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ISSN 1862-5258<br />

Jan/Feb<br />

<strong>01</strong> | 2<strong>01</strong>6<br />

Basics<br />

ISSN 1862-5258<br />

Public Procurement | 34<br />

May 2006<br />

Highlights<br />

Automotive | 12<br />

Foam | 30<br />

bioplastics MAGAZINE Vol. 11<br />

bioplastics magazine<br />

Vol. 1<br />

Top Talk:<br />

Interview with Helmut Traitler,<br />

VP Packaging of Nestlé | 10


Editorial<br />

dear<br />

readers<br />

Ten years of bioplastics MAGAZINE… whew – how the time has flown. I remember well<br />

how it all began. I first came into contact with bioplastics when I took on an assignment<br />

from IBAW (today European Bioplastics) to act as a PR-consultant for the “Innovationparc<br />

– bioplastics in packaging” at interpack 2005 in Düsseldorf. And,<br />

like so many other people, I was impressed. Throughout the summer after<br />

the trade fair, I couldn’t sleep, obsessed by the thought that bioplastics<br />

were the future – and that I wanted to be a part of it. I had been badly bitten<br />

by the bioplastics virus, you might say. So, I asked the experts “What’s the<br />

name of your industry’s trade journal? I want a subscription!” But there<br />

was none... And that’s how it all started.<br />

This 10 th anniversary also means a year in which we’re rolling out a few<br />

special projects:<br />

First of all, we are promoting our new App for smartphones and tablets.<br />

The App itself is free of charge and can be downloaded from the Apple<br />

appstore and from the Android Google playstore. During our anniversary<br />

year, all our content can also be downloaded for free. This means that<br />

you can read bioplastics MAGAZINE and follow us on twitter on your mobile<br />

devices – wherever you are.<br />

Of course, we’ll also have a booth at K’2<strong>01</strong>6, the world’s number one<br />

trade show for the plastics and rubber industry in October in Düsseldorf,<br />

Germany. Here, we’re planning a celebration party with music, cool<br />

drinks and snacks – and you, faithful reader, are invited. More details will<br />

follow in a later issue of the magazine.<br />

Now, about the current issue: we’re kicking off the new year with highlights on<br />

automotive applications and on foam. In the Basics section, we discuss the possibilities<br />

and challenges of public procurement. Can government stimulate and support<br />

the use of bioplastics by mandating their purchase and use in products for the public<br />

sector?<br />

We’d also like to introduce a new series in which we’re marking our anniversary<br />

year with a blast from the past. Here we’ll be re-publishing interesting articles from<br />

the early years of bioplastics MAGAZINE. Apart from the cover, have a look at page 32.<br />

Lastly, we’d like to invite you again to our 4 th PLA World Congress in Munich, Germany<br />

on May 25 th and 26 th . The Green Bag Conference, however, has regretfully had to<br />

be postponed to an as yet unknown date, due to insuperable challenges.<br />

For current news, be sure to check the latest reports, breaking news and daily news<br />

updates at www.bioplasticsmagazine.com.<br />

We hope you enjoy reading bioplastics MAGAZINE.<br />

Sincerely yours<br />

bioplastics MAGAZINE Vol. 11<br />

ISSN 1862-5258<br />

Basics<br />

bioplastics magazine<br />

Vol. 1<br />

ISSN 1862-5258<br />

Public Procurement | 34<br />

Highlights<br />

Automotive | 12<br />

Foam | 30<br />

Jan/Feb<br />

Top Talk:<br />

Interview with Helmut Traitler,<br />

VP Packaging of Nestlé | 10<br />

May 2006<br />

<strong>01</strong> | 2<strong>01</strong>6<br />

Follow us on twitter!<br />

www.twitter.com/bioplasticsmag<br />

Like us on Facebook!<br />

www.facebook.com/bioplasticsmagazine<br />

Michael Thielen<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 3


Content<br />

Imprint<br />

<strong>01</strong>|2<strong>01</strong>6<br />

Jan / Feb<br />

Automotive<br />

12 Lightweighting is key<br />

14 Carbon/Flax hybrid automotive roof<br />

15 Smart bioplastics for automotive<br />

applications<br />

16 Biocomposites in the automotive industry<br />

Materials<br />

18 The gluten solution<br />

20 Making Levulinic Acid happen<br />

24 Breakthrough platform technology for<br />

new building block<br />

Opinion<br />

26 Bioplastics industry struggling to meet<br />

expected demand<br />

38 Biopolymers will weather the crash in<br />

petroleum prices<br />

3 Editorial<br />

5 News<br />

22 Material News<br />

28 Application News<br />

Foam<br />

30 PLA foam expanding into new areas<br />

Basics: Public Procurement<br />

34 “The biobased office” for the procurement<br />

of the future<br />

34 Mandatory Federal purchasing of<br />

biobased products<br />

10 Years Ago<br />

32 Polyamide from bio-amber<br />

42 Glossary<br />

46 Suppliers Guide<br />

49 Event Calendar<br />

50 Companies in this issue<br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Karen Laird (KL)<br />

Samuel Brangenberg (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Florian Junker<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

junker@showju-systems.de<br />

Chris Shaw<br />

Chris Shaw Media Ltd<br />

Media Sales Representative<br />

phone: +44 (0) 1270 522130<br />

mobile: +44 (0) 7983 967471<br />

Layout/Production<br />

Ulrich Gewehr (Dr. Gupta Verlag)<br />

Max Godenrath (Dr. Gupta Verlag)<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

1004 Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

Total print run: 3,600 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified<br />

subscribers (149 Euro for 6 issues).<br />

bioplastics MAGAZINE is read in<br />

92 countries.<br />

Every effort is made to verify all<br />

Information published, but Polymedia<br />

Publisher cannot accept responsibility<br />

for any errors or omissions or for any<br />

losses that may arise as a result. No<br />

items may be reproduced, copied or<br />

stored in any form, including electronic<br />

format, without the prior consent of the<br />

publisher. Opinions expressed in articies<br />

do not necessarily reflect those of<br />

Polymedia Publisher.<br />

All articies appearing in bioplastics<br />

MAGAZINE, or on the website www.<br />

bioplasticsmagazine.com are strictly<br />

covered by copyright.<br />

bioplastics MAGAZINE welcomes contributions<br />

for publication. Submissions are<br />

accepted on the basis of full assignment<br />

of copyright to Polymedia Publisher<br />

GmbH unless otherwise agreed in advance<br />

and in writing. We reserve the right<br />

to edit items for reasons of space, clarity<br />

or legality. Please contact the editorial<br />

office via mt@bioplasticsmagazine.com.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks<br />

is not an indication that such names are<br />

not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped in bioplastic envelopes<br />

sponsored by Flexico Verpackungen<br />

Deutschland, Maropack GmbH & Co.<br />

KG, and Neemann<br />

Erratum<br />

For mailing our last issue we used envelopes<br />

that were we no longer permitted<br />

to use, as the new company name is<br />

Coveris Flexibles Deutschland GmbH. We<br />

sincerely apologize for this mistake.<br />

Cover<br />

Photo: Michael Thielen<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

https://www.facebook.com/bioplasticsmagazine


daily upated news at<br />

www.bioplasticsmagazine.com<br />

News<br />

SPC published position paper against oxo-additives<br />

The Sustainable Packaging Coalition (SPC), Charlottesville, Virginia, USA, has released a formal position paper against<br />

biodegradability additives for petroleum-based plastics, which are marketed as enhancing the sustainability of plastic by<br />

rendering the material biodegradable. The SPC has evaluated the use of biodegradability additives for conventional petroleumbased<br />

plastics, and has found that these additives do not offer any sustainability advantage and they may actually result in more<br />

environmental harm.<br />

The position paper lists the following reasons for the stance against these additives:<br />

• They don’t enable compostability, which is the meaningful indicator of a material’s ability to beneficially return nutrients to<br />

the environment.<br />

• They are designed to compromise the durability of plastic and the additive manufacturers have not yet demonstrated an<br />

absence of adverse effects on recycling.<br />

• The creation of a litter friendly material is a step in the wrong direction, particularly when the material may undergo<br />

extensive fragmentation and generation of micro-pollution before any biodegradation occurs.<br />

• The biodegradation of petroleum-based plastics releases fossil carbon into the atmosphere, creating harmful greenhouse<br />

gas emissions.<br />

Concerning litter and micro-pollution, the position paper says: “Most additives are designed to fragment petroleum-based<br />

plastics into small pieces in order to make it sufficiently available to the microorganisms that perform biodegradation.”<br />

However, bioplastics MAGAZINE has been waiting for 10 years now for satisfactory, scientifically backed evidence that a complete<br />

biodegradation by microorganisms will happen, in whatever timeframe. The SPC paper continues that the “fragmented micropieces<br />

remain invisible to the naked eye, yet their effects as micro-litter can be detrimental. Beyond the well-documented<br />

environmental impacts of micro-pollution, the marketing of biodegradable petroleum-based plastics as being less detrimental<br />

to the environment may contribute to improper end-of-life disposal and pollution.”<br />

In her December 30, 2<strong>01</strong>5 article at Plastics Today (bit.ly/1OM7BeC) Clare Goldsberry expresses that she doesn’t think<br />

“that most people want plastics to disappear. What we’d like to see disappear is the litter in our communities and in the<br />

world’s waterways. And that’s not a plastics problem – that’s a people problem. An additive that makes plastic litter degrade to<br />

fragments in 180 days is not exactly what I’d call a solution.” MT<br />

The complete SPC position paper can be downloaded for free from http://bit.ly/200Nv8U<br />

Jumbo merger in the chemical industry<br />

DuPont (Wilmington, Delaware, USA) and The Dow Chemical Company (Midland, Michigan, USA) announced in mid December<br />

2<strong>01</strong>5 hat their boards of directors unanimously approved a definitive agreement under which the companies will combine<br />

in an all-stock merger of equals. The combined company will be named DowDuPont. The parties intend to subsequently<br />

pursue a separation of DowDuPont into three independent, publicly traded companies through tax-free spin-offs. This would<br />

occur as soon as feasible, which is expected to be 18 – 24 months following the closing of the merger, subject to regulatory<br />

and board approval.<br />

The companies will include a leading global pure-play Agriculture company; a leading global pure-play Material Science<br />

company; and a leading technology and innovation-driven Specialty Products company. Each of the businesses will have clear<br />

focus, an appropriate capital structure, a distinct and compelling investment thesis, scale advantages, and focused investments<br />

in innovation to better deliver superior solutions and choices for customers.<br />

It is expected that the well known biobased plastic products will be continued under the the newly to be created Material<br />

Science Company: This company will be a pure-play industrial leader, consisting of DuPont’s Performance Materials segment,<br />

as well as Dow’s Performance Plastics, Performance Materials and Chemicals, Infrastructure Solutions, and Consumer<br />

Solutions (excluding the Dow Electronic Materials business) operating segments. The combination of complementary<br />

capabilities will create a low-cost, innovation-driven leader that can provide customers in high-growth, high-value industry<br />

segments in packaging, transportation, and infrastructure solutions, among others with a broad and deep portfolio of costeffective<br />

offerings. Combined pro forma 2<strong>01</strong>4 revenue for Material Science is approximately USD 51 billion.<br />

Upon completion of the transaction, Andrew N. Liveris, President, Chairman and CEO of Dow, will become Executive<br />

Chairman of the newly formed DowDuPont Board of Directors and Edward D. Breen, Chair and CEO of DuPont, will become<br />

Chief Executive Officer of DowDuPont. In these roles, both Liveris and Breen will report to the Board of Directors. In addition,<br />

when named, the chief financial officer will report to Breen. MT<br />

www.dupont.com | www.dow.com | www.dowdupontunlockingvalue.com<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 5


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

Newlight, Innogas and FGV collaborate in Malaysia<br />

on biodegradable polymers from palm oil waste<br />

The world’s largest crude palm oil producer - Malaysia-based Felda Global Ventures Berhad – is collaborating with Newlight<br />

Technologies and Innogas Technologies on a project aimed at the development of biodegradable polymers from palm oil biomass<br />

waste in Malaysia. A Memorandum of Understanding was signed by the three companies late December 2<strong>01</strong>5. The MoU will<br />

remain valid for six months or such extended period as will be agreed in writing by the parties FGV-Newlight-Innogas MoU.<br />

Based in California, Newlight Technologies has developed a carbon capture technology that combines air with methanebased<br />

greenhouse gas emissions to produce a thermoplastic material called AirCarbon. Innogas Technologies is a Malaysiabased<br />

consulting company specialized in process plant engineering and technology for chemical and renewable energy.<br />

FGV Group President and CEO Dato’ Mohd Emir Mavani Abdullah said as part of the company’s commitment to sustainability,<br />

it is always looking for innovative ways to manage its palm oil waste effectively. The collaborative sustainable biomass project<br />

is also aimed at diversifying and further developing the company’s new revenue streams, in line with a core pillar in its five-year<br />

transformation strategy of revenue enhancement. “This waste to wealth project will elevate the sustainability standards of the<br />

palm oil industries in Malaysia and the region as a whole, significantly reducing carbon emissions emitted,” said Dato Emir.<br />

“FGV is keen to partner with Newlight Technologies and Innogas Technologies through this MOU to bring the first cost<br />

effective technology in the world to produce biodegradable plastic by processing 100 % of bio-waste from our palm oil mills.”<br />

Newlight Technologies will convert biogas from FGV’s palm oil mills into AirCarbon thermoplastics. “Together, FGV and<br />

Newlight Technologies have the opportunity to make important economic and environmental progress, and we look forward to<br />

working together in this project,” said CEO Mark Herrema.<br />

The project will launch in Q2 2<strong>01</strong>6. Construction of the first plant will take around 14 months and is slated to begin in Q4 2<strong>01</strong>6.<br />

The partners plan to expand the project to ten palm oil mills over the next five years.<br />

Innogas Technologies CEO Denny Yeoh said; “Innogas Technologies holds an exclusive license for a patented state-of-the<br />

art technology to process ligno-cellulosic biomass material such as palm oil mill waste which generates a significant amount<br />

of biogas, compared to conventional technologies. “The Company will transfer this license to the joint-venture company, which<br />

will then have the exclusive use of this license in Malaysia.” KL<br />

www.feldaglobal.com<br />

Anellotech brings 100 % biobased PET<br />

another step closer<br />

Anellotech, Pearl River, New York, USA, a sustainable technology company focused on producing<br />

cost-competitive renewable chemicals from non-food biomass, has announced that it has entered<br />

into the next phase of its strategic partnership with Osaka, Japan-based Suntory Holdings Limited,<br />

one of the world’s leading consumer beverage companies<br />

This marks a major milestone in making 100 % biobased polyester and biobased PET bottles a<br />

reality.<br />

The partnership, which began in 2<strong>01</strong>2 under a collaboration agreement that has provided<br />

more than USD 15 million in funding to date, is focused on advancing the development and<br />

commercialization of cost-competitive 100 % biobased plastics for use in beverage bottles as part<br />

of Suntory’s commitment to sustainable business practices.<br />

Suntory currently uses 30 % plant-derived materials (sugar cane derived monoethylene glycol<br />

MEG) for their Mineral Water Suntory Tennensui brands and is pursuing the development of a<br />

100 % biobottle through this partnership. Approximately 54 million tonnes of PET are manufactured<br />

globally each year. Despite strong industry demand, there is no commercially-available, biobased<br />

paraxylene, the key component needed to make terephthalic acid, und thus 100 % biobased<br />

polyethylene terephthalate (PET) for use in beverage bottles, on the market today.<br />

The Anellotech alliance with Suntory supports the development of bio-aromatics including<br />

bio-paraxylene. As an integral component in the biobased value chain, Anellotech’s proprietary<br />

thermal catalytic biomass conversion technology (Bio-TCat) cost-competitively produces drop in<br />

green aromatics, including paraxylene and benzene, from non-food biomass. MT<br />

www.anellotech.com | www.suntory.com<br />

6 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


News<br />

BioAmber and<br />

Reverdia sign nonassertion<br />

agreement<br />

BioAmber Inc., which is headquartered in Montreal and<br />

Reverdia, the Netherlands-based joint venture between Royal<br />

DSM an d Roquette Frères, are both involved in the production<br />

and commercialization of bio-based succinic acid using their<br />

own unique proprietary yeast-based technologies.<br />

Pursuant to the key provisions of this agreement, BioAmber<br />

will benefit from non-assertion covenants with respect to<br />

certain intellectual property rights of Reverdia in the field<br />

of bio-based succinic acid, in exchange for undisclosed<br />

financial consideration. Furthermore, the agreement provides<br />

comfort to both BioAmber and Reverdia to continue the<br />

implementation of their respective businesses using their<br />

own unique, proprietary yeast-based technologies.<br />

“In today’s increasingly complex intellectual property<br />

environment, the conclusion of this agreement illustrates<br />

how two proactive companies operating in the same field can<br />

find a constructive solution that allows them to focus on the<br />

execution of their respective business plans rather than seeking<br />

confrontation and conflict,” said JF Huc, BioAmber’s Chief<br />

Executive Officer. “It allows BioAmber to eliminate the risk of<br />

litigation and uncertainty at a predictable cost,” he added.<br />

”This Agreement demonstrates that Reverdia’s<br />

Biosuccinium low pH yeast technology is a leading technology<br />

in the field of bio-based succinic acid and that by working with<br />

partners in the industry, we will speed up the adoption of biobased<br />

materials and validate bio-based succinic acid as a<br />

key building block for the bio-based economy,” said Marcel<br />

Lubben, Reverdia’s President. “It is our belief that the yeastbased<br />

technologies have a significant competitive advantage<br />

over bacterial-based technologies for the production of biobased<br />

succinic acid,” he added.<br />

Both Marcel Lubben and Jean-Francois Huc believe that<br />

the market for succinic acid will benefit from having strong<br />

players able to deliver on the rapidly growing demand in<br />

bio-plastics, polyurethanes, solvents, coatings and other<br />

applications. KL<br />

www.bio-amber.com | www.reverdia.com<br />

Bioplastic from<br />

biodiesel co-product<br />

glycerol<br />

An agreement signed today by Bio-on and S.E.C.I. S.p.A.<br />

(part of Gruppo Industriale Maccaferri Holding), will see<br />

Italy’s and the world’s first facility for the production<br />

of PHA bioplastics from a co-product from biodiesel<br />

production, namely glycerol.<br />

The two companies will collaborate on the construction<br />

of a production site with an initial output of 5 thousand<br />

tonnes/year, scalable to 10 thousand tonnes/year.<br />

S.E.C.I. is investing EUR 55 million in the facility,<br />

which will be located at an Eridania Sadam (also part<br />

of Maccaferri Holding) site and will be the world’s most<br />

advanced plant producing PHAs biopolymers from<br />

glycerol.<br />

PHAs, or polyhydroxyalkanoates, are bioplastics that<br />

can replace a number of traditional polymers currently<br />

made with petrochemical processes using hydrocarbons.<br />

The PHAs developed by Bio-on guarantee the same<br />

thermo-mechanical properties with the advantage of<br />

being completely naturally biodegradable.<br />

“We are investing EUR 4 million in purchasing the<br />

license for this new technology developed by Bio-on,” says<br />

Eridania Sadam Chairman Massimo Maccaferri, “because<br />

this all-natural bioplastic represents a technological<br />

challenge that can contribute towards the growth of our<br />

group in the new “green” chemistry industry, with an ecocompatible<br />

and eco-sustainable approach”.<br />

“We will create Italy’s first PHAs production plant from<br />

glycerol with one of Europe’s most important industrial<br />

groups,” explains Marco Astorri, Chairman of Bio-on<br />

“We have granted the first technological license from<br />

glycerol in line with our expectations and will be entering<br />

into a new collaboration to develop the promising highperforming<br />

biopolymers business developed by Bio-on.<br />

and produced in Italy from glycerol by S.E.C.I.” KL<br />

www.maccaferri.it | www.bio-on.it<br />

Magnetic<br />

for Plastics<br />

www.plasticker.com<br />

• International Trade<br />

in Raw Materials, Machinery & Products Free of Charge.<br />

• Daily News<br />

from the Industrial Sector and the Plastics Markets.<br />

• Current Market Prices<br />

for Plastics.<br />

• Buyer’s Guide<br />

for Plastics & Additives, Machinery & Equipment, Subcontractors<br />

and Services.<br />

• Job Market<br />

for Specialists and Executive Staff in the Plastics Industry.<br />

Up-to-date • Fast • Professional<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 7


