances I think we need<br />
to stop for a moment and think about how we got to where we<br />
are today, particularly as it relates to bioplastics.<br />
Humankind was using biobased products long before<br />
they were called natural or some other new catchword. Our<br />
paints, inks, coatings, dyes, lubricants, fuels, soaps, and other<br />
industrial products were made from plants and animals. It<br />
was only when petroleum was discovered in the 1860’s that<br />
we begin to move to a hydrocarbon economy away from a<br />
carbohydrate economy.<br />
There was even an argument about whether we would fuel<br />
our vehicles with plant-derived ethanol or petroleum-derived<br />
gasoline, or even electricity, and books have been written on<br />
the battles so I will not attempt to recount those issues, just<br />
be aware of them as part of the changing landscape.<br />
For the United States, in the 1930’s there emerged<br />
something called the Chemurgic Movement. Several leading<br />
industrialists and scientists felt we could create new industrial<br />
markets for agricultural materials and help prop up agriculture<br />
commodity prices. The 1938 Farm Bill created a series of US<br />
Department of Agriculture (USDA) research institutes to work<br />
on new industrial products using agricultural commodities.<br />
These would become the Agricultural Research Service<br />
where I worked in biobased technology transfer for 10 years.<br />
Meanwhile oil prices continued to go up and down with wild<br />
swings. Every time it seems biobased products were gaining a<br />
foothold once again, the price of oil would dip and any market<br />
advantage for biobased products disappeared. Finally, following<br />
the first world oil embargo in the mid-1970’s it appeared<br />
petroleum prices were only going one direction – up. This was<br />
true right up until the last few years. As this is being written a<br />
barrel of oil was priced at below USD 35. Gasoline in the U.S. is<br />
below two dollar a gallon and there are predictions of one dollar<br />
a gallon gasoline. It remains to be seen what impact these low<br />
petroleum prices will have on the development of alternative<br />
biobased feed stocks. However, many very large international<br />
industrial chemical companies have committed resources to<br />
develop alternative biological sources for many chemicals and<br />
are making and selling commercial materials.<br />
In the mid-80’s USDA published the findings of a Farm and<br />
Forest Task Force that looked at how many acres of agricultural<br />
products could be grown to meet industrial product demands.<br />
USDA’s Economic Research Service even published yearly<br />
updates about the number of acres or hectares that were<br />
grown and used to make biobased products. But it was not<br />
until 2002 that a decision was made by the Administration<br />
and Congress to help develop markets for the tremendous<br />
biomass in the U.S. Part of that 2002 Farm Bill was a provision<br />
to create a biobased markets development program to include<br />
a U.S. Certified Biobased Products label and to carve out a<br />
federal procurement preference for the purchase of biobased<br />
products. This was to become the BioPreferred program.<br />
Michael asked me to talk about the role of bioplastics in this<br />
movement. One of the first platforms to have success in the<br />
marketplace was PLA, particularly for single use items. But<br />
even that had many challenges and major investors pulled out<br />
because the technology was not making any money. That is no<br />
longer the case. Since those bold first steps there are at least<br />
38 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
five new pathways to bioplastics and each has different<br />
technologies at work. While bioplastics is only 1 % of the<br />
total worldwide market it is the fastest growing plastics<br />
sector. And with any new industry there will be winners<br />
and losers. Some technologies will advance and become<br />
profitable. Others will not. I am not sure even a crystal ball<br />
can tell us which technologies will succeed and which will<br />
fail.<br />
However, major world-wide chemical companies have<br />
now made significant financial investments to make<br />
polymers (not just plastic) using biomass, instead of<br />
petroleum. And many of those products are now being<br />
marketed commercially. There are also major advances in<br />
using bioplastics to produce the covers for our electronic<br />
products. And why not as our pocket phones are out of date<br />
as soon as we buy them. Same with our laptops.<br />
Many of the finished products and intermediate chemicals<br />
currently labeled as USDA Certified Biobased Products are<br />
either biopolymers or biobased building block chemicals<br />
used to make finished biopolymers.<br />
Some of you have heard me speak about the Great<br />
Garbage Patch of the Pacific Ocean which is filled with<br />
petroleum-based plastic particles hundreds of miles wide<br />
and miles deep from micro-particles to huge chunks of<br />
floating plastic debris. But these dumps exist in many other<br />
oceans and they are killing machines for seabirds and<br />
turtles as well as other marine life.<br />
Since humankind – to a great extent – seems to be<br />
unwilling to reduce, recycle, and reuse; and attempts<br />
to clean up these garbage patches is a daunting if not<br />
impossible task, would it not just make sense to make as<br />
many of our plastic materials we use in everyday life with<br />
a built-in expiration date preferable with a take-back policy<br />
for recycling. At the same time it also makes sense to buy<br />
and sell only single use items that can be fully biodegraded<br />
in composting facilities and not just break into smaller<br />
pieces that persist in the environment for eons.<br />
Additionally, research continues into the possible health<br />
impacts of using petroleum-based plastics and petroleumbased<br />
plasticizers to make containers to hold food and other<br />
products we consume. Whether or not there is a health issue<br />
with these containers in the final analysis is not the driver.<br />
In this case perception is reality. If consumers perceive a<br />
possible health issue from petro-plasticizers may exist<br />
they are already seeking and are willing to pay for biobased<br />
alternatives. One of the fastest growing biobased materials<br />
currently labeled by USDA are biobased plasticizers.<br />
Since this is an opinion piece, in conclusion I will state<br />
that I am bullish on the future of biobased products and<br />
bioplastics. I believe we will weather this current round<br />
of low oil prices and continue the research to make even<br />
better bioplastics and to make them price competitive with<br />
petroleum plastics. The price of petroleum will swing back<br />
the other way once marginal operations have been driven<br />
out of business. Again, my opinion, but it is the belief of many<br />
that the current glut of cheaper petroleum is a business<br />
practice to bankrupt operators that must have USD 75 – 100<br />
a barrel oil to be profitable. By making bioplastics an<br />
integral part of the plastic mix, even with lower petroleum<br />
prices, because of unique properties, the industry should<br />
be poised to explode when petroleum prices spike again. •<br />
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Empack Benelux<br />
@EmpackBenelux #Empack<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 39
Basics<br />
Mandatory Federal purchasing<br />
of biobased products<br />
About the USDA BioPreferred ® Program<br />
By Michael Thielen<br />
Managed by the U.S. Department of Agriculture (USDA),<br />
the Federal Biobased Products Preferred Procurement<br />
Program (BioPreferred ® Program) provides that<br />
Federal agencies in the USA must give purchasing preference<br />
to biobased products designated by this program [1, 2]. The<br />
authority for the program is included in the Farm Security and<br />
Rural Investment Act (FSRIA) of 2002, reauthorized and expanded<br />
as part of the Agricultural Act of 2<strong>01</strong>4 (the 2<strong>01</strong>4 Farm<br />
Bill) [3]. Section 9002 of this Act provides for a preferred procurement<br />
and labeling program and defines biobased products<br />
as commercial or industrial products that are composed,<br />
in whole or in significant part, of biological products or renewable<br />
domestic agricultural materials (including plant, animal,<br />
and marine materials) or forestry materials. Domestic content<br />
is interpreted to mean content not only from the USA<br />
but also from any country with which the United States has a<br />
preferential trade agreement. Countries that are signatories<br />
to NAFTA and CAFTA, for example, will have their qualifying<br />
biobased products treated as domestic products.<br />
The purpose of the BioPreferred program is to spur<br />
economic development, create new jobs and provide new<br />
markets for farm commodities. The increased development,<br />
purchase, and use of biobased products reduces the USA’s<br />
