Homogeneous CO Hydrogenation: Ligand Effects on the Lewis Acid ...

Table 3. Selected bond lengths [Å] and angles [°] for 8 (AJMM42) (CCDC 768183).
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Re(1)-C(1) 1.983(3)
Re(1)-C(4) 1.989(3)
Re(1)-C(2) 1.991(3)
Re(1)-C(3) 1.992(3)
Re(1)-P(1) 2.4437(6)
Re(1)-P(2) 2.4490(6)
Re(2)-C(6) 1.995(3)
Re(2)-C(8) 1.998(3)
Re(2)-C(5) 1.999(3)
Re(2)-C(7) 1.999(3)
Re(2)-P(4) 2.4475(7)
Re(2)-P(3) 2.4496(7)
C(1)-Re(1)-C(4) 95.62(11)
C(1)-Re(1)-C(2) 93.09(11)
C(4)-Re(1)-C(2) 171.12(11)
C(1)-Re(1)-C(3) 179.94(16)
C(4)-Re(1)-C(3) 84.43(12)
C(2)-Re(1)-C(3) 86.86(11)
C(1)-Re(1)-P(1) 89.41(6)
C(4)-Re(1)-P(1) 90.19(7)
C(2)-Re(1)-P(1) 88.16(7)
C(3)-Re(1)-P(1) 90.56(7)
C(1)-Re(1)-P(2) 90.47(6)
C(4)-Re(1)-P(2) 90.09(7)
C(2)-Re(1)-P(2) 91.58(7)
C(3)-Re(1)-P(2) 89.56(7)
P(1)-Re(1)-P(2) 179.70(2)
C(6)-Re(2)-C(8) 175.49(10)
C(6)-Re(2)-C(5) 91.18(10)
C(8)-Re(2)-C(5) 86.44(10)
C(6)-Re(2)-C(7) 91.53(10)
C(8)-Re(2)-C(7) 91.00(10)
C(5)-Re(2)-C(7) 176.48(10)
C(6)-Re(2)-P(4) 86.72(8)
C(8)-Re(2)-P(4) 89.64(7)
C(5)-Re(2)-P(4) 94.33(7)
C(7)-Re(2)-P(4) 88.06(7)
C(6)-Re(2)-P(3) 88.77(8)
C(8)-Re(2)-P(3) 95.09(7)
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