Events<br />

The world’s largest<br />

conference on<br />

biocomposites<br />

By:<br />

Asta Partanen and Michael Carus<br />

nova-Institute<br />

Hürth, Germany<br />

From 16 – 17 December 2<strong>01</strong>5, the world’s largest conference<br />

on Wood-Plastic Composites (WPC) and Natural<br />

Fibre Composites (NFC) with more than 220 participants<br />

took place for the sixth time in Cologne, Germany. The<br />

conference was sponsored by Beologic, Corbion-Purac and<br />

Plasthill. Coperion sponsored the Wood and Natural Fibre<br />

Composite Award 2<strong>01</strong>5.<br />

The range of topics that addressed the whole variety of<br />

bio-composites was presented by top speakers from the<br />

industry and research. Construction and automotive are the<br />

biggest markets for WPC and NFC today, these materials<br />

offer huge replacement potential in plastics and composites<br />

if one looks at application fields beyond decking and<br />

automotive interior applications. Biobased raw materials<br />

lead to local added value through innovative production<br />

processes and products, but require a great amount of<br />

know-how for raw materials, processes, properties, recipes<br />

and application fields. The conference provided an up-todate<br />

picture of different technologies and most promising<br />

applications.<br />

Dr. Asta Partanen, project leader of the conference, gave<br />

the outline of “Status and Future Markets for Biobased<br />

Composites in Europe until 2020”. The presentation gave<br />

insight into the new market and trend report, which was<br />

published in June 2<strong>01</strong>5: “Wood-Plastic Composites (WPC)<br />

and Natural Fibre Composites (NFC): European and<br />

Global Markets 2<strong>01</strong>2 and Future Trends in Automotive and<br />

Construction”. According to the study the share of WPC<br />

and NFC in the total composite market – including glass,<br />

carbon, wood and Natural Fibre Composites – is already<br />

an impressive 15 %. The production volume of WPC was<br />

260,000 t in the EU in 2<strong>01</strong>2, for NFC 92,000 t. The full study<br />

can be downloaded at http://bio-based.eu/markets/.<br />

Ten years ago the WPC & NFC Conference started as<br />

First German WPC-Conference. Good reason for Dr. Hans<br />

Korte from Dr. Hans Korte Innovationberatung Holz &<br />

Fasern, Wismar, to summarize what happened in the<br />

technical development starting at the end of 1990s in the<br />

field of WPC. The German WPC market is continuously<br />

growing, as was reported by Dr. Peter Sauerwein from the<br />

“Association of the German Wood-Based Panel Industry<br />

(VHI)”. An analyses of commercially available European<br />

decking samples was presented by Dr. Andreas Haider<br />

from Wood K plus, Austria. Some products in the market<br />

show an overall better performance compared to 2008 – in<br />

particular regarding water absorbance and colour fading<br />

but also the mechanical properties. Dr. Wayne Song, WPCC<br />

(Wood-Plastic Composite Council of China) presented the<br />

latest market news and trends, especially in interior walls<br />

in the Chinese markets, that does not grow as much as<br />

was predicted by Chinese representatives in previous<br />

conferences.<br />

As every year, the Wood and Natural Fibre Composite<br />

Award was a highlight of the conference. The participants<br />

chose by far the natural fibre-reinforced, 100 % biobased<br />

coffin as their winner (Onora, s-Hertogenbosch, The<br />

Netherlands.<br />

Second highlight was the trend in WPC and NFC<br />

granulates. So far, also mainly small producers and traders<br />

were offering WPC and NFC granulates with a limited<br />

technical support and often missing data for simulations.<br />

But also this is changing since big global players are<br />

offering their new developed materials, such as PolyOne<br />

(see article on p. 12).<br />

Developments in the use of biobased polymers in the<br />

automotive industry were shown by a number of companies<br />

(see detailed report on p. 16f).<br />

Michael Carus, managing director of nova-Institute,<br />

summed up: “It was impressive to see the dynamic in the<br />

WPC and NFC sector: Improved bio-composite properties,<br />

a broad range of professional players and the penetration<br />

of new markets such as consumer goods. The participants<br />

enjoyed the high quality of the presentations and exhibition<br />

and meeting the who-is-who of the whole sector. Many<br />

reported excellent business opportunities.”<br />

The award winning coffin in the left corner of the picture.<br />

See a more detailed report on this product in<br />

bioplastics MAGAZINE issue 06/2<strong>01</strong>5, p 36.<br />

Information:<br />

All presentations are now available at http://bio-based.eu/proceedings.<br />

In order to keep track of the the growing trends in the market and high<br />

demand the next conference will be held by nova-Institute in Cologne in<br />

Autumn 2<strong>01</strong>7.<br />

8 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


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Events<br />

4 th PLA World Congress<br />

24 – 25 MAY 2<strong>01</strong>6 MUNICH › GERMANY<br />

bioplastics MAGAZINE presents:<br />

3 rd PLA World Congress<br />

The PLA World Congress in Munich/Germany, organised by bioplastics MAGAZINE<br />

27 + 28 MAY 2<strong>01</strong>4 MUNICH ›<br />

now for the 4 GERMANY<br />

th time, is the must-attend conference for everyone interested in PLA,<br />

its benefits, and challenges. The conference offers high class presentations from<br />

top individuals in the industry and also offers excellent networkung opportunities<br />

along with a table top exhibition. Please find below the preliminary programme.<br />

Find more details and register at the conference website<br />

www.pla-world-congress.com<br />

4 th PLA World Congress, preliminary programme<br />

Constance Ißbrücker, European Bioplastics<br />

Michael Carus, nova-Institute<br />

Mariagiovanna Vetere, NatureWorks<br />

Patrick Zimmermann, FKuR<br />

Björn Bergmann, Fraunhofer ICT<br />

Udo Mühlbauer, Uhde Inventa-Fischer<br />

Vittorio Bortolon, Plantura Italia<br />

Jan Henke, ISCC<br />

Amparo Verdú Solís, AIMPLAS<br />

Tanja Siebert, Fraunhofer IVV<br />

Daniel Ganz, Sukano<br />

Hugo Vuurens, Corbion Purac<br />

Ramani Narayan, Michigan State University<br />

Jan Noordegraaf, Synbra<br />

Bert Lagrain, KU Leuven<br />

Gerald Schennink, Wageningen UR<br />

Panel discussion: t.b.d.<br />

Keynote Speech: t.b.d.<br />

The role of PLA in the Bio-based Economy<br />

Ingeo – developing new applications in a circular economy perspective<br />

t.b.d.<br />

InnoREX: European project reveals processing options for intensified PLA production<br />

New features of Uhde Inventa-Fischer’s PLAneo ® process<br />

Plantura, ecofriendly automotive biopolymer<br />

Sustainable supply chains for PLA production<br />

New PLA based fibres for automotive interior applications<br />

Present and potential future recycling of PLA waste – Chances and opportunities<br />

Sustainability without compromises – Discover a toolbox of solutions for PLA<br />

Latest application innovations in PLA bioplastics<br />

Understanding the PLA molecule – From stereochemistry to applicability<br />

An expanding update on BioFoam E-PLA foam applications<br />

PLA: a perfect marriage between bio- and chemical technology<br />

PLA for durable applications comparing PLA hybrids with nucleated PLA (t.b.c.)<br />

PLA market development: chances, obstacle and challenges (t.b.c.)<br />

Call for papers is still open.<br />

Please send your abstract to mt@bioplasticsmagazine.com<br />

Info<br />

See a video-clip of the<br />

3 rd PLA World Conference 2<strong>01</strong>4<br />

at https://youtu.be/5o-6Ej7Q0_0<br />

10 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


4 th PLA World Congress<br />

24 – 25 MAY 2<strong>01</strong>6 MUNICH › GERMANY<br />

is a versatile bioplastics raw<br />

PLA material from renewable resources.<br />

It is being used for films and rigid packaging,<br />

for fibres in woven and non-woven applications.<br />

Automotive industry<br />

and consumer electronics are thoroughly<br />

investigating and even already applying PLA.<br />

New methods of polymerizing, compounding<br />

or blending of PLA have broadened the range<br />

of properties and thus the range of possible<br />

applications.<br />

That‘s why bioplastics MAGAZINE is now<br />

organizing the 4 th PLA World Congress on:<br />

24 – 25 May 2<strong>01</strong>6 in Munich / Germany<br />

Experts from all involved fields will share their<br />

knowledge and contribute to a comprehensive<br />

overview of today‘s opportunities and challenges<br />

and discuss the possibilities, limitations<br />

and future prospects of PLA for all kind of<br />

applications. Like the three congresses<br />

the 4 th PLA World Congress will also offer<br />

excellent networking opportunities for all<br />

delegates and speakers as well as exhibitors<br />

of the table-top exhibition.<br />

The conference will comprise high class presentations on<br />

The team of bioplastics MAGAZINE is looking<br />

forward to seeing you in Munich.<br />

› Latest developments<br />

› Market overview<br />

EARLY BIRD DISCOUNT<br />

Register now to benefit from the<br />

Early Bird fee of just EUR 799<br />

(after Feb 28, 2<strong>01</strong>6 it will be 899).<br />

› High temperature behaviour<br />

› Barrier issues<br />

› Additives / Colorants<br />

› Applications (film and rigid packaging, textile,<br />

automotive,electronics, toys, and many more)<br />

› Fibers, fabrics, textiles, nonwovens<br />

Contact us at: mt@bioplasticsmagazine.com<br />

for exhibition and sponsoring opportunities<br />

www.pla-world-congress.com<br />

› Reinforcements<br />

› End of life options<br />

(recycling,composting, incineration etc)<br />

organized by<br />

Gold Sponsor:


Automotive<br />

Lightweighting<br />

is key<br />

Reaching lightweighting goals<br />

with new natural fiber reinforced<br />

solutions<br />

Charpy<br />

unnotched<br />

Flexural<br />

modulus<br />

100 %<br />

80 %<br />

60 %<br />

40 %<br />

20 %<br />

0 %<br />

Tensile<br />

strength<br />

Flexural<br />

strength<br />

Tensile<br />

modulus<br />

Tensile<br />

elongation<br />

Coupling Technologie 1 Coupling Technologie 2<br />

Graph 1: Performance comparison between the two coupling<br />

technologies on Natural Engineered Fiber 1<br />

Graph 2: Comparison of reSound NF 40% natural fiber reinforced<br />

solution vs. ultimate target profile<br />

Specific gravity<br />

100 %<br />

HDT A<br />

HDT B<br />

Charpy unnotched<br />

impact strength<br />

80 %<br />

60 %<br />

40 %<br />

20 %<br />

0 %<br />

Flexural modulus<br />

Ultimate target<br />

Results<br />

Tensile strength<br />

at break<br />

Tensile modulus<br />

Flexural strength<br />

at break<br />

Manufacturers of semi-structural automotive applications<br />

now have the option to reduce part weight by<br />

5 % or more, maintain mechanical performance, and<br />

even use more sustainable materials. A triad of developments<br />

makes this possible.<br />

Automobile manufacturers need to improve their vehicles’<br />

fuel efficiencies, as required by global regulations. Reducing a<br />

vehicle’s weight is one of the most direct ways to improve fuel<br />

efficiency. Not only do lower-weight vehicles use less fuel, but<br />

they also generate lower carbon dioxide (CO 2<br />

) emissions. For<br />

carmakers marketing their vehicles in Europe, failure to reach<br />

incremental CO 2<br />

limits imposed by the European Commission<br />

would force OEMs to pay a significant penalty of up to 95 € per<br />

gram of CO 2<br />

over the limit and for each new car sold.<br />

PolyOne recognized the challenges these new regulations<br />

placed on manufacturers in the automotive industry and set<br />

out to develop a solution that could meet the mechanical<br />

properties of parts made with short glass fiber reinforced<br />

polypropylene (GFR-PP), but with a density at least 5 % less<br />

than that of GFR-PP. The Company targeted more than 20<br />

demanding automotive applications; many of these are large<br />

parts, such as instrument panel carriers and lighting systems,<br />

so a 5 – 10 % reduction in density could lead to significant<br />

overall weight reduction.<br />

A reduction of this magnitude is what automotive customers<br />

said was necessary for them to consider alternate materials<br />

to those already proven suitable for commercial use.<br />

PolyOne’s search for a solution to the lightweighting challenge<br />

led to the development of a new natural fiber reinforced<br />

thermoplastic (NFR-TP) that supports lightweighting goals in<br />

the automotive and other industries, while also maintaining<br />

the necessary mechanical performance characteristics.<br />

Develop a novel compounding process<br />

The Company is one of the world’s leading developers of<br />

thermoplastic compounds, with research and development<br />

experts at laboratories around the world. As the process to<br />

develop a lightweight replacement for GFR-PP began, the experts<br />

there recognized that a new type of compounding process showed<br />

promise for the manufacture of strong, stable compounds even<br />

with materials of different polarities. R&D teams at PolyOne had<br />

been working for two years to optimize the process, and believed<br />

this new compounding technology could be key to manufacturing<br />

NFR-TP solutions with excellent mechanical properties. It seemed<br />

a critical part of the solution to the long-recognized challenge of<br />

the ability of a non-polar thermoplastic material to couple with a<br />

polar reinforcing material.<br />

12 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Automotive<br />

This new compounding technology proved to be the first leg<br />

in the triad of developments that led to success.<br />

Find the best fiber for the job<br />

When it comes to reinforcing polypropylene with natural<br />

fiber, many routes, variables, and choices can have a<br />

significant influence on the final solution:<br />

• type of PP (homo- or copolymer)<br />

• melt index<br />

• type of reinforcing fiber<br />

• coupling technology<br />

• manufacturing process<br />

A design of experiment (DOE) helped reduce these input<br />

variables down to three: the type of fiber, coupling technology<br />

for the fiber and the PP, and manufacturing process<br />

(compound extrusion). PolyOne’s R&D experts already<br />

had developed what the researchers felt might be the best<br />

manufacturing process, but they needed to find the right<br />

materials. A PP homopolymer was determined to be the<br />

optimal matrix material with the appropriate melt index.<br />

So the best fiber for the applications targeted needed to<br />

be found, and a coupling technology to enable these fibers<br />

to bond well with the thermoplastic matrix material. Natural<br />

fibers made sense because of their low density; but to serve<br />

the automotive industry, fibers need to be available globally,<br />

with consistent sizing and quality.<br />

Testing of many types of natural fiber led to an engineered<br />

fiber, available globally as a modified product of an established<br />

wood fabrication industry. These fibers are supplied with<br />

consistent length and thickness, facilitating production<br />

of a compound with consistent properties – if the new<br />

compounding technology was able to evenly distribute the<br />

fibers throughout the matrix material, and helped create a<br />

powerful bond between fiber and matrix material.<br />

A powerful bond<br />

The best fibers would be worth little if they could not be<br />

properly mixed into and bonded with the thermoplastic matrix.<br />

PolyOne’s search for solutions to these challenges led them to<br />

a coupling technology that forged the necessary bond, as seen<br />

in Graph 1. Coupling Technology 1 is an advanced technology<br />

while Coupling Technology 2 is a more classical technology.<br />

Coupling Technology 1 was tested on multiple fibers but<br />

ultimately PolyOne settled on the natural engineered fiber<br />

mentioned earlier.<br />

Testing began to determine whether the positive results<br />

seen in lab testing could be maintained at commercial<br />

scale. In addition, it needed to be investigated whether the<br />

new compounding process had an influence on the property<br />

profile at various reinforcing fiber amounts (30 % and 40 %<br />

in weight).<br />

The properties of the material manufactured on industrial<br />

scale machinery are very similar to the original target, and<br />

realize a density reduction versus short glass fiber alternatives<br />

of at least 5 % (Graph 2). The new formulations were named<br />

reSound NF natural fiber reinforced solutions; reSound is<br />

PolyOne’s brand name for formulations that contain 30 % or<br />

more of renewably resourced materials. u<br />

By:<br />

Marc Mézailles<br />

Global Automotive Industry Manager,<br />

PolyOne Corporation<br />

Lyon, France<br />

Photo 1: Lightweight and strong: Tests have proven the mechanical<br />

performance of parts molded from reSound NF natural fiber<br />

reinforced solutions.<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 13


Automotive<br />

Drop-in solution for your existing equipment and<br />

processes<br />

Injection molding of tensile bars and then larger parts<br />

(Photo 1) proved the mechanical performance and easy<br />

processability of reSound NF formulation. Like most natural<br />

fiber reinforced thermoplastics, reSound NF material should<br />

be processed at temperatures below 200 °C in order to<br />

maintain the integrity of the naturally-originating fibers.<br />

Using low temperatures also offers potential energy savings<br />

and short cooling times, providing an efficient yield for<br />

manufacturers.<br />

Further testing revealed that reSound NF material is<br />

compatible with and shows robust property retention when<br />

molded on machinery outfitted with the MuCell ® foaming<br />

technology from Trexel. The retention is as robust as PP‐SGF<br />

for tensile properties, is even more robust for flexural<br />

properties, and clearly more stable for impact properties.<br />

The reSound NF solutions also are compatible with chemical<br />

foaming technologies, and exhibit strong bonding with<br />

selected thermoplastic elastomers, also found in PolyOne’s<br />

solutions portfolio. Separate trials also proved that customers<br />

could select a reSound NF concentrate, rather than a fully<br />

compounded formulation with a predetermined percentage<br />

of fiber loading, if they wanted to adjust final reinforcement<br />

levels vs. application needs.<br />

Finally, tests also were conducted to determine the<br />

recyclability of reSound NF material. Tensile bars were<br />

molded, reground, and molded again with the regrind material<br />

only. This was repeated three times.<br />

These results show a very stable performance towards<br />

regrinding for reSound NF versus PP-SGF. It seems the<br />

limitation in the on-line re-introduction of reground PP-SGF<br />

into the manufacturing process does not apply to reSound<br />

NF material, which offers a potential “no scrap” process for<br />

manufacturers.<br />

Time for a change<br />

Advanced material and manufacturing technologies have<br />

been combined to create reSound NF, a NFR-TP solution<br />

with a low specific gravity but offering excellent mechanical<br />

properties. Manufacturers can select reSound NF natural fiber<br />

reinforced solutions to reduce parts’ weights 5 – 10 % lower<br />

than ones made using comparable glass fiber formulations.<br />

Compared to other natural fiber reinforced solutions,<br />

reSound NF solutions offer mechanical property improvements<br />

of more than 20 % for tensile and flexural properties, 10 °C<br />

to 20 °C higher heat deflection temperature, and more than<br />

50 % in impact strength.<br />

Customers can process reSound NF material on existing<br />

machinery and tooling at low injection molding temperatures,<br />

resulting in short cycle times. These new natural fiber<br />

reinforced polymer formulations enable automotive OEMs and<br />

their suppliers to meet goals for lightweighting, sustainability,<br />

production efficiency and performance.<br />

Customers from non-automotive industries that value<br />

lightweighting and sustainable solutions in technical<br />

applications can benefit from reSound NF formulations too.<br />

www.polyone.com<br />

Carbon/Flax hybrid automotive roof<br />

The CARBIO project has developed a carbon/flax hybrid automotive roof using Composite Evolution’s Biotex Flax material.<br />

The project, which involves Jaguar Land Rover, is developing novel carbon/flax hybrid composites to produce automotive<br />

structures with reduced weight, cost, environmental impact and improved noise, vibration and harshness (NVH).<br />

The adoption of carbon fibre-epoxy composites to reduce vehicle weight is presenting significant challenges to the volume<br />

automotive industry. Compared to carbon, flax fibres are renewable, lower in cost, CO 2<br />

neutral and have excellent vibration<br />

damping properties. In addition, bio-epoxy resins based on cashew nut shell liquid (CNSL) can offer enhanced toughness,<br />

damping and sustainability over synthetic epoxies.<br />

By creating a hybrid structure using flax-bioepoxy to replace some of the carbon, enhanced properties such as lower weight,<br />

cost, NVH and environmental impact can be gained.<br />

A 50/50 carbon/flax hybrid biocomposite, made from Biotex Flax supplied by Composites Evolution and prepregged by SHD<br />

Composite Materials, has significantly contributed to achieving the objectives of the project. With equal bending stiffness to<br />

carbon fibre, the hybrid biocomposite has:<br />

• 15 % lower cost<br />

• 7 % lower weight<br />

• 58 % higher vibration damping<br />

The prototype roof, designed by Delta Motorsport and manufactured<br />

by KS Composites, was displayed at the Advanced Engineering show, last<br />

November in Birmingham, UK.<br />

The CARBIO project is part-funded by Innovate UK. The partners are<br />

Composites Evolution, SHD Composite Materials, KS Composites, Delta<br />

Motorsport, Jaguar Land Rover and Cranfield University. MT<br />

http://carbioproject.com<br />

14 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Automotive<br />

Smart bioplastics for<br />

automotive applications<br />

By:<br />

Francesca Brunori<br />

Advanced Development Engine Systems<br />

Röchling Automotive<br />

Laives, Italy<br />

Röchling Automotive reports promising results on the development<br />

of automotive parts made of Plantura PLA<br />

based biopolymers.<br />

In collaboration with Plantura Italia Srl (Italy) and Corbion<br />

Purac (The Netherlands), Röchling Automotive is working<br />

towards greener products offering similar or enhanced<br />

technical functionality.<br />

Plantura has a CO 2<br />

equivalent emission of approximately<br />

0.5 tonnes for each ton of produced raw material. This is<br />

around 70 % lower than PP, and close to 90 % less than PA6.<br />

There are currently four standard grades available that are<br />

suitable for low to medium demanding automotive underthe-hood<br />

applications and – using the glass fiber filled<br />

grade – in underbody applications. The talc filled standard<br />

grade, as well as natural fiber filled grades, are suitable for<br />

automotive interior applications. As these different standard<br />

grades, which boast a biocontent of up to 95 %, can be finetuned<br />

to meet specific customer needs and final application<br />

requirements, the material has already been used in series<br />

production in sectors other than the automotive market. The<br />

compounds can be processed and recycled with conventional<br />

plastics processing and recycling technologies.<br />

In comparison to standard PLA, Plantura showed significant<br />

improvements in thermal stability and chemical resistance.<br />

Long term thermal stability was tested according to thermal<br />

cycle tests performed from -40 °C to 140 °C according to an<br />

OEM’s specification. When tested at temperatures as low as<br />

-30 °C, the material demonstrated an outstanding impact<br />

resistance for shockproof parts, showing that Plantura 30 %<br />

GF can offer values of up to 50 % higher Charpy impact<br />

strength compared to a PA6 GF+M30. The materials also<br />

exhibit excellent hydrolysis resistance.<br />

Prototype filter boxes (cf. fig. 1) as well as interior parts<br />

were tested according to the OEM’s complete specifications,<br />

with very promising results<br />

The use of Plantura for the air flaps (fig. 3) of an Active Grille<br />

Shutter (fig. 2) was investigated and the initial results bode<br />

well for the future. The injection molded Plantura component<br />

has a higher stiffness compared to the component produced<br />

with the standard material (PA6 GF30). Because of this,<br />

deflection is lower during use, which can be used to reduce<br />

air leakage. Moreover, thanks to the lower shrinkage of the<br />

material, it is also possible to reduce the deformation of the<br />

final component. Another big advantage to using Plantura for<br />

this application is that the dimensional stability will increase<br />

over the lifetime of the component, due to the fact that no<br />

humidity is absorbed. The scratch resistance behavior of PLA,<br />

an extremely important aspect when it comes to aesthetic<br />

components in general, and in this case for aesthetic Active<br />

Grille Shutters In particular, is well known and taken into<br />

consideration in the Plantura formulations.<br />

The continuous development of the material has led to<br />

higher, and increasingly interesting cost efficiency. With its<br />

significant contribution to an improved CO 2<br />

balance, Plantura<br />

could become an important concept in the automotive world.<br />

www.roechling.com<br />

Fig. 1: Filter box made of Plantura 30 % Wood Fibers<br />

Fig. 2: Assembled Active Grille Shutter<br />

Fig. 3: Air flaps of Active Grille Shutter made of<br />

Plantura 30 % Glass Fiber reinforced<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 15


