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ICEM11 Final Program 9.7.11pm_ICEM07 Final Program ... - Events

ICEM11 Final Program 9.7.11pm_ICEM07 Final Program ... - Events

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Abstracts Session<br />

7) A NEW SAFETY CONCEPT FOR GEOLOGICAL DISPOSAL IN JAPAN (II) (wP-59357)<br />

Kazumi Kitayama, Nuclear Waste Management Organization of Japan (NUMO) (Japan)<br />

In a previous paper for ICEM2009 a new safety concept was proposed for the geological disposal program in Japan, which was<br />

a development of the conventional multi-barrier system concept that takes greater account of the actual behaviour in a deep geological<br />

environment. This paper describes progress of the study. In particular, it points out that geological disposal provides passive<br />

defence-in-depth safety functions based on geochemical equilibrium, and that natural analogues are effective in understanding the<br />

behaviour of engineered/natural barriers over hundreds of thousands of years and in further developing safety concepts. In addition,<br />

a long-term safety concept based on the realistic evolution of a geological disposal system can be explained to both the general<br />

public and experts in a straightforward and comprehensible manner.<br />

Detailed discussion of specific long-term behaviour of engineered and natural barriers, including possible interaction between<br />

barriers, will be reported in the paper.<br />

8) THERMO-HYDRO-MECHANICAL SIMULATION OF A HEATING AND HYDRATION<br />

EXPERIMENTAL STUDY (CHINA-MOCK-UP) IN UNSATURATED GMZ BENTONITE (wP-59212)<br />

Liang Chen, Ju Wang, Yuemiao Liu, Beijing Research Institute Of Uranium Geology;<br />

Federic Collin, University Of Liège; Jingli Xie, Beijing Research Institute Of Uranium Geology (China/Belgium)<br />

The preliminary repository concept for disposal of high level radioactive waste in China is a shaft-tunnel model, located in saturated<br />

zones in granite. The engineered barrier system (EBS) is composed of vitrified waste, canisters, buffer materials, backfill<br />

and seals. Unsaturated compacted bentonite is foreseen by lots of countries as a backfill and sealing material. At the present stage,<br />

the Gaomiaozi (GMZ) bentonite is considered as the candidate buffer and backfill material for the Chinese repository. In order to<br />

study the behavior of this material in coupled THMC conditions, a mock-up facility, named China-Mock-up, has been installed in<br />

Beijing Research Institute of Uranium Geology. The heater, which substitutes a loaded waste canister, is placed inside of the facility.<br />

To simulate the impact of groundwater, the water inflow of the barrier from outer surface is also possible. This paper presents<br />

a numerical study of the coupled THM behavior of China-mock-up test. In the paper, the basic physical characters of GMZ bentonite<br />

and experimental facility of China-mock-up test are firstly presented. Based on the experimental studies, the numerical simulation<br />

is realized by the program of LAGAMINE. In the simulation, the following physical phenomena are taken account: the<br />

transport of liquid (advection) and heat ...<br />

SESSION 33 — RECENT ADVANCES IN PROCESSING AND IMMBOLIZATION OF HLW,<br />

FISSLE MATERIAL AND TRANSUANIC (TRU) - PART 1 OF 2 (2.14)<br />

1) URANIUM METAL OXIDATION, GRINDING AND ENCAPSULATION IN BOROBOND:<br />

TRU WASTE MANAGEMENT (w/oP-59279)<br />

Kevin Cook, Larry Addington, Beth Utley, Boron Products (USA)<br />

Hydrogen generation mitigation for K Basin sludge was examined by encapsulation of uranium metal in BoroBond®, pre-oxidation<br />

of uranium metal with Fentons reagent and grinding of Densalloy SD170, an irradiated uranium metal surrogate. Encapsulation<br />

in BoroBond® resulted in pressure increase rates at 60°C ranging from 0.116 torr/h to 0.186 torr/h compared to 0.240 torr/h<br />

for a uranium metal in water standard. Samples cast with higher water content led to increased rates. A Fentons reagent system<br />

consisting of a simple reagent mix of FeSO4•7H2O, H2O2 and HCl effectively oxidized ¼ cubes of uranium metal in under four<br />

days at room temperature. Increased peroxide addition rate, increased FeSO4•7H2O concentration and low pH all increase the corrosion<br />

rate. Densalloy SD170 with an average particle size of 581 µm with 7.63 % of particles less than 90 µm was milled so that<br />

over 90 % of the Densalloy mass measured less than 90 µm in 6 hours of milling. Acceptable wear rates were seen on wear components<br />

that were from standard materials (Nitronic SS and 440SS).<br />

2) RESULTS OF INVESTIGATION OF HIGH LEVEL SOLID RADIOACTIVE WASTE<br />

FROM PITS NO1 AND NO2 AT THE GREMIKHA SITE (w/oP-59390)<br />

B.S. Stepennov, V.M. Afanasyev, A.Yu. Kazennov, N.V. Kartashev, A.V. Korolev, O.E. Kiknadze, D.V. Pavlov, Kurchatov<br />

Institute; V.V. Eremenko, FGUP SevRAO; G. Fady, CEA; Lucien Pillette-Cousin, Areva TA (Russia/France)<br />

One of the legacies of the Cold War period is the unsafe and uncontrolled storage of high level radioactive waste at the former<br />

soviet navy bases. At the former naval maintenance base of Gremikha in the North-West of Russia, it has been necessary to conduct<br />

characterization of high level waste in order to decide the best way to recover and condition it, with good radiation protection<br />

and safety conditions. France, represented by CEA, associated with AREVA TA as technical support, funded the studies performed<br />

by the Russian partners to define conditions of characterization of this high level waste that has been stored for tens of years in two<br />

pits, filled with water and containing sludge. The Russian Kurchatov Institute conducted the clarification of the water contained in<br />

the pit by removal of sludge using filtration techniques. Then, a 3D model of the content of the pits was realized including all<br />

objects identified after water clarification. Specific methods and technologies were used for that because the dose rates near some<br />

objects were as high as 400 Gy/h. Data obtained makes it possible now to choose the best option for the management of the identified<br />

high level solid radioactive waste. The paper presents the techniques used for clarification of water contained in the pits, the<br />

main results and the expected way forward to recover and condition this high level waste.<br />

97

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