reliance on petroleum, increases the use of renewable<br />
agricultural resources, and contributes to reducing adverse<br />
environmental and health impacts [2].<br />
Mandatory Federal Purchasing<br />
The program requires, that all Federal agencies in the USA<br />
must purchase biobased products in categories identified by<br />
USDA. To date, USDA has identified 97 categories of biobased<br />
products for which agencies and their contractors have<br />
purchasing requirements. These categories include such that<br />
refer to biobased plastic products, e.g. carpets of other floor<br />
coverings (7 %), plastic lumber (23 %), dispoasable containers<br />
(72 %), cutlery (48 %), tableware (72 %), films (non-durable:<br />
85 % – semi-durable: 45 %), packaging and insulating<br />
materials (74%), plastic insulating foam for construction<br />
(7 %), thermal shipping containers (durable: 21 % - nondurable:<br />
82 %), and some more. Each mandatory purchasing<br />
category specifies the minimum biobased content according<br />
to ASTM D6866 (see figures in parentheses).<br />
Excemptions from the mandatory purchasing are products<br />
that are<br />
• not reasonably available<br />
• fail to meet performance standards for the application<br />
intended<br />
• available only at an unreasonable price.<br />
The BioPreferred program does not provide financial support<br />
for its participants. However, USDA’s Rural Development<br />
agency offers loan and grant programs. More information<br />
about this offer can be found on the USDA’s BioPreferred<br />
website [4],<br />
Voluntary Labeling<br />
Consumers are increasingly looking for products with<br />
sustainable attributes. That’s why USDA wants to make it<br />
easy for consumers to identify biobased products. The USDA<br />
Certified Biobased Product label (see picture), displayed on<br />
a product certified by USDA, is designed to provide useful<br />
information to consumers about the biobased content of the<br />
product [2].<br />
Companies offering biobased products that meet USDA<br />
criteria may apply for certification, allowing them to display<br />
the USDA Certified Biobased Product label on the product.<br />
This label assures a consumer that the product contains a<br />
verified amount of renewable biological ingredients (referred<br />
to as biobased content). Consumers can trust the label to<br />
mean what it says because manufacturer’s claims concerning<br />
the biobased content are third-party certified and strictly<br />
monitored by USDA [2].<br />
What Are Biobased Products?<br />
Biobased products are derived from plants and other<br />
renewable agricultural, marine, and forestry materials and<br />
provide an alternative to conventional petroleum derived<br />
products.<br />
Biodegradability required<br />
For some products, such as single use bioplastic products<br />
must meet the appropriate standard for biodegradability<br />
(ASTM D 6400) in order to be designated for the BioPreferred<br />
procurement program. Some examples are cutlery, garbage<br />
bags or food containers [1].<br />
www.biopreferred.gov<br />
[1] Duncan, M.: Federal Agencies in the USA shall buy bioplastics products,<br />
bioplastics MAGAZINE Vol 1, 2006, p 28-29<br />
[2] N.N.: What is BioPreferred, http://www.biopreferred.gov/BioPreferred/<br />
faces/pages/AboutBioPreferred.xhtml<br />
[3] N.N.: The 2<strong>01</strong>4 Farm Bill: https://www.gpo.gov/fdsys/pkg/BILLS-<br />
113hr2642enr/pdf/BILLS-113hr2642enr.pdf<br />
[4] N.N.: USDA Loans and Grants, http://www.biopreferred.gov/BioPreferred/<br />
faces/pages/USDALoansAndGrants.xhtml<br />
40 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Internationaler Kongress<br />
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09. und 10. März 2<strong>01</strong>6, Mannheim<br />
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IWKS, Alzenau und Hanau<br />
Veranstaltung der VDI Wissensforum GmbH | www.kunststoffe-im-auto.de | Telefon +49 211 6214-2<strong>01</strong> | Fax +49 211 6214-154
Basics<br />
Glossary 4.1 last update issue 04/2<strong>01</strong>5<br />
In bioplastics MAGAZINE again and again<br />
the same expressions appear that some of our readers<br />
might not (yet) be familiar with. This glossary shall help<br />
with these terms and shall help avoid repeated explanations<br />
such as PLA (Polylactide) in various articles.<br />
Bioplastics (as defined by European Bioplastics<br />
e.V.) is a term used to define two different<br />
kinds of plastics:<br />
a. Plastics based on → renewable resources<br />
(the focus is the origin of the raw material<br />
used). These can be biodegradable or not.<br />
b. → Biodegradable and → compostable<br />
plastics according to EN13432 or similar<br />
standards (the focus is the compostability of<br />
the final product; biodegradable and compostable<br />
plastics can be based on renewable<br />
(biobased) and/or non-renewable (fossil) resources).<br />
Bioplastics may be<br />
- based on renewable resources and biodegradable;<br />
- based on renewable resources but not be<br />
biodegradable; and<br />
- based on fossil resources and biodegradable.<br />
1 st Generation feedstock | Carbohydrate rich<br />
plants such as corn or sugar cane that can<br />
also be used as food or animal feed are called<br />
food crops or 1 st generation feedstock. Bred<br />
my mankind over centuries for highest energy<br />
efficiency, currently, 1 st generation feedstock<br />
is the most efficient feedstock for the production<br />
of bioplastics as it requires the least<br />
amount of land to grow and produce the highest<br />
yields. [bM 04/09]<br />
2 nd Generation feedstock | refers to feedstock<br />
not suitable for food or feed. It can be either<br />
non-food crops (e.g. cellulose) or waste materials<br />
from 1 st generation feedstock (e.g.<br />
waste vegetable oil). [bM 06/11]<br />
3 rd Generation feedstock | This term currently<br />
relates to biomass from algae, which<br />
– having a higher growth yield than 1 st and 2 nd<br />
generation feedstock – were given their own<br />
category.<br />
Aerobic digestion | Aerobic means in the<br />
presence of oxygen. In →composting, which is<br />
an aerobic process, →microorganisms access<br />
the present oxygen from the surrounding atmosphere.<br />
They metabolize the organic material<br />
to energy, CO 2<br />
, water and cell biomass,<br />
whereby part of the energy of the organic material<br />
is released as heat. [bM 03/07, bM 02/09]<br />
Since this Glossary will not be printed<br />
in each issue you can download a pdf version<br />
from our website (bit.ly/OunBB0)<br />
bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />
Version 4.0 was revised using EuBP’s latest version (Jan 2<strong>01</strong>5).<br />
[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />
Anaerobic digestion | In anaerobic digestion,<br />
organic matter is degraded by a microbial<br />
population in the absence of oxygen<br />
and producing methane and carbon dioxide<br />
(= →biogas) and a solid residue that can be<br />
composted in a subsequent step without<br />
practically releasing any heat. The biogas can<br />
be treated in a Combined Heat and Power<br />
Plant (CHP), producing electricity and heat, or<br />
can be upgraded to bio-methane [14] [bM 06/09]<br />
Amorphous | non-crystalline, glassy with unordered<br />
lattice<br />
Amylopectin | Polymeric branched starch<br />
molecule with very high molecular weight<br />
(biopolymer, monomer is →Glucose) [bM 05/09]<br />
Amylose | Polymeric non-branched starch<br />
molecule with high molecular weight (biopolymer,<br />
monomer is →Glucose) [bM 05/09]<br />
Biobased | The term biobased describes the<br />
part of a material or product that is stemming<br />
from →biomass. When making a biobasedclaim,<br />
the unit (→biobased carbon content,<br />
→biobased mass content), a percentage and<br />
the measuring method should be clearly stated [1]<br />
Biobased carbon | carbon contained in or<br />
stemming from →biomass. A material or<br />
product made of fossil and →renewable resources<br />
contains fossil and →biobased carbon.<br />
The biobased carbon content is measured via<br />
the 14 C method (radio carbon dating method)<br />
that adheres to the technical specifications as<br />
described in [1,4,5,6].<br />
Biobased labels | The fact that (and to<br />
what percentage) a product or a material is<br />
→biobased can be indicated by respective<br />
labels. Ideally, meaningful labels should be<br />
based on harmonised standards and a corresponding<br />
certification process by independent<br />
third party institutions. For the property<br />
biobased such labels are in place by certifiers<br />
→DIN CERTCO and →Vinçotte who both base<br />
their certifications on the technical specification<br />
as described in [4,5]<br />
A certification and corresponding label depicting<br />
the biobased mass content was developed<br />
by the French Association Chimie du Végétal<br />
[ACDV].<br />
Biobased mass content | describes the<br />
amount of biobased mass contained in a material<br />
or product. This method is complementary<br />
to the 14 C method, and furthermore, takes<br />
