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-29-<br />

This situation allows the investigation of the influence of different<br />

redox conditions on the volatiles. This chapter reports the observa-<br />

tions made on volatile organic compounds in these three widely<br />

differing oceanic regions.<br />

METHODS<br />

Sampling<br />

In February, 1977, seawater samples were collected in the<br />

Sargasso Sea near Bermuda from the R/V Panulirus II (32°10'N x 64030'W,<br />

about 3000 m depth). The weather was marked by strong winds and<br />

approximately 3-m swells. Water was collected with a single 30-liter<br />

Niskin (Teflon coated spring) and transferred into 2-liter round<br />

bottom flasks on the deck. Upon our return to the dock, water was<br />

transferred to the stripper, spiked with an internal standard, and<br />

stripped. Traps, stored in screw-cap vials, were returned to Woods<br />

Hole for gas chromatography analysis. Hydrographic data were provided<br />

by Dr. B. Morris and Ms. E. Schroeder from the regular Panulirus<br />

station visited within a week of our sample collection.<br />

Seawater samples were also collected from 6 hydrocasts made from<br />

the R/V Oceanus (cruise 22) in the western Equatorial Atlantic in<br />

March, 1977 (Figure 2-1). Sampling occurred between 10:00 and 14:00<br />

local time. PVC Niskins (5- or 30-liter with Teflon coated stainless<br />

steel springs) were used. Sample depths were computed from reversing<br />

thermometer data. Water was transferred in a closed system from the<br />

Niskins through glass to 2-liter round bottom flasks. Samples for<br />

salinity, nutrients, and chlorophyll ~ were also drawn from the same<br />

Niskins.

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