22.03.2013 Views

MCI Project Summaries 2008 - Smithsonian Institution

MCI Project Summaries 2008 - Smithsonian Institution

MCI Project Summaries 2008 - Smithsonian Institution

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

<strong>MCI</strong> 6233 Isotope Ratio Mass Spectroscopy (IR-MS) Analysis of Natural and<br />

Synthetic Indigo<br />

<strong>MCI</strong> Staff: Mary W. Ballard, Elizabeth Shuster, Cathy Zaret, Greg Henkes, Odile Madden<br />

This research project is to determine whether isotope ratio mass spectroscopy (IR-MS)<br />

and Raman spectroscopic analysis can aid in the discrimination of synthetic and natural indigo<br />

dyes derived from plants incorporated into cultural artifacts.<br />

The chemical compositions of natural and synthetic indigo are the same, so<br />

differentiating between the two in the analysis of art and historical artifacts has been<br />

problematic. Indigo played an important role in early trade patterns between East and West.<br />

where the indigo plant matter had only 10% of the tinctorial strength of the Indigofera plants did<br />

not grow. In 1897 synthetic indigo became available and nearly completely superseded natural<br />

indigo by 1920.<br />

The differentiation of natural vs. synthetic indigo in a cultural object can contribute<br />

significantly to establishing its authenticity and provenance. Isotope ratio mass spectroscopy<br />

potentially offers a minimally invasive means to this end because the carbon isotopes in natural<br />

indigo derived from plants are guided by photosynthetic processes, which makes them easy to<br />

distinguish from the carbon isotopes in synthetic indigo. In addition to identifying natural and<br />

synthetic indigo, it may be possible to pinpoint the geographic sources of natural indigo used in<br />

cultural artifacts, since hydrogen and oxygen isotopes very geographically. In order to test this<br />

hypothesis, the<br />

tendencies of carbon, nitrogen, oxygen, and hydrogen isotopes toward fractionation in natural<br />

and synthetic indigo at various stages of processing will be recorded.<br />

83

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!