Automotive<br />

Biocomposites in the<br />

automotive industry<br />

By:<br />

Michael Carus and Asta Partanen<br />

Nova-Institute<br />

Hürth, Germany<br />

“Nature 50 – long fibre” for injection moulding with a cold-press<br />

method. These long fibre pellets with more than 50 % hemp<br />

fibre content, polypropylene and additives are produced with<br />

pellet technology. They can be used for injection moulded parts<br />

with standard machines and standard tools as a substitution<br />

of PC/ABS with 20 % glass fibre content. Their fibre structure<br />

gives them a unique look and makes them suitable also for<br />

use outside the automotive industry. (courtesy HIB TRIM PART<br />

SOLUTIONS)<br />

The second biggest application sector for biocomposites<br />

is the automotive interior sector. The main application is<br />

the construction sector and third is consumer goods. At<br />

the world’s largest conference on Wood-Plastic Composites<br />

(WPC) and Natural Fibre Composites (NFC) with more than<br />

220 participants in December 2<strong>01</strong>5 in Cologne, Germany (see<br />

p. 8), one extended session informed about the latest status of<br />

biocomposites in the automotive industry.<br />

Biocomposites contain wood or natural fibres or/and<br />

biobased polymers. So far, almost all biocomposites contain<br />

wood or natural fibres, but only a few using biobased<br />

polymers. Experts speak about Wood-Plastic Composites<br />

(WPC) and Natural Fibre Composites (NFC). Especially in<br />

the interior applications in middle and high class cars, NFC<br />

are well established and a growing market. The dominating<br />

technology is compression moulding, with a natural fibre nonwoven<br />

fleece. One of the leading experts is Werner Klusmeier<br />

(Yanfeng Europe Automotive Interior Systems (formerly JCI))<br />

and speaker at the conference summarized: “There is a<br />

diversity of reasons for the use of natural fibres: Advantages<br />

in the ecological footprint, affordable production costs as well<br />

as good acoustic and mechanical properties. Furthermore,<br />

natural fibre reinforced plastics convince with their low<br />

weight. They enable savings in mass of up to 30 % – which is<br />

a decisive plus in times of lightweight construction. Natural<br />

fibre composites have been and are still further developed<br />

in terms of lightweight construction and strength. They have<br />

become integral parts of the automotive industry.”<br />

The combination of compression moulding and simultaneous<br />

back injection moulding can bring further weight reduction,<br />

as Tayfun Buzkan and Motoki Maekawa from Toyota Boshoku<br />

Europe demonstrated in their presentation. The material<br />

performance completely meets automotive requirements and<br />

reduces production time.<br />

Developments in the use of biobased polymers in the<br />

automotive industry were shown by Global Marketing Director<br />

bioplastics at Corbion Purac, François de Bie, together<br />

Biocomposites with Natural Fibres, Wood Fibres and Recycled Cotton in the European Automotive Production in 2<strong>01</strong>2<br />

Biocomposites<br />

Natural Fibre<br />

Composites<br />

Wood-Plastic<br />

Composites<br />

Recycled Cotton<br />

Reinforced Plastics<br />

Volume fibres in<br />

tonnes in 2<strong>01</strong>2<br />

Volume<br />

biocomposites in<br />

tonnes in 2<strong>01</strong>2<br />

30,000 60,000<br />

30,000 60,000<br />

Processing technologies<br />

95 % compression moulding,<br />

5 % injection moulding & others<br />

45 % extrusion & thermoforming,<br />

50 % compression moulding & others<br />

5 % injection moulding<br />

Matrice<br />

55 % thermoplastics,<br />

45 % thermosets<br />

Extrusion:<br />

100 % thermoplastics,<br />

compression moulding:<br />

>90 % thermoset<br />

20,000 30,000 mainly compression moulding >90 % thermoset<br />

Total 80,000 150,000<br />

16 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Automotive<br />

with Francesca Brunori from Röchling Automotive. They<br />

presented their latest cooperation results on high heat PLA<br />

100% biobased natural fibre filled compounds with injection<br />

and compression moulding. The material is ready to use and<br />

Röchling is already in contact with different OEMs (see also<br />

page 15).<br />

Experts expect a growth in injection moulding for WPC and<br />

NFC: So far, also mainly small producers and traders were<br />

offering WPC and NFC granulates with a limited technical<br />

support and often missing data for simulations. But also<br />

this is changing since big global players are offering their<br />

new developed materials: “Sustainable Light weighting<br />

Thermoplastic Solutions for Automotives” (see also page<br />

12) was presented by Marc Mézailles from PolyOne Global<br />

Engineered Materials. This innovation from PolyOne breaks<br />

the conventional material property balance and opens<br />

the industrial use of natural fibres reinforced solutions in<br />

many demanding end applications and markets, including<br />

automotive, with a 5 to 10% light weighting potential vs.<br />

standard solutions. The material has a typical 30% fibre<br />

content, the fibre is an engineered industrial wood fibre, and<br />

a new coupling technology as well as a specific compounding<br />

process is used. PolyOne a first official OEM approval on a<br />

critical semi-structural application, and continues to be<br />

evaluated by several key OEMs and their Tier One suppliers.<br />

Today, as the last survey from nova-Institute showed,<br />

about 4 kg natural and wood fibres per vehicle in average<br />

are used European automotive production; but vehicles with<br />

considerably larger amounts of 20 kg natural and wood fibres<br />

have been successfully produced in series for years and could<br />

credit these amounts in the future.<br />

Most experts expect a continuously growth in the use of<br />

WPC and especially NFC in the automotive industry because<br />

of the high light weight potential of these materials, the<br />

continuously improvement of technologies and properties<br />

and new professional players. The combination with biobased<br />

polymers to realize fully biobased biocomposites is just<br />

starting and could become an additional market for biobased<br />

polymers such as PLA or PBS.<br />

www.nova-institute.com<br />

This table is showing the main reason, why Natural Fibre<br />

Composites (NFC) are such an exciting material for the automotive<br />

industry<br />

NF compression moulded – superior lightweight properties<br />

Automotive interior parts Area weight in g/m 2<br />

WPC – extruded and moulded 2,500<br />

Injection moulded pure plastc or glass fibre<br />

reinforced plastics<br />

>2,200<br />

Compression moulded PP-NF 1,800<br />

Compression moulded PP-NF with bonding<br />

agent MAPP<br />

1,500<br />

Compression moulded thermosets-NF 1,400 – 1,500<br />

Compression moulded thermosets-NF<br />

In development, production expected after<br />

2<strong>01</strong>8<br />

800 – 1,000<br />

All figures and tables are teken from the study<br />

“Wood-Plastic Composites (WPC) and Natural<br />

Fibre Composites (NFC): European and Global<br />

Markets 2<strong>01</strong>2 and Future Trends in Automotive and<br />

Construction“. The full study can be downloaded at<br />

http://bio-based.eu/markets<br />

All presentations of the conference are now available at<br />

http://bio-based.eu/proceedings<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 17


Materials<br />

The gluten solution<br />

New TPVs derived from wheat gluten<br />

By Karen Laird<br />

While gluten has got a lot of bad press over the past<br />

few years, there is still good news to report. Gluten,<br />

it turns out, can actually serve as the basis for a new<br />

type of biobased plastic material, say scientists at the KU<br />

Leuven in Belgium. These researchers are working on the development<br />

of a new type of thermoplastic vulcanisate – based<br />

on gluten.<br />

But what is gluten? Very simply put, is the seed storage<br />

protein in mature cereal seeds. More specifically, it is a protein<br />

composite, meaning it is a substance made up of several<br />

different proteins, in this case gliadin and a glutenin. The<br />

cross-linking of gliadin molecules and glutenin molecules<br />

creates the primary properties associated with gluten.<br />

According to Lien Telen, a postdoctoral researcher at KU<br />

Leuven who has spent the past five years exploring the the<br />

use of wheat gluten to produce thermoplastic elastomers,<br />

there are a number of aspects that make gluten an attractive<br />

starting point for novel biobased materials. In the first place,<br />

there is a lot of it: as a co-product of industrial gluten-starch<br />

separation or bioethanol production, gluten is available in<br />

Europe in quantities of up to 1 million tonnes on an annual<br />

basis. Only part of this gluten is used as a high-value bakery<br />

ingredient, while the excess is mostly used in animal feed.<br />

Secondly, unlike most other proteinaceous resources,<br />

gluten contains high molar mass constituents and unique<br />

network forming properties, which means it can readily be<br />

converted into a variety of biobased materials.<br />

The development that has received the most attention of the<br />

gluten team at KU Leuven, said Telen, has been the glutenbased<br />

TPVs (TPV stands for thermoplastic vulcanizates).<br />

These new materials are colorable and can be processed on<br />

conventional processing equipment. Unlike the olefin-based<br />

rubbers in conventional TPVs, wheat gluten intrinsically<br />

crosslinks under the influence of heat, eliminating the need<br />

for an additional chemical crosslinker. Gluten-based TPVs<br />

combine the typical properties and functional performance<br />

of rubbers with the melt processability of thermoplastic<br />

polymers, resulting in recyclable materials. Telen explains:<br />

“The gluten TPV consists of (non-recyclable) crosslinked<br />

gluten particles within a thermoplastic matrix. The main<br />

advantage of these TPVs is that they have elastomeric<br />

characteristics at room temperature combined with the<br />

melt processability of thermoplastic materials. The rubber<br />

particles are very small (a few µm) and will flow in the melt<br />

of the thermoplastic matrix making the entire material<br />

recyclable using standard thermoplastic polymer processing<br />

equipment such as extrusion and injection molding.”<br />

The gluten team is also working on improving the<br />

properties of the new TPVs, which, said Telen, “fall short on<br />

water-resistance, oil and chemical resistance and operational<br />

temperature range”. Yet what also sets gluten-based TPVs<br />

apart is the possibility of combining elastomeric behavior and<br />

biodegradability in a single material, a combination not seen in<br />

conventional oil-based TPVs. Depending on the thermoplastic<br />

component, the gluten TPV’s can be designed to be fully<br />

biodegradable. TPVs with a polyethylene or polyamide matrix<br />

are not completely biodegradable, as the matrix remains<br />

intact, making them unsuitable for composting.<br />

“However, completely biodegradable and (home)<br />

compostable TPVs have also been developed using a<br />

biodegradable and (home) compostable matrix,” said Telen.<br />

Applications for these materials could include indoor soft<br />

touch materials, or functional biodegradation applications in<br />

the agricultural and horticultural sectors.<br />

Next to gluten-based TPVs, the researchers at KU Leuven<br />

are looking at other materials as well. “In the absence of<br />

a plasticizer, the heat induced crosslinking results in a<br />

glassy, rigid material with material properties comparable<br />

to Polystyrene (PS)”, said Telen. “Gluten composites: rigid<br />

gluten bioplastic reinforced with flax fibers are another focus.<br />

Research on these materials is ongoing and very promising.”<br />

http://chem.kuleuven.be<br />

60 – 80 % biobased non biodegradable 100 % biobased biodegradable<br />

anaerobic<br />

TPV 1 2 3 4<br />

Tensile modulus (MPa) 333 197 265 494<br />

Tensile elongation (%) 247 240 120 18<br />

Tensile strength (MPa) 16 12 9 12<br />

Shore D hardness 42 48 43 51<br />

Melting temperature (°C) 129 118 125 140<br />

Crystallization temperature (°C) 113 60 50 85<br />

18 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Market study on<br />

Bio-based Building Blocks and Polymers in the World<br />

Capacities, Production and Applications: Status Quo and Trends towards 2020<br />

Bio-based polymers: Will the positive growth trend continue?<br />

Bio-based polymers: Worldwide production<br />

capacity will triple from 5.7 million tonnes in<br />

2<strong>01</strong>4 to nearly 17 million tonnes in 2020. The<br />

data show a 10% growth rate from 2<strong>01</strong>2 to 2<strong>01</strong>3<br />

and even 11% from 2<strong>01</strong>3 to 2<strong>01</strong>4. However,<br />

growth rate is expected to decrease in 2<strong>01</strong>5.<br />

Consequence of the low oil price?<br />

million t/a<br />

Bio-based polymers: Evolution of worldwide production capacities<br />

from 2<strong>01</strong>1 to 2020<br />

20<br />

actual data<br />

forecast<br />

The new third edition of the well-known 500<br />

page-market study and trend reports on<br />

“Bio-based Building Blocks and Polymers<br />

in the World – Capacities, Production and<br />

Applications: Status Quo and Trends Towards<br />

2020” is available by now. It includes consistent<br />

data from the year 2<strong>01</strong>2 to the latest data of 2<strong>01</strong>4<br />

and the recently published data from European<br />

Bioplastics, the association representing the<br />

interests of Europe’s bioplastics industry.<br />

Bio-based drop-in PET and the new polymer<br />

PHA show the fastest rates of market growth.<br />

Europe looses considerable shares in total<br />

production to Asia. The bio-based polymer<br />

turnover was about € 11 billion worldwide<br />

in 2<strong>01</strong>4 compared to € 10 billion in 2<strong>01</strong>3.<br />

http://bio-based.eu/markets<br />

©<br />

15<br />

10<br />

5<br />

2<strong>01</strong>1<br />

-Institut.eu | 2<strong>01</strong>5<br />

2% of total<br />

polymer capacity,<br />

€11 billion turnover<br />

2<strong>01</strong>2<br />

Epoxies<br />

PE<br />

2<strong>01</strong>3<br />

PUR<br />

PBS<br />

2<strong>01</strong>4<br />

CA<br />

PBAT<br />

2<strong>01</strong>5<br />

PET<br />

PA<br />

2<strong>01</strong>6<br />

PTT<br />

PHA<br />

2<strong>01</strong>7<br />

PEF<br />

2<strong>01</strong>8<br />

Starch<br />

Blends<br />

EPDM<br />

PLA<br />

2<strong>01</strong>9<br />

2020<br />

Full study available at www.bio-based.eu/markets<br />

The nova-Institute carried out this study in<br />

collaboration with renowned international<br />

experts from the field of bio-based building<br />

blocks and polymers. The study investigates<br />

every kind of bio-based polymer and, for the<br />

second time, several major building blocks<br />

produced around the world.<br />

What makes this report unique?<br />

■ The 500 page-market study contains<br />

over 200 tables and figures, 96 company<br />

profiles and 11 exclusive trend reports<br />

written by international experts.<br />

■ These market data on bio-based building<br />

blocks and polymers are the main source<br />

of the European Bioplastics market data.<br />

■ In addition to market data, the report offers a<br />

complete and in-depth overview of the biobased<br />

economy, from policy to standards<br />

& norms, from brand strategies to<br />

environmental assessment and many more.<br />

■ A comprehensive short version<br />

(24 pages) is available for free at<br />

http://bio-based.eu/markets<br />

To whom is the report addressed?<br />

■ The whole polymer value chain:<br />

agro-industry, feedstock suppliers,<br />

chemical industry (petro-based and<br />

bio-based), global consumer<br />

industries and brands owners<br />

■ Investors<br />

■ Associations and decision makers<br />

Content of the full report<br />

This 500 page-report presents the findings of<br />

nova-Institute’s market study, which is made up<br />

of three parts: “market data”, “trend reports”<br />

and “company profiles” and contains over 200<br />

tables and figures.<br />

The “market data” section presents market<br />

data about total production capacities and the<br />

main application fields for selected bio-based<br />

polymers worldwide (status quo in 2<strong>01</strong>1, 2<strong>01</strong>3<br />

and 2<strong>01</strong>4, trends and investments towards<br />

2020). This part not only covers bio-based<br />

polymers, but also investigates the current biobased<br />

building block platforms.<br />

The “trend reports” section contains a total of<br />

eleven independent articles by leading experts<br />

Order the full report<br />

The full report can be ordered for 3,000 €<br />

plus VAT and the short version of the report<br />

can be downloaded for free at:<br />

www.bio-based.eu/markets<br />

Contact<br />

Dipl.-Ing. Florence Aeschelmann<br />

+49 (0) 22 33 / 48 14-48<br />

florence.aeschelmann@nova-institut.de<br />

in the field of bio-based polymers. These trend<br />

reports cover in detail every important trend<br />

in the worldwide bio-based building block and<br />

polymer market.<br />

The final “company profiles” section includes<br />

96 company profiles with specific data<br />

including locations, bio-based building blocks<br />

and polymers, feedstocks and production<br />

capacities (actual data for 2<strong>01</strong>1, 2<strong>01</strong>3 and<br />

2<strong>01</strong>4 and forecasts for 2020). The profiles also<br />

encompass basic information on the companies<br />

(joint ventures, partnerships, technology and<br />

bio-based products). A company index by biobased<br />

building blocks and polymers, with list of<br />

acronyms, follows.


Materials<br />

Making Levulinic Acid happen<br />

A new (?) building block not only for bioplastics<br />

No. Levulinic acid (LA) is not exactly a new building block<br />

or better a new platform chemical. It has been known<br />

of since 1840. “Everybody knows the benefits of levulinic<br />

acid, but few are using it yet – because it has been too<br />

expensive so far”, Maxim Katinov, CEO of Caserta, Italy based<br />

GFBiochemicals told bioplastics MAGAZINE during a plant visit<br />

in early December.<br />

GFBiochemicals is the first and only company to produce<br />

levulinic acid at commercial scale directly from biomass. The<br />

10,000 tonnes/annum commercial-scale production plant in<br />

Caserta started production in July 2<strong>01</strong>5. The plant uses new<br />

and modified conversion, recovery and purification technology<br />

owned by GFBiochemicals. The company also has offices in<br />

Milan, Italy and Geleen, the Netherlands. In-house application<br />

and R&D is supported by a highly skilled and prolific<br />

management team with decades of experience in innovation,<br />

production and business development of biobased chemicals.<br />

“We have the best people and they are passionate about what<br />

they do”, as Maxim proudly told us. “Many of them left leading<br />

world renowned chemical companies in the Netherlands to<br />

join a startup“, he added.<br />

Levulinic acid is a biobased platform chemical with<br />

applications in the chemical and biofuel sectors. “Levulinic<br />

acid is an essential building block for a green future,” as<br />

Marcel van Berkel, CCO of GFBiochemicals pointed out. In<br />

2004, the US Department of Energy (DoE) identified LA as one<br />

of the 12 most important platform chemicals [1].<br />

Levulinic acid for affordable prices<br />

Fundamentally lower price ranges are now possible for<br />

derivatives using GFBiochemicals technology. “We don’t need<br />

outputs of 150,000 tonnes to be successful,” said Maxim<br />

Katinov. “We can do it economically with three, five or ten<br />

thousand tonnes. And so we can produce and deliver levulinic<br />

acid for prices the market can afford”. The current price level<br />

is at about USD 4 – 5 per kg, but this company is targeting<br />

substantially lower prices, “in the range of one Dollar, when<br />

we reach maturity and produce at large scale,” Marcel van<br />

Berkel commented.<br />

Possible bioplastic applications<br />

Among the possible applications for LA we find quite<br />

a number of biopolymer-products or pre-products for<br />

bioplastics such as Me-BDO (Methyl butanediol for biobased<br />

polyesters or as building block for polyurethanes), Gamma<br />

valerolactone, an amino acid to make Nylons or specialty<br />

acrylates, DPA (Diphenolic acid to replace BPA, Bisphenol A,<br />

in Epoxies or Polycarbonate. BPA is cheaper but toxic),<br />

Co-nutrients during PHB production with metabolically<br />

engineered strains, and many more.<br />

Markets for levulinic acid and its derivatives include<br />

furthermore green solvents, coatings and resins, plasticizers,<br />

but also flavours and fragrances, personal care and<br />

pharmaceutical products, agrochemicals, fuel additives and<br />

biofuels.<br />

LA from renewable resources<br />

Traditionally levulinic acid is produced from petroleum via<br />

butane/benzene. “The first biobased routes went through<br />

furfural and furfuryl alcohole”, said Aris de Rijke, Director<br />

Technology & Engineering. “We however, go a direct route<br />

from biomass in a continuous process. Today we are using<br />

industrial corn starch, but in the long run we aim at using<br />

wood waste or other cellulosic waste streams such as straw<br />

or bagasse”.<br />

And a share of the energy used to run the process comes<br />

from char, a by-product of the LA-production from biomass.<br />

All in all, levulinic acid is a product of which we can expect<br />

interesting developments. Or maybe even “the transition to a<br />

new economy”, as Maxim Kativov said. MT<br />

[1] www.nrel.gov/docs/fy04osti/35523.pdf<br />

www.gfbiochemicals.com<br />

Pre-treatment Reactor Flash<br />

Energy recovery<br />

Cellulosic Biomass<br />

Steam<br />

Proprietary technology<br />

Solid/liquid<br />

separatrion<br />

Product<br />

recovery &<br />

concentration<br />

Final<br />

purification<br />

Biochar<br />

Steam<br />

O<br />

CH 3<br />

HO<br />

O<br />

Levulinic acid<br />

20 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


MARCH 30 – APRIL 1, 2<strong>01</strong>6<br />

Orlando World Center Marriott<br />

A Collaborative Biopolymers Forum<br />

for the Global Ingeo Community<br />

@NatureWorks #ITR2<strong>01</strong>6 www.innovationtakesroot.com


Material news<br />

New amorphous PHA<br />

grades as performance<br />

additives for PVC and PLA<br />

Metabolix (Cambridge, Massachusetts, USA) is launching its<br />

new line of amorphous polyhydroxyalkanoate (PHA) grades to be<br />

used as performance additives for PVC and PLA. Production of the<br />

new materials is underway at a U.S. pilot plant and will ramp up to<br />

270 tonnes (600,000 pounds) annual nameplate capacity during 2<strong>01</strong>6.<br />

