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Salinity Intrusion and Seasonal Water Quality Variations in the Tidal ...

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<strong>in</strong>fluences chemical process like sorption-desorption <strong>and</strong> flocculation as well as<br />

physical process like vertical mix<strong>in</strong>g, stratification etc. which <strong>in</strong> turn <strong>in</strong>fluence <strong>the</strong><br />

distribution <strong>and</strong> speciation of many trace elements. The level of sal<strong>in</strong>ity also<br />

<strong>in</strong>fluences <strong>the</strong> survival of fresh water microbes.<br />

The concentration of various cations <strong>and</strong> anions be<strong>in</strong>g constant <strong>in</strong> sea water, <strong>the</strong><br />

degree of dilution of sea water with fresh water <strong>in</strong> <strong>the</strong> tidal canals is reflected <strong>in</strong> <strong>the</strong><br />

chloride concentration. Any deviation <strong>in</strong> <strong>the</strong> dilution factor <strong>in</strong> <strong>the</strong> case of non­<br />

conservative dissolved chemicals sheds some light <strong>in</strong>to <strong>the</strong> physico-chemical changes<br />

that sal<strong>in</strong>ity <strong>in</strong>trusion becomes <strong>the</strong> platform for. Chloride <strong>in</strong> sea water is around<br />

19000mg/L <strong>and</strong> <strong>in</strong> fresh water it is around 10-40 mg/L depend<strong>in</strong>g on anthropogenic<br />

<strong>in</strong>puts. Hence chloride levels, be<strong>in</strong>g a conservative <strong>in</strong>gredient, register <strong>the</strong> degree of<br />

dilution with<strong>in</strong> reliable marg<strong>in</strong>s. But if chloride level is <strong>the</strong> <strong>in</strong>dicator of dilution, <strong>the</strong><br />

calcium concentration <strong>in</strong> <strong>the</strong> canals is at least two times more than <strong>the</strong> Calcium ions<br />

enter<strong>in</strong>g from <strong>the</strong> seas. Hence precipitation of calcium as calcium phosphate, if at all,<br />

does not rise to very high levels.<br />

Iron <strong>in</strong> sea water is less than 20Jlg/L. Hence total Fe appear<strong>in</strong>g <strong>in</strong> <strong>the</strong> water bodies<br />

is entirely from terrestrial wash out <strong>in</strong> which economic activities make up a major<br />

share. Soluble phosphate, though a major plant nutrient, does not go beyond 30Jlg/L<br />

<strong>in</strong> <strong>the</strong> surface layers of <strong>the</strong> sea water. This fact implies that sea water does not add to<br />

P04 3 -levels <strong>in</strong> <strong>the</strong> tidal canals. Phosphate concentration sharply falls <strong>in</strong> <strong>the</strong> <strong>in</strong>itial<br />

stages of sal<strong>in</strong>ity <strong>in</strong>trusion <strong>in</strong> December-January, because of dilution of sewage rich<br />

water body with sea water <strong>and</strong> a dramatic rise <strong>in</strong> photosyn<strong>the</strong>tic activity. Phosphate<br />

steadily rises <strong>the</strong>reafter because of <strong>the</strong> accumulation of sewage as natural flush<strong>in</strong>g is<br />

62

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