Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid ...

Table 4. Bond lengths [Å] and angles [°] for [Na(THF) 3][3-E 1Ph 1] (AJMM48) (CCDC
770346).
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Re(1)-C(2) 1.8799(6)
Re(1)-C(1) 1.9428(6)
Re(1)-C(3) 2.1361(6)
Re(1)-O(4) 2.2470(5)
Re(1)-P(1) 2.39823(18)
Re(1)-P(2) 2.41937(18)
P(1)-C(25) 1.8182(7)
P(1)-C(19) 1.8350(6)
P(1)-C(13) 1.8357(6)
P(2)-C(39) 1.8289(6)
P(2)-C(33) 1.8380(7)
P(2)-C(27) 1.8432(7)
Na(1)-O(7) 2.2839(6)
Na(1)-O(3) 2.2935(6)
Na(1)-O(5) 2.3030(6)
Na(1)-O(6) 2.3082(7)
Na(1)-O(1)#1 2.5061(6)
O(1)-C(1) 1.1649(8)
O(1)-Na(1)#2 2.5060(6)
O(2)-C(2) 1.1719(8)
O(3)-C(3) 1.2416(8)
O(4)-C(4) 1.4379(8)
O(4)-B(1) 1.5731(9)
O(5)-C(45) 1.4370(9)
O(5)-C(48) 1.4372(9)
O(6)-C(52) 1.4314(10)
O(6)-C(49) 1.4357(9)
O(7)-C(53) 1.4307(11)
O(7)-C(56) 1.4401(12)
B(1)-C(5) 1.6289(9)
B(1)-C(9) 1.6386(9)
B(1)-C(26) 1.6461(8)
C(3)-C(4) 1.5181(9)
C(5)-C(6) 1.5407(8)
C(5)-C(12) 1.5417(10)
C(6)-C(7) 1.5408(9)
C(7)-C(8) 1.5420(10)
C(8)-C(9) 1.5423(9)
C(9)-C(10) 1.5420(10)
C(10)-C(11) 1.5390(10)
C(11)-C(12) 1.5393(10)
C(13)-C(18) 1.3984(9)
C(13)-C(14) 1.3988(10)
C(14)-C(15) 1.3938(10)
C(15)-C(16) 1.3899(12)
C(16)-C(17) 1.3903(13)
C(17)-C(18) 1.3913(10)
C(19)-C(24) 1.3986(9)
C(19)-C(20) 1.3992(9)
C(20)-C(21) 1.3945(10)
C(21)-C(22) 1.3906(12)
C(22)-C(23) 1.3884(11)
C(23)-C(24) 1.3986(9)
C(25)-C(26) 1.5402(9)
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