other chemical elements besides the biobased<br />
carbon into account, such as oxygen, nitrogen<br />
and hydrogen. A measuring method has<br />
been developed and tested by the Association<br />
Chimie du Végétal (ACDV) [1]<br />
Biobased plastic | A plastic in which constitutional<br />
units are totally or partly from →<br />
biomass [3]. If this claim is used, a percentage<br />
should always be given to which extent<br />
the product/material is → biobased [1]<br />
[bM <strong>01</strong>/07, bM 03/10]<br />
Biodegradable Plastics | Biodegradable Plastics<br />
are plastics that are completely assimilated<br />
by the → microorganisms present a defined<br />
environment as food for their energy. The<br />
carbon of the plastic must completely be converted<br />
into CO 2<br />
during the microbial process.<br />
The process of biodegradation depends on<br />
the environmental conditions, which influence<br />
it (e.g. location, temperature, humidity) and<br />
on the material or application itself. Consequently,<br />
the process and its outcome can vary<br />
considerably. Biodegradability is linked to the<br />
structure of the polymer chain; it does not depend<br />
on the origin of the raw materials.<br />
There is currently no single, overarching standard<br />
to back up claims about biodegradability.<br />
One standard for example is ISO or in Europe:<br />
EN 14995 Plastics- Evaluation of compostability<br />
- Test scheme and specifications<br />
[bM 02/06, bM <strong>01</strong>/07]<br />
Biogas | → Anaerobic digestion<br />
Biomass | Material of biological origin excluding<br />
material embedded in geological formations<br />
and material transformed to fossilised<br />
material. This includes organic material, e.g.<br />
trees, crops, grasses, tree litter, algae and<br />
waste of biological origin, e.g. manure [1, 2]<br />
Biorefinery | the co-production of a spectrum<br />
of bio-based products (food, feed, materials,<br />
chemicals including monomers or building<br />
blocks for bioplastics) and energy (fuels, power,<br />
heat) from biomass.[bM 02/13]<br />
Blend | Mixture of plastics, polymer alloy of at<br />
least two microscopically dispersed and molecularly<br />
distributed base polymers<br />
Bisphenol-A (BPA) | Monomer used to produce<br />
different polymers. BPA is said to cause<br />
health problems, due to the fact that is behaves<br />
like a hormone. Therefore it is banned<br />
for use in children’s products in many countries.<br />
BPI | Biodegradable Products Institute, a notfor-profit<br />
association. Through their innovative<br />
compostable label program, BPI educates<br />
manufacturers, legislators and consumers<br />
about the importance of scientifically based<br />
standards for compostable materials which<br />
biodegrade in large composting facilities.<br />
Carbon footprint | (CFPs resp. PCFs – Product<br />
Carbon Footprint): Sum of →greenhouse<br />
gas emissions and removals in a product system,<br />
expressed as CO 2<br />
equivalent, and based<br />
on a →life cycle assessment. The CO 2<br />
equivalent<br />
of a specific amount of a greenhouse gas<br />
is calculated as the mass of a given greenhouse<br />
gas multiplied by its →global warmingpotential<br />
[1,2,15]<br />
42 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Basics<br />
Carbon neutral, CO 2<br />
neutral | describes a<br />
product or process that has a negligible impact<br />
on total atmospheric CO 2<br />
levels. For<br />
example, carbon neutrality means that any<br />
CO 2<br />
released when a plant decomposes or<br />
is burnt is offset by an equal amount of CO 2<br />
absorbed by the plant through photosynthesis<br />
when it is growing.<br />
Carbon neutrality can also be achieved<br />
through buying sufficient carbon credits to<br />
make up the difference. The latter option is<br />
not allowed when communicating → LCAs<br />
or carbon footprints regarding a material or<br />
product [1, 2].<br />
Carbon-neutral claims are tricky as products<br />
will not in most cases reach carbon neutrality<br />
if their complete life cycle is taken into consideration<br />
(including the end-of life).<br />
If an assessment of a material, however, is<br />
conducted (cradle to gate), carbon neutrality<br />
might be a valid claim in a B2B context. In this<br />
case, the unit assessed in the complete life<br />
cycle has to be clarified [1]<br />
Cascade use | of →renewable resources means<br />
to first use the →biomass to produce biobased<br />
industrial products and afterwards – due to<br />
their favourable energy balance – use them<br />
for energy generation (e.g. from a biobased<br />
plastic product to →biogas production). The<br />
feedstock is used efficiently and value generation<br />
increases decisively.<br />
Catalyst | substance that enables and accelerates<br />
a chemical reaction<br />
Cellophane | Clear film on the basis of →cellulose<br />
[bM <strong>01</strong>/10]<br />
Cellulose | Cellulose is the principal component<br />
of cell walls in all higher forms of plant<br />
life, at varying percentages. It is therefore the<br />
most common organic compound and also<br />
the most common polysaccharide (multisugar)<br />
[11]. Cellulose is a polymeric molecule<br />
with very high molecular weight (monomer is<br />
→Glucose), industrial production from wood<br />
or cotton, to manufacture paper, plastics and<br />
fibres [bM <strong>01</strong>/10]<br />
Cellulose ester | Cellulose esters occur by<br />
the esterification of cellulose with organic acids.<br />
The most important cellulose esters from<br />
a technical point of view are cellulose acetate<br />
(CA with acetic acid), cellulose propionate<br />
(CP with propionic acid) and cellulose butyrate<br />
(CB with butanoic acid). Mixed polymerisates,<br />
such as cellulose acetate propionate<br />
(CAP) can also be formed. One of the most<br />
well-known applications of cellulose aceto<br />
butyrate (CAB) is the moulded handle on the<br />
Swiss army knife [11]<br />
Cellulose acetate CA | → Cellulose ester<br />
CEN | Comité Européen de Normalisation<br />
(European organisation for standardization)<br />
Certification | is a process in which materials/products<br />
undergo a string of (laboratory)<br />
tests in order to verify that the fulfil certain<br />
requirements. Sound certification systems<br />
should be based on (ideally harmonised) European<br />
standards or technical specifications<br />
(e.g. by →CEN, USDA, ASTM, etc.) and be<br />
performed by independent third party laboratories.<br />
Successful certification guarantees<br />
a high product safety - also on this basis interconnected<br />
labels can be awarded that help<br />
the consumer to make an informed decision.<br />
Compost | A soil conditioning material of decomposing<br />
organic matter which provides nutrients<br />
and enhances soil structure.<br />
[bM 06/08, 02/09]<br />
Compostable Plastics | Plastics that are<br />
→ biodegradable under →composting conditions:<br />
specified humidity, temperature,<br />
→ microorganisms and timeframe. In order<br />
to make accurate and specific claims about<br />
compostability, the location (home, → industrial)<br />
and timeframe need to be specified [1].<br />
Several national and international standards<br />
exist for clearer definitions, for example EN<br />
14995 Plastics - Evaluation of compostability -<br />
Test scheme and specifications. [bM 02/06, bM <strong>01</strong>/07]<br />
Composting | is the controlled →aerobic, or<br />
oxygen-requiring, decomposition of organic<br />
materials by →microorganisms, under controlled<br />
conditions. It reduces the volume and<br />
mass of the raw materials while transforming<br />
them into CO 2<br />
, water and a valuable soil conditioner<br />
– compost.<br />
When talking about composting of bioplastics,<br />
foremost →industrial composting in a<br />
managed composting facility is meant (criteria<br />
defined in EN 13432).<br />
The main difference between industrial and<br />
home composting is, that in industrial composting<br />
facilities temperatures are much<br />
higher and kept stable, whereas in the composting<br />
pile temperatures are usually lower,<br />
and less constant as depending on factors<br />
such as weather conditions. Home composting<br />
is a way slower-paced process than<br />
industrial composting. Also a comparatively<br />
smaller volume of waste is involved. [bM 03/07]<br />
Compound | plastic mixture from different<br />
raw materials (polymer and additives) [bM 04/10)<br />
Copolymer | Plastic composed of different<br />
monomers.<br />
Cradle-to-Gate | Describes the system<br />
boundaries of an environmental →Life Cycle<br />
Assessment (LCA) which covers all activities<br />
from the cradle (i.e., the extraction of raw materials,<br />
agricultural activities and forestry) up<br />
to the factory gate<br />
Cradle-to-Cradle | (sometimes abbreviated<br />
as C2C): Is an expression which communicates<br />
the concept of a closed-cycle economy,<br />
in which waste is used as raw material<br />
(‘waste equals food’). Cradle-to-Cradle is not<br />
a term that is typically used in →LCA studies.<br />
Cradle-to-Grave | Describes the system<br />