“The commercial launch of these new grades of amorphous PHA<br />

represents an important development for Metabolix as we advance<br />

our business strategy focused on specialty biopolymers,” said Johan<br />

van Walsem, Metabolix’s chief operating officer. “This expanded pilot<br />

capacity is strategic for us to support existing customers and opens<br />

new market development opportunities in our target application<br />

spaces.”<br />

Amorphous PHA (a-PHA) is a softer and more rubbery (low<br />

glass transition temperature or T g) version of PHA that offers a<br />

fundamentally different performance profile from crystalline forms<br />

of PHA. Metabolix’s a-PHA is produced by fermentation and extracted<br />

using a patented solvent recovery process. The production process has<br />

been reviewed by EPA and recently cleared the Premanufacture Notice<br />

(PMN) requirement for new materials placed into commerce. Several<br />

certifications are pending on a-PHA as a biobased material and for the<br />

full range of biodegradation scenarios enabled when a-PHA is used<br />

alone or with other complementary materials. Metabolix plans to seek<br />

FDA clearance for a-PHA in food contact applications, which would<br />

further expand the range of PHA compositions available for use in food<br />

contact materials. Metabolix previously received FDA clearance for use<br />

of its semi-crystalline PHA grades in food contact applications.<br />

At low loading levels, a-PHA can serve as a process aid and<br />

performance modifier for PVC. It increases productivity during<br />

processing and enhances mechanical performance, with the potential<br />

to also deliver cost savings in PVC material systems. In highly filled<br />

composite systems, the use of a-PHA enables increased use of wood<br />

pulp, mineral fillers and PVC recyclate to replace virgin PVC and<br />

achieve improved mechanical properties. Metabolix is working closely<br />

with customers on a wide range of applications utilizing a-PHA as a<br />

modifier for PVC. These applications include a floor backing material<br />

that utilizes PVC recyclate, a highly-filled vinyl flooring system, wire and<br />

cable insulation, roofing membranes, PVC/wood polymer composites<br />

and other construction and building materials (see p. 23).<br />

Amorphous PHA also complements the bio-content and<br />

compostability profile of the biopolymer PLA while delivering significant<br />

improvements in mechanical properties such as increased toughness,<br />

strength and ductility. Based on these product advantages, Metabolix<br />

is working with customers interested in achieving better performance<br />

with PLA biopolymers. Many of these customers are focused on<br />

developing a-PHA-modified PLA materials for sustainable, bio-based,<br />

and compostable packaging solutions. In addition to conducting<br />

numerous trials for transparent packaging films, Metabolix is working<br />

with customers interested in a-PHA-modified PLA for thermoformed<br />

transparent clamshells used in food service and consumer packaging<br />

as well as a-PHA-modified PLA for non-wovens used in personal care<br />

applications. MT<br />

www.metabolix.com<br />

Biobased and<br />

biodegradable<br />

thermoelastomers<br />

TerraVerdae BioWorks, Edmonton, Alberta,<br />

Canada, an industrial biotechnology company<br />

developing advanced bioplastics and biomaterials<br />

from environmentally sustainable, single-carbon<br />

(C1) feedstocks, has announced that<br />

it has entered into a strategic partnership agreement<br />

with PolyFerm, Kingston, Ontario, Canada.<br />

PolyFerm is a biopolymer company that<br />

is focused on developing renewable and<br />

biodegradable alternatives to petrochemicalbased<br />

elastomers. The partnership expands<br />

TerraVerdae’s product and technology portfolio<br />

into the high growth market of biodegradable<br />

thermoelastomers.<br />

PolyFerm has developed the only line of<br />

biodegradable thermoelastomers in the<br />

industry made entirely from renewable<br />

feedstocks. PolyFerm’s product line, marketed<br />

as VersaMer, is a medium-chain-length PHA<br />

material with enhanced elastomeric properties<br />

that can be engineered to multiple applications.<br />

This addresses a large unmet need within<br />

the biopolymer industry, with applications for<br />

adhesives and sealants, plastic additives, inks and<br />

toners, paints and coatings, and medical devices.<br />

“This strategic partnership allows us to offer<br />

our customers the most comprehensive product<br />

portfolio of high-value biodegradable polymers and<br />

opens up significant opportunities in new, highgrowth<br />

markets,” said William Bardosh, CEO and<br />

founder of TerraVerdae BioWorks. “<br />

“With TerraVerdae, we have found an ideal<br />

partner to help us penetrate new markets with<br />

our high-performance polymer and elastomer<br />

products,” said Bruce Ramsay, Founder and CTO of<br />

PolyFerm Canada. “TerraVerdae’s demonstrated<br />

ability to scale up complex bioprocesses to meet<br />

the performance specifications demanded by<br />

industry is a great fit with our technology.”<br />

Elastomeric PHAs represent one of the<br />

most versatile classes of engineered materials<br />

for a number of commercial uses. These<br />

biodegradable materials combine the look, feel<br />

and elasticity of conventional thermoset rubber<br />

with improved processing efficiencies and are<br />

capable of withstanding large deformations<br />

while regaining their original shape. They also<br />

exhibit unique performance characteristics<br />

such as toughness, resilience, stretchability, and<br />

stiffness. KL<br />

www.polyfermcanada.com | www.terraverdae.com<br />

22 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


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Plasticizers<br />

Processing Aids, Activators<br />

Silanes, Desiccants<br />

Antitack Agents<br />

Heat Transfer Fluids<br />

Material news<br />

Volume 7, September 2<strong>01</strong>5<br />

PHA in PVC-WPC applications<br />

In a recent blog posted by Metabolix Vice President of Marketing and Corporate Communications, Lynne Brum, the use<br />

of Metabolix I6003 PHAs in WPC was touted as a “cost effective solution which imparts superior mechanical properties and<br />

process benefits in wood filled PVC building materials.”<br />

Wood fiber polymer composites (WPC), wrote Brum, are materials made by combining wood particles or other fibrous materials with<br />

polymer resins and additives to improve performance. WPCs, which require little maintenance have become popular replacements<br />

for solid wood. Common applications for these composites are in products such as decking, fences, railings and outdoor landscaping<br />

features. PVC is one of the key base polymers used in wood polymer composites for decking and railing systems.<br />

Miscibility between PVC and plasticizer is essential for good performance. PHA and PVC materials are highly miscible and<br />

moreover, have similar processing windows. Because of their miscibility with PVC, the PHA additives will not migrate out of the<br />

PVC and are easy to handle and process under the same conditions as PVC.<br />

Exploring the use of Metabolix I6003 PHAs in WPC, it was found that I6003, a<br />

multifunctional process aid, acted as an efficient fusion promoter, improved wood filler<br />

incorporation and dispersion, and significantly reduced torque in the extrude.<br />

Metabolix has worked with customers to develop new PVC-WPC formulations<br />

for decking and railing systems. Incorporating Metabolix PHA material into these<br />

formulations at a low loading level, made it possible to increase the proportion of wood<br />

flour used and at the same time to decrease the amount of PVC needed. The data<br />

generated by Metabolix showed that during processing, the addition of PHA, even at<br />

a low level, reduced torque and improved processing of the wood polymer composite<br />

material. For railing applications, the end-product also exhibited significantly improved<br />

mechanical properties and surface finish.<br />

This work demonstrates that PHA materials can offer significant performance benefits<br />

– and consequently costs advantages, as well – in PVC wood polymer composite systems.<br />

Brum said the company is looking forward to working with PVC wood polymer composite<br />

manufacturers to develop new solutions for decking and railing systems. KL<br />

www.metabolix.com | http://bit.ly/1Rsqp4w<br />

SEEING POLYMERS<br />

WITH DIFFERENT EYES...<br />

Weltautomarkt 2<strong>01</strong>6<br />

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Magazine for the Polymer Industry<br />

Sulphenamides and network structure<br />

Ultra-clear silicone<br />

Optimising tear resistance<br />

Compound development<br />

sensorial material selection<br />

low output applications<br />

tpu in cardiac device leads<br />

Thermoplastic<br />

Elastomers<br />

magazine<br />

international<br />

POLYURETHANES MAGAZINE INTERNATIONAL<br />

Interview with J. MacCleary, Covestro<br />

CPI Polyurethanes Technical Conference review<br />

Spray polyurethane foam<br />

Reactive catalysts<br />

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bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 23


Materials<br />

Breakthrough<br />

platform technology for<br />

new building block<br />

In mid-January, science and agricultural leaders DuPont<br />

Industrial Biosciences, Wilmington Delaware, USA and<br />

Archer Daniels Midland Company (ADM), Chicago, Illinois,<br />

USA announced a new breakthrough process with the<br />

potential to expand the materials landscape in the 21 st<br />

century with exciting and truly novel, high-performance<br />

renewable materials. The technology has applications in<br />

packaging, textiles, engineering plastics and many other<br />

industries.<br />

The companies have developed a method for producing<br />

furan dicarboxylic methyl ester (FDME) from fructose.<br />

FDME is a high-purity derivative of furandicarboxylic acid<br />

(FDCA), one of the 12 building blocks identified by the<br />

U.S. Department<br />

of Energy that<br />

can be converted<br />

into a number of<br />

high-value, biobased<br />

chemicals<br />

or materials that<br />

can deliver high<br />

performance in<br />

a number of applications.<br />

It<br />

has long been<br />

sought-after and<br />

researched, but<br />

has not yet been<br />

available at commercial<br />

scale and<br />

at reasonable<br />

cost. The new<br />

FDME technology<br />

is a more efficient<br />

and simple process<br />

than traditional conversion approaches and results<br />

in higher yields, lower energy usage and lower capital expenditures.<br />

generic bottle picture (no PTF)<br />

This partnership brings together ADM’s world-leading<br />

expertise in fructose production, and carbohydrate<br />

chemistry with DuPont’s biotechnology, chemistry,<br />

materials and applications expertise, all backed by a<br />

strong joint intellectual-property portfolio.<br />

“This molecule is a game-changing platform technology.<br />

It will enable cost-efficient production of a variety of 100 %<br />

renewable, high-performance chemicals and polymers<br />

with applications across a broad range of industries,” said<br />

Simon Herriott, global business director for biomaterials<br />

at DuPont. “ADM is an agribusiness powerhouse with<br />

strong technology development capabilities. They are the<br />

ideal partner with which to develop this new, renewable<br />

supply chain for FDME.”<br />

One of the first polymers under development utilizing<br />

FDME is polytrimethylene furandicarboxylate (PTF), a novel<br />

polyester also made from DuPont’s proprietary plant based<br />

Bio-PDO (1,3-propanediol). PTF is a 100 % renewable<br />

and recyclable polymer that, when used to make bottles<br />

and other beverage packages, substantially improves<br />

gas-barrier properties compared to other polyesters.<br />

This makes PTF<br />

a great choice<br />

for customers<br />

in the beverage<br />

packaging<br />

industry looking<br />

to improve the<br />

shelf life of their<br />

products.<br />

“We are excited<br />

about the potential<br />

FDME has to<br />

help our customers<br />

reach new<br />

markets and develop<br />

better-performing<br />

products,<br />

all made from<br />

sustainable, biobased<br />

starting<br />

materials,” said<br />

Kevin Moore, president, renewable chemicals at ADM.<br />

“With their strong leadership in the biomaterials industry,<br />

DuPont is a great partner that can help us bring this product<br />

to market for our customers.”<br />

ADM and DuPont are taking the initial step in the<br />

process of bringing FDME to market by moving forward<br />

on the scale-up phase of the project. The two companies<br />

are planning to build an integrated 60 tonnes/year<br />

demonstration plant in Decatur, Illinois, USA, which<br />

will provide potential customers with sufficient product<br />

quantities for testing and research. MT<br />

www.dupont.com | www.adm.com<br />

24 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Drive Innovation<br />

Become a Member<br />

Join university researchers and industry members<br />

to push the boundaries of renewable resources<br />

and establish new processes and products.<br />

www.cb2.iastate.edu<br />

See us at K 2<strong>01</strong>6<br />

October 19-26, 2<strong>01</strong>6<br />

Düsseldorf, Germany<br />

Hall 5, US Pavilion


Opinion<br />

Bioplastics industry struggling<br />

to meet expected demand<br />

Avantium and Mitsui announced in December their<br />

plan to bring 100 % bio-based PEF (Polyethylene<br />

Furanoate) packaging to the Tokyo Olympics in<br />

2020. This press release captures the importance of both<br />

partnerships and professional marketing in today’s bioplastic<br />

business.<br />

Today, bioplastics are generally sold at a premium<br />

compared to conventional plastics, and the current low<br />

prices of crude oil are not making the competition any<br />

easier. It is therefore of the utmost importance to build<br />

maximum exposure for the new products. The higher price<br />

of bioplastics for instance in packaging is compensated<br />

by added brand or product value. Major sports events are<br />

the candy shops for marketing professionals. The London<br />

Olympic Games in 2<strong>01</strong>2 were broadcast to 220 different<br />

countries with over 3.6 billion viewers. The bioplastic<br />

industry has been able to get its fair share of the publicity.<br />

McDonald’s decided to use Novamont’s Mater-Bi bioplastic<br />

for the disposable foodservice packaging in their Olympic<br />

park restaurant during London Olympic Games. Rio 2<strong>01</strong>6<br />

has published sustainability guidelines encouraging the<br />

use of biodegradable compostable packaging for fast<br />

food outlets, and recyclable bioplastics for other types of<br />

packaging. The choice of event for Avantium’s and Mitsui’s<br />

launch was an expected yet very smart move.<br />

Along with the increasing media exposure, more and<br />

more brand owners are considering bioplastics as part of<br />

their sustainability programme. Shiseido plans to switch<br />

over 70 % of the polyethylene used in their domestic<br />

cosmetics containers from petroleum-based to bio-based<br />

by 2020. Procter & Gamble has announced replacing 25 %<br />

of their petroleum-based raw materials with renewable<br />

materials in all products and packaging by 2020. Also<br />

the Swedish furniture giant IKEA is planning to have all<br />

plastics used in the company’s home furnishings made<br />

from 100 % renewable and/or recyclable materials with<br />

the same schedule as Shiseido and P&G. These global<br />

brands are considered to be innovators in the adoption<br />

curve of bioplastics. We at Pöyry believe this trend of<br />

brand owner targets will expand from innovators to early<br />

adopters in the next ten years. Will there be enough supply<br />

to meet these targets?<br />

The market data of European Bioplastics forecasts<br />

that the production capacities of bioplastics will reach<br />

almost 8 million tonnes in 2<strong>01</strong>9 with non-biodegradable<br />

bioplastics representing the major part of the growth.<br />

As a combined management consulting and engineering<br />

company we keep a tight eye on the development and<br />

realisation of investment projects. Today, we see some<br />

major challenges with the build-up of new bioplastic<br />

production. Much of the volume growth is counting on new<br />

bio-based PE, PET, PEF and PLA production.<br />

Braskem is still the only producer of sugar-based PE<br />

on the market with no announcements of new entrants.<br />

In addition, Mitsui decided to bury their bio-ethylene<br />

joint venture with Dow Chemical last October by selling<br />

all its shares of the company. On the positive side, SABIC<br />

launched a portfolio of renewable PE and PP in 2<strong>01</strong>4 but<br />

the actual production volumes remain unknown. There is<br />

also an on-going debate whether these ISCC Plus certified<br />

renewable polyolefins can be marketed as bio-based<br />

products.<br />

The development of bio-based PET and PEF is going<br />

forward, but the production output is lagging behind<br />

The Chasm<br />

Innovators Early adopters Early majority Late majority Laggards<br />

26 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Opinion<br />

By:<br />

Henna Poikolainen and Juulia Kuhlman<br />

Pöyry Management Consulting<br />

Vantaa, Finland<br />

market projections. For instance, the largest biobased<br />

monoethylene glycol project to date – 500,000<br />

t/a in Brazil by JBF Industries – has been put on hold<br />

and some sources expect it to be cancelled. There is<br />

a lot of activity in developing catalytic processes for<br />

bio-MEG but there will be little production available<br />

for P&G, IKEA and alike by 2020.<br />

The future supply looks more promising for PLA.<br />

Corbion succeeded in signing letters of intent for<br />

one-third of the 75,000 t/a capacity planned for their<br />

new facility in Thailand and decided to go forward<br />

with the investment. NatureWorks awarded the<br />

engineering contract of a new production plant in<br />

Southeast Asia to Jacobs back in 2<strong>01</strong>3 but we are<br />

still waiting for news on the location.<br />

Press releases of new bioplastic projects paint<br />

a distorted picture of the supply volumes. Only<br />

few projects reach full capacity with the initially<br />

announced timing. New technologies, developing<br />

markets and exclusive partnerships make the<br />

bioplastics industry demanding, risky and timeconsuming<br />

to enter. Sustainable biomass sourcing<br />

with transparent traceability is a prerequisite for<br />

any collaboration with the major brand owners.<br />

Similarly to Corbion, many producers seek to<br />

secure major offtake of planned capacity prior to a<br />

final investment decision which prolongs time-tomarket.<br />

Project financing is rarely straightforward.<br />

Many bioplastics projects are risky investments<br />

even at high crude oil prices. It is challenging to<br />

convince investors of the profitability of capital<br />

intensive projects when the return on investment is<br />

dependent on a biopremium.<br />

The supply of bioplastics is expected to show<br />

double-digit growth for the next ten years, but the<br />

curve is unlikely to depict as exponential a growth<br />

as project announcements would indicate. Securing<br />

an adequate supply of bioplastics will be a major<br />

issue for the brands aiming to reach their targets<br />

by 2020. Most brands are unwilling to commit to a<br />

single supplier. There should be at least two or three<br />

certified suppliers to secure supply, but this is rarely<br />

the case in today’s bioplastic market. There is great<br />

variation in polymer grades and switching costs are<br />

still too high. Hence, bioplastic producers should<br />

not see new entrants as unwelcome competitors,<br />

but rather as a necessity for market formation. We<br />

foresee more and more partnerships with bioplastic<br />

producers and brand owners. Tight collaboration<br />

with brand owners can speed-up market entry and<br />

take the bioplastics industry to the next level.<br />

www.poyry.com<br />

About the authors:<br />

Henna Poikolainen and Juulia<br />

Kuhlman are both consultants at Pöyry<br />

Management Consulting. Pöyry is one<br />

of the leading advisors to the world’s<br />

energy, forest and bio-based industries.<br />

In the past 5 years, the authors have<br />

been supporting clients e.g. in market<br />

entry, product portfolio and partnering<br />

strategies; in supply, demand and cost<br />

analyses; and in technology evaluation<br />

and pre-feasibility assessments. In<br />

2<strong>01</strong>5, Pöyry published a multiclient<br />

report “BioSight up to 2025” analysing<br />

the supply, demand and dynamics of<br />

the bio-based chemical business: www.<br />

poyry.com/biosight<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 27


Application News<br />

New biobased<br />

sustainable eyewear<br />

Eyewear company Charmant USA has announced<br />

the launch of Awear, a line of eco-friendly eyeglasses.<br />

Composed of recyclable plant-based biobased plastics,<br />

plus biodegradable demo lenses. Its inaugural collection<br />

of ergonomic eyewear was designed to be lightweight,<br />

fashion-forward and completely eco-friendly.<br />

The brand boasts an unyielding commitment to<br />

environmentally conscious practices, from design to<br />

production. All of the glasses’ frames and sun lenses<br />

are made with sustainable materials – the frames<br />

themselves are created from recyclable plant-based<br />

biobased polyamide. And since the bio-polyamide is<br />

made from a plant-based material, each ergonomically<br />

fitted frame boasts reduced carbon-dioxide emissions<br />

and water use compared with conventional eyewear.<br />

Production is another important factor for the company.<br />

The temple pieces for each pair of glasses (made of a<br />

biobased elastomer material) are hand-assembled,<br />

ultimately making the process more energy efficient. The<br />

frames are also designed with a high-chemical resistant<br />

material that eliminates the need for spray coating pieces,<br />

a factor that reduces overall water usage in production.<br />

Even the demo lenses are biobased and biodegradable<br />

and are made from PLA.<br />

“Awear is different and exceptional from any other<br />

eyewear collection,” Michele Ziss, director of product<br />

and marketing at Charmant, said in a statement. “The<br />

materials and production processes have distinctive<br />

properties and a unique story because they are<br />

environmentally friendly.”<br />

Aimed at style-conscious and environmentally savvy<br />

millennials, Awear debuts this month with seven optical<br />

frames and two styles of sunglasses for men and women.<br />

Yosuke Shimano, the collection’s lead designer,<br />

credited the vivacity of life in the landscapes that<br />

surround him for inspiring the range of translucent yet<br />

saturated colors.<br />

“It is with this concept, that Awear can make an equally<br />

bold style and eco-savvy statement,” the company added. KL<br />

www.awearcharmant.com<br />

PHA for safer toys<br />

Italy-based Bio-on laboratories have created a new type<br />

of bioplastic, designed to make safe and eco-sustainable<br />

children’s toys. Dubbed Minerv PHA Supertoys, the new<br />

material has now been used for the first time for the<br />

manufacture of building bricks.<br />

Based on Bio-on’s biodegradable biopolymer (PHA),<br />

which has already been tested in applications ranging<br />

from automotive to design to biomedical, biobased<br />

Supertoys is safe, and hygienic, and it meets and exceeds<br />

the provisions of the recent European Directive 2009/48/<br />

EC, known as the TDS (Toy Safety Directive), implemented<br />

into the standard international procedure for toy safety<br />

evaluation EN 71.<br />

Bio-On has developed an exclusive process for the<br />

production of a family of PHA polymers from agricultural<br />

waste (including molasses and sugar cane and sugar<br />

beet syrups). Bio-On PHA is certified by Vincotte and by<br />

USDA (United States Department of Agriculture) as 100 %<br />

biobased and completely biodegradable.<br />

The Minerv PHA Supertoys project was launched<br />

by Bio-on with no commercial goal, aiming solely to<br />

demonstrate whether or not specific, eco-sustainable and<br />

completely biodegradable formulations could be created<br />

to manufacture child-safe, environmentally friendly toys,<br />

without compromising on the functionality or aesthetic<br />

appeal of the end product.<br />

“The presence of toxic substances in toys is still a very<br />

serious problem today,” says Bio-on S.p.A. Chairman<br />

Marco Astorri. “We are convinced that this new discovery<br />

can make a decisive contribution to the health of our<br />

children.”<br />

The first product chosen as the demonstrator for the<br />

new material was a LEGO ® -style building bricks. Astorri<br />

explained that the company had chosen this product,<br />

because of the relative difficulty in producing it. “It has a<br />

tolerance of 2 µm and the fact that we have succeeded in<br />

guaranteeing such a high quality level gives us confidence<br />

for future developments,” he said.<br />

The research project is open to all laboratories and<br />

companies around the world working on toy design. The<br />

goal is to create two types of bioplastic by the end of 2<strong>01</strong>7:<br />

