tel-00344949, version 1 - 7 Dec 2008 3. Article soumis à GCA en révision Figure 3.6 : Core to rim profile across the olivine 5‐20. The compositions of the phases in FAMOUS picrites were extensively analyzed �Bougault and Hekinian, 1974; Bryan, 1979; Kamenetsky, 1996; Laubier et al., 2007�, and representative analyses obtained <strong>du</strong>ring the course of the present study are given in Table 3.1. Briefly, olivine phenocrysts are chemically homogeneous �Fig. 3.6� with high‐Mg content �Fo88‐91�. Some crystals enclosed in the microcrystalline groundmass exhibit a Fe‐ rich rim �Fo82� restricted to the outer 10 μm boundary. This rim was pro<strong>du</strong>ced by a late re‐ equilibration with the matrix. The few spinels we have analyzed in ARP73 10‐03 are identical in composition to those studied by Kamenetsky �1996�. They are homogeneous magnesiochromite �MgO � 16.7‐17.3 wt% and Cr2O3 � 41.6‐43.6 wt%� with a low TiO2 concentration ��0.36 wt%�. 98
tel-00344949, version 1 - 7 Dec 2008 3. Article soumis à GCA en révision Table 3.1: Chemical composition for the major phases of our picrite ARP73‐10‐03. Pillow Rim Olivine 4-11 Olivine 5-20 glass core rim inclusion core rim inclusion n 18 - - 2 - - 4 SiO2 49,06 40,7 41,34 49,53 41,59 40,94 50,03 TiO2 0,68 n,d, n,d, 0,69 n,d, n,d, 0,63 Al2O3 16,22 n,d, 0,1 16 n,d, 0,11 16,27 Cr2O3 0,08 n,d, 0,12 n,d, n,d, 0,16 n,d, FeO 8,12 10,24 10,43 7,9 8,34 9,79 7,11 MnO 0,1 0,27 0,15 0,19 0,1 0,14 0,19 MgO 9,79 48,72 48,75 9,04 50,26 49,61 8,01 CaO 13,43 0,39 0,32 14,19 0,29 0,35 14,98 Na2O 1,75 n,d, n,d, 1,58 n,d, n,d, 1,56 K2O 0,06 n,d, n,d, 0,12 n,d, n,d, 0,04 P2O5 0,05 n,d, n,d, n,d, n,d, n,d, 0,1 NiO 0,06 0,08 0,17 0,23 0,28 0,38 n,d, Total 99,4 100,5 101,4 99,5 100,9 101,5 99 size (µm) - - - 185 - - 265 Fo - 89,5 89,3 - 91,5 90 - The temperature of melt‐olivine equilibrium calculated for the pillow natural quenched glass is 1200°C �Jones, 2003� and the calculated composition of equilibrium olivine is Fo90.1 for a Kd � 0.30 �Ford et al., 1983�. This value is close to the average of olivines from this sample and suggests that crystals in this picrite are phenocrysts. This is also suggested by the chemistry of the melt trapped by the phenocrysts in the ARP73‐10‐ 03 picrite. Kamenetsky �1996� has shown that the compositions of the original melts trapped in olivine and chromite phenocrysts are very close to the composition of the quenched pillow rim glass. These observations indicate unambiguously that olivine phenocrysts were transported to the surface by their parental magma. 4. LI ABUNDANCE AND ISOTOPIC COMPOSITION IN ARP73‐10‐03 PHASES 4.1. Fine grained groundmass and glass The microlitic groundmass has not been analyzed <strong>du</strong>e to the large ion probe beam compared to the size of the glass patches in this part of the section. Thus the measurements reflect the proportions of each of the phases in the analyzed area. On the contrary, the glass 99
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