MCI Project Summaries 2008 - Smithsonian Institution
MCI Project Summaries 2008 - Smithsonian Institution
MCI Project Summaries 2008 - Smithsonian Institution
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<strong>MCI</strong> 6233 Isotope Ratio Mass Spectroscopy (IR-MS) Analysis of Natural and<br />
Synthetic Indigo<br />
<strong>MCI</strong> Staff: Mary W. Ballard, Elizabeth Shuster, Cathy Zaret, Greg Henkes, Odile Madden<br />
This research project is to determine whether isotope ratio mass spectroscopy (IR-MS)<br />
and Raman spectroscopic analysis can aid in the discrimination of synthetic and natural indigo<br />
dyes derived from plants incorporated into cultural artifacts.<br />
The chemical compositions of natural and synthetic indigo are the same, so<br />
differentiating between the two in the analysis of art and historical artifacts has been<br />
problematic. Indigo played an important role in early trade patterns between East and West.<br />
where the indigo plant matter had only 10% of the tinctorial strength of the Indigofera plants did<br />
not grow. In 1897 synthetic indigo became available and nearly completely superseded natural<br />
indigo by 1920.<br />
The differentiation of natural vs. synthetic indigo in a cultural object can contribute<br />
significantly to establishing its authenticity and provenance. Isotope ratio mass spectroscopy<br />
potentially offers a minimally invasive means to this end because the carbon isotopes in natural<br />
indigo derived from plants are guided by photosynthetic processes, which makes them easy to<br />
distinguish from the carbon isotopes in synthetic indigo. In addition to identifying natural and<br />
synthetic indigo, it may be possible to pinpoint the geographic sources of natural indigo used in<br />
cultural artifacts, since hydrogen and oxygen isotopes very geographically. In order to test this<br />
hypothesis, the<br />
tendencies of carbon, nitrogen, oxygen, and hydrogen isotopes toward fractionation in natural<br />
and synthetic indigo at various stages of processing will be recorded.<br />
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