Minerv PHA Supertoys type R, a rigid, strong grade, and<br />

Minerv PHA Supertoys type F, which will be ductile and<br />

flexible. KL/MT<br />

www.bio-on.it<br />

28 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Application News<br />

New Ice-cream container<br />

At the SIGEP Exhibition in Rimini, Italy (23 – 27 January 2<strong>01</strong>6) a new line of ice-cream containers made from BioFoam ® has<br />

been introduced by the companies Erreme (Foligno, Italy) and Domogel (Costa di Mezzate, Italy). They are two of the leading<br />

producers of ice-cream packaging in Italy. The BioFoam containers are produced by Synprodo, Wijchen, The Netherlands. The<br />

ice containers are put into the market under the name Greeny and come in two models 500 ml and 1000 ml. The insulating<br />

properties of the containers keep the ice cool<br />

for several hours allowing the consumers to<br />

take it home for consumption. Assuming an<br />

external temperature of 25 °C, the temperature<br />

of the ice cream stored in a BioFoam container<br />

will vary by 2 °C per hour. With a thermoformed<br />

layer of PLA on the inside the entire container<br />

is still completely bio-based and compostable<br />

(certified as industrially compostable according<br />

to EN13432). In Italy officially allowed by law since<br />

last year, consumers can dispose of the empty<br />

containers in their biowaste bin.<br />

After an official Press Conference and during the<br />

following days on the exhibition the revolutionary<br />

new concept for Italy gained a lot of interest and<br />

the producers are confident that the coming years<br />

the Greeny box will grow and take market share<br />

on the Italian and other markets.<br />

www.greeny.it<br />

www.synprodo.com<br />

9. Biowerkstoff-Kongress<br />

HIGHLIGHTS OF THE WORLDWIDE BIOECONOMY:<br />

1 st Day (5 April 2<strong>01</strong>6)<br />

• Policy & markets<br />

• New bio-based building blocks<br />

• Biorefineries<br />

• Innovation Award<br />

“Bio-based Material of the Year 2<strong>01</strong>6”<br />

2 nd Day (6 April 2<strong>01</strong>6)<br />

• Building blocks and polymers<br />

• Polyhydroxyalkanoates (PHA)<br />

• Lignin utilisation<br />

Organiser<br />

Venue & Accomodation<br />

Maternushaus Cologne, Germany<br />

Kardinal-Frings-Str. 1–3, 50668 Cologne<br />

+49 (0)221 163 10 | info@maternushaus.de<br />

Book now<br />

10% reduction – enter code bpm10<br />

during your booking process<br />

www.nova-institute.eu<br />

Contact<br />

Dominik Vogt<br />

Conference Manager<br />

+49 (0)2233 4814-49<br />

dominik.vogt@nova-institut.de<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 29


Foam<br />

PLA foam expanding<br />

<br />

into new areas<br />

By:<br />

Sarah Heine, CEO<br />

Biopolymer Network<br />

Rotorua, New Zealand<br />

The Biopolymer Network Limited (BPN) team from Rotorua,<br />

New Zealand, who developed Zealafoam ® , a PLA based alternative<br />

to expanded polystyrene (EPS), continues to develop<br />

new opportunities for bio-based foam. Leveraging off their<br />

patented process which uses CO 2<br />

as a green blowing agent to<br />

produce low density particle PLA foam, BPN has developed a variety<br />

of prototypes of varying shape and dimension. These include<br />

cups, films or other articles depending on the target application.<br />

PLA foamed cups have been developed to target the growing<br />

demand for bio-based disposable cups for both hot and cold<br />

beverages. The foaming process increases the glass transition<br />

temperature (T g<br />

) and/or crystallinity of the PLA, depending on<br />

the grade of PLA used, resulting in better thermal stability than<br />

non-foamed PLA cups. Thermal conductivity measurements<br />

show that the foamed cups have good insulation properties,<br />

while mechanical testing indicates the prototypes have good<br />

impact resistant properties. While work is ongoing to target hot<br />

beverage applications, the current technology is ideal for cold<br />

beverages.<br />

Similarly, the team has created a thin PLA foamed film using<br />

this process. Currently there is interest from industry in the use<br />

of PLA film for packaging and labelling applications. Printing on<br />

clear PLA film can however prove a challenge, with a white base<br />

coat required prior to printing. The BPN process results in an<br />

opaque, smooth and shiny surface that is ideal for printing and<br />

the product is light weight. The manufacturing process can be<br />

manipulated to significantly improve the elastic modulus and the<br />

yield stress of the product, over solid PLA film, while decreasing<br />

the strain percentage at break. These properties make the<br />

material an excellent product for the targeted applications.<br />

BPN has also studied the incorporation of different biomass in<br />

all their foamed products, from particle foam to foamed film. The<br />

focus has been on available low value biomass such as pine bark,<br />

canola meal or dried distiller grains and excellent foam has been<br />

achieved with biomass loadings as high as 15 %. The resulting<br />

foam exhibits altered properties, depending on the biomass<br />

loading and therefore can target different applications, with a<br />

reduced product cost achieved by the substitution of a processed<br />

plastic with a low cost biomass.<br />

Traditionally, Zealafoam particle foam has been moulded using<br />

existing expanded polystyrene (EPS) equipment to produce low<br />

density foam with similar mechanical and thermal insulation<br />

properties to that of EPS. Zealafoam is a closed cell foam<br />

with properties primarily determined by the properties and<br />

morphology of the polymer, the foam or cellular structure, and<br />

the bulk density. Using these principles, BPN have produced a<br />

more diverse range of products incorporating their technology<br />

for new applications, combining the functionality of excellent<br />

insulating properties and light weight with the many advantages<br />

of a bio-based plastic.<br />

This research was funded by New Zealand’s Ministry of<br />

Business, Innovation and Employment.<br />

www.biopolymernetwork.com<br />

30 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


organized by<br />

supported by<br />

20. - 22.10.2<strong>01</strong>6<br />

Messe Düsseldorf, Germany<br />

Bioplastics in<br />

Packaging<br />

BIOPLASTICS<br />

BUSINESS<br />

BREAKFAST<br />

B<br />

3<br />

PLA, an Innovative<br />

Bioplastic<br />

Bioplastics in<br />

Durable Applications<br />

Subject to changes<br />

Call for Papers now open<br />

www.bioplastics-breakfast.com<br />

Contact: Dr. Michael Thielen (mt@bioplasticsmagazine.com)<br />

At the World‘s biggest trade show on plastics and rubber:<br />

K‘2<strong>01</strong>6 in Düsseldorf bioplastics will certainly play an<br />

important role again.<br />

On three days during the show from Oct 20 - 22, 2<strong>01</strong>6<br />

bioplastics MAGAZINE will host a Bioplastics Business<br />

Breakfast: From 8 am to 12 noon the delegates get the<br />

chance to listen and discuss highclass presentations and<br />

benefit from a unique networking opportunity.<br />

The trade fair opens at 10 am.<br />

BIO-BASED START-UP DAY<br />

7 April 2<strong>01</strong>6 · Maternushaus · Cologne · Germany<br />

Organiser<br />

www.nova-institute.eu<br />

Venue & Accomodation<br />

Maternushaus Cologne, Germany<br />

Kardinal-Frings-Str. 1–3, 50668 Cologne<br />

+49 (0)221 163 10 | info@maternushaus.de<br />

Contact<br />

Dominik Vogt<br />

Conference Manager<br />

+49 (0)2233 4814-49<br />

dominik.vogt@nova-institut.de<br />

HIGH-POTENTIAL START-UPS FROM BIO-BASED<br />

CHEMISTRY, POLYMERS AND BIOTECHNOLOGY<br />

The Bio-based Start-up Day will bring start-ups, investors and industry<br />

together by giving the floor to everyone and providing great opportunities of<br />

networking. The day will start with a keynote speech followed by presentations<br />

of start-ups. Related clusters such as CLIB2021 and IBB Netzwerk will also<br />

have the chance to present their own young start-ups. In a special meeting<br />

session the audience will have the opportunity to meet the start-ups and<br />

investors in person. Investors will afterwards provide<br />

an insight into their incentives and experiences working<br />

with start-ups in the bio-based and biotech sector. The<br />

day will end with a discussion and a coming together.<br />

Great networking opportunities all day long!<br />

More information: www.bio-based.eu/startup


Polyamides are made by polycondensation of dicarbonic acids with diamines or by polyaddition<br />

of lactames. e.g. PA 66 or PA 6. Succinic acid and its derivates 1,4 –di-amino butane or<br />

in academic research have been magnetic and crystallographic data. Furthermore, there is<br />

no clarity regarding melting point and temperature stability to be found in the literature, an<br />

important subject to enable its practical use. The Fraunhofer-UMSICHT scientists synthesized<br />

high melting point of 329 °C indicates high density of hydrogen bonding of the amide groups.<br />

10 years ago<br />

Published in bioplastics MAGAZINE<br />

10 YEARS AGO<br />

new<br />

series<br />

In January 2<strong>01</strong>6, Dr. Stephan Kabasci (Fraunhofer UMSICHT) comments:<br />

“Succinic acid fermentation was improved considerably with respect to concentration<br />

and yield in the course of the project. PA44, however, proved to be highly sensitive to<br />

temperature so that thermoplastic melt processing was not feasible.”<br />

Materials<br />

Succinic acid: versatile platform chemical<br />

The Fraunhofer-Institut für Umwelt, Sicherheits- und Energietechnik UMSICHT<br />

in Oberhausen, Germany has recently published some basic findings about the<br />

synthesis of polyamide from succinic acid, a substance that can be derived from<br />

renewable sources. A poster, presented at the International Conference on Renewable<br />

Resources and Biorefineries in Ghent, Belgium (Sept. 19 – 21, 2005) won<br />

the conference’s “Poster Award”.<br />

Succinic acid [HOC(O)CH 2<br />

CH 2<br />

C(O)OH] is a platform chemical that can be used<br />

directly or as intermediate for a large number of applications such as for plastics,<br />

paints, food additives and other industrial and consumer products. Today, succinic<br />

acid is produced mainly by chemical processes from petrochemical feedstocks.<br />

“But it can also be won from renewable sources” says Dr. Stephan Kabasci, one<br />

of the authors of the poster. For the fermentation of succinic acid from glucose,<br />

From starch to polyamide –<br />

via succinic acid<br />

Polyamide from bio-amber<br />

Synthesis of polyamide<br />

two strains of anaerobic bacteria have been tested on a laboratory scale: Anaerobiospirillum<br />

succiniciproducens (DSM 6400) and Actinobacillus succinogenes<br />

(ATCC 55618). Other experiments with starch from different sources showed that<br />

the highest succinate concentration was achieved with maize starch (see Fig. 1).<br />

2-pyrrolidinone are therefore raw materials for the production of polyamide 4.4 or polyamide<br />

4.<br />

Only a few articles have been published in literature in relation to polyamide 4.4. Main topics<br />

polyamide 4.4 in a polycondensation process. The resulting product takes up water to form<br />

gelatinous mass and is a very hard material in dry state.<br />

The melting point of a sample that has not been fully refined is shown in Fig. 2. The extreme<br />

A comprehensive article about polyamides made from bio-based succinic acid, their potential<br />

for packaging and technical applications and including a discussion of the cost issue is<br />

planned for the next issue of bioplastics magazine.<br />

www.umsicht.fraunhofer.de/english<br />

Formation of Succinic acid by fermentation of starch types<br />

Start concentration of starch types :15gL -1<br />

Succinic Acid Concentration / gL -1<br />

7<br />

6<br />

5<br />

4<br />

3<br />

2<br />

1<br />

Maize Starch<br />

Potato Starch<br />

Wheat Sarch<br />

0<br />

0 40 80 120 160 200 240<br />

time / h<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

Succinate Yield<br />

[g/100 g substrate]<br />

Fig. 1: Left: Succinate production from starch types by fermentation<br />

Right: Specific Yield of succinate from different substrates<br />

Glucose<br />

Maize starch<br />

Wheat starch<br />

Potato starch<br />

Cellulose<br />

endo 0,45<br />

first heating and cooling<br />

20-250-50 °C, desorption of water<br />

0,40<br />

second heating 20 KMin -1<br />

0,35<br />

0,30<br />

0,25<br />

0,20<br />

0,15<br />

0,10<br />

329 °C<br />

80 120 160 200 240 280 320 360<br />

temperature / °C<br />

heat flow / mWmg -1<br />

Fig. 2: DSC thermogramof raw Polyamide 4.4<br />

14 bioplastics [06/<strong>01</strong>] Vol. 1<br />

32 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


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Basics<br />

“The biobased office” for the<br />

procurement of the future<br />

The German Agency for Renewable Resources<br />

promotes a viable sustainable procurement.<br />

German law lacks a legal basis for sustainable public<br />

procurement. Legislation requiring resource and environmental<br />

considerations to be taken into account<br />

when purchasing goods and services for the public sector has<br />

not yet been put in place.<br />

Hence, the implementation of sustainable public<br />

procurement in Germany has been patchy in many aspects, a<br />

fact that is also reflected in the development of a recognized<br />

environmental label. It would therefore be helpful first to<br />

formulate significant sustainability criteria and thus to gain<br />

experience with public procurement and, at the same time,<br />

to gradually develop a sustainable procurement culture. That<br />

would also give producers the opportunity to adopt a goaloriented<br />

perspective. However, many public authorities are<br />

struggling with such an approach.<br />

Clearly, sustainable procurement is a new approach – and<br />

it is one that involves more effort, as information will have to<br />

be collected, old and familiar procurement habits abandoned<br />

and market availability studied. However, the single most<br />

important reason for the slow progress in this area is the lack<br />

of encouragement and support from decision makers.<br />

Of course there are good examples as well, such as that<br />

of Berlin. Berlin not only has administrative regulations<br />

providing for the implementation of environmental protection<br />

requirements in the procurement of goods, works and services<br />

[1], but has also developed specific minimum requirements for<br />

many product groups, which serve as practical procurement<br />

guides. Another positive sign was the recent publication from<br />

the Öko-Institute of a study showing the financial savings<br />

and environmental benefits potentially resulting from the<br />

implementation of environmentally-friendly procurement<br />

processes.<br />

The Agency for Renewable Resources (Fachagentur<br />

Nachwachsende Rohstoffe, FNR) also encourages<br />

environmentally friendly procurement. On behalf of the<br />

Federal Ministry for Food and Agriculture (BMEL), a project<br />

called the “Use of biobased products in public procurement”<br />

was established at the FNR in 2<strong>01</strong>0. The project aims to<br />

promote environmental and natural resource stewardship,<br />

as well as to enhance the security of the resource supply by<br />

fostering the use of biobased products. Public institutions,<br />

in their role as pioneers, could leverage their purchasing<br />

The bio-based office<br />

34 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Basics<br />

power to further advance the use of biobased products. This<br />

commitment to biobased products is also reflected in the EUfinanced<br />

projects of the FNR.<br />

The biobased office<br />

The FNR project entitled “Use of biobased products in public<br />

procurement” is currently touring Germany with a model of a<br />

biobased office serving as an exhibition booth. Tour schedule:<br />

http://www.das-nachwachsende-buero.de/service/tourenplan/<br />

The booth showcases the products with which a biobased,<br />

environmentally-friendly office setting can be created. Given<br />

the 17 million office workspaces in Germany alone, the use<br />

of biobased office products offers enormous potential for a<br />

reduction of CO 2<br />

emissions.<br />

Nearly 100 biobased products, ranging from office furniture<br />

to office design and furnishings can be viewed and touched at<br />

the fully accessible, 12 m 2 exhibition booth. The selection of<br />

bioplastic products featured have been made available by a<br />

variety of companies, both large and small. The entire range of<br />

products featured in the exhibition booth, and the companies<br />

producing these, are listed in a complimentary brochure, but<br />

can also be found on: www.das-nachwachsende-buero.de.<br />

Sustainability in procurement law and procurement<br />

processes of biobased products<br />

Plastics play a major role in office equipment. In addition to a<br />

growing use of recycled plastic materials, products made from<br />

biobased materials are also on the rise. According to public<br />

procurement law, it may be necessary to substantiate and<br />

submit proof of the sustainability claims of biobased plastics<br />

(e.g. the environmental benefits of the product).<br />

Implementation of the European public procurement<br />

directives will require an overhaul of public procurement law and<br />

the strengthening of sustainable and innovative procurement<br />

practices. Following the incorporation of these directives<br />

into German law in April 2<strong>01</strong>6, it should be easier for public<br />

procurers to write tenders with sustainable (environmental,<br />

social and innovative) requirements, which relate to:<br />

• the terms of references / technical specifications<br />

• the qualification / selection criteria<br />

• the contract / award criteria<br />

• requirements for the implementation of a contract<br />

as long as there is an objective connection with the contract<br />

at hand.<br />

Proof of the required properties can be provided by an<br />

overall reference to a recognized label or certificate. Moreover,<br />

e-procurement will be the standard procedure.<br />

However, for the heterogeneous group of manufacturers<br />

of biobased products – mainly made up of SMEs – such<br />

certifications and e-procurement requirements pose a serious<br />

impediment to doing business with public procurers. Another<br />

problem is the wide use of framework agreements, which make<br />

it difficult for SMEs to participate. Hence, SMEs are more likely<br />

to opt for direct award procedures with volumes below the<br />

€ 10.000 threshold.<br />

With sales figures like these, however, no real market<br />

breakthrough, of the kind envisioned by the “bioeconomy”<br />

policy strategy, is possible.<br />

<br />

By:<br />

Monika Missalla-Steinmann<br />

Public relations officer<br />

Agency for Renewable Resources (FNR)<br />

Gülzow, Germany<br />

Office materials made of biobased plastic<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 35