boundaries of a full →Life Cycle Assessment<br />
from manufacture (cradle) to use phase and<br />
disposal phase (grave).<br />
Crystalline | Plastic with regularly arranged<br />
molecules in a lattice structure<br />
Density | Quotient from mass and volume of<br />
a material, also referred to as specific weight<br />
DIN | Deutsches Institut für Normung (German<br />
organisation for standardization)<br />
DIN-CERTCO | independant certifying organisation<br />
for the assessment on the conformity<br />
of bioplastics<br />
Dispersing | fine distribution of non-miscible<br />
liquids into a homogeneous, stable mixture<br />
Drop-In bioplastics | chemically indentical<br />
to conventional petroleum based plastics,<br />
but made from renewable resources. Examples<br />
are bio-PE made from bio-ethanol (from<br />
e.g. sugar cane) or partly biobased PET; the<br />
monoethylene glykol made from bio-ethanol<br />
(from e.g. sugar cane). Developments to<br />
make terephthalic acid from renewable resources<br />
are under way. Other examples are<br />
polyamides (partly biobased e.g. PA 4.10 or PA<br />
6.10 or fully biobased like PA 5.10 or PA10.10)<br />
EN 13432 | European standard for the assessment<br />
of the → compostability of plastic<br />
packaging products<br />
Energy recovery | recovery and exploitation<br />
of the energy potential in (plastic) waste for<br />
the production of electricity or heat in waste<br />
incineration pants (waste-to-energy)<br />
Environmental claim | A statement, symbol<br />
or graphic that indicates one or more environmental<br />
aspect(s) of a product, a component,<br />
packaging or a service. [16]<br />
Enzymes | proteins that catalyze chemical<br />
reactions<br />
Enzyme-mediated plastics | are no →bioplastics.<br />
Instead, a conventional non-biodegradable<br />
plastic (e.g. fossil-based PE) is enriched<br />
with small amounts of an organic additive.<br />
Microorganisms are supposed to consume<br />
these additives and the degradation process<br />
should then expand to the non-biodegradable<br />
PE and thus make the material degrade. After<br />
some time the plastic is supposed to visually<br />
disappear and to be completely converted to<br />
carbon dioxide and water. This is a theoretical<br />
concept which has not been backed up by<br />
any verifiable proof so far. Producers promote<br />
enzyme-mediated plastics as a solution to littering.<br />
As no proof for the degradation process<br />
has been provided, environmental beneficial<br />
effects are highly questionable.<br />
Ethylene | colour- and odourless gas, made<br />
e.g. from, Naphtha (petroleum) by cracking or<br />
from bio-ethanol by dehydration, monomer of<br />
the polymer polyethylene (PE)<br />
European Bioplastics e.V. | The industry association<br />
representing the interests of Europe’s<br />
thriving bioplastics’ industry. Founded<br />
in Germany in 1993 as IBAW, European<br />
Bioplastics today represents the interests<br />
of about 50 member companies throughout<br />
the European Union and worldwide. With<br />
members from the agricultural feedstock,<br />
chemical and plastics industries, as well as<br />
industrial users and recycling companies, European<br />
Bioplastics serves as both a contact<br />
platform and catalyst for advancing the aims<br />
of the growing bioplastics industry.<br />
Extrusion | process used to create plastic<br />
profiles (or sheet) of a fixed cross-section<br />
consisting of mixing, melting, homogenising<br />
and shaping of the plastic.<br />
FDCA | 2,5-furandicarboxylic acid, an intermediate<br />
chemical produced from 5-HMF.<br />
The dicarboxylic acid can be used to make →<br />
PEF = polyethylene furanoate, a polyester that<br />
could be a 100% biobased alternative to PET.<br />
Fermentation | Biochemical reactions controlled<br />
by → microorganisms or → enyzmes (e.g. the<br />
transformation of sugar into lactic acid).<br />
FSC | Forest Stewardship Council. FSC is an<br />
independent, non-governmental, not-forprofit<br />
organization established to promote the<br />
responsible and sustainable management of<br />
the world’s forests.<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 43
Basics<br />
Gelatine | Translucent brittle solid substance,<br />
colorless or slightly yellow, nearly tasteless<br />
and odorless, extracted from the collagen inside<br />
animals‘ connective tissue.<br />
Genetically modified organism (GMO) |<br />
Organisms, such as plants and animals,<br />
whose genetic material (DNA) has been altered<br />
are called genetically modified organisms<br />
(GMOs). Food and feed which contain<br />
or consist of such GMOs, or are produced<br />
from GMOs, are called genetically modified<br />
(GM) food or feed [1]. If GM crops are used<br />
in bioplastics production, the multiple-stage<br />
processing and the high heat used to create<br />
the polymer removes all traces of genetic<br />
material. This means that the final bioplastics<br />
product contains no genetic traces. The<br />
resulting bioplastics is therefore well suited<br />
to use in food packaging as it contains no genetically<br />
modified material and cannot interact<br />
with the contents.<br />
Global Warming | Global warming is the rise<br />
in the average temperature of Earth’s atmosphere<br />
and oceans since the late 19th century<br />
and its projected continuation [8]. Global<br />
warming is said to be accelerated by → green<br />
house gases.<br />
Glucose | Monosaccharide (or simple sugar).<br />
G. is the most important carbohydrate (sugar)<br />
in biology. G. is formed by photosynthesis or<br />
hydrolyse of many carbohydrates e. g. starch.<br />
Greenhouse gas GHG | Gaseous constituent<br />
of the atmosphere, both natural and anthropogenic,<br />
that absorbs and emits radiation at<br />
specific wavelengths within the spectrum of<br />
infrared radiation emitted by the earth’s surface,<br />
the atmosphere, and clouds [1, 9]<br />
Greenwashing | The act of misleading consumers<br />
regarding the environmental practices<br />
of a company, or the environmental benefits<br />
of a product or service [1, 10]<br />
Granulate, granules | small plastic particles<br />
(3-4 millimetres), a form in which plastic is<br />
sold and fed into machines, easy to handle<br />
and dose.<br />
HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />
organic compound derived from sugar dehydration.<br />
It is a platform chemical, a building<br />
block for 20 performance polymers and over<br />
175 different chemical substances. The molecule<br />
consists of a furan ring which contains<br />
both aldehyde and alcohol functional groups.<br />
5-HMF has applications in many different<br />
industries such as bioplastics, packaging,<br />
pharmaceuticals, adhesives and chemicals.<br />
One of the most promising routes is 2,5 furandicarboxylic<br />
acid (FDCA), produced as an intermediate<br />
when 5-HMF is oxidised. FDCA is<br />
used to produce PEF, which can substitute<br />
terephthalic acid in polyester, especially polyethylene<br />
terephthalate (PET). [bM 03/14]<br />
Home composting | →composting [bM 06/08]<br />
Humus | In agriculture, humus is often used<br />
simply to mean mature →compost, or natural<br />
compost extracted from a forest or other<br />
spontaneous source for use to amend soil.<br />
Hydrophilic | Property: water-friendly, soluble<br />
in water or other polar solvents (e.g. used<br />
in conjunction with a plastic which is not water<br />
resistant and weather proof or that absorbs<br />
water such as Polyamide (PA).<br />
Hydrophobic | Property: water-resistant, not<br />
soluble in water (e.g. a plastic which is water<br />
resistant and weather proof, or that does not<br />
absorb any water such as Polyethylene (PE)<br />
or Polypropylene (PP).<br />
Industrial composting | is an established process<br />
with commonly agreed upon requirements<br />
(e.g. temperature, timeframe) for transforming<br />
biodegradable waste into stable, sanitised<br />
products to be used in agriculture. The criteria<br />
for industrial compostability of packaging have<br />
been defined in the EN 13432. Materials and<br />
products complying with this standard can be<br />
certified and subsequently labelled accordingly<br />
[1,7] [bM 06/08, 02/09]<br />
ISO | International Organization for Standardization<br />
JBPA | Japan Bioplastics Association<br />
Land use | The surface required to grow sufficient<br />
feedstock (land use) for today’s bioplastic<br />
production is less than 0.<strong>01</strong> percent of the<br />
global agricultural area of 5 billion hectares.<br />
It is not yet foreseeable to what extent an increased<br />
use of food residues, non-food crops<br />
or cellulosic biomass (see also →1 st /2 nd /3 rd<br />
generation feedstock) in bioplastics production<br />
might lead to an even further reduced<br />
land use in the future [bM 04/09, <strong>01</strong>/14]<br />
LCA | is the compilation and evaluation of the<br />
input, output and the potential environmental<br />
impact of a product system throughout its life<br />
cycle [17]. It is sometimes also referred to as<br />
life cycle analysis, ecobalance or cradle-tograve<br />
