Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid ...

Table 3. Selected bond lengths [Å] and angles [°] for [1-M 1][OTf] (AJMM45) (CCDC
779779).
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Re(1)-C(5) 1.973(2)
Re(1)-C(2) 2.0001(19)
Re(1)-C(3) 2.016(2)
Re(1)-C(4) 2.0208(17)
Re(1)-C(1) 2.027(2)
Re(1)-P(1) 2.4846(5)
C(5)-Re(1)-C(2) 90.36(8)
C(5)-Re(1)-C(3) 90.61(8)
C(2)-Re(1)-C(3) 89.93(8)
C(5)-Re(1)-C(4) 85.82(7)
C(2)-Re(1)-C(4) 176.14(8)
C(3)-Re(1)-C(4) 90.62(7)
C(5)-Re(1)-C(1) 91.87(8)
C(2)-Re(1)-C(1) 88.30(8)
C(3)-Re(1)-C(1) 176.96(8)
C(4)-Re(1)-C(1) 91.31(7)
C(5)-Re(1)-P(1) 176.54(6)
C(2)-Re(1)-P(1) 92.90(7)
C(3)-Re(1)-P(1) 88.23(6)
C(4)-Re(1)-P(1) 90.94(5)
C(1)-Re(1)-P(1) 89.40(6)
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S230