Basics<br />

The Blauer Engel is highly accepted in Germany<br />

Environmentally-friendly procurement in Germany is<br />

strongly influenced by the ecolabel Blauer Engel (Blue<br />

Angel). The label is highly accepted among public procurers<br />

in Germany. The Blauer Engel was explicitly introduced<br />

as an environmental policy instrument by the state, which<br />

contributed to its credibility. Most product certifications,<br />

however, are based on energy saving and energy efficiency.<br />

Biobased plastics, can currently not be certified under the<br />

Blauer Engel. However, this may change in the near future,<br />

as a result of an ongoing study commissioned by the Federal<br />

Environment Agency, which is examining this issue.<br />

While the “Blauer Engel” is a respected national eco-label,<br />

the question is, what are the possibilities for certification<br />

available to businesses in the international market?<br />

In the EU, biobased plastics can be certified under the<br />

Vincotte/biobased certification system. However, this solely<br />

applies to the biobased content of a product, not to its<br />

sustainability. The Vincotte / compost certificate is not likely to<br />

play a role in the field of office supplies. Not many authorities<br />

will want to compost their biobased plastic stapler.<br />

Blauer Engel<br />

Raw materials associations and the different countries<br />

of origin complicate the verification process. A step in the<br />

right direction would be to establish criteria to determine<br />

the sustainability of individual commodities, which could<br />

then be granted a corresponding recognized quality label. A<br />

certification system of this kind would at least provide insight<br />

into the predominant raw material content (e.g. wood). The<br />

hurdles to sustainable procurement are particularly high<br />

at this point. No conventional product carries such a high<br />

burden of proof.<br />

Sustainable procurement requires creativity and<br />

dialogue<br />

Life cycle costs or life cycle assessments are also playing an<br />

increasingly important role in the sustainability assessment<br />

carried out as part of the process of evaluation and awarding<br />

of contracts. However, the difficulty is knowing how to go<br />

about a life cycle assessment of a granulate that is based<br />

on raw materials derived from different origins. Moreover,<br />

such calculations will mean very little in the case of office<br />

accessories. Nevertheless, these are questions that need to<br />

36 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Basics<br />

be raised and addressed by the biobased sector, together<br />

with the decision makers in public procurement.<br />

What are other possibilities for biobased plastics in<br />

public procurement?<br />

Procurement law not only defines the what, but also<br />

the how of purchasing. One possibility would be to require<br />

the use of products or materials designated as biobased<br />

or from renewable resources in the specifications. The<br />

invitation to tender can state clearly and transparently<br />

that this requirement constitutes an award criterion, to<br />

which a particular weighting has been assigned.<br />

Relating resource security to the award of a<br />

procurement contract is slightly more complicated, as<br />

resource security is understood to refer not only to the<br />

finite supply of fossil fuels, but also to the dependency on<br />

imports. This makes establishing an objective connection<br />

somewhat more difficult.<br />

Security of supply is an important building block for<br />

the realization of a biobased economy. The same goes<br />

for the widely documented CO 2<br />

savings over the lifetime<br />

of a biobased product. Both aspects are difficult to prove,<br />

even when using eco-labels as proof for awarding a<br />

contract.<br />

At this point, general societal responsibility in<br />

public procurement will take the form of promoting<br />

an open and creative dialogue between producers and<br />

public procurers, with a view to achieving an effective<br />

breakthrough of biobased products in the market.<br />

Nevertheless, this does not excuse the sector from<br />

thinking about how a scientifically proven, independent<br />

and transparent and possibly globally applicable<br />

certification scheme or label could be launched.<br />

On the other hand, the tax-financed public sector has<br />

a duty to use the opportunities created by procurement<br />

law to support societal goals such as energy and<br />

resource security or climate protection measures for the<br />

benefit of the general public.<br />

The Agency for Renewable Resources, with its “Use<br />

of biobased products in public procurement” project,<br />

is open for a dialogue concerning the procurement of<br />

biobased products.<br />

The FNR is also involved in Europe-wide projects on<br />

biobased products and services in public procurement<br />

with the EU projects InnProBio “Forum for Bio-Based<br />

Innovation in Public Procurement” and OpenBio<br />

“Opening bio-based markets via standards, labelling and<br />

procurement”.<br />

[1] Verwaltungsvorschrift für die Anwendung von Umweltschutzanforderungen<br />

bei der Beschaffung von Liefer-, Bau- und<br />

Dienstleistungen - VwVBU<br />

http://beschaffung.fnr.de<br />

www.das-nachwachsende-buero.de<br />

www.innprobio.eu<br />

www.open-bio.eu<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 37


Opinion<br />

Biopolymers<br />

will weather<br />

the crash in<br />

petroleum<br />

prices<br />

By:<br />

Ron Buckhalt<br />

Before you read this column, you should know that I retired<br />

on December 31, 2<strong>01</strong>5 as Manager of the (USDA)<br />

BioPreferred Program. So anything I say here is as a<br />

private citizen, not a government employee. However I was<br />

involved with bioproducts for nearly 40 years and have some<br />

institutional knowledge.<br />

I would like to first thank, Michael Thielen for allowing me<br />

a few paragraphs to reflect on advancements made in the<br />

bioproducts industry over the last few decades.<br />

But before we discuss the recent advances I think we need<br />

to stop for a moment and think about how we got to where we<br />

are today, particularly as it relates to bioplastics.<br />

Humankind was using biobased products long before<br />

they were called natural or some other new catchword. Our<br />

paints, inks, coatings, dyes, lubricants, fuels, soaps, and other<br />

industrial products were made from plants and animals. It<br />

was only when petroleum was discovered in the 1860’s that<br />

we begin to move to a hydrocarbon economy away from a<br />

carbohydrate economy.<br />

There was even an argument about whether we would fuel<br />

our vehicles with plant-derived ethanol or petroleum-derived<br />

gasoline, or even electricity, and books have been written on<br />

the battles so I will not attempt to recount those issues, just<br />

be aware of them as part of the changing landscape.<br />

For the United States, in the 1930’s there emerged<br />

something called the Chemurgic Movement. Several leading<br />

industrialists and scientists felt we could create new industrial<br />

markets for agricultural materials and help prop up agriculture<br />

commodity prices. The 1938 Farm Bill created a series of US<br />

Department of Agriculture (USDA) research institutes to work<br />

on new industrial products using agricultural commodities.<br />

These would become the Agricultural Research Service<br />

where I worked in biobased technology transfer for 10 years.<br />

Meanwhile oil prices continued to go up and down with wild<br />

swings. Every time it seems biobased products were gaining a<br />

foothold once again, the price of oil would dip and any market<br />

advantage for biobased products disappeared. Finally, following<br />

the first world oil embargo in the mid-1970’s it appeared<br />

petroleum prices were only going one direction – up. This was<br />

true right up until the last few years. As this is being written a<br />

barrel of oil was priced at below USD 35. Gasoline in the U.S. is<br />

below two dollar a gallon and there are predictions of one dollar<br />

a gallon gasoline. It remains to be seen what impact these low<br />

petroleum prices will have on the development of alternative<br />

biobased feed stocks. However, many very large international<br />

industrial chemical companies have committed resources to<br />

develop alternative biological sources for many chemicals and<br />

are making and selling commercial materials.<br />

In the mid-80’s USDA published the findings of a Farm and<br />

Forest Task Force that looked at how many acres of agricultural<br />

products could be grown to meet industrial product demands.<br />

USDA’s Economic Research Service even published yearly<br />

updates about the number of acres or hectares that were<br />

grown and used to make biobased products. But it was not<br />

until 2002 that a decision was made by the Administration<br />

and Congress to help develop markets for the tremendous<br />

biomass in the U.S. Part of that 2002 Farm Bill was a provision<br />

to create a biobased markets development program to include<br />

a U.S. Certified Biobased Products label and to carve out a<br />

federal procurement preference for the purchase of biobased<br />

products. This was to become the BioPreferred program.<br />

Michael asked me to talk about the role of bioplastics in this<br />

movement. One of the first platforms to have success in the<br />

marketplace was PLA, particularly for single use items. But<br />

even that had many challenges and major investors pulled out<br />

because the technology was not making any money. That is no<br />

longer the case. Since those bold first steps there are at least<br />

38 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


five new pathways to bioplastics and each has different<br />

technologies at work. While bioplastics is only 1 % of the<br />

total worldwide market it is the fastest growing plastics<br />

sector. And with any new industry there will be winners<br />

and losers. Some technologies will advance and become<br />

profitable. Others will not. I am not sure even a crystal ball<br />

can tell us which technologies will succeed and which will<br />

fail.<br />

However, major world-wide chemical companies have<br />

now made significant financial investments to make<br />

polymers (not just plastic) using biomass, instead of<br />

petroleum. And many of those products are now being<br />

marketed commercially. There are also major advances in<br />

using bioplastics to produce the covers for our electronic<br />

products. And why not as our pocket phones are out of date<br />

as soon as we buy them. Same with our laptops.<br />

Many of the finished products and intermediate chemicals<br />

currently labeled as USDA Certified Biobased Products are<br />

either biopolymers or biobased building block chemicals<br />

used to make finished biopolymers.<br />

Some of you have heard me speak about the Great<br />

Garbage Patch of the Pacific Ocean which is filled with<br />

petroleum-based plastic particles hundreds of miles wide<br />

and miles deep from micro-particles to huge chunks of<br />

floating plastic debris. But these dumps exist in many other<br />

oceans and they are killing machines for seabirds and<br />

turtles as well as other marine life.<br />

Since humankind – to a great extent – seems to be<br />

unwilling to reduce, recycle, and reuse; and attempts<br />

to clean up these garbage patches is a daunting if not<br />

impossible task, would it not just make sense to make as<br />

many of our plastic materials we use in everyday life with<br />

a built-in expiration date preferable with a take-back policy<br />

for recycling. At the same time it also makes sense to buy<br />

and sell only single use items that can be fully biodegraded<br />

in composting facilities and not just break into smaller<br />

pieces that persist in the environment for eons.<br />

Additionally, research continues into the possible health<br />

impacts of using petroleum-based plastics and petroleumbased<br />

plasticizers to make containers to hold food and other<br />

products we consume. Whether or not there is a health issue<br />

with these containers in the final analysis is not the driver.<br />

In this case perception is reality. If consumers perceive a<br />

possible health issue from petro-plasticizers may exist<br />

they are already seeking and are willing to pay for biobased<br />

alternatives. One of the fastest growing biobased materials<br />

currently labeled by USDA are biobased plasticizers.<br />

Since this is an opinion piece, in conclusion I will state<br />

that I am bullish on the future of biobased products and<br />

bioplastics. I believe we will weather this current round<br />

of low oil prices and continue the research to make even<br />

better bioplastics and to make them price competitive with<br />

petroleum plastics. The price of petroleum will swing back<br />

the other way once marginal operations have been driven<br />

out of business. Again, my opinion, but it is the belief of many<br />

that the current glut of cheaper petroleum is a business<br />

practice to bankrupt operators that must have USD 75 – 100<br />

a barrel oil to be profitable. By making bioplastics an<br />

integral part of the plastic mix, even with lower petroleum<br />

prices, because of unique properties, the industry should<br />

be poised to explode when petroleum prices spike again. •<br />

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Empack Benelux<br />

@EmpackBenelux #Empack<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 39


Basics<br />

Mandatory Federal purchasing<br />

of biobased products<br />

About the USDA BioPreferred ® Program<br />

By Michael Thielen<br />

Managed by the U.S. Department of Agriculture (USDA),<br />

the Federal Biobased Products Preferred Procurement<br />

Program (BioPreferred ® Program) provides that<br />

Federal agencies in the USA must give purchasing preference<br />

to biobased products designated by this program [1, 2]. The<br />

authority for the program is included in the Farm Security and<br />

Rural Investment Act (FSRIA) of 2002, reauthorized and expanded<br />

as part of the Agricultural Act of 2<strong>01</strong>4 (the 2<strong>01</strong>4 Farm<br />

Bill) [3]. Section 9002 of this Act provides for a preferred procurement<br />

and labeling program and defines biobased products<br />

as commercial or industrial products that are composed,<br />

in whole or in significant part, of biological products or renewable<br />

domestic agricultural materials (including plant, animal,<br />

and marine materials) or forestry materials. Domestic content<br />

is interpreted to mean content not only from the USA<br />

but also from any country with which the United States has a<br />

preferential trade agreement. Countries that are signatories<br />

to NAFTA and CAFTA, for example, will have their qualifying<br />

biobased products treated as domestic products.<br />

The purpose of the BioPreferred program is to spur<br />

economic development, create new jobs and provide new<br />

markets for farm commodities. The increased development,<br />

purchase, and use of biobased products reduces the USA’s<br />

reliance on petroleum, increases the use of renewable<br />

agricultural resources, and contributes to reducing adverse<br />

environmental and health impacts [2].<br />

Mandatory Federal Purchasing<br />

The program requires, that all Federal agencies in the USA<br />

must purchase biobased products in categories identified by<br />

USDA. To date, USDA has identified 97 categories of biobased<br />

products for which agencies and their contractors have<br />

purchasing requirements. These categories include such that<br />

refer to biobased plastic products, e.g. carpets of other floor<br />

coverings (7 %), plastic lumber (23 %), dispoasable containers<br />

(72 %), cutlery (48 %), tableware (72 %), films (non-durable:<br />

85 % – semi-durable: 45 %), packaging and insulating<br />

materials (74%), plastic insulating foam for construction<br />

(7 %), thermal shipping containers (durable: 21 % - nondurable:<br />

82 %), and some more. Each mandatory purchasing<br />

category specifies the minimum biobased content according<br />

to ASTM D6866 (see figures in parentheses).<br />

Excemptions from the mandatory purchasing are products<br />

that are<br />

• not reasonably available<br />

• fail to meet performance standards for the application<br />

intended<br />

• available only at an unreasonable price.<br />

The BioPreferred program does not provide financial support<br />

for its participants. However, USDA’s Rural Development<br />

agency offers loan and grant programs. More information<br />

about this offer can be found on the USDA’s BioPreferred<br />

website [4],<br />

Voluntary Labeling<br />

Consumers are increasingly looking for products with<br />

sustainable attributes. That’s why USDA wants to make it<br />

easy for consumers to identify biobased products. The USDA<br />

Certified Biobased Product label (see picture), displayed on<br />

a product certified by USDA, is designed to provide useful<br />

information to consumers about the biobased content of the<br />

product [2].<br />

Companies offering biobased products that meet USDA<br />

criteria may apply for certification, allowing them to display<br />

the USDA Certified Biobased Product label on the product.<br />

This label assures a consumer that the product contains a<br />

verified amount of renewable biological ingredients (referred<br />

to as biobased content). Consumers can trust the label to<br />

mean what it says because manufacturer’s claims concerning<br />

the biobased content are third-party certified and strictly<br />

monitored by USDA [2].<br />

What Are Biobased Products?<br />

Biobased products are derived from plants and other<br />

renewable agricultural, marine, and forestry materials and<br />

provide an alternative to conventional petroleum derived<br />

products.<br />

Biodegradability required<br />

For some products, such as single use bioplastic products<br />

must meet the appropriate standard for biodegradability<br />

(ASTM D 6400) in order to be designated for the BioPreferred<br />

procurement program. Some examples are cutlery, garbage<br />

bags or food containers [1].<br />

www.biopreferred.gov<br />

[1] Duncan, M.: Federal Agencies in the USA shall buy bioplastics products,<br />

bioplastics MAGAZINE Vol 1, 2006, p 28-29<br />

[2] N.N.: What is BioPreferred, http://www.biopreferred.gov/BioPreferred/<br />

faces/pages/AboutBioPreferred.xhtml<br />

[3] N.N.: The 2<strong>01</strong>4 Farm Bill: https://www.gpo.gov/fdsys/pkg/BILLS-<br />

113hr2642enr/pdf/BILLS-113hr2642enr.pdf<br />

[4] N.N.: USDA Loans and Grants, http://www.biopreferred.gov/BioPreferred/<br />

faces/pages/USDALoansAndGrants.xhtml<br />

40 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


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IWKS, Alzenau und Hanau<br />

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Basics<br />

Glossary 4.1 last update issue 04/2<strong>01</strong>5<br />

In bioplastics MAGAZINE again and again<br />

the same expressions appear that some of our readers<br />

might not (yet) be familiar with. This glossary shall help<br />

with these terms and shall help avoid repeated explanations<br />

such as PLA (Polylactide) in various articles.<br />

Bioplastics (as defined by European Bioplastics<br />

e.V.) is a term used to define two different<br />

kinds of plastics:<br />

a. Plastics based on → renewable resources<br />

(the focus is the origin of the raw material<br />

used). These can be biodegradable or not.<br />

b. → Biodegradable and → compostable<br />

plastics according to EN13432 or similar<br />

standards (the focus is the compostability of<br />

the final product; biodegradable and compostable<br />

plastics can be based on renewable<br />

(biobased) and/or non-renewable (fossil) resources).<br />

Bioplastics may be<br />

- based on renewable resources and biodegradable;<br />

- based on renewable resources but not be<br />

biodegradable; and<br />

- based on fossil resources and biodegradable.<br />

1 st Generation feedstock | Carbohydrate rich<br />

plants such as corn or sugar cane that can<br />

also be used as food or animal feed are called<br />

food crops or 1 st generation feedstock. Bred<br />

my mankind over centuries for highest energy<br />

efficiency, currently, 1 st generation feedstock<br />

is the most efficient feedstock for the production<br />

of bioplastics as it requires the least<br />

amount of land to grow and produce the highest<br />

yields. [bM 04/09]<br />

2 nd Generation feedstock | refers to feedstock<br />

not suitable for food or feed. It can be either<br />

non-food crops (e.g. cellulose) or waste materials<br />

from 1 st generation feedstock (e.g.<br />

waste vegetable oil). [bM 06/11]<br />

3 rd Generation feedstock | This term currently<br />

relates to biomass from algae, which<br />

– having a higher growth yield than 1 st and 2 nd<br />

generation feedstock – were given their own<br />

category.<br />

Aerobic digestion | Aerobic means in the<br />

presence of oxygen. In →composting, which is<br />

an aerobic process, →microorganisms access<br />

the present oxygen from the surrounding atmosphere.<br />

They metabolize the organic material<br />

to energy, CO 2<br />

, water and cell biomass,<br />

whereby part of the energy of the organic material<br />

is released as heat. [bM 03/07, bM 02/09]<br />

Since this Glossary will not be printed<br />

in each issue you can download a pdf version<br />

from our website (bit.ly/OunBB0)<br />

bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />

Version 4.0 was revised using EuBP’s latest version (Jan 2<strong>01</strong>5).<br />

