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ICEM11 Final Program 9.7.11pm_ICEM07 Final Program ... - Events

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Abstracts Session 8<br />

SESSION 8 — EXPERIENCES IN ER CLEAN-UP METHODS AND ACTIONS (4.4)<br />

1) GROUNDWATER REMEDIATION OF HEXAVALENT CHROMIUM ALONG THE<br />

COLUMBIA RIVER AT THE HANFORD SITE IN WASHINGTON STATE, USA (wP-59030)<br />

Dyan Foss, CH2M Hill Plateau Remediation Company; Briant Charboneau, DOE RL (USA)<br />

The U.S. Department of Energy Hanford Site, formerly used for nuclear weapons production, encompasses 1500 square kilometers<br />

in southeast Washington State along the Columbia River. A principle threat to the river are the groundwater plumes of hexavalent<br />

chromium (Cr(VI)), which affect approximately 9.8 square kilometers, and 4.1 kilometers of shoreline.<br />

Cleanup goals are to stop Cr(VI) from entering the river by the end of 2012 and remediate the groundwater plumes to the drinking<br />

water standards by the end of 2020. Five groundwater pump-and-treat systems are currently in operation for the remediation of<br />

Cr(VI).<br />

Since the 1990s, over 13.6 billion liters of groundwater have been treated; over 1,435 kg of Cr(VI) have been removed. This<br />

paper describes the unique aspects of the site, its environmental setting, hydrogeology, groundwater-river interface, riverine<br />

hydraulic effects, remediation activities completed to date, a summary of the current and proposed pump-and-treat operations, the<br />

in situ redox manipulation barrier, and the effectiveness of passive barriers, resins, and treatability testing results of calcium polysulfide,<br />

biostimulation, and electrocoagulation, currently under evaluation.<br />

2) ENVIRONMENTAL REMEDIATION OF AN ALSTOM GRID INDUSTRIAL SITE (FRANCE) (wP-59270)<br />

Stéphanie Romero, ALSTOM GRID (France)<br />

ALSTOM Grid is the project owner of the remediation of a former industrial site, located in Saint-Ouen, north of Paris. The<br />

industrial activity (power transformer production) started in 1921 and stopped in 2006. The type of pollution is linked with the former<br />

activity. It’s an organic pollution: hydrocarbon, PCB and chlorinated volatile organic compounds. The clean-up concerns soil<br />

and groundwater.<br />

The main specificity of the project is that the remediation is operated inside the existing industrial buildings which must be<br />

kept in place and restituted to the owner after the works. The treatment of soil requires excavating soil up to 9 m deep (1 m under<br />

the level of the groundwater) inside the buildings. As a consequence, some impressive devices were set up to ensure the stability<br />

of the buildings during the clean-up, like support structures of the foundations and strengthening of the building fronts.<br />

In the same time, it has to be pointed out that great diversity of clean-up actions is performed on the site: the soil is excavated<br />

to be treated on site (bioremediation or chemical treatment) or off site. The treatment of groundwater consists of pumping the oil<br />

staying on the surface and oxidizing the dissolved pollution.<br />

This project is probably the first experience of this scale in France with multi-contaminated soil and groundwater decontamination<br />

in keeping and reinforcing the existing buildings.<br />

3) DESIGN AND INSTALLATION OF A PERMEABLE TREATMENT WALL TO PASSIVELY<br />

REMOVE STRONTIUM-90 FROM GROUNDWATER AT A FORMER COMMERCIAL<br />

NUCLEAR FUEL REPROCESSING FACILITY IN NEW YORK (wP-59292)<br />

Douglas Bablitch, Rupeet Malhotra, Richard Frappa, Scott Warner, AMEC Geomatrix (USA)<br />

A permeable treatment wall (PTW) was designed and installed at the West Valley Development Project (WVDP), a former<br />

commercial nuclear fuel reprocessing facility in New York, to passively remove and contain the expansion of strontium-90 (Sr-90)<br />

in the site groundwater. AMEC engineers and geologists have collaborated with researchers at the State University of New York at<br />

Buffalo (UB) and West Valley Environmental Services LLC to design and install an approximately 260 meter (860-foot) long by<br />

0.9 meter (3-foot) thick zone of granular zeolite (a natural aggregate composed of approximately 85 percent of the mineral clinoptilolite)<br />

that will remove Sr-90 in situ from groundwater through ion-exchange reactions. The PTW was designed to meet the functional<br />

objectives for up to 20 years; performance monitoring will be conducted regularly and will be used to assess the lifetime efficacy<br />

of the PTW. The zeolite-filled PTW was the selected remedial alternative due to its hydraulically passive operations and lower<br />

life-cycle cost over other more traditional active treatment alternatives such as pump and treat.<br />

The design relied heavily on detailed site characterization of site soils and groundwater conditions and bench and pilot scale<br />

evaluations of various zeolite materials. The design specified the use of a one-pass…<br />

4) DECOMMISSIONING OF THE ACTIVE STORAGE FACILITY FOR RESIDUALS IN RHEINSBERG<br />

(BRANDENBURG/GERMANY) AND RESULTS OF GROUNDWATER MONITORING (wP-59134)<br />

Mathias Steinhoff, Öko-Institut e.V. (Germany)<br />

The Active Storage Facility for Residuals (Aktives Lager für Rückstände ALfR) an open air controlled area has been used<br />

for storage of radioactive waste (liquid and solide waste) at the site of the NPP Rheinsberg in the former GDR. Liquid waste has<br />

been cemented and dumped for near surface final disposal.<br />

During period of operation of ALfR some incidents happened. Residues of evapo-rated cooling water of unknown amount (ca.<br />

1-10 m³), the drop out from small leak-ages and wash off from contaminated open air storage barrels contaminated the soil.<br />

Since 1997 the buildings of the ALfR are decommissioned and the site will be reme-diated. From the beginning of decommissioning<br />

up to now the groundwater has been monitored.<br />

This paper shows different steps of decommissioning and explains the experience of groundwater monitoring. Currently 33<br />

sampling points are used for sampling groundwater of different layers. The radiological parameters under examination are Cobalt-<br />

60, Cesium-137, Strontium-90 and Tritium. Non radiological Parameters like Bore, Potassium, Sodium, Nitrate, pH value and TOC<br />

(total organic carbon) are also investigated.<br />

Since 1997 activity concentration of Cobalt-60 and Tritium in groundwater has de-creased. The activity concentration of Strontium-90<br />

had increased from 1997 to 2007. Since 2007<br />

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