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Solitons in Nonlocal Media

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δ = arctan<br />

ǫa s<strong>in</strong>(2θ)<br />

ǫa+2ǫ⊥+ǫa cos(2θ)<br />

for the extraord<strong>in</strong>ary plane wave is<br />

<br />

cos<br />

2 θ<br />

ne =<br />

1.4 Liquid Crystals<br />

<br />

, be<strong>in</strong>g θ the angle between k and ˆn. 1 The refractive <strong>in</strong>dex<br />

ǫ⊥<br />

+ s<strong>in</strong>2 −1<br />

θ<br />

ǫ (1.10)<br />

Remarkably, while l<strong>in</strong>ear optical propagation <strong>in</strong> NLC is generally <strong>in</strong>volved due to the<br />

lack of homogeneity, <strong>in</strong> most practical cases a description <strong>in</strong> terms of ord<strong>in</strong>ary and<br />

extraord<strong>in</strong>ary waves holds valid. I will deepen this po<strong>in</strong>t <strong>in</strong> the next chapters.<br />

Another important optical feature of NLC (which allows the experimental observation<br />

of optical propagation <strong>in</strong>side the NLC, as shown later) is their strong Rayleigh scat-<br />

ter<strong>in</strong>g 2 (58): <strong>in</strong> the visible range, light scattered by nematics is larger by a factor 10 6<br />

than <strong>in</strong> isotropic fluids. In fact <strong>in</strong> NLC scatter<strong>in</strong>g is due to random variations <strong>in</strong> the<br />

dielectric tensor ǫ, caused by fluctuations <strong>in</strong> density, temperature, etc., or <strong>in</strong> orientation<br />

of ˆn (due to thermal agitation). The latter is the dom<strong>in</strong>ant effect <strong>in</strong> the nematic phase,<br />

be<strong>in</strong>g absent <strong>in</strong> isotropic fluids.<br />

Let me consider a plane wave with wavevector k<strong>in</strong>. The light scattered around the<br />

solid angle dΩ, centered around the direction of the output wavevector kout, can be<br />

evaluated through the scatter<strong>in</strong>g differential cross section dσ/dΩ (58)<br />

dσ<br />

dΩ =<br />

<br />

ǫak2 <br />

|nη(q)|<br />

0<br />

4π<br />

2 2 î · âµ<br />

ˆf · ˆn + î · ˆn ˆf · âµ<br />

µ=1,2<br />

(1.11)<br />

where k0 = 2π/λ is the wavenumber <strong>in</strong> vacuum, q is the scatter<strong>in</strong>g vector def<strong>in</strong>ed<br />

by kout = k<strong>in</strong> + q and I took a s<strong>in</strong>gle value for all NLC elastic constants; î and ˆf<br />

are two unit vectors parallel to <strong>in</strong>put and scattered fields, respectively; â1 and â2<br />

are directions which diagonalize the NLC free energy for a fixed q (58), 〈〉 stands for<br />

thermal average and |nη(q)| 2 is the director component due to molecular fluctuations,<br />

with η any direction <strong>in</strong> the plane of â1 and â2.<br />

From (1.11) it is possible to deduce that scatter<strong>in</strong>g is strong for crossed polarizations,<br />

i.e., when <strong>in</strong>cident and scattered field are orthogonal to each other, and is particularly<br />

strong for low q. Moreover, given that |nη(q)| 2 ∝ q −2 and be<strong>in</strong>g |q| ∝ k0, the scattered<br />

power <strong>in</strong> NLC shows a trend with the <strong>in</strong>verse square of <strong>in</strong>cident wavelength (60).<br />

1 Moreover, S lies between the optical axis and the wavevector k <strong>in</strong> positive uniaxials.<br />

2 Rayleigh scatter<strong>in</strong>g implies no energy exchange between the electromagnetic field and the material,<br />

i.e. photons are elastically scattered.<br />

11

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