analysis. [bM <strong>01</strong>/09]<br />
Littering | is the (illegal) act of leaving waste<br />
such as cigarette butts, paper, tins, bottles,<br />
cups, plates, cutlery or bags lying in an open<br />
or public place.<br />
Marine litter | Following the European Commission’s<br />
definition, “marine litter consists of<br />
items that have been deliberately discarded,<br />
unintentionally lost, or transported by winds<br />
and rivers, into the sea and on beaches. It<br />
mainly consists of plastics, wood, metals,<br />
glass, rubber, clothing and paper”. Marine<br />
debris originates from a variety of sources.<br />
Shipping and fishing activities are the predominant<br />
sea-based, ineffectively managed<br />
landfills as well as public littering the main<br />
land-based sources. Marine litter can pose a<br />
threat to living organisms, especially due to<br />
ingestion or entanglement.<br />
Currently, there is no international standard<br />
available, which appropriately describes the<br />
biodegradation of plastics in the marine environment.<br />
However, a number of standardisation<br />
projects are in progress at ISO and ASTM<br />
level. Furthermore, the European project<br />
OPEN BIO addresses the marine biodegradation<br />
of biobased products.<br />
Mass balance | describes the relationship between<br />
input and output of a specific substance<br />
within a system in which the output from the<br />
system cannot exceed the input into the system.<br />
First attempts were made by plastic raw material<br />
producers to claim their products renewable<br />
(plastics) based on a certain input<br />
of biomass in a huge and complex chemical<br />
plant, then mathematically allocating this<br />
biomass input to the produced plastic.<br />
These approaches are at least controversially<br />
disputed [bM 04/14, 05/14, <strong>01</strong>/15]<br />
Microorganism | Living organisms of microscopic<br />
size, such as bacteria, funghi or yeast.<br />
Molecule | group of at least two atoms held<br />
together by covalent chemical bonds.<br />
Monomer | molecules that are linked by polymerization<br />
to form chains of molecules and<br />
then plastics<br />
Mulch film | Foil to cover bottom of farmland<br />
Organic recycling | means the treatment of<br />
separately collected organic waste by anaerobic<br />
digestion and/or composting.<br />
Oxo-degradable / Oxo-fragmentable | materials<br />
and products that do not biodegrade!<br />
The underlying technology of oxo-degradability<br />
or oxo-fragmentation is based on special additives,<br />
which, if incorporated into standard<br />
resins, are purported to accelerate the fragmentation<br />
of products made thereof. Oxodegradable<br />
or oxo-fragmentable materials do<br />
not meet accepted industry standards on compostability<br />
such as EN 13432. [bM <strong>01</strong>/09, 05/09]<br />
PBAT | Polybutylene adipate terephthalate, is<br />
an aliphatic-aromatic copolyester that has the<br />
properties of conventional polyethylene but is<br />
fully biodegradable under industrial composting.<br />
PBAT is made from fossil petroleum with<br />
first attempts being made to produce it partly<br />
from renewable resources [bM 06/09]<br />
PBS | Polybutylene succinate, a 100% biodegradable<br />
polymer, made from (e.g. bio-BDO)<br />
and succinic acid, which can also be produced<br />
biobased [bM 03/12].<br />
PC | Polycarbonate, thermoplastic polyester,<br />
petroleum based and not degradable, used<br />
for e.g. baby bottles or CDs. Criticized for its<br />
BPA (→ Bisphenol-A) content.<br />
PCL | Polycaprolactone, a synthetic (fossil<br />
based), biodegradable bioplastic, e.g. used as<br />
a blend component.<br />
PE | Polyethylene, thermoplastic polymerised<br />
from ethylene. Can be made from renewable<br />
resources (sugar cane via bio-ethanol) [bM 05/10]<br />
PEF | polyethylene furanoate, a polyester<br />
made from monoethylene glycol (MEG) and<br />
→FDCA (2,5-furandicarboxylic acid , an intermediate<br />
chemical produced from 5-HMF). It<br />
can be a 100% biobased alternative for PET.<br />
PEF also has improved product characteristics,<br />
such as better structural strength and<br />
improved barrier behaviour, which will allow<br />
for the use of PEF bottles in additional applications.<br />
[bM 03/11, 04/12]<br />
PET | Polyethylenterephthalate, transparent<br />
polyester used for bottles and film. The<br />
polyester is made from monoethylene glycol<br />
(MEG), that can be renewably sourced from<br />
bio-ethanol (sugar cane) and (until now fossil)<br />
terephthalic acid [bM 04/14]<br />
PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />
thermoplastic polymer and the<br />
simplest linear, aliphatic polyester. Besides<br />
ist use in the biomedical field, PGA has been<br />
introduced as a barrier resin [bM 03/09]<br />
PHA | Polyhydroxyalkanoates (PHA) or the<br />
polyhydroxy fatty acids, are a family of biodegradable<br />
polyesters. As in many mammals,<br />
including humans, that hold energy reserves<br />
in the form of body fat there are also bacteria<br />
that hold intracellular reserves in for of<br />
of polyhydroxy alkanoates. Here the microorganisms<br />
store a particularly high level of<br />
44 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Basics<br />
energy reserves (up to 80% of their own body<br />
weight) for when their sources of nutrition become<br />
scarce. By farming this type of bacteria,<br />
and feeding them on sugar or starch (mostly<br />
from maize), or at times on plant oils or other<br />
nutrients rich in carbonates, it is possible to<br />
obtain PHA‘s on an industrial scale [11]. The<br />
most common types of PHA are PHB (Polyhydroxybutyrate,<br />
PHBV and PHBH. Depending<br />
on the bacteria and their food, PHAs with<br />
different mechanical properties, from rubbery<br />
soft trough stiff and hard as ABS, can be produced.<br />
Some PHSs are even biodegradable in<br />
soil or in a marine environment<br />
PLA | Polylactide or Polylactic Acid (PLA), a<br />
biodegradable, thermoplastic, linear aliphatic<br />
polyester based on lactic acid, a natural acid,<br />
is mainly produced by fermentation of sugar<br />
or starch with the help of micro-organisms.<br />
Lactic acid comes in two isomer forms, i.e. as<br />
laevorotatory D(-)lactic acid and as dextrorotary<br />
L(+)lactic acid.<br />
Modified PLA types can be produced by the<br />
use of the right additives or by certain combinations<br />
of L- and D- lactides (stereocomplexing),<br />
which then have the required rigidity for<br />
use at higher temperatures [13] [bM <strong>01</strong>/09, <strong>01</strong>/12]<br />
Plastics | Materials with large molecular<br />
chains of natural or fossil raw materials, produced<br />
by chemical or biochemical reactions.<br />
PPC | Polypropylene Carbonate, a bioplastic<br />
made by copolymerizing CO 2<br />
with propylene<br />
oxide (PO) [bM 04/12]<br />
PTT | Polytrimethylterephthalate (PTT), partially<br />
biobased polyester, is similarly to PET<br />
produced using terephthalic acid or dimethyl<br />
terephthalate and a diol. In this case it is a<br />
biobased 1,3 propanediol, also known as bio-<br />
PDO [bM <strong>01</strong>/13]<br />
Renewable Resources | agricultural raw materials,<br />
which are not used as food or feed,<br />
but as raw material for industrial products<br />
or to generate energy. The use of renewable<br />
resources by industry saves fossil resources<br />
and reduces the amount of → greenhouse gas<br />
emissions. Biobased plastics are predominantly<br />
made of annual crops such as corn,<br />
cereals and sugar beets or perennial cultures<br />
such as cassava and sugar cane.<br />
Resource efficiency | Use of limited natural<br />
resources in a sustainable way while minimising<br />
impacts on the environment. A resource<br />
efficient economy creates more output<br />
or value with lesser input.<br />
Seedling Logo | The compostability label or<br />
logo Seedling is connected to the standard<br />
EN 13432/EN 14995 and a certification process<br />
managed by the independent institutions<br />
→DIN CERTCO and → Vinçotte. Bioplastics<br />
products carrying the Seedling fulfil the criteria<br />
laid down in the EN 13432 regarding industrial<br />
compostability. [bM <strong>01</strong>/06, 02/10]<br />
Saccharins or carbohydrates | Saccharins or<br />
carbohydrates are name for the sugar-family.<br />
Saccharins are monomer or polymer sugar<br />
units. For example, there are known mono-,<br />
di- and polysaccharose. → glucose is a monosaccarin.<br />
They are important for the diet and<br />
produced biology in plants.<br />
Semi-finished products | plastic in form of<br />
sheet, film, rods or the like to be further processed<br />
into finshed products<br />
Sorbitol | Sugar alcohol, obtained by reduction<br />
of glucose changing the aldehyde group<br />
to an additional hydroxyl group. S. is used as<br />
a plasticiser for bioplastics based on starch.<br />
Starch | Natural polymer (carbohydrate)<br />
consisting of → amylose and → amylopectin,<br />
gained from maize, potatoes, wheat, tapioca<br />
etc. When glucose is connected to polymerchains<br />
