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ICEM11 Final Program 9.7.11pm_ICEM07 Final Program ... - Events

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Abstracts Session 24<br />

in the disposal environment for packages (physical and chemical conditions, temperature variations, groundwater, radiation fields);<br />

(vii) testing and non-destructive monitoring techniques for quality assurance of cementitious materials; (viii) waste acceptance criteria<br />

for waste packages, waste forms and backfills; transport, long term storage and disposal requirements; and finally (ix) modelling<br />

or simulation of long term behaviours of cementations materials used for packaging, waste immobilization and backfilling,…<br />

2) ELUTION BEHAVIOR OF HEAVY METALS FROM CEMENT SOLIDIFIED PRODUCTS<br />

OF INCINERATED ASH WASTE (wP-59102)<br />

Yoshihiro Meguro, Yoshimi Kawato, Takuya Nakayama,Osamu Tomioka,<br />

Motoyuki Mitsuda, Japan Atomic Energy Agency (Japan)<br />

Combustible radioactive wastes generated from the operation of nuclear facilities are incinerated for volume reduction in<br />

Japan. In Japan Atomic Energy Agency (JAEA) the incinerated ash is planned to be solidified using cement and to be buried in the<br />

ground. Incinerated ashes with various compositions and properties are generated because there are facilities of several kinds of<br />

types such as reactors, nuclear fuel cycle facilities, and hot laboratories in JAEA. And also a small amount of heavy metal, which<br />

is hazardous chemical substance for environment, is also included in the incinerated ash.<br />

The authors push forward a study to determine conditions to produce solidified products of the incinerated ash with cement.<br />

Here relationships between solidification conditions and solidification characteristics have been investigated. The solidification<br />

conditions are the ash composition, cement materials, ash filling rate and water/cement ratio, and the solidification characteristics<br />

are including curing rate and expansion behavior. And also characteristics of the solidified product have been studied, these are<br />

compressive strength, elution behavior of radionuclides and the heavy metals from the solidified products, gas generation by radiolysis,<br />

and so on.<br />

In the present paper, our recent results about the elution behavior of the hazardous heavy metals from synthetic solidified…<br />

3)IMMOBILISATION OF RADWASTE IN SYNTHETIC ROCK: AN ALTERNATIVE TO CEMENTATION (w/P-59008)<br />

Bernard Rottner, Onet Technologies (France)<br />

SOGETER is a waste conditioning process for Low Level radwaste (LLW) or Intermediate Level radwaste (ILW) like sludge,<br />

soil, ashes, evaporator concentrate, concrete rubble, asbestos, sand, & Usually such radioactive waste is solidified into a cement<br />

matrix, resulting in a factor 2 to 5 volume increase: 1 m3 of initial raw waste generates 2 to 5 m3 of solidified waste.<br />

Sogeter consists in melting the waste at high temperature, up to 2000 K, and producing a synthetic rock. The main component<br />

of the matrix is the waste itself; therefore 1 m3 of initial raw waste generates only 0.2 to 0.5 m3 of solidified waste.<br />

Compared to cementation, synthetic rock decreases the volume to be disposed of by a factor of 4 to 25.<br />

By mixing different types of waste, or using additives, the composition of the waste is adjusted, so that a fluid melt is obtained<br />

at temperatures less than 2000 K, and so that the final 200 L ingot may be cooled down within 2 days, without shattering or disaggregating.<br />

We tested a wide range of compositions, demonstrating that almost every type of waste may be conditioned with Sogeter.<br />

We designed the industrial facility, based on a very robust and…<br />

SESSION 24 — L/ILW WASTE CHARACTERIZATION, ASSAY, AND TRACKING SYSTEMS - PART 1 OF 2 (1.7)<br />

1) A PROPOSED FIGURE OF MERIT FOR EVALUATING THE PERFORMANCE<br />

OF RADIATION IDENTIFICATION AND DETECTION SYSTEMS (wP-59159)<br />

Ronald Keyser, Timothy Twomey, ORTEC - AMETEK; Michael D. Belbot, Thermo Fisher Scientific;<br />

Neil Andrew Webster, Thermo Fisher Scientific, Radiation Measurement & Security Instruments (USA)<br />

The instruments used to monitor the radioactive content of waste materials, either in container monitors, hand held radiation<br />

detectors, or mobile analysis systems, are constructed of widely different ways with widely varying detector materials and analysis<br />

software. However, within the various groupings (e.g., automatic waste monitors), all instruments are expected to solve the same<br />

problem, that is, to detect and identify any radioactive material present according to the prescribed investigation methods. The best<br />

way to compare the performance of different instruments is with a numerical score or Figure of Merit (FOM). The FOM must quantity<br />

the performance of the instrument with respect to false positives (FP) and false negatives (FN). The minimization of FN for<br />

certain radionuclides (e.g., uranium and plutonium or SNM) is more important than the minimization of FN for non-threat nuclides<br />

(e.g., low NORM). Likewise, the minimization of FP for SNM is also more important than falsely reporting the common NORM<br />

nuclides. The performance depends on the details of the testing, so the analysis conditions must also be included in the statement<br />

of the FOM. A FOM has been developed based on the number of true positives (TP), the number of false important positives (FIP),<br />

the number…<br />

2) CHARACTERIZATION OF LEGACY LOW LEVEL WASTE AT THE SVAFO<br />

FACILITY USING GAMMA NON-DESTRUCTIVE ASSAY AND X-RAY<br />

NON-DESTRUCTIVE EXAMINATION TECHNIQUES (wP-59289)<br />

Stephen Halliwell, VJ Technologies Inc;<br />

Gary Mottershead, VJ Technologies Inc; Fredrik Ekenborg (USA/France/Sweden)<br />

Over 7000 drums containing legacy, low level radioactive waste are stored at four SVAFO facilities on the Studsvik site which<br />

is located near Nyköping, Sweden. The vast majority of the waste drums (>6000) were produced between 1969 and 1979. The<br />

remainder were produced from 1980 onwards.<br />

Characterization of the waste was achieved using a combination of non-destructive techniques via mobile equipment located<br />

in the AU building at the Studsvik site. Each drum was weighed and a dose rate measurement was recorded. Gamma spectroscopy<br />

was used to measure and estimate radionuclide content. Real time xray examination was performed to identify such prohibited<br />

items as free liquids.<br />

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