Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid ...

Table of Contents
I. General Considerations S3
II. Reductions of trans-[(PPh 3) 2Re(<strong>CO</strong>) 4] + ([1-Ph 2] + ) S4
III. Synthesis of Complexes with Pendent Boranes S15
IV. Reductions of Bis(phosphine) complexes S56
A. Reductions of trans-[(Ph 2PCH 2B(C 8H 14)) 2Re(<strong>CO</strong>) 4] + ([1-M 2] + ) S56
B. Pulsed gradient spin-echo NMR experiments on
[(Ph 2PCH 2B(C 8H 14)) 2Re(<strong>CO</strong>) 3(CHO)] (2-E 2)
C. Reactivity Studies of 2-E 2
D. Mechanistic Studies on the Reduction of trans-
[(Ph 2P(CH 2) 2B(C 8H 14)) 2Re(<strong>CO</strong>) 4] + ([1-E 2] + )
E. Reductions of trans-[(Ph 2P(CH 2) 2B(C 8H 14)) 2Mn(<strong>CO</strong>) 4] + ([1-E 2-Mn] + ) S92
F. Reductions of trans-[(Ph 2P(CH 2) 3B(C 8H 14)) 2Re(<strong>CO</strong>) 4] + ([1-P 2] + ) S98
V. Equilibrium Studies of bis(phosphine) complexes S106
VI. Reductions of monophosphine complexes S112
A. Reductions of [(PPh 3)Re(<strong>CO</strong>) 5] + ([1-Ph 1] + ) S112
B. Reductions of [(Ph 2PCH 2B(C 8H 14))Re(<strong>CO</strong>) 5] + ([1-M 1] + ) S113
C. Reductions of [(Ph 2P(CH 2) 2B(C 8H 14))Re(<strong>CO</strong>) 5] + ([1-E 1] + ) S134
D. Reductions of trans-[(PPh 3)(Ph 2P(CH 2) 2B(C 8H 14))Re(<strong>CO</strong>) 4] + ([1-E 1Ph 1] + ) S139
E. Reductions of [(Ph 2P(CH 2) 3B(C 8H 14))Re(<strong>CO</strong>) 5] + ([1-P 1] + ) S147
VII. Crystallographic Details. S151
References S350
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