in definite way the result (product) is<br />
called starch. Each molecule is based on 300<br />
-12000-glucose units. Depending on the connection,<br />
there are two types → amylose and →<br />
amylopectin known. [bM 05/09]<br />
Starch derivatives | Starch derivatives are<br />
based on the chemical structure of → starch.<br />
The chemical structure can be changed by<br />
introducing new functional groups without<br />
changing the → starch polymer. The product<br />
has different chemical qualities. Mostly the<br />
hydrophilic character is not the same.<br />
Starch-ester | One characteristic of every<br />
starch-chain is a free hydroxyl group. When<br />
every hydroxyl group is connected with an<br />
acid one product is starch-ester with different<br />
chemical properties.<br />
Starch propionate and starch butyrate |<br />
Starch propionate and starch butyrate can be<br />
synthesised by treating the → starch with propane<br />
or butanic acid. The product structure<br />
is still based on → starch. Every based → glucose<br />
fragment is connected with a propionate<br />
or butyrate ester group. The product is more<br />
hydrophobic than → starch.<br />
Sustainable | An attempt to provide the best<br />
outcomes for the human and natural environments<br />
both now and into the indefinite future.<br />
One famous definition of sustainability is the<br />
one created by the Brundtland Commission,<br />
led by the former Norwegian Prime Minister<br />
G. H. Brundtland. The Brundtland Commission<br />
defined sustainable development as<br />
development that ‘meets the needs of the<br />
present without compromising the ability of<br />
future generations to meet their own needs.’<br />
Sustainability relates to the continuity of economic,<br />
social, institutional and environmental<br />
aspects of human society, as well as the nonhuman<br />
environment).<br />
Sustainable sourcing | of renewable feedstock<br />
for biobased plastics is a prerequisite<br />
for more sustainable products. Impacts such<br />
as the deforestation of protected habitats<br />
or social and environmental damage arising<br />
from poor agricultural practices must<br />
be avoided. Corresponding certification<br />
schemes, such as ISCC PLUS, WLC or Bon-<br />
Sucro, are an appropriate tool to ensure the<br />
sustainable sourcing of biomass for all applications<br />
around the globe.<br />
Sustainability | as defined by European Bioplastics,<br />
has three dimensions: economic, social<br />
and environmental. This has been known<br />
as “the triple bottom line of sustainability”.<br />
This means that sustainable development involves<br />
the simultaneous pursuit of economic<br />
prosperity, environmental protection and social<br />
equity. In other words, businesses have<br />
to expand their responsibility to include these<br />
environmental and social dimensions. Sustainability<br />
is about making products useful to<br />
markets and, at the same time, having societal<br />
benefits and lower environmental impact<br />
than the alternatives currently available. It also<br />
implies a commitment to continuous improvement<br />
that should result in a further reduction<br />
of the environmental footprint of today’s products,<br />
processes and raw materials used.<br />
Thermoplastics | Plastics which soften or<br />
melt when heated and solidify when cooled<br />
(solid at room temperature).<br />
Thermoplastic Starch | (TPS) → starch that<br />
was modified (cooked, complexed) to make it<br />
a plastic resin<br />
Thermoset | Plastics (resins) which do not<br />
soften or melt when heated. Examples are<br />
epoxy resins or unsaturated polyester resins.<br />
Vinçotte | independant certifying organisation<br />
for the assessment on the conformity of bioplastics<br />
WPC | Wood Plastic Composite. Composite<br />
materials made of wood fiber/flour and plastics<br />
(mostly polypropylene).<br />
Yard Waste | Grass clippings, leaves, trimmings,<br />
garden residue.<br />
References:<br />
[1] Environmental Communication Guide,<br />
European Bioplastics, Berlin, Germany,<br />
2<strong>01</strong>2<br />
[2] ISO 14067. Carbon footprint of products -<br />
Requirements and guidelines for quantification<br />
and communication<br />
[3] CEN TR 15932, Plastics - Recommendation<br />
for terminology and characterisation<br />
of biopolymers and bioplastics, 2<strong>01</strong>0<br />
[4] CEN/TS 16137, Plastics - Determination<br />
of bio-based carbon content, 2<strong>01</strong>1<br />
[5] ASTM D6866, Standard Test Methods for<br />
Determining the Biobased Content of<br />
Solid, Liquid, and Gaseous Samples Using<br />
Radiocarbon Analysis<br />
[6] SPI: Understanding Biobased Carbon<br />
Content, 2<strong>01</strong>2<br />
[7] EN 13432, Requirements for packaging<br />
recoverable through composting and biodegradation.<br />
Test scheme and evaluation<br />
criteria for the final acceptance of packaging,<br />
2000<br />
[8] Wikipedia<br />
[9] ISO 14064 Greenhouse gases -- Part 1:<br />
Specification with guidance..., 2006<br />
[10] Terrachoice, 2<strong>01</strong>0, www.terrachoice.com<br />
[11] Thielen, M.: Bioplastics: Basics. Applications.<br />
Markets, Polymedia Publisher,<br />
2<strong>01</strong>2<br />
[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />
FNR, 2005<br />
[13] de Vos, S.: Improving heat-resistance of<br />
PLA using poly(D-lactide),<br />
bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />
[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />
MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />
[15] ISO 14067 onb Corbon Footprint of<br />
Products<br />
[16] ISO 14021 on Self-declared Environmental<br />
claims<br />
[17] ISO 14044 on Life Cycle Assessment<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 45
Suppliers Guide<br />
1. Raw Materials<br />
AGRANA Starch<br />
Thermoplastics<br />
Conrathstrasse 7<br />
A-3950 Gmuend, Austria<br />
Tel: +43 676 8926 19374<br />
lukas.raschbauer@agrana.com<br />
www.agrana.com<br />
Evonik Industries AG<br />
Paul Baumann Straße 1<br />
45772 Marl, Germany<br />
Tel +49 2365 49-4717<br />
evonik-hp@evonik.com<br />
www.vestamid-terra.com<br />
www.evonik.com<br />
Kingfa Sci. & Tech. Co., Ltd.<br />
No.33 Kefeng Rd, Sc. City, Guangzhou<br />
Hi-Tech Ind. Development Zone,<br />
Guangdong, P.R. China. 510663<br />
Tel: +86 (0)20 6622 1696<br />
info@ecopond.com.cn<br />
www.ecopond.com.cn<br />
FLEX-162 Biodeg. Blown Film Resin!<br />
Bio-873 4-Star Inj. Bio-Based Resin!<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
suppguide@bioplasticsmagazine.com<br />
Showa Denko Europe GmbH<br />
Konrad-Zuse-Platz 4<br />
81829 Munich, Germany<br />
Tel.: +49 89 93996226<br />
www.showa-denko.com<br />
support@sde.de<br />
Jincheng, Lin‘an, Hangzhou,<br />
Zhejiang 311300, P.R. China<br />
China contact: Grace Jin<br />
mobile: 0086 135 7578 9843<br />
Grace@xinfupharm.com<br />
Europe contact(Belgium): Susan Zhang<br />
mobile: 0032 478 991619<br />
zxh0612@hotmail.com<br />
www.xinfupharm.com<br />
1.1 bio based monomers<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel. +49 2154 9251-0<br />
Tel.: +49 2154 9251-51<br />
sales@fkur.com<br />
www.fkur.com<br />
Stay permanently listed in the<br />
Suppliers Guide with your company<br />
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For only 6,– EUR per mm, per issue you<br />
can be present among top suppliers in<br />
the field of bioplastics.<br />
For Example:<br />
PTT MCC Biochem Co., Ltd.<br />
info@pttmcc.com / www.pttmcc.com<br />
Tel: +66(0) 2 140-3563<br />
MCPP Germany GmbH<br />
+49 (0) 152-<strong>01</strong>8 920 51<br />
frank.steinbrecher@mcpp-europe.com<br />
MCPP France SAS<br />
+33 (0) 6 07 22 25 32<br />
fabien.resweber@mcpp-europe.com<br />
Corbion Purac<br />
Arkelsedijk 46, P.O. Box 21<br />
4200 AA Gorinchem -<br />
The Netherlands<br />
Tel.: +31 (0)183 695 695<br />
Fax: +31 (0)183 695 604<br />
www.corbion.com/bioplastics<br />
bioplastics@corbion.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
39 mm<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
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www.bioplasticsmagazine.com<br />
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DuPont de Nemours International S.A.<br />
2 chemin du Pavillon<br />
1218 - Le Grand Saconnex<br />
Switzerland<br />
Tel.: +41 22 171 51 11<br />
Fax: +41 22 580 22 45<br />
www.renewable.dupont.com<br />
www.plastics.dupont.com<br />
Tel: +86 351-8689356<br />
Fax: +86 351-8689718<br />
www.ecoworld.jinhuigroup.com<br />
ecoworldsales@jinhuigroup.com<br />
62 136 Lestrem, France<br />
Tel.: + 33 (0) 3 21 63 36 00<br />
www.roquette-performance-plastics.com<br />
1.2 compounds<br />
API S.p.A.<br />
Via Dante Alighieri, 27<br />
36065 Mussolente (VI), Italy<br />
Telephone +39 0424 579711<br />
www.apiplastic.com<br />
www.apinatbio.com<br />
NUREL Engineering Polymers<br />
Ctra. Barcelona, km 329<br />
50<strong>01</strong>6 Zaragoza, Spain<br />
Tel: +34 976 465 579<br />
inzea@samca.com<br />
www.inzea-biopolymers.com<br />
PolyOne<br />
Avenue Melville Wilson, 2<br />
Zoning de la Fagne<br />
5330 Assesse<br />
Belgium<br />
Tel.: + 32 83 660 211<br />
www.polyone.com<br />