[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />

Anaerobic digestion | In anaerobic digestion,<br />

organic matter is degraded by a microbial<br />

population in the absence of oxygen<br />

and producing methane and carbon dioxide<br />

(= →biogas) and a solid residue that can be<br />

composted in a subsequent step without<br />

practically releasing any heat. The biogas can<br />

be treated in a Combined Heat and Power<br />

Plant (CHP), producing electricity and heat, or<br />

can be upgraded to bio-methane [14] [bM 06/09]<br />

Amorphous | non-crystalline, glassy with unordered<br />

lattice<br />

Amylopectin | Polymeric branched starch<br />

molecule with very high molecular weight<br />

(biopolymer, monomer is →Glucose) [bM 05/09]<br />

Amylose | Polymeric non-branched starch<br />

molecule with high molecular weight (biopolymer,<br />

monomer is →Glucose) [bM 05/09]<br />

Biobased | The term biobased describes the<br />

part of a material or product that is stemming<br />

from →biomass. When making a biobasedclaim,<br />

the unit (→biobased carbon content,<br />

→biobased mass content), a percentage and<br />

the measuring method should be clearly stated [1]<br />

Biobased carbon | carbon contained in or<br />

stemming from →biomass. A material or<br />

product made of fossil and →renewable resources<br />

contains fossil and →biobased carbon.<br />

The biobased carbon content is measured via<br />

the 14 C method (radio carbon dating method)<br />

that adheres to the technical specifications as<br />

described in [1,4,5,6].<br />

Biobased labels | The fact that (and to<br />

what percentage) a product or a material is<br />

→biobased can be indicated by respective<br />

labels. Ideally, meaningful labels should be<br />

based on harmonised standards and a corresponding<br />

certification process by independent<br />

third party institutions. For the property<br />

biobased such labels are in place by certifiers<br />

→DIN CERTCO and →Vinçotte who both base<br />

their certifications on the technical specification<br />

as described in [4,5]<br />

A certification and corresponding label depicting<br />

the biobased mass content was developed<br />

by the French Association Chimie du Végétal<br />

[ACDV].<br />

Biobased mass content | describes the<br />

amount of biobased mass contained in a material<br />

or product. This method is complementary<br />

to the 14 C method, and furthermore, takes<br />

other chemical elements besides the biobased<br />

carbon into account, such as oxygen, nitrogen<br />

and hydrogen. A measuring method has<br />

been developed and tested by the Association<br />

Chimie du Végétal (ACDV) [1]<br />

Biobased plastic | A plastic in which constitutional<br />

units are totally or partly from →<br />

biomass [3]. If this claim is used, a percentage<br />

should always be given to which extent<br />

the product/material is → biobased [1]<br />

[bM <strong>01</strong>/07, bM 03/10]<br />

Biodegradable Plastics | Biodegradable Plastics<br />

are plastics that are completely assimilated<br />

by the → microorganisms present a defined<br />

environment as food for their energy. The<br />

carbon of the plastic must completely be converted<br />

into CO 2<br />

during the microbial process.<br />

The process of biodegradation depends on<br />

the environmental conditions, which influence<br />

it (e.g. location, temperature, humidity) and<br />

on the material or application itself. Consequently,<br />

the process and its outcome can vary<br />

considerably. Biodegradability is linked to the<br />

structure of the polymer chain; it does not depend<br />

on the origin of the raw materials.<br />

There is currently no single, overarching standard<br />

to back up claims about biodegradability.<br />

One standard for example is ISO or in Europe:<br />

EN 14995 Plastics- Evaluation of compostability<br />

- Test scheme and specifications<br />

[bM 02/06, bM <strong>01</strong>/07]<br />

Biogas | → Anaerobic digestion<br />

Biomass | Material of biological origin excluding<br />

material embedded in geological formations<br />

and material transformed to fossilised<br />

material. This includes organic material, e.g.<br />

trees, crops, grasses, tree litter, algae and<br />

waste of biological origin, e.g. manure [1, 2]<br />

Biorefinery | the co-production of a spectrum<br />

of bio-based products (food, feed, materials,<br />

chemicals including monomers or building<br />

blocks for bioplastics) and energy (fuels, power,<br />

heat) from biomass.[bM 02/13]<br />

Blend | Mixture of plastics, polymer alloy of at<br />

least two microscopically dispersed and molecularly<br />

distributed base polymers<br />

Bisphenol-A (BPA) | Monomer used to produce<br />

different polymers. BPA is said to cause<br />

health problems, due to the fact that is behaves<br />

like a hormone. Therefore it is banned<br />

for use in children’s products in many countries.<br />

BPI | Biodegradable Products Institute, a notfor-profit<br />

association. Through their innovative<br />

compostable label program, BPI educates<br />

manufacturers, legislators and consumers<br />

about the importance of scientifically based<br />

standards for compostable materials which<br />

biodegrade in large composting facilities.<br />

Carbon footprint | (CFPs resp. PCFs – Product<br />

Carbon Footprint): Sum of →greenhouse<br />

gas emissions and removals in a product system,<br />

expressed as CO 2<br />

equivalent, and based<br />

on a →life cycle assessment. The CO 2<br />

equivalent<br />

of a specific amount of a greenhouse gas<br />

is calculated as the mass of a given greenhouse<br />

gas multiplied by its →global warmingpotential<br />

[1,2,15]<br />

42 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Basics<br />

Carbon neutral, CO 2<br />

neutral | describes a<br />

product or process that has a negligible impact<br />

on total atmospheric CO 2<br />

levels. For<br />

example, carbon neutrality means that any<br />

CO 2<br />

released when a plant decomposes or<br />

is burnt is offset by an equal amount of CO 2<br />

absorbed by the plant through photosynthesis<br />

when it is growing.<br />

Carbon neutrality can also be achieved<br />

through buying sufficient carbon credits to<br />

make up the difference. The latter option is<br />

not allowed when communicating → LCAs<br />

or carbon footprints regarding a material or<br />

product [1, 2].<br />

Carbon-neutral claims are tricky as products<br />

will not in most cases reach carbon neutrality<br />

if their complete life cycle is taken into consideration<br />

(including the end-of life).<br />

If an assessment of a material, however, is<br />

conducted (cradle to gate), carbon neutrality<br />

might be a valid claim in a B2B context. In this<br />

case, the unit assessed in the complete life<br />

cycle has to be clarified [1]<br />

Cascade use | of →renewable resources means<br />

to first use the →biomass to produce biobased<br />

industrial products and afterwards – due to<br />

their favourable energy balance – use them<br />

for energy generation (e.g. from a biobased<br />

plastic product to →biogas production). The<br />

feedstock is used efficiently and value generation<br />

increases decisively.<br />

Catalyst | substance that enables and accelerates<br />

a chemical reaction<br />

Cellophane | Clear film on the basis of →cellulose<br />

[bM <strong>01</strong>/10]<br />

Cellulose | Cellulose is the principal component<br />

of cell walls in all higher forms of plant<br />

life, at varying percentages. It is therefore the<br />

most common organic compound and also<br />

the most common polysaccharide (multisugar)<br />

[11]. Cellulose is a polymeric molecule<br />

with very high molecular weight (monomer is<br />

→Glucose), industrial production from wood<br />

or cotton, to manufacture paper, plastics and<br />

fibres [bM <strong>01</strong>/10]<br />

Cellulose ester | Cellulose esters occur by<br />

the esterification of cellulose with organic acids.<br />

The most important cellulose esters from<br />

a technical point of view are cellulose acetate<br />

(CA with acetic acid), cellulose propionate<br />

(CP with propionic acid) and cellulose butyrate<br />

(CB with butanoic acid). Mixed polymerisates,<br />

such as cellulose acetate propionate<br />

(CAP) can also be formed. One of the most<br />

well-known applications of cellulose aceto<br />

butyrate (CAB) is the moulded handle on the<br />

Swiss army knife [11]<br />

Cellulose acetate CA | → Cellulose ester<br />

CEN | Comité Européen de Normalisation<br />

(European organisation for standardization)<br />

Certification | is a process in which materials/products<br />

undergo a string of (laboratory)<br />

tests in order to verify that the fulfil certain<br />

requirements. Sound certification systems<br />

should be based on (ideally harmonised) European<br />

standards or technical specifications<br />

(e.g. by →CEN, USDA, ASTM, etc.) and be<br />

performed by independent third party laboratories.<br />

Successful certification guarantees<br />

a high product safety - also on this basis interconnected<br />

labels can be awarded that help<br />

the consumer to make an informed decision.<br />

Compost | A soil conditioning material of decomposing<br />

organic matter which provides nutrients<br />

and enhances soil structure.<br />

[bM 06/08, 02/09]<br />

Compostable Plastics | Plastics that are<br />

→ biodegradable under →composting conditions:<br />

specified humidity, temperature,<br />

→ microorganisms and timeframe. In order<br />

to make accurate and specific claims about<br />

compostability, the location (home, → industrial)<br />

and timeframe need to be specified [1].<br />

Several national and international standards<br />

exist for clearer definitions, for example EN<br />

14995 Plastics - Evaluation of compostability -<br />

Test scheme and specifications. [bM 02/06, bM <strong>01</strong>/07]<br />

Composting | is the controlled →aerobic, or<br />

oxygen-requiring, decomposition of organic<br />

materials by →microorganisms, under controlled<br />

conditions. It reduces the volume and<br />

mass of the raw materials while transforming<br />

them into CO 2<br />

, water and a valuable soil conditioner<br />

– compost.<br />

When talking about composting of bioplastics,<br />

foremost →industrial composting in a<br />

managed composting facility is meant (criteria<br />

defined in EN 13432).<br />

The main difference between industrial and<br />

home composting is, that in industrial composting<br />

facilities temperatures are much<br />

higher and kept stable, whereas in the composting<br />

pile temperatures are usually lower,<br />

and less constant as depending on factors<br />

such as weather conditions. Home composting<br />

is a way slower-paced process than<br />

industrial composting. Also a comparatively<br />

smaller volume of waste is involved. [bM 03/07]<br />

Compound | plastic mixture from different<br />

raw materials (polymer and additives) [bM 04/10)<br />

Copolymer | Plastic composed of different<br />

monomers.<br />

Cradle-to-Gate | Describes the system<br />

boundaries of an environmental →Life Cycle<br />

Assessment (LCA) which covers all activities<br />

from the cradle (i.e., the extraction of raw materials,<br />

agricultural activities and forestry) up<br />

to the factory gate<br />

Cradle-to-Cradle | (sometimes abbreviated<br />

as C2C): Is an expression which communicates<br />

the concept of a closed-cycle economy,<br />

in which waste is used as raw material<br />

(‘waste equals food’). Cradle-to-Cradle is not<br />

a term that is typically used in →LCA studies.<br />

Cradle-to-Grave | Describes the system<br />

boundaries of a full →Life Cycle Assessment<br />

from manufacture (cradle) to use phase and<br />

disposal phase (grave).<br />

Crystalline | Plastic with regularly arranged<br />

molecules in a lattice structure<br />

Density | Quotient from mass and volume of<br />

a material, also referred to as specific weight<br />

DIN | Deutsches Institut für Normung (German<br />

organisation for standardization)<br />

DIN-CERTCO | independant certifying organisation<br />

for the assessment on the conformity<br />

of bioplastics<br />

Dispersing | fine distribution of non-miscible<br />

liquids into a homogeneous, stable mixture<br />

Drop-In bioplastics | chemically indentical<br />

to conventional petroleum based plastics,<br />

but made from renewable resources. Examples<br />

are bio-PE made from bio-ethanol (from<br />

e.g. sugar cane) or partly biobased PET; the<br />

monoethylene glykol made from bio-ethanol<br />

(from e.g. sugar cane). Developments to<br />

make terephthalic acid from renewable resources<br />

are under way. Other examples are<br />

polyamides (partly biobased e.g. PA 4.10 or PA<br />

6.10 or fully biobased like PA 5.10 or PA10.10)<br />

EN 13432 | European standard for the assessment<br />

of the → compostability of plastic<br />

packaging products<br />

Energy recovery | recovery and exploitation<br />

of the energy potential in (plastic) waste for<br />

the production of electricity or heat in waste<br />

incineration pants (waste-to-energy)<br />

Environmental claim | A statement, symbol<br />

or graphic that indicates one or more environmental<br />

aspect(s) of a product, a component,<br />

packaging or a service. [16]<br />

Enzymes | proteins that catalyze chemical<br />

reactions<br />

Enzyme-mediated plastics | are no →bioplastics.<br />

Instead, a conventional non-biodegradable<br />

plastic (e.g. fossil-based PE) is enriched<br />

with small amounts of an organic additive.<br />

Microorganisms are supposed to consume<br />

these additives and the degradation process<br />

should then expand to the non-biodegradable<br />

PE and thus make the material degrade. After<br />

some time the plastic is supposed to visually<br />

disappear and to be completely converted to<br />

carbon dioxide and water. This is a theoretical<br />

concept which has not been backed up by<br />

any verifiable proof so far. Producers promote<br />

enzyme-mediated plastics as a solution to littering.<br />

As no proof for the degradation process<br />

has been provided, environmental beneficial<br />

effects are highly questionable.<br />

Ethylene | colour- and odourless gas, made<br />

e.g. from, Naphtha (petroleum) by cracking or<br />

from bio-ethanol by dehydration, monomer of<br />

the polymer polyethylene (PE)<br />

European Bioplastics e.V. | The industry association<br />

representing the interests of Europe’s<br />

thriving bioplastics’ industry. Founded<br />

in Germany in 1993 as IBAW, European<br />

Bioplastics today represents the interests<br />

of about 50 member companies throughout<br />

the European Union and worldwide. With<br />

members from the agricultural feedstock,<br />

chemical and plastics industries, as well as<br />

industrial users and recycling companies, European<br />

Bioplastics serves as both a contact<br />

platform and catalyst for advancing the aims<br />

of the growing bioplastics industry.<br />

Extrusion | process used to create plastic<br />

profiles (or sheet) of a fixed cross-section<br />

consisting of mixing, melting, homogenising<br />

and shaping of the plastic.<br />

FDCA | 2,5-furandicarboxylic acid, an intermediate<br />

chemical produced from 5-HMF.<br />

The dicarboxylic acid can be used to make →<br />

PEF = polyethylene furanoate, a polyester that<br />

could be a 100% biobased alternative to PET.<br />

Fermentation | Biochemical reactions controlled<br />

by → microorganisms or → enyzmes (e.g. the<br />

transformation of sugar into lactic acid).<br />

FSC | Forest Stewardship Council. FSC is an<br />

independent, non-governmental, not-forprofit<br />

organization established to promote the<br />

responsible and sustainable management of<br />

the world’s forests.<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 43


Basics<br />

Gelatine | Translucent brittle solid substance,<br />

colorless or slightly yellow, nearly tasteless<br />

and odorless, extracted from the collagen inside<br />

animals‘ connective tissue.<br />

Genetically modified organism (GMO) |<br />

Organisms, such as plants and animals,<br />

whose genetic material (DNA) has been altered<br />

are called genetically modified organisms<br />

(GMOs). Food and feed which contain<br />

or consist of such GMOs, or are produced<br />

from GMOs, are called genetically modified<br />

(GM) food or feed [1]. If GM crops are used<br />

in bioplastics production, the multiple-stage<br />

processing and the high heat used to create<br />

the polymer removes all traces of genetic<br />

material. This means that the final bioplastics<br />

product contains no genetic traces. The<br />

resulting bioplastics is therefore well suited<br />

to use in food packaging as it contains no genetically<br />

modified material and cannot interact<br />

with the contents.<br />

Global Warming | Global warming is the rise<br />

in the average temperature of Earth’s atmosphere<br />

and oceans since the late 19th century<br />

and its projected continuation [8]. Global<br />

warming is said to be accelerated by → green<br />

house gases.<br />

Glucose | Monosaccharide (or simple sugar).<br />

G. is the most important carbohydrate (sugar)<br />

in biology. G. is formed by photosynthesis or<br />

hydrolyse of many carbohydrates e. g. starch.<br />

Greenhouse gas GHG | Gaseous constituent<br />

of the atmosphere, both natural and anthropogenic,<br />

that absorbs and emits radiation at<br />

specific wavelengths within the spectrum of<br />

infrared radiation emitted by the earth’s surface,<br />

the atmosphere, and clouds [1, 9]<br />

Greenwashing | The act of misleading consumers<br />

regarding the environmental practices<br />

of a company, or the environmental benefits<br />

of a product or service [1, 10]<br />

Granulate, granules | small plastic particles<br />

(3-4 millimetres), a form in which plastic is<br />

sold and fed into machines, easy to handle<br />

and dose.<br />

HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />

organic compound derived from sugar dehydration.<br />

It is a platform chemical, a building<br />

block for 20 performance polymers and over<br />

175 different chemical substances. The molecule<br />

consists of a furan ring which contains<br />

both aldehyde and alcohol functional groups.<br />

5-HMF has applications in many different<br />

industries such as bioplastics, packaging,<br />

pharmaceuticals, adhesives and chemicals.<br />

One of the most promising routes is 2,5 furandicarboxylic<br />

acid (FDCA), produced as an intermediate<br />

when 5-HMF is oxidised. FDCA is<br />

used to produce PEF, which can substitute<br />

terephthalic acid in polyester, especially polyethylene<br />

terephthalate (PET). [bM 03/14]<br />

Home composting | →composting [bM 06/08]<br />

Humus | In agriculture, humus is often used<br />

simply to mean mature →compost, or natural<br />

compost extracted from a forest or other<br />

spontaneous source for use to amend soil.<br />

Hydrophilic | Property: water-friendly, soluble<br />

in water or other polar solvents (e.g. used<br />

in conjunction with a plastic which is not water<br />

resistant and weather proof or that absorbs<br />

water such as Polyamide (PA).<br />

Hydrophobic | Property: water-resistant, not<br />

soluble in water (e.g. a plastic which is water<br />

resistant and weather proof, or that does not<br />

absorb any water such as Polyethylene (PE)<br />

or Polypropylene (PP).<br />

Industrial composting | is an established process<br />

with commonly agreed upon requirements<br />

(e.g. temperature, timeframe) for transforming<br />

biodegradable waste into stable, sanitised<br />

products to be used in agriculture. The criteria<br />

for industrial compostability of packaging have<br />

been defined in the EN 13432. Materials and<br />

products complying with this standard can be<br />

certified and subsequently labelled accordingly<br />

[1,7] [bM 06/08, 02/09]<br />

ISO | International Organization for Standardization<br />

JBPA | Japan Bioplastics Association<br />

Land use | The surface required to grow sufficient<br />

feedstock (land use) for today’s bioplastic<br />

production is less than 0.<strong>01</strong> percent of the<br />

global agricultural area of 5 billion hectares.<br />

It is not yet foreseeable to what extent an increased<br />

use of food residues, non-food crops<br />

or cellulosic biomass (see also →1 st /2 nd /3 rd<br />

generation feedstock) in bioplastics production<br />

might lead to an even further reduced<br />

land use in the future [bM 04/09, <strong>01</strong>/14]<br />

LCA | is the compilation and evaluation of the<br />

input, output and the potential environmental<br />

impact of a product system throughout its life<br />

cycle [17]. It is sometimes also referred to as<br />

life cycle analysis, ecobalance or cradle-tograve<br />

analysis. [bM <strong>01</strong>/09]<br />

Littering | is the (illegal) act of leaving waste<br />

such as cigarette butts, paper, tins, bottles,<br />

cups, plates, cutlery or bags lying in an open<br />

or public place.<br />

Marine litter | Following the European Commission’s<br />

definition, “marine litter consists of<br />

items that have been deliberately discarded,<br />

unintentionally lost, or transported by winds<br />

and rivers, into the sea and on beaches. It<br />

mainly consists of plastics, wood, metals,<br />

glass, rubber, clothing and paper”. Marine<br />

debris originates from a variety of sources.<br />

Shipping and fishing activities are the predominant<br />

sea-based, ineffectively managed<br />

landfills as well as public littering the main<br />

land-based sources. Marine litter can pose a<br />

threat to living organisms, especially due to<br />

ingestion or entanglement.<br />

Currently, there is no international standard<br />

available, which appropriately describes the<br />

biodegradation of plastics in the marine environment.<br />

However, a number of standardisation<br />

projects are in progress at ISO and ASTM<br />

level. Furthermore, the European project<br />

OPEN BIO addresses the marine biodegradation<br />

of biobased products.<br />

Mass balance | describes the relationship between<br />

input and output of a specific substance<br />

within a system in which the output from the<br />

system cannot exceed the input into the system.<br />

First attempts were made by plastic raw material<br />

producers to claim their products renewable<br />

(plastics) based on a certain input<br />

of biomass in a huge and complex chemical<br />

plant, then mathematically allocating this<br />

biomass input to the produced plastic.<br />

These approaches are at least controversially<br />

disputed [bM 04/14, 05/14, <strong>01</strong>/15]<br />

Microorganism | Living organisms of microscopic<br />

size, such as bacteria, funghi or yeast.<br />

Molecule | group of at least two atoms held<br />

together by covalent chemical bonds.<br />

Monomer | molecules that are linked by polymerization<br />

to form chains of molecules and<br />

then plastics<br />

Mulch film | Foil to cover bottom of farmland<br />

Organic recycling | means the treatment of<br />

separately collected organic waste by anaerobic<br />

digestion and/or composting.<br />

Oxo-degradable / Oxo-fragmentable | materials<br />

and products that do not biodegrade!<br />

The underlying technology of oxo-degradability<br />

or oxo-fragmentation is based on special additives,<br />

which, if incorporated into standard<br />

resins, are purported to accelerate the fragmentation<br />

of products made thereof. Oxodegradable<br />

or oxo-fragmentable materials do<br />

not meet accepted industry standards on compostability<br />

such as EN 13432. [bM <strong>01</strong>/09, 05/09]<br />

PBAT | Polybutylene adipate terephthalate, is<br />

an aliphatic-aromatic copolyester that has the<br />

properties of conventional polyethylene but is<br />

fully biodegradable under industrial composting.<br />

PBAT is made from fossil petroleum with<br />

first attempts being made to produce it partly<br />

from renewable resources [bM 06/09]<br />

PBS | Polybutylene succinate, a 100% biodegradable<br />

polymer, made from (e.g. bio-BDO)<br />

and succinic acid, which can also be produced<br />

biobased [bM 03/12].<br />

PC | Polycarbonate, thermoplastic polyester,<br />

petroleum based and not degradable, used<br />

for e.g. baby bottles or CDs. Criticized for its<br />

BPA (→ Bisphenol-A) content.<br />

PCL | Polycaprolactone, a synthetic (fossil<br />

based), biodegradable bioplastic, e.g. used as<br />

a blend component.<br />

PE | Polyethylene, thermoplastic polymerised<br />

from ethylene. Can be made from renewable<br />

resources (sugar cane via bio-ethanol) [bM 05/10]<br />

PEF | polyethylene furanoate, a polyester<br />

made from monoethylene glycol (MEG) and<br />

→FDCA (2,5-furandicarboxylic acid , an intermediate<br />

chemical produced from 5-HMF). It<br />

can be a 100% biobased alternative for PET.<br />

PEF also has improved product characteristics,<br />

such as better structural strength and<br />

improved barrier behaviour, which will allow<br />

for the use of PEF bottles in additional applications.<br />

[bM 03/11, 04/12]<br />

PET | Polyethylenterephthalate, transparent<br />

polyester used for bottles and film. The<br />

polyester is made from monoethylene glycol<br />

(MEG), that can be renewably sourced from<br />

bio-ethanol (sugar cane) and (until now fossil)<br />

terephthalic acid [bM 04/14]<br />

PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />

thermoplastic polymer and the<br />

simplest linear, aliphatic polyester. Besides<br />

ist use in the biomedical field, PGA has been<br />

introduced as a barrier resin [bM 03/09]<br />

PHA | Polyhydroxyalkanoates (PHA) or the<br />

polyhydroxy fatty acids, are a family of biodegradable<br />

polyesters. As in many mammals,<br />

including humans, that hold energy reserves<br />

in the form of body fat there are also bacteria<br />

that hold intracellular reserves in for of<br />

of polyhydroxy alkanoates. Here the microorganisms<br />

store a particularly high level of<br />

44 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Basics<br />

energy reserves (up to 80% of their own body<br />

weight) for when their sources of nutrition become<br />

scarce. By farming this type of bacteria,<br />

and feeding them on sugar or starch (mostly<br />

from maize), or at times on plant oils or other<br />

nutrients rich in carbonates, it is possible to<br />

obtain PHA‘s on an industrial scale [11]. The<br />

most common types of PHA are PHB (Polyhydroxybutyrate,<br />

PHBV and PHBH. Depending<br />

on the bacteria and their food, PHAs with<br />

different mechanical properties, from rubbery<br />

soft trough stiff and hard as ABS, can be produced.<br />

Some PHSs are even biodegradable in<br />

soil or in a marine environment<br />

PLA | Polylactide or Polylactic Acid (PLA), a<br />

biodegradable, thermoplastic, linear aliphatic<br />

polyester based on lactic acid, a natural acid,<br />

is mainly produced by fermentation of sugar<br />

or starch with the help of micro-organisms.<br />

Lactic acid comes in two isomer forms, i.e. as<br />

laevorotatory D(-)lactic acid and as dextrorotary<br />

L(+)lactic acid.<br />

Modified PLA types can be produced by the<br />

use of the right additives or by certain combinations<br />

of L- and D- lactides (stereocomplexing),<br />

which then have the required rigidity for<br />

use at higher temperatures [13] [bM <strong>01</strong>/09, <strong>01</strong>/12]<br />

Plastics | Materials with large molecular<br />

chains of natural or fossil raw materials, produced<br />

by chemical or biochemical reactions.<br />

PPC | Polypropylene Carbonate, a bioplastic<br />

made by copolymerizing CO 2<br />

with propylene<br />

oxide (PO) [bM 04/12]<br />

PTT | Polytrimethylterephthalate (PTT), partially<br />

biobased polyester, is similarly to PET<br />

produced using terephthalic acid or dimethyl<br />

terephthalate and a diol. In this case it is a<br />

biobased 1,3 propanediol, also known as bio-<br />

PDO [bM <strong>01</strong>/13]<br />

Renewable Resources | agricultural raw materials,<br />

which are not used as food or feed,<br />

but as raw material for industrial products<br />

or to generate energy. The use of renewable<br />

resources by industry saves fossil resources<br />

and reduces the amount of → greenhouse gas<br />

emissions. Biobased plastics are predominantly<br />

made of annual crops such as corn,<br />

cereals and sugar beets or perennial cultures<br />

such as cassava and sugar cane.<br />

Resource efficiency | Use of limited natural<br />

resources in a sustainable way while minimising<br />

impacts on the environment. A resource<br />

efficient economy creates more output<br />

or value with lesser input.<br />

Seedling Logo | The compostability label or<br />

logo Seedling is connected to the standard<br />

EN 13432/EN 14995 and a certification process<br />

managed by the independent institutions<br />

→DIN CERTCO and → Vinçotte. Bioplastics<br />

products carrying the Seedling fulfil the criteria<br />

laid down in the EN 13432 regarding industrial<br />

compostability. [bM <strong>01</strong>/06, 02/10]<br />

Saccharins or carbohydrates | Saccharins or<br />

carbohydrates are name for the sugar-family.<br />

Saccharins are monomer or polymer sugar<br />

units. For example, there are known mono-,<br />

di- and polysaccharose. → glucose is a monosaccarin.<br />

They are important for the diet and<br />

produced biology in plants.<br />

Semi-finished products | plastic in form of<br />

sheet, film, rods or the like to be further processed<br />

into finshed products<br />

Sorbitol | Sugar alcohol, obtained by reduction<br />

of glucose changing the aldehyde group<br />

to an additional hydroxyl group. S. is used as<br />

a plasticiser for bioplastics based on starch.<br />

Starch | Natural polymer (carbohydrate)<br />

consisting of → amylose and → amylopectin,<br />

gained from maize, potatoes, wheat, tapioca<br />

etc. When glucose is connected to polymerchains<br />

in definite way the result (product) is<br />

called starch. Each molecule is based on 300<br />

-12000-glucose units. Depending on the connection,<br />

there are two types → amylose and →<br />

amylopectin known. [bM 05/09]<br />

Starch derivatives | Starch derivatives are<br />

based on the chemical structure of → starch.<br />

The chemical structure can be changed by<br />

introducing new functional groups without<br />

changing the → starch polymer. The product<br />

has different chemical qualities. Mostly the<br />

hydrophilic character is not the same.<br />

Starch-ester | One characteristic of every<br />

starch-chain is a free hydroxyl group. When<br />

every hydroxyl group is connected with an<br />

acid one product is starch-ester with different<br />

chemical properties.<br />

Starch propionate and starch butyrate |<br />

Starch propionate and starch butyrate can be<br />

synthesised by treating the → starch with propane<br />

or butanic acid. The product structure<br />

is still based on → starch. Every based → glucose<br />

fragment is connected with a propionate<br />

or butyrate ester group. The product is more<br />

hydrophobic than → starch.<br />

Sustainable | An attempt to provide the best<br />

outcomes for the human and natural environments<br />

both now and into the indefinite future.<br />

One famous definition of sustainability is the<br />

one created by the Brundtland Commission,<br />

led by the former Norwegian Prime Minister<br />

G. H. Brundtland. The Brundtland Commission<br />

defined sustainable development as<br />

development that ‘meets the needs of the<br />

present without compromising the ability of<br />

future generations to meet their own needs.’<br />

Sustainability relates to the continuity of economic,<br />

social, institutional and environmental<br />

aspects of human society, as well as the nonhuman<br />

environment).<br />

Sustainable sourcing | of renewable feedstock<br />

for biobased plastics is a prerequisite<br />

for more sustainable products. Impacts such<br />

as the deforestation of protected habitats<br />

or social and environmental damage arising<br />

from poor agricultural practices must<br />

be avoided. Corresponding certification<br />

schemes, such as ISCC PLUS, WLC or Bon-<br />

Sucro, are an appropriate tool to ensure the<br />

sustainable sourcing of biomass for all applications<br />

around the globe.<br />

Sustainability | as defined by European Bioplastics,<br />

has three dimensions: economic, social<br />

and environmental. This has been known<br />

as “the triple bottom line of sustainability”.<br />

This means that sustainable development involves<br />

the simultaneous pursuit of economic<br />

prosperity, environmental protection and social<br />

equity. In other words, businesses have<br />

to expand their responsibility to include these<br />

environmental and social dimensions. Sustainability<br />

is about making products useful to<br />

markets and, at the same time, having societal<br />

benefits and lower environmental impact<br />

than the alternatives currently available. It also<br />

implies a commitment to continuous improvement<br />

that should result in a further reduction<br />

of the environmental footprint of today’s products,<br />

processes and raw materials used.<br />

Thermoplastics | Plastics which soften or<br />

melt when heated and solidify when cooled<br />

(solid at room temperature).<br />

Thermoplastic Starch | (TPS) → starch that<br />

was modified (cooked, complexed) to make it<br />

a plastic resin<br />

Thermoset | Plastics (resins) which do not<br />

soften or melt when heated. Examples are<br />

epoxy resins or unsaturated polyester resins.<br />

Vinçotte | independant certifying organisation<br />

for the assessment on the conformity of bioplastics<br />

WPC | Wood Plastic Composite. Composite<br />

materials made of wood fiber/flour and plastics<br />

(mostly polypropylene).<br />

Yard Waste | Grass clippings, leaves, trimmings,<br />

garden residue.<br />

References:<br />

[1] Environmental Communication Guide,<br />

European Bioplastics, Berlin, Germany,<br />

2<strong>01</strong>2<br />

[2] ISO 14067. Carbon footprint of products -<br />

Requirements and guidelines for quantification<br />

and communication<br />

[3] CEN TR 15932, Plastics - Recommendation<br />

for terminology and characterisation<br />

of biopolymers and bioplastics, 2<strong>01</strong>0<br />

[4] CEN/TS 16137, Plastics - Determination<br />

of bio-based carbon content, 2<strong>01</strong>1<br />

[5] ASTM D6866, Standard Test Methods for<br />

Determining the Biobased Content of<br />

Solid, Liquid, and Gaseous Samples Using<br />

Radiocarbon Analysis<br />

[6] SPI: Understanding Biobased Carbon<br />

Content, 2<strong>01</strong>2<br />

[7] EN 13432, Requirements for packaging<br />

recoverable through composting and biodegradation.<br />

Test scheme and evaluation<br />

criteria for the final acceptance of packaging,<br />

2000<br />

[8] Wikipedia<br />

[9] ISO 14064 Greenhouse gases -- Part 1:<br />

Specification with guidance..., 2006<br />

[10] Terrachoice, 2<strong>01</strong>0, www.terrachoice.com<br />

[11] Thielen, M.: Bioplastics: Basics. Applications.<br />

Markets, Polymedia Publisher,<br />

2<strong>01</strong>2<br />

[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />

FNR, 2005<br />

[13] de Vos, S.: Improving heat-resistance of<br />

PLA using poly(D-lactide),<br />

bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />

[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />

MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />

[15] ISO 14067 onb Corbon Footprint of<br />

Products<br />

[16] ISO 14021 on Self-declared Environmental<br />

claims<br />

[17] ISO 14044 on Life Cycle Assessment<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 45


