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Salinity Intrusion and Seasonal Water Quality Variations in the Tidal ...

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pH was chosen as a regular parameter to be monitored because it is <strong>in</strong>dicative of <strong>the</strong><br />

degree of <strong>the</strong> sal<strong>in</strong>e water <strong>in</strong>trusion, biogeochemical processes <strong>and</strong> contam<strong>in</strong>ation. Fresh<br />

water is generally acidic where as seawater is alkal<strong>in</strong>e. Thus <strong>the</strong> pH variation around <strong>the</strong><br />

year, cover<strong>in</strong>g all seasons, was expected to be reveal<strong>in</strong>g. Alkal<strong>in</strong>ity, conductivity,<br />

chloride, hardness <strong>and</strong> sulphate are directly related to sal<strong>in</strong>ity <strong>in</strong>trusion. When sal<strong>in</strong>ity<br />

starts pick<strong>in</strong>g up, all <strong>the</strong> above parameters show a ris<strong>in</strong>g tendency, unless some o<strong>the</strong>r<br />

chemical sub-routes are <strong>in</strong>volved. Hence <strong>the</strong> rise <strong>and</strong> fall could be <strong>in</strong> phase with <strong>the</strong><br />

migration of sal<strong>in</strong>ity. This possibility was explored by monitor<strong>in</strong>g <strong>the</strong> above parameters.<br />

Nitrate <strong>and</strong> phosphate are <strong>the</strong> essential plant nutrients <strong>and</strong> <strong>the</strong>ir ratio is <strong>in</strong>dicative of<br />

sewage contam<strong>in</strong>ation. Increased pH <strong>and</strong> <strong>the</strong> <strong>in</strong>trusion ofmar<strong>in</strong>e cations could lead to <strong>the</strong><br />

flocculation of phosphate. Nitrate is a very unstable component <strong>in</strong> an oxygen-depleted<br />

aquatic ecosystem <strong>and</strong> hence, <strong>the</strong> concentration ofnitrate <strong>and</strong> DO are complimentary. In<br />

<strong>the</strong> absence of DO, nitrate is reduced by <strong>the</strong> oxygen-dem<strong>and</strong><strong>in</strong>g wastes. Aga<strong>in</strong> DIP <strong>and</strong><br />

DIN are <strong>the</strong> essential parameters for <strong>the</strong> budgetary model<strong>in</strong>g of <strong>the</strong> water body.<br />

Solubility of iron is directly related to pH <strong>and</strong> DO. Iron is immediately precipitated to <strong>the</strong><br />

sediments by hydrogen sulfide <strong>in</strong> anoxic conditions. On <strong>in</strong>teraction with alkal<strong>in</strong>e mar<strong>in</strong>e<br />

water, Fe was expected to be removed from <strong>the</strong> water column. DO, COD <strong>and</strong> BOD are<br />

<strong>the</strong> most important parameters required to def<strong>in</strong>e <strong>the</strong> quality of a water body. Percent<br />

saturation of DO is a direct measure of<strong>the</strong> purity ofwater.<br />

(The st<strong>and</strong>ard Operat<strong>in</strong>g Procedure has been documented)<br />

***********<br />

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