1.3 PLA<br />
www.facebook.com<br />
www.issuu.com<br />
www.twitter.com<br />
Shenzhen Esun Ind. Co;Ltd<br />
www.brightcn.net<br />
www.esun.en.alibaba.com<br />
bright@brightcn.net<br />
Tel: +86-755-2603 1978<br />
www.youtube.com<br />
46 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Suppliers Guide<br />
1.4 starch-based bioplastics<br />
Limagrain Céréales Ingrédients<br />
ZAC „Les Portes de Riom“ - BP 173<br />
63204 Riom Cedex - France<br />
Tel. +33 (0)4 73 67 17 00<br />
Fax +33 (0)4 73 67 17 10<br />
www.biolice.com<br />
BIOTEC<br />
Biologische Naturverpackungen<br />
Werner-Heisenberg-Strasse 32<br />
46446 Emmerich/Germany<br />
Tel.: +49 (0) 2822 – 92510<br />
info@biotec.de<br />
www.biotec.de<br />
Grabio Greentech Corporation<br />
Tel: +886-3-598-6496<br />
No. 91, Guangfu N. Rd., Hsinchu<br />
Industrial Park,Hukou Township,<br />
Hsinchu County 30351, Taiwan<br />
sales@grabio.com.tw<br />
www.grabio.com.tw<br />
1.5 PHA<br />
PolyOne<br />
Avenue Melville Wilson, 2<br />
Zoning de la Fagne<br />
5330 Assesse<br />
Belgium<br />
Tel.: + 32 83 660 211<br />
www.polyone.com<br />
2. Additives/Secondary raw materials<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
3. Semi finished products<br />
3.1 films<br />
Infiana Germany GmbH & Co. KG<br />
Zweibrückenstraße 15-25<br />
913<strong>01</strong> Forchheim<br />
Tel. +49-9191 81-0<br />
Fax +49-9191 81-212<br />
www.infiana.com<br />
Natur-Tec ® - Northern Technologies<br />
42<strong>01</strong> Woodland Road<br />
Circle Pines, MN 55<strong>01</strong>4 USA<br />
Tel. +1 763.404.8700<br />
Fax +1 763.225.6645<br />
info@natur-tec.com<br />
www.natur-tec.com<br />
NOVAMONT S.p.A.<br />
Via Fauser , 8<br />
28100 Novara - ITALIA<br />
Fax +39.0321.699.6<strong>01</strong><br />
Tel. +39.0321.699.611<br />
www.novamont.com<br />
President Packaging Ind., Corp.<br />
PLA Paper Hot Cup manufacture<br />
In Taiwan, www.ppi.com.tw<br />
Tel.: +886-6-570-4066 ext.5531<br />
Fax: +886-6-570-4077<br />
sales@ppi.com.tw<br />
6. Equipment<br />
6.1 Machinery & Molds<br />
Uhde Inventa-Fischer GmbH<br />
Holzhauser Strasse 157–159<br />
D-13509 Berlin<br />
Tel. +49 30 43 567 5<br />
Fax +49 30 43 567 699<br />
sales.de@uhde-inventa-fischer.com<br />
Uhde Inventa-Fischer AG<br />
Via Innovativa 31<br />
CH-7<strong>01</strong>3 Domat/Ems<br />
Tel. +41 81 632 63 11<br />
Fax +41 81 632 74 03<br />
sales.ch@uhde-inventa-fischer.com<br />
www.uhde-inventa-fischer.com<br />
9. Services<br />
Osterfelder Str. 3<br />
46047 Oberhausen<br />
Tel.: +49 (0)208 8598 1227<br />
Fax: +49 (0)208 8598 1424<br />
thomas.wodke@umsicht.fhg.de<br />
www.umsicht.fraunhofer.de<br />
Institut für Kunststofftechnik<br />
Universität Stuttgart<br />
Böblinger Straße 70<br />
7<strong>01</strong>99 Stuttgart<br />
Tel +49 711/685-62814<br />
Linda.Goebel@ikt.uni-stuttgart.de<br />
www.ikt.uni-stuttgart.de<br />
TianAn Biopolymer<br />
No. 68 Dagang 6th Rd,<br />
Beilun, Ningbo, China, 315800<br />
Tel. +86-57 48 68 62 50 2<br />
Fax +86-57 48 68 77 98 0<br />
enquiry@tianan-enmat.com<br />
www.tianan-enmat.com<br />
Metabolix, Inc.<br />
Bio-based and biodegradable resins<br />
and performance additives<br />
21 Erie Street<br />
Cambridge, MA 02139, USA<br />
US +1-617-583-1700<br />
DE +49 (0) 221 / 88 88 94 00<br />
www.metabolix.com<br />
info@metabolix.com<br />
1.6 masterbatches<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Taghleef Industries SpA, Italy<br />
Via E. Fermi, 46<br />
33058 San Giorgio di Nogaro (UD)<br />
Contact Emanuela Bardi<br />
Tel. +39 0431 627264<br />
Mobile +39 342 6565309<br />
emanuela.bardi@ti-films.com<br />
www.ti-films.com<br />
4. Bioplastics products<br />
Minima Technology Co., Ltd.<br />
Esmy Huang, Marketing Manager<br />
No.33. Yichang E. Rd., Taipin City,<br />
Taichung County<br />
411, Taiwan (R.O.C.)<br />
Tel. +886(4)2277 6888<br />
Fax +883(4)2277 6989<br />
Mobil +886(0)982-829988<br />
esmy@minima-tech.com<br />
Skype esmy325<br />
www.minima-tech.com<br />
Molds, Change Parts and Turnkey<br />
Solutions for the PET/Bioplastic<br />
Container Industry<br />
284 Pinebush Road<br />
Cambridge Ontario<br />
Canada N1T 1Z6<br />
Tel. +1 519 624 9720<br />
Fax +1 519 624 9721<br />
info@hallink.com<br />
www.hallink.com<br />
6.2 Laboratory Equipment<br />
MODA: Biodegradability Analyzer<br />
SAIDA FDS INC.<br />
143-10 Isshiki, Yaizu,<br />
Shizuoka,Japan<br />
Tel:+81-54-624-6260<br />
Info2@moda.vg<br />
www.saidagroup.jp<br />
7. Plant engineering<br />
EREMA Engineering Recycling<br />
Maschinen und Anlagen GmbH<br />
Unterfeldstrasse 3<br />
4052 Ansfelden, AUSTRIA<br />
Phone: +43 (0) 732 / 3190-0<br />
Fax: +43 (0) 732 / 3190-23<br />
erema@erema.at<br />
www.erema.at<br />
narocon<br />
Dr. Harald Kaeb<br />
Tel.: +49 30-28096930<br />
kaeb@narocon.de<br />
www.narocon.de<br />
nova-Institut GmbH<br />
Chemiepark Knapsack<br />
Industriestrasse 300<br />
50354 Huerth, Germany<br />
Tel.: +49(0)2233-48-14 40<br />
E-Mail: contact@nova-institut.de<br />
www.biobased.eu<br />
Bioplastics Consulting<br />
Tel. +49 2161 664864<br />
info@polymediaconsult.com<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 47
Suppliers Guide<br />
9. Services (continued)<br />
UL International TTC GmbH<br />
Rheinuferstrasse 7-9, Geb. R33<br />
47829 Krefeld-Uerdingen, Germany<br />
Tel.: +49 (0) 2151 5370-333<br />
Fax: +49 (0) 2151 5370-334<br />
ttc@ul.com<br />
www.ulttc.com<br />
European Bioplastics e.V.<br />
Marienstr. 19/20<br />
1<strong>01</strong>17 Berlin, Germany<br />
Tel. +49 30 284 82 350<br />
Fax +49 30 284 84 359<br />
info@european-bioplastics.org<br />
www.european-bioplastics.org<br />
10.2 Universities<br />
Michigan State University<br />
Department of Chemical<br />
Engineering & Materials Science<br />
Professor Ramani Narayan<br />
East Lansing MI 48824, USA<br />
Tel. +1 517 719 7163<br />
narayan@msu.edu<br />
10.3 Other Institutions<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
suppguide@bioplasticsmagazine.com<br />
Stay permanently listed in the<br />
Suppliers Guide with your company<br />
logo and contact information.<br />
For only 6,– EUR per mm, per issue you<br />
can be present among top suppliers in<br />
the field of bioplastics.<br />
For Example:<br />
10. Institutions<br />
10.1 Associations<br />
BPI - The Biodegradable<br />
Products Institute<br />
331 West 57th Street, Suite 415<br />
New York, NY 10<strong>01</strong>9, USA<br />
Tel. +1-888-274-5646<br />
info@bpiworld.org<br />
IfBB – Institute for Bioplastics<br />
and Biocomposites<br />
University of Applied Sciences<br />
and Arts Hanover<br />
Faculty II – Mechanical and<br />
Bioprocess Engineering<br />
Heisterbergallee 12<br />
30453 Hannover, Germany<br />
Tel.: +49 5 11 / 92 96 - 22 69<br />
Fax: +49 5 11 / 92 96 - 99 - 22 69<br />
lisa.mundzeck@fh-hannover.de<br />
http://www.ifbb-hannover.de/<br />
Biobased Packaging Innovations<br />
Caroli Buitenhuis<br />
IJburglaan 836<br />
1087 EM Amsterdam<br />
The Netherlands<br />
Tel.: +31 6-24216733<br />
http://www.biobasedpackaging.nl<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Sample Charge:<br />
39mm x 6,00 €<br />
= 234,00 € per entry/per issue<br />
Sample Charge for one year:<br />
6 issues x 234,00 EUR = 1,404.00 €<br />
39 mm<br />
The entry in our Suppliers Guide is<br />
bookable for one year (6 issues) and<br />
extends automatically if it’s not canceled<br />
three month before expiry.<br />
‘Basics‘ book on bioplastics<br />
This book, created and published by Polymedia Publisher, maker<br />
of bioplastics MAGAZINE is available in English and German language<br />
(German now in the second, revised edition).<br />
The book is intended to offer a rapid and uncomplicated introduction<br />
into the subject of bioplastics, and is aimed at all interested readers, in<br />
particular those who have not yet had the opportunity to dig deeply into<br />
the subject, such as students or those just joining this industry, and lay<br />
readers. It gives an introduction to plastics and bioplastics, explains which<br />
renewable resources can be used to produce bioplastics, what types of bioplastic<br />
exist, and which ones are already on the market. Further aspects,<br />
such as market development, the agricultural land required, and waste<br />
disposal, are also examined.<br />
An extensive index allows the reader to find specific aspects quickly,<br />
and is complemented by a comprehensive literature list and a guide to<br />
sources of additional information on the Internet.<br />
The author Michael Thielen is editor and publisher bioplastics MAGA-<br />
ZINE. He is a qualified machinery design engineer with a degree in plastics<br />
technology from the RWTH University in Aachen. He has written<br />
several books on the subject of blow-moulding technology and disseminated<br />
his knowledge of plastics in numerous presentations, seminars,<br />
guest lectures and teaching assignments.<br />
110 pages full color, paperback<br />
ISBN 978-3-9814981-1-0: Bioplastics<br />
ISBN 978-3-9814981-2-7: Biokunststoffe<br />
neu: 2. überarbeitete Auflage<br />
Order now for € 18.65 or US-$ 25.00 (+ VAT where applicable, plus shipping and handling, ask for details)<br />