Suppliers Guide<br />

1. Raw Materials<br />

AGRANA Starch<br />

Thermoplastics<br />

Conrathstrasse 7<br />

A-3950 Gmuend, Austria<br />

Tel: +43 676 8926 19374<br />

lukas.raschbauer@agrana.com<br />

www.agrana.com<br />

Evonik Industries AG<br />

Paul Baumann Straße 1<br />

45772 Marl, Germany<br />

Tel +49 2365 49-4717<br />

evonik-hp@evonik.com<br />

www.vestamid-terra.com<br />

www.evonik.com<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 510663<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.ecopond.com.cn<br />

FLEX-162 Biodeg. Blown Film Resin!<br />

Bio-873 4-Star Inj. Bio-Based Resin!<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Showa Denko Europe GmbH<br />

Konrad-Zuse-Platz 4<br />

81829 Munich, Germany<br />

Tel.: +49 89 93996226<br />

www.showa-denko.com<br />

support@sde.de<br />

Jincheng, Lin‘an, Hangzhou,<br />

Zhejiang 311300, P.R. China<br />

China contact: Grace Jin<br />

mobile: 0086 135 7578 9843<br />

Grace@xinfupharm.com<br />

Europe contact(Belgium): Susan Zhang<br />

mobile: 0032 478 991619<br />

zxh0612@hotmail.com<br />

www.xinfupharm.com<br />

1.1 bio based monomers<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel: +66(0) 2 140-3563<br />

MCPP Germany GmbH<br />

+49 (0) 152-<strong>01</strong>8 920 51<br />

frank.steinbrecher@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0) 6 07 22 25 32<br />

fabien.resweber@mcpp-europe.com<br />

Corbion Purac<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem -<br />

The Netherlands<br />

Tel.: +31 (0)183 695 695<br />

Fax: +31 (0)183 695 604<br />

www.corbion.com/bioplastics<br />

bioplastics@corbion.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

39 mm<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

DuPont de Nemours International S.A.<br />

2 chemin du Pavillon<br />

1218 - Le Grand Saconnex<br />

Switzerland<br />

Tel.: +41 22 171 51 11<br />

Fax: +41 22 580 22 45<br />

www.renewable.dupont.com<br />

www.plastics.dupont.com<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.ecoworld.jinhuigroup.com<br />

ecoworldsales@jinhuigroup.com<br />

62 136 Lestrem, France<br />

Tel.: + 33 (0) 3 21 63 36 00<br />

www.roquette-performance-plastics.com<br />

1.2 compounds<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36065 Mussolente (VI), Italy<br />

Telephone +39 0424 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50<strong>01</strong>6 Zaragoza, Spain<br />

Tel: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

www.polyone.com<br />

1.3 PLA<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

Shenzhen Esun Ind. Co;Ltd<br />

www.brightcn.net<br />

www.esun.en.alibaba.com<br />

bright@brightcn.net<br />

Tel: +86-755-2603 1978<br />

www.youtube.com<br />

46 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Suppliers Guide<br />

1.4 starch-based bioplastics<br />

Limagrain Céréales Ingrédients<br />

ZAC „Les Portes de Riom“ - BP 173<br />

63204 Riom Cedex - France<br />

Tel. +33 (0)4 73 67 17 00<br />

Fax +33 (0)4 73 67 17 10<br />

www.biolice.com<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

Grabio Greentech Corporation<br />

Tel: +886-3-598-6496<br />

No. 91, Guangfu N. Rd., Hsinchu<br />

Industrial Park,Hukou Township,<br />

Hsinchu County 30351, Taiwan<br />

sales@grabio.com.tw<br />

www.grabio.com.tw<br />

1.5 PHA<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

www.polyone.com<br />

2. Additives/Secondary raw materials<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

3. Semi finished products<br />

3.1 films<br />

Infiana Germany GmbH & Co. KG<br />

Zweibrückenstraße 15-25<br />

913<strong>01</strong> Forchheim<br />

Tel. +49-9191 81-0<br />

Fax +49-9191 81-212<br />

www.infiana.com<br />

Natur-Tec ® - Northern Technologies<br />

42<strong>01</strong> Woodland Road<br />

Circle Pines, MN 55<strong>01</strong>4 USA<br />

Tel. +1 763.404.8700<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.6<strong>01</strong><br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

President Packaging Ind., Corp.<br />

PLA Paper Hot Cup manufacture<br />

In Taiwan, www.ppi.com.tw<br />

Tel.: +886-6-570-4066 ext.5531<br />

Fax: +886-6-570-4077<br />

sales@ppi.com.tw<br />

6. Equipment<br />

6.1 Machinery & Molds<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

D-13509 Berlin<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

sales.de@uhde-inventa-fischer.com<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31<br />

CH-7<strong>01</strong>3 Domat/Ems<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

sales.ch@uhde-inventa-fischer.com<br />

www.uhde-inventa-fischer.com<br />

9. Services<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

Fax: +49 (0)208 8598 1424<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

7<strong>01</strong>99 Stuttgart<br />

Tel +49 711/685-62814<br />

Linda.Goebel@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

Metabolix, Inc.<br />

Bio-based and biodegradable resins<br />

and performance additives<br />

21 Erie Street<br />

Cambridge, MA 02139, USA<br />

US +1-617-583-1700<br />

DE +49 (0) 221 / 88 88 94 00<br />

www.metabolix.com<br />

info@metabolix.com<br />

1.6 masterbatches<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Taghleef Industries SpA, Italy<br />

Via E. Fermi, 46<br />

33058 San Giorgio di Nogaro (UD)<br />

Contact Emanuela Bardi<br />

Tel. +39 0431 627264<br />

Mobile +39 342 6565309<br />

emanuela.bardi@ti-films.com<br />

www.ti-films.com<br />

4. Bioplastics products<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, Marketing Manager<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima-tech.com<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel. +1 519 624 9720<br />

Fax +1 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

6.2 Laboratory Equipment<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6260<br />

Info2@moda.vg<br />

www.saidagroup.jp<br />

7. Plant engineering<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4052 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

E-Mail: contact@nova-institut.de<br />

www.biobased.eu<br />

Bioplastics Consulting<br />

Tel. +49 2161 664864<br />

info@polymediaconsult.com<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 47


Suppliers Guide<br />

9. Services (continued)<br />

UL International TTC GmbH<br />

Rheinuferstrasse 7-9, Geb. R33<br />

47829 Krefeld-Uerdingen, Germany<br />

Tel.: +49 (0) 2151 5370-333<br />

Fax: +49 (0) 2151 5370-334<br />

ttc@ul.com<br />

www.ulttc.com<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

1<strong>01</strong>17 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

10.2 Universities<br />

Michigan State University<br />

Department of Chemical<br />

Engineering & Materials Science<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

10.3 Other Institutions<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

10. Institutions<br />

10.1 Associations<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10<strong>01</strong>9, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

lisa.mundzeck@fh-hannover.de<br />

http://www.ifbb-hannover.de/<br />

Biobased Packaging Innovations<br />

Caroli Buitenhuis<br />

IJburglaan 836<br />

1087 EM Amsterdam<br />

The Netherlands<br />

Tel.: +31 6-24216733<br />

http://www.biobasedpackaging.nl<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

39 mm<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

‘Basics‘ book on bioplastics<br />

This book, created and published by Polymedia Publisher, maker<br />

of bioplastics MAGAZINE is available in English and German language<br />

(German now in the second, revised edition).<br />

The book is intended to offer a rapid and uncomplicated introduction<br />

into the subject of bioplastics, and is aimed at all interested readers, in<br />

particular those who have not yet had the opportunity to dig deeply into<br />

the subject, such as students or those just joining this industry, and lay<br />

readers. It gives an introduction to plastics and bioplastics, explains which<br />

renewable resources can be used to produce bioplastics, what types of bioplastic<br />

exist, and which ones are already on the market. Further aspects,<br />

such as market development, the agricultural land required, and waste<br />

disposal, are also examined.<br />

An extensive index allows the reader to find specific aspects quickly,<br />

and is complemented by a comprehensive literature list and a guide to<br />

sources of additional information on the Internet.<br />

The author Michael Thielen is editor and publisher bioplastics MAGA-<br />

ZINE. He is a qualified machinery design engineer with a degree in plastics<br />

technology from the RWTH University in Aachen. He has written<br />

several books on the subject of blow-moulding technology and disseminated<br />

his knowledge of plastics in numerous presentations, seminars,<br />

guest lectures and teaching assignments.<br />

110 pages full color, paperback<br />

ISBN 978-3-9814981-1-0: Bioplastics<br />

ISBN 978-3-9814981-2-7: Biokunststoffe<br />

neu: 2. überarbeitete Auflage<br />

Order now for € 18.65 or US-$ 25.00 (+ VAT where applicable, plus shipping and handling, ask for details)<br />

order at www.bioplasticsmagazine.de/books, by phone +49 2161 6884463 or by e-mail books@bioplasticsmagazine.com<br />

Or subscribe and get it as a free gift (see page 57 for details, outside German y only)<br />

48 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Events<br />

Subscribe<br />

now at<br />

Event<br />

Calendar<br />

ISSN 1862-5258<br />

bioplasticsmagazine.com<br />

the next six issues for €149.– 1)<br />

Nov / Dec<br />

06 | 2<strong>01</strong>5<br />

Highlights<br />

Films / Flexibles / Bags | 12<br />

Consumer Electronics | 24<br />

Basics<br />

Plastics from CO 2 | 50<br />

Special offer<br />

for students and<br />

young professionals<br />

1,2) € 99.-<br />

ISSN 1862-5258<br />

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or similar proof ...<br />

Basics<br />

Public Procurement | 34<br />

ISSN 1862-5258<br />

Highlights<br />

Automotive | 12<br />

Foam | 30<br />

Jan/Feb<br />

May 2006<br />

<strong>01</strong> | 2<strong>01</strong>6<br />

BioMass for Sustainable Future:<br />

Re-Invention of Polymeric Materials<br />

09.02.2<strong>01</strong>6 - 11.02.2<strong>01</strong>6 - Las Vegas, Nevada, USA<br />

www.BioPlastConference.com<br />

You can meet us<br />

Sustainable Plastics 2<strong>01</strong>6<br />

<strong>01</strong>.03.2<strong>01</strong>6 - 02.03.2<strong>01</strong>6 - Cologne, Germany<br />

www.amiplastics-na.com/events/Event.aspx?code=C706&sec=5459<br />

Plastics in Automotive Engineering<br />

09.03.2<strong>01</strong>6 - 10.03.2<strong>01</strong>6 - Mannheim, Germany<br />

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World Bio Markets<br />

14.03.2<strong>01</strong>6 - 17.03.2<strong>01</strong>6 - Amsterdam, The Netherlands<br />

www.worldbiomarkets.com<br />

Innovation Takes Root<br />

30.03.2<strong>01</strong>6 - <strong>01</strong>.04.2<strong>01</strong>6 - Orlando Florida, USA<br />

www.innovationtakesroot.com<br />

9 th International Conference on Biobased Materials<br />

05.04.2<strong>01</strong>6 - 06.04.2<strong>01</strong>6 - Cologne, Germany<br />

biowerkstoff-kongress.de<br />

Empack 2<strong>01</strong>6 (with Biobased Village)<br />

12.04.2<strong>01</strong>6 - 14.04.2<strong>01</strong>6 - Utrecht, The Netherlands<br />

bit.ly/1m03cuf<br />

3 rd Bioplastic Materials Topical Conference<br />

19.04.2<strong>01</strong>6 - 21.04.2<strong>01</strong>6 - Bloomington, (MN) USA<br />

www. www.eiseverywhere.com/ehome/130808?eb=227133<br />

Chinaplas 2<strong>01</strong>6<br />

25.04.2<strong>01</strong>6 - 28.04.2<strong>01</strong>6 - Shanghai, China<br />

bioplastics MAGAZINE Vol. 10<br />

Cover Story<br />

Shopping bags in Italy | 18<br />

bioplastics MAGAZINE Vol. 11<br />

Vol. 1<br />

... is read in 92 countries<br />

bioplastics magazine<br />

Top Talk:<br />

Interview with Helmut Traitler,<br />

VP Packaging of Nestlé | 10<br />

www.ChinaplasOnline.com<br />

4 th PLA World Congress<br />

organized by bioplastics MAGAZINE<br />

24 - 25. 05.2<strong>01</strong>6 - Munich, Germany<br />

www.pla-world-congress.com<br />

Biobased Products Europe<br />

25 - 26. 05.2<strong>01</strong>6 - Amsterdam, The Netherlands<br />

http://www.biobasedproductsworld.com/europe<br />

+<br />

or<br />

3 rd Bioplastics Buisness Breakfast K‘2<strong>01</strong>6<br />

organized by bioplastics MAGAZINE<br />

20 - 22.10.2<strong>01</strong>6 - Düsseldorf, Germany<br />

www.bioplastics-breakfast.com<br />

Mention the promotion code ‘watch‘ or ‘book‘<br />

and you will get our watch or the book 3)<br />

Bioplastics Basics. Applications. Markets. for free<br />

1) Offer valid until 30 April 2<strong>01</strong>6<br />

3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />

bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11 49


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

Agrana Starch Thermoplastics 46<br />

AIMPLAS 10<br />

Annellotech 6<br />

API 46<br />

Archer Daniels Midland 24<br />

Avantium 26<br />

Beologic 8<br />

BioAmber 7<br />

Biobased Packaging Innovations 48<br />

Bio-On 7, 28<br />

Biopolymer Network 30<br />

BioPreferred 38, 40<br />

Biotec 47<br />

BMEL 34<br />

BPI 28 48<br />

Braskem 2<br />

Braskem 26<br />

Center for Bioplastics and Biocomposites 25<br />

Charmant 28<br />

Composites Evolution 14<br />

Coperion 8<br />

Corbion 8, 10, 15, 16, 27 46<br />

Cranfield University 14<br />

Delta Motorsport 14<br />

Domogel 29<br />

Dow 5, 26<br />

DowDuPont 5<br />

Dr. Hans Korte Innov.Beratung 8<br />

DSM 7<br />

DuPont 5, 24 46<br />

empack 39<br />

Erema 47<br />

Erreme 29<br />

European Bioplastics 10, 26 48<br />

Evonik 46, 51<br />

Fachagentur Nachw. Rohstoffe FNR 34<br />

Felda Global Ventures 6<br />

FKuR 10 2, 46<br />

Fraunhofer ICT 10<br />

Fraunhofer IVV 10<br />

Fraunhofer UMSICHT 32 47<br />

GFBiochemicals 20<br />

Grabio Greentech 47<br />

Grafe 46, 47<br />

Hallink 47<br />

HIB Trimpart Solutions 16<br />

IKEA 26<br />

Infiana Germany 47<br />

Innogas 6<br />

Innovate UK 14<br />

Institut for bioplastics & biocomp.(IfBB) 48<br />

ISCC 10, 26<br />

Jacobs 27<br />

Jaguar Land Rover 14<br />

JBF Industries 26<br />

Jinhui Zhaolong 46<br />

Kingfa 46<br />

KS Composites 14<br />

KU Leiven 10, 18<br />

LEGO 28<br />

Limagrain Céréales Ingrédients 47<br />

Maccaferri Holding 7<br />

Mattiussi Ecologia 2<br />

McDonalds 26<br />

Metabolix 22, 23 47<br />

Michigan State University 10 48<br />

Minima Technology 47<br />

Mitsui 26<br />

narocon 47<br />

NatureWorks 10, 27 21<br />

Natur-Tec 47<br />

Newlight Technologies 6<br />

nova-Institut 8, 10, 16 19, 29, 31, 47<br />

Novamont 26 47, 52<br />

NUREL Engineering Polymers 46<br />

Öko Institut 34<br />

Onora 8<br />

Plantura Italia 10, 15<br />

Plasthill 8<br />

plasticker 7<br />

Plastics Today 5<br />

PolyFerm 22<br />

PolyOne 8, 12, 17 46, 47<br />

Pöyry 26<br />

President Packaging 47<br />

Procter & Gamble 26<br />

PTT MCC Biochem 33, 46<br />

Reverdia 7<br />

Röchling 15, 16<br />

Roquette 7 46<br />

S.E.C.I. 7<br />

Sabic 26<br />

Saida 47<br />

SHD Composite Materials 14<br />

SHENZHEN ESUN INDUSTRIAL 46<br />

Shiseido 26<br />

Showa Denko 46<br />

SPC, The Sustainable Packaging Coalition 5<br />

Sukano 10<br />

Suntory Holdings 6<br />

Synbra 10<br />

Synprodo 29<br />

Taghleef Industries 47<br />

TerraVeradae BioWorks 22<br />

TianAn Biopolymer 47<br />

Toyota Boshoku Europa 16<br />

Uhde Inventa-Fischer 10 47<br />

UL International TTC 47<br />

Univ. Stuttgart (IKT) 47<br />

US Dept. of Energy DoE 20, 24<br />

USDA 38, 40<br />

VDI 41<br />

VHI 8<br />

Vinçotte 28, 36<br />

Wageningen (WUR) 10<br />

Wood K plus 8<br />

WPC Council of China 8<br />

Yanfeng Europe Autom. Int. Systems 16<br />

Zhejiang Hangzhou Xinfu Pharmaceutical 46<br />

TU Munich 46<br />

Uhde Inventa-Fischer 17,55<br />

UL International TTC 55<br />

UNEP 7<br />

Univ. Stuttgart (IKT) 55<br />

Veolia 32<br />

Vinçotte 18,37<br />

World Economic Forum 8<br />

WWF 8<br />

ZERO 8<br />

Zhejiang Hangzhou Xinfu Pharmaceutical 54<br />

Editorial Planner<br />

2<strong>01</strong>6<br />

<strong>Issue</strong> Month Publ.-Date<br />

edit/advert/<br />

Deadline<br />

02/2<strong>01</strong>6 Mar/Apr 04 Apr 16 04 Mar 16 Thermoforming /<br />

Rigid Packaging<br />

Editorial Focus (1) Editorial Focus (2) Basics<br />

Marine Pollution /<br />

Marine Degaradation<br />

Design for Recyclability<br />

03/2<strong>01</strong>6 May/Jun 06 Jun 16 06 May 16 Injection moulding Joining of bioplastics<br />

(welding, glueing etc),<br />

Adhesives<br />

PHA (update)<br />

04/2<strong>01</strong>6 Jul/Aug <strong>01</strong> Aug 16 <strong>01</strong> Jul 16 Blow Moulding Toys Additives<br />

Trade-Fair<br />

Specials<br />

Chinaplas<br />

preview<br />

Chinaplas<br />

Review<br />

05/2<strong>01</strong>6 Sep/Oct 04 Oct 16 02 Sep 16 Fiber / Textile /<br />

Nonwoven<br />

Polyurethanes /<br />

Elastomers/Rubber<br />

Co-Polyesters<br />

K'2<strong>01</strong>6 preview<br />

06/2<strong>01</strong>6 Nov/Dec 05 Dec 16 04 Nov 16 Films / Flexibles /<br />

Bags<br />

Consumer & Office<br />

Electronics<br />

Certification - Blessing<br />

and Curse<br />

K'2<strong>01</strong>6 Review<br />

50 bioplastics MAGAZINE [<strong>01</strong>/16] Vol. 11


Green up your flooring<br />

High performance naturally<br />

Biobased polyamides for carpeted floors can improve the overall environmental sustainability of building<br />

interiors. Used for floorings, VESTAMID® Terra withstands typical mechanical and physical loads in office<br />

and public buildings, and durably retains the attractive surface of the floorings.<br />

Evonik offers a variety of technical longchain polyamides suchs as PA610, PA1<strong>01</strong>0 and PA1<strong>01</strong>2. They<br />

all share a similar to improved technical performance compared to conventional engineering polyamides<br />

while also having a significantly lower carbon footprint.<br />

www.vestamid-terra.com


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USED FOR ALL TYPES<br />

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MATER-BI has unique,<br />

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It is biodegradable and compostable<br />

and contains renewable raw materials.<br />

It is the ideal solution for organic<br />

waste collection bags and is<br />

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compost.<br />

r7_10.2<strong>01</strong>5

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