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Algemene en technische scheikunde

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En voor de tweede stof:<br />

m = n ∗ M<br />

9.3 g = 0.15 ∗ (a + 2 ∗ z) mol ∗ g<br />

mol<br />

0.15 ∗ a + 0.3 ∗ z = 9.3<br />

Dit geeft dus het volg<strong>en</strong>de stelsel:<br />

<br />

0.3 ∗ a + 0.45 ∗ z = 15.9<br />

0.15 ∗ a + 0.3 ∗ z = 9.3<br />

Als we de tweede vergelijking twee keer van de eerste aftrekk<strong>en</strong>, geeft dat:<br />

0.3 ∗ a + 0.45 ∗ z − 2 ∗ (0.15 ∗ a + 0.3 ∗ z) = 15.9 − 2 ∗ 9.3<br />

−0.15 ∗ z = −2.7<br />

z = 18<br />

Stof Z heeft dus e<strong>en</strong> molaire massa van 18 g/mol. De molaire massa van stof A wordt dan:<br />

0.3 ∗ a + 0.45 ∗ z = 15.9<br />

0.3 ∗ a + 0.45 ∗ 18 = 15.9<br />

Stof A heeft dus e<strong>en</strong> molaire massa van 26 g/mol.<br />

Oef<strong>en</strong>ing 5<br />

Vraag<br />

a = 26<br />

A piece of nickel foil, 0.550 mm thick and with a square surface with a side of 1.25 cm, is<br />

allowed to <strong>en</strong>tirely react with fluorine, F2, to give a nickel fluoride.<br />

1. How many moles of nickel foil were used? (The d<strong>en</strong>sity of nickel is 8.908 g/cm 3 .)<br />

2. If you obtain 1.261 g of the nickel fluoride, what is the empirical formula?<br />

Oplossing - 1<br />

Het aantal mol nikkel kunn<strong>en</strong> we uit het volume, de massadichtheid <strong>en</strong> de molaire massa hal<strong>en</strong>:<br />

n = m<br />

M<br />

ρ ∗ V<br />

n =<br />

58.96 g/mol<br />

8.908 ∗ 0.055 ∗ 1.252 g/cm<br />

n =<br />

58.96<br />

3 ∗ cm3 g/mol<br />

n = 0.0130 mol<br />

(29)<br />

(30)<br />

(31)<br />

(32)<br />

(33)<br />

14

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