order at www.bioplasticsmagazine.de/books, by phone +49 2161 6884463 or by e-mail books@bioplasticsmagazine.com<br />
Or subscribe and get it as a free gift (see page 57 for details, outside German y only)<br />
48 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
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<strong>01</strong> | 2<strong>01</strong>6<br />
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You can meet us<br />
Sustainable Plastics 2<strong>01</strong>6<br />
<strong>01</strong>.03.2<strong>01</strong>6 - 02.03.2<strong>01</strong>6 - Cologne, Germany<br />
www.amiplastics-na.com/events/Event.aspx?code=C706&sec=5459<br />
Plastics in Automotive Engineering<br />
09.03.2<strong>01</strong>6 - 10.03.2<strong>01</strong>6 - Mannheim, Germany<br />
bit.ly/1lZNn6R<br />
World Bio Markets<br />
14.03.2<strong>01</strong>6 - 17.03.2<strong>01</strong>6 - Amsterdam, The Netherlands<br />
www.worldbiomarkets.com<br />
Innovation Takes Root<br />
30.03.2<strong>01</strong>6 - <strong>01</strong>.04.2<strong>01</strong>6 - Orlando Florida, USA<br />
www.innovationtakesroot.com<br />
9 th International Conference on Biobased Materials<br />
05.04.2<strong>01</strong>6 - 06.04.2<strong>01</strong>6 - Cologne, Germany<br />
biowerkstoff-kongress.de<br />
Empack 2<strong>01</strong>6 (with Biobased Village)<br />
12.04.2<strong>01</strong>6 - 14.04.2<strong>01</strong>6 - Utrecht, The Netherlands<br />
bit.ly/1m03cuf<br />
3 rd Bioplastic Materials Topical Conference<br />
19.04.2<strong>01</strong>6 - 21.04.2<strong>01</strong>6 - Bloomington, (MN) USA<br />
www. www.eiseverywhere.com/ehome/130808?eb=227133<br />
Chinaplas 2<strong>01</strong>6<br />
25.04.2<strong>01</strong>6 - 28.04.2<strong>01</strong>6 - Shanghai, China<br />
bioplastics MAGAZINE Vol. 10<br />
Cover Story<br />
Shopping bags in Italy | 18<br />
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Vol. 1<br />
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bioplastics magazine<br />
Top Talk:<br />
Interview with Helmut Traitler,<br />
VP Packaging of Nestlé | 10<br />
www.ChinaplasOnline.com<br />
4 th PLA World Congress<br />
organized by bioplastics MAGAZINE<br />
24 - 25. 05.2<strong>01</strong>6 - Munich, Germany<br />
www.pla-world-congress.com<br />
Biobased Products Europe<br />
25 - 26. 05.2<strong>01</strong>6 - Amsterdam, The Netherlands<br />
http://www.biobasedproductsworld.com/europe<br />
+<br />
or<br />
3 rd Bioplastics Buisness Breakfast K‘2<strong>01</strong>6<br />
organized by bioplastics MAGAZINE<br />
20 - 22.10.2<strong>01</strong>6 - Düsseldorf, Germany<br />
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Mention the promotion code ‘watch‘ or ‘book‘<br />
and you will get our watch or the book 3)<br />
Bioplastics Basics. Applications. Markets. for free<br />
1) Offer valid until 30 April 2<strong>01</strong>6<br />
3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />
bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 49
Companies in this issue<br />
Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />
Agrana Starch Thermoplastics 46<br />
AIMPLAS 10<br />
Annellotech 6<br />
API 46<br />
Archer Daniels Midland 24<br />
Avantium 26<br />
Beologic 8<br />
BioAmber 7<br />
Biobased Packaging Innovations 48<br />
Bio-On 7, 28<br />
Biopolymer Network 30<br />
BioPreferred 38, 40<br />
Biotec 47<br />
BMEL 34<br />
BPI 28 48<br />
Braskem 2<br />
Braskem 26<br />
Center for Bioplastics and Biocomposites 25<br />
Charmant 28<br />
Composites Evolution 14<br />
Coperion 8<br />
Corbion 8, 10, 15, 16, 27 46<br />
Cranfield University 14<br />
Delta Motorsport 14<br />
Domogel 29<br />
Dow 5, 26<br />
DowDuPont 5<br />
Dr. Hans Korte Innov.Beratung 8<br />
DSM 7<br />
DuPont 5, 24 46<br />
empack 39<br />
Erema 47<br />
Erreme 29<br />
European Bioplastics 10, 26 48<br />
Evonik 46, 51<br />
Fachagentur Nachw. Rohstoffe FNR 34<br />
Felda Global Ventures 6<br />
FKuR 10 2, 46<br />
Fraunhofer ICT 10<br />
Fraunhofer IVV 10<br />
Fraunhofer UMSICHT 32 47<br />
GFBiochemicals 20<br />
Grabio Greentech 47<br />
Grafe 46, 47<br />
Hallink 47<br />
HIB Trimpart Solutions 16<br />
IKEA 26<br />
Infiana Germany 47<br />
Innogas 6<br />
Innovate UK 14<br />
Institut for bioplastics & biocomp.(IfBB) 48<br />
ISCC 10, 26<br />
Jacobs 27<br />
Jaguar Land Rover 14<br />
JBF Industries 26<br />
Jinhui Zhaolong 46<br />
Kingfa 46<br />
KS Composites 14<br />
KU Leiven 10, 18<br />
LEGO 28<br />
Limagrain Céréales Ingrédients 47<br />
Maccaferri Holding 7<br />
Mattiussi Ecologia 2<br />
McDonalds 26<br />
Metabolix 22, 23 47<br />
Michigan State University 10 48<br />
Minima Technology 47<br />
Mitsui 26<br />
narocon 47<br />
NatureWorks 10, 27 21<br />
Natur-Tec 47<br />
Newlight Technologies 6<br />
nova-Institut 8, 10, 16 19, 29, 31, 47<br />
Novamont 26 47, 52<br />
NUREL Engineering Polymers 46<br />
Öko Institut 34<br />
Onora 8<br />
Plantura Italia 10, 15<br />
Plasthill 8<br />
plasticker 7<br />
Plastics Today 5<br />
PolyFerm 22<br />
PolyOne 8, 12, 17 46, 47<br />
Pöyry 26<br />
President Packaging 47<br />
Procter & Gamble 26<br />
PTT MCC Biochem 33, 46<br />
Reverdia 7<br />
Röchling 15, 16<br />
Roquette 7 46<br />
S.E.C.I. 7<br />
Sabic 26<br />
Saida 47<br />
SHD Composite Materials 14<br />
SHENZHEN ESUN INDUSTRIAL 46<br />
Shiseido 26<br />
Showa Denko 46<br />
SPC, The Sustainable Packaging Coalition 5<br />
Sukano 10<br />
Suntory Holdings 6<br />
Synbra 10<br />
Synprodo 29<br />
Taghleef Industries 47<br />
TerraVeradae BioWorks 22<br />
TianAn Biopolymer 47<br />
Toyota Boshoku Europa 16<br />
Uhde Inventa-Fischer 10 47<br />
UL International TTC 47<br />
Univ. Stuttgart (IKT) 47<br />
US Dept. of Energy DoE 20, 24<br />
USDA 38, 40<br />
VDI 41<br />
VHI 8<br />
Vinçotte 28, 36<br />
Wageningen (WUR) 10<br />
Wood K plus 8<br />
WPC Council of China 8<br />
Yanfeng Europe Autom. Int. Systems 16<br />
Zhejiang Hangzhou Xinfu Pharmaceutical 46<br />
TU Munich 46<br />
Uhde Inventa-Fischer 17,55<br />
UL International TTC 55<br />
UNEP 7<br />
Univ. Stuttgart (IKT) 55<br />
Veolia 32<br />
Vinçotte 18,37<br />
World Economic Forum 8<br />
WWF 8<br />
ZERO 8<br />
Zhejiang Hangzhou Xinfu Pharmaceutical 54<br />
Editorial Planner<br />
2<strong>01</strong>6<br />
<strong>Issue</strong> Month Publ.-Date<br />
edit/advert/<br />
Deadline<br />
02/2<strong>01</strong>6 Mar/Apr 04 Apr 16 04 Mar 16 Thermoforming /<br />
Rigid Packaging<br />
Editorial Focus (1) Editorial Focus (2) Basics<br />
Marine Pollution /<br />
Marine Degaradation<br />
Design for Recyclability<br />
03/2<strong>01</strong>6 May/Jun 06 Jun 16 06 May 16 Injection moulding Joining of bioplastics<br />
(welding, glueing etc),<br />
Adhesives<br />
PHA (update)<br />
04/2<strong>01</strong>6 Jul/Aug <strong>01</strong> Aug 16 <strong>01</strong> Jul 16 Blow Moulding Toys Additives<br />
Trade-Fair<br />
Specials<br />
Chinaplas<br />
preview<br />
Chinaplas<br />
Review<br />
05/2<strong>01</strong>6 Sep/Oct 04 Oct 16 02 Sep 16 Fiber / Textile /<br />
Nonwoven<br />
Polyurethanes /<br />
Elastomers/Rubber<br />
Co-Polyesters<br />
K'2<strong>01</strong>6 preview<br />
06/2<strong>01</strong>6 Nov/Dec 05 Dec 16 04 Nov 16 Films / Flexibles /<br />
Bags<br />
Consumer & Office<br />
Electronics<br />
Certification - Blessing<br />
and Curse<br />
K'2<strong>01</strong>6 Review<br />
50 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11
Green up your flooring<br />
High performance naturally<br />
Biobased polyamides for carpeted floors can improve the overall environmental sustainability of building<br />
interiors. Used for floorings, VESTAMID® Terra withstands typical mechanical and physical loads in office<br />
and public buildings, and durably retains the attractive surface of the floorings.<br />
Evonik offers a variety of technical longchain polyamides suchs as PA610, PA1<strong>01</strong>0 and PA1<strong>01</strong>2. They<br />
all share a similar to improved technical performance compared to conventional engineering polyamides<br />
while also having a significantly lower carbon footprint.<br />
www.vestamid-terra.com
www.novamont.com<br />
BIODEGRADABLE AND COMPOSTABLE BIOPLASTIC<br />
CONTROLLED, ITALIAN, GUARANTEED<br />
EcoComunicazione.it<br />
QUALITY OUR TOP PRIORITY<br />
Using the MATER-BI trademark licence<br />
means that NOVAMONT’s partners agree<br />
to comply with strict quality parameters and<br />
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These are designed to ensure that films<br />
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over 1000 products have been tested.<br />
THE GUARANTEE<br />
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MATER-BI is part of a virtuous<br />
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that involves everyone,<br />
from the farmer to the composter,<br />
from the converter via the retailer<br />
to the consumer.<br />
USED FOR ALL TYPES<br />
OF WASTE DISPOSAL<br />
MATER-BI has unique,<br />
environmentally-friendly properties.<br />
It is biodegradable and compostable<br />
and contains renewable raw materials.<br />
It is the ideal solution for organic<br />
waste collection bags and is<br />
organically recycled into fertile<br />
compost.<br />
r7_10.2